Crystal chemistry of selenates with mineral-like structures: V. Crystal structures of (H3O)2[(UO2)(SeO4)2(H2O)](H2O)2 and (H3O)2[(UO2)(SeO4)2(H2O)](H2O), new compounds with rhomboclase and goldichite topology     

S. V. Krivovichev 《Geology of Ore Deposits》2008,50(8):789-794

The crystal structures of two new compounds (H₃O)₂[(UO₂)(SeO₄)₂(H₂O)](H₂O)₂ (1, orthorhombic, Pnma, a = 14.0328(18), b = 11.6412(13), c = 8.2146(13) Å, V = 134.9(3) ų) and (H₃O)₂[(UO₂)(SeO₄)₂(H₂O)](H₂O) (2, monoclinic, P2₁/c, a = 7.8670(12), b = 7.5357(7), c = 21.386(3) Å, β = 101.484(12)°, V = 1242.5(3) ų) have been solved by direct methods and refined to R ₁ = 0.076 and 0.080, respectively. The structures of both compounds contain sheet complexes [(UO₂)(SeO₄)₂]^2? formed by cornershared [(UO₂)O₄(H₂O)] bipyramids and SeO₄ tetrahedrons. The sheets are parallel to the (100) plane in structure 1 and to (?102) in structure 2. The [(UO₂)(SeO₄)₂(H₂O)]^2? layers are linked by hydrogen bonds via interlayer groups H₂O and H₃O⁺. The sheet topologies in structures 1 and 2 are different and correspond to the topologies of octahedral and tetrahedral complexes in rhomboclase (H₂O₂)⁺[Fe(SO₄)₂(H₂O)₂] and goldichite K[Fe(SO₄)₂(H₂O)₂](H₂O)₂, respectively.  相似文献   

Geochemical types of Volkhovites and possible diamond resource potential of areas occupied by Holocene fluidisites     

G. T. Skublov  Yu. B. Marin  S. G. Skublov  Yu. N. Tarasenko 《Geology of Ore Deposits》2008,50(7):535-550

Volkhovites—tektite-like glasses—have been detected in the Holocene glacial drift along the right bank of the Volkhov River. A cryptomagmatic model of their formation and pre-Holocene age of volkhovite melts, cinder, and frothed glasses has been suggested (Skublov et al., 2007). Four geochemical types of volkhovites are distinguished: (1) manganous (Mn, Fe, Cr, V, Si, Nb, Pb, H), (2) magnesian (Mg, Al, Ti, F, B), (3) potassic (K, Rb, Cs), and (4) calcic (Ca, REEs, Ba, U, Th, Ta, Hf, Y, Sc, Cl). In light of the geochemical data, volkhovites are regarded as natural silicate glasses of kimberlite-carbonatite composition. Their types are called kimberlitic (Mn type), kimberlitic-carbonatitic (Mg type), lamproitic-carbonatitic (K type), and carbonatitic (Ca type). Volkhovites are suggested to be indicators of undiscovered diamond mineralization of kimberlite or carbonatite (Chagatai) types.  相似文献   

Rotational and magnetic corrections to the g-mode frequencies in a one-dimensional MHD model     

M. S. Dvornikov  T. I. Rashba  V. B. Semikoz 《Astronomy Reports》2008,52(4):335-342

The central magnetic field and rotation of the solar radiative zone are responsible for corrections to the g-mode frequencies. Magnetogravitational spectra are calculated analytically in a simple one-dimensional MHD model that goes beyond the WKB approximation and avoid any cusp resonances that trap the wave within the radiative zone in the presence of a weak magnetic background. The calculations are compared with spacecraft observations of the 1% frequency shifts for candidate g-modes found in the SOHO GOLF experiment. The magnetic correction is the main contribution for a strong magnetic field satisfying the approximation used. It is shown that a constant magnetic field of 700 kG in the radiative zone provides the required frequency shift for the n = ?10 g-mode. The rotational correction, which is due to the Coriolis force in the one-dimensional model used, is much less than a percent (α_Ω ≤ 0.003).  相似文献   

Evaluation of distributed recharge in an upland semi-arid karst system: the West Bank Mountain Aquifer,Middle East   总被引：2，自引：0，他引：2  

A. G. Hughes  M. M. Mansour  N. S. Robins 《Hydrogeology Journal》2008,16(5):845-854

Assessment of recharge in a structurally complex upland karst limestone aquifer situated in a semi-arid environment is difficult. Resort to surrogate indicators such as measurement of spring outflow and borehole discharge, is a common alternative, and attempts to apply conventional soil moisture deficit analysis may not adequately account for the intermittent spate conditions that arise in such environments. A modelling approach has been made using the West Bank Mountain Aquifer system in the Middle East as a trial. The model uses object oriented software which allows various objects to be switched on and off. Each of the main recharge processes identified in the West Bank is incorporated. The model allows either conventional soil moisture deficit analysis calculations or wetting threshold calculations to be made as appropriate, and accommodates both direct recharge and secondary recharge. Daily time steps enable recharge and runoff routing to be calculated for each node. Model runs have enabled a series of simulations for each of the three aquifer basins in the West Bank and for the whole of the West Bank. These provide recharge estimates comparable to those prepared by earlier workers by conventional means. The model is adaptable and has been successfully used in other environments.  相似文献   

Artificial neural network and liquefaction susceptibility assessment: a case study using the 2001 Bhuj earthquake data,Gujarat, India   总被引：2，自引：0，他引：2  

D. Ramakrishnan  T. N. Singh  N. Purwar  K. S. Barde  Akshay. Gulati  S. Gupta 《Computational Geosciences》2008,12(4):491-501

This study pertains to prediction of liquefaction susceptibility of unconsolidated sediments using artificial neural network (ANN) as a prediction model. The backpropagation neural network was trained, tested, and validated with 23 datasets comprising parameters such as cyclic resistance ratio (CRR), cyclic stress ratio (CSR), liquefaction severity index (LSI), and liquefaction sensitivity index (LSeI). The network was also trained to predict the CRR values from LSI, LSeI, and CSR values. The predicted results were comparable with the field data on CRR and liquefaction severity. Thus, this study indicates the potentiality of the ANN technique in mapping the liquefaction susceptibility of the area.  相似文献   

Estimation of hydraulic permeability considering the micro morphology of rocks of the borehole YAXCOPOIL-1 (Impact crater Chicxulub,Mexico)     

S. I. Mayr  H. Burkhardt  Yu. Popov  A. Wittmann 《International Journal of Earth Sciences》2008,97(2):385-399

Internal surface, formation factor, Nuclear Magnetic Resonance (NMR)-T2 relaxation times and pore radius distributions were measured on representative core samples for the estimation of hydraulic permeability. Permeability is estimated using various versions of the classic Kozeny–Carman-equation (K–C) and a further development of K–C, the fractal PaRiS-model, taking into account the internal surface. In addition to grain and pore size distribution, directly connected to permeability, internal surface reflects the internal structure (“micro morphology”). Lithologies could be grouped with respect to differences in internal surface. Most melt rich impact breccia lithologies exhibit large internal surfaces, while Tertiary post-impact sediments and Cretaceous lithologies in displaced megablocks display smaller internal surfaces. Investigations with scanning electron microscopy confirm the correlation between internal surface and micro morphology. In addition to different versions of K–C, estimations by means of NMR, pore radius distributions and some gas permeability measurements serve for cross-checking and calibration. In general, the different estimations from the independent methods and the measurements are in satisfactory accordance. For Tertiary limestones and Suevites bulk with very high porosities (up to 35%) permeabilites between 10⁻¹⁴ and 10⁻¹⁶ m² are found, whereas in lower Suevite, Cretaceous anhydrites and dolomites, bulk permeabilites are between 10⁻¹⁵ and 10⁻²³ m².  相似文献   

Hydrogeologic assessment of escalating groundwater exploitation in the Indus Basin, Pakistan   总被引：1，自引：1，他引：0  

S. Khan  T. Rana  H. F. Gabriel  Muhammad K. Ullah 《Hydrogeology Journal》2008,16(8):1635-1654

Groundwater development has contributed significantly to food security and reduction in poverty in Pakistan. Due to rapid population growth there has been a dramatic increase in the intensity of groundwater exploitation leading to declining water tables and deteriorating groundwater quality. In such prevailing conditions, the hydrogeological appraisal of escalating groundwater exploitation has become of paramount importance. Keeping this in view, a surface water–groundwater quantity and quality model was developed to assess future groundwater trends in the Rechna Doab (RD), a sub-catchment of the Indus River Basin. Scenario analysis shows that if dry conditions persist, there will be an overall decline in groundwater levels of around 10 m for the whole of RD during the next 25 years. The lower parts of RD with limited surface water supplies will undergo the highest decline in groundwater levels (10 to 20 m), which will make groundwater pumping very expensive for farmers. There is a high risk of groundwater salinization due to vertical upconing and lateral movement of highly saline groundwater into the fresh shallow aquifers in the upper parts of RD. If groundwater pumping is allowed to increase at the current rate, there will be an overall decline in groundwater salinity for the lower and middle parts of RD because of enhanced river leakage.  相似文献   

Field scale heterogeneity of redox conditions in till-upscaling to a catchment nitrate model     

J. R. Hansen  V. Ernstsen  J. C. Refsgaard  S. Hansen 《Hydrogeology Journal》2008,16(7):1251-1266

Point scale studies in different settings of glacial geology show a large local variation of redox conditions. There is a need to develop an upscaling methodology for catchment scale models. This paper describes a study of field-scale heterogeneity of redox-interfaces in a till aquitard within an area of 600?×?600 m. The results showed significant variation of the depths to the redox-interface and thickness of the aquitard. Nitrate was present above the redox-interface but reduced to non-detectable levels a few metres below the interface. An upscaling approach for an area of 92 km² is proposed. Two models are proposed to predict the depth to the redox-interface in the aquitard and the resulting nitrate recharge concentrations to an underlying aquifer. The first model assumes that the depth to the redox-interface reflects the hydraulic head in the aquitard, and the second model assumes that the depth of the redox-interface is randomly distributed according to a log-normal probability distribution function. The upscaling approach using the random redox model estimated recharge concentrations comparable to the observed concentration in the underlying aquifer. The presented upscaling approach is applicable in distributed catchment models where sub-grid variability cannot be represented by the large grids.  相似文献   

Comment on “Spherical harmonic analysis of Earth’s conductive heat flow” by V. M. Hamza, R. R. Cardoso and C. F. Ponte Neto     

Henry N. Pollack  David S. Chapman 《International Journal of Earth Sciences》2008,97(2):227-231

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High-resolution seismic analysis of the coastal Mecklenburg Bay (North German Basin): the pre-Alpine evolution     

H. Zöllner  K. Reicherter  P. Schikowsky 《International Journal of Earth Sciences》2008,97(5):1013-1027

The pre-Alpine structural and geological evolution in the northern part of the North German Basin have been revealed on the basis of a very dense reflection seismic profile grid. The study area is situated in the coastal Mecklenburg Bay (Germany), part of the southwestern Baltic Sea. From the central part of the North German Basin to the northern basin margin in the Grimmen High area a series of high-resolution maps show the evolution from the base Zechstein to the Lower Jurassic. We present a map of basement faults affecting the pre-Zechstein. The pre-Alpine structural evolution of the region has been determined from digital mapping of post-Permian key horizons traced on the processed seismic time sections. The geological evolution of the North German Basin can be separated into four distinct periods in the Rerik study area. During Late Permian and Early Triassic evaporites and clastics were deposited. Salt movement was initiated after the deposition of the Middle Triassic Muschelkalk. Salt pillows, which were previously unmapped in the study area, are responsible for the creation of smaller subsidence centers and angular unconformities in the Late Triassic Keuper, especially in the vicinity of the fault-bounded Grimmen High. In this area, partly Lower Jurassic sediments overlie the Keuper unconformably. The change from extension to compression in the regional stress field remobilized the salt, leading to a major unconformity marked at the base of the Late Cretaceous.  相似文献