Cuban zeolite for lead sorption: application for water decontamination and metal quantification in water using nondestructive techniques   总被引：1，自引：1，他引：0  

Y. Enamorado-Horrutiner  M. E. Villanueva-Tagle  M. Behar  G. Rodríguez-Fuentes  J. Ferraz Dias  M. S. Pomares-Alfonso 《International Journal of Environmental Science and Technology》2016,13(5):1245-1256

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Vermiculite bio-barriers for Cu and Zn remediation: an eco-friendly approach for freshwater and sediments protection     

C. Ferronato  B. Silva  F. Costa  T. Tavares 《International Journal of Environmental Science and Technology》2016,13(5):1219-1228

The increase in heavy metal contamination in freshwater systems causes serious environmental problems in most industrialized countries, and the effort to find eco-friendly techniques for reducing water and sediment contamination is fundamental for environmental protection. Permeable barriers made of natural clays can be used as low-cost and eco-friendly materials for adsorbing heavy metals from water solution and thus reducing the sediment contamination. This study discusses the application of permeable barriers made of vermiculite clay for heavy metals remediation at the interface between water and sediments and investigates the possibility to increase their efficiency by loading the vermiculite surface with a microbial biofilm of Pseudomonas putida, which is well known to be a heavy metal accumulator. Some batch assays were performed to verify the uptake capacity of two systems and their adsorption kinetics, and the results indicated that the vermiculite bio-barrier system had a higher removal capacity than the vermiculite barrier (+34.4 and 22.8 % for Cu and Zn, respectively). Moreover, the presence of P. putida biofilm strongly contributed to fasten the kinetics of metals adsorption onto vermiculite sheets. In open-system conditions, the presence of a vermiculite barrier at the interface between water and sediment could reduce the sediment contamination up to 20 and 23 % for Cu and Zn, respectively, highlighting the efficiency of these eco-friendly materials for environmental applications. Nevertheless, the contribution of microbial biofilm in open-system setup should be optimized, and some important considerations about biofilm attachment in a continuous-flow system have been discussed.  相似文献   

<Emphasis Type="Italic">Robinia pseudoacacia</Emphasis> and <Emphasis Type="Italic">Melandrium album</Emphasis> in trace elements biomonitoring and air pollution tolerance index study     

A. Nadgórska-Socha  M. Kandziora-Ciupa  R. Ciepał  G. Barczyk 《International Journal of Environmental Science and Technology》2016,13(7):1741-1752

The accumulation efficiency of selected trace elements in the leaves of Melandrium album and Robinia pseudoacacia grown on heavy metal contaminated sites in comparison with a non-contaminated one was evaluated. The study was undertaken to calculate air pollution tolerance index and to determine the contents of selected metabolites: glutathione, non-protein thiols, ascorbic acid, chlorophyll and the activity of antioxidant enzymes: guaiacol peroxidase and superoxide dismutase. Such estimations can be useful in better understanding of plants defense strategies and potential to grow in contaminated environments. The results in the most contaminated site revealed higher contents of metals in M. album leaves, especially Zn, Cd and Pb (3.4, 6 and 2.3 times higher, respectively) in comparison with the R. pseudoacacia. Better accumulation capacity found in M. album was shown by metal accumulation index values. The plants could be used as indicators of Zn, Cd (both species) and Pb (M. album) in the soil. Glutathione content (in both species) and peroxidase activity (in M. album), general markers of heavy metals contamination, were increased in contaminated sites. In most cases in contaminated areas R. pseudoacacia had decreased ascorbic acid and chlorophyll levels. Opposite tendency was recorded in M. album leaves, where similar or higher contents of the above-mentioned metabolites were found. In our study, M. album and R. pseudoacacia proved to be sensitive species with the air pollution tolerance index lower than 11 and can be recommended as bioindicators.  相似文献   

Effectiveness of vegetative filter strips in abating fecal coliform based on modified soil and water assessment tool     

J. Bai  Z. Shen  T. Yan 《International Journal of Environmental Science and Technology》2016,13(7):1723-1730

Pathogenic bacteria are a serious public health concern. Exposure to these microorganisms can result in illnesses or even death. Therefore, it is important to control pathogenic bacteria sources, transport mechanisms and fate. Best management practices proved to be very effective in the control of non-point source pollution. In this study, the soil and water assessment tool (SWAT) was modified and used to simulate the fecal coliform in Chao River of Miyun Reservoir watershed, China. The model was then used to explore the effectiveness of vegetative filter strips (VFS) in reducing fecal coliform abundance throughout the watershed. The water temperature equation within the SWAT was modified to align the model more closely with the characteristics of the study area and generate a more accurate simulation. The DAFS_ratio (20, 50, 80, 120 and 150) and DF_con (0.25, 0.4, 0.6 and 0.75) parameters were considered for VFS to see their effects on removal efficiency. The results show that calibration and validation results for fecal coliform and flow can be accepted. Different values for DAFS_ratio and DF_con have great influence on VFS. Increasing values resulted in a decrease in the removal efficiency of VFS.  相似文献   

Removal of heavy metal ions from drinking water by alginate-immobilised <Emphasis Type="Italic">Chlorella sorokiniana</Emphasis>     

A. Petrovič  M. Simonič 《International Journal of Environmental Science and Technology》2016,13(7):1761-1780

This paper investigates the potential of alginate-immobilised Chlorella sorokiniana for removing Cu²⁺, Ni²⁺ and Cd²⁺ ions from drinking water solutions. The effects of initial metal concentrations, contact times and temperatures on the biosorptions and removal efficiencies of the tested metals were investigated at initial pH values of 5, and pH effects were studied within the range of 3–7. When studying the effects of initial metal concentrations, the highest experimental removal yields achieved for Cu²⁺, Ni²⁺ and Cd²⁺ ions were 97.10, 50.94 and 64.61 %, respectively. The maximum biosorption capacities obtained by the Langmuir isotherm model for the biosorptions of Cu²⁺, Ni²⁺ and Cd²⁺ ions by alginate-immobilised C. sorokiniana were found to be 179.90, 86.49 and 164.50 mg/g biosorbent, respectively. The experimental data followed pseudo-second-order kinetics. At an initial metal concentration of 25 mg/L, immobilised algae could be used in at least 5 successive biosorption–desorption cycles. SEM and EDS analyses revealed that the metals bonded to the biosorbent. Bi- and multi-metal systems of Cu²⁺, Ni²⁺ and Cd²⁺ were investigated at initial metal concentrations of 30, 50 and 100 mg/L. The removal of Cd²⁺ as well as Ni²⁺ in such systems was negatively affected by the presence of Cu²⁺. The removal efficiency for Cu²⁺ in multi-metal systems decreased by 5–7 %, whilst in the cases of Cd²⁺ and Ni²⁺ the efficiencies decreased by up to 30 %. Nevertheless, the results obtained show that alginate-immobilised C. sorokiniana can efficiently remove the metals tested from polluted drinking water sources.  相似文献   

Evaluation of rainfall and wetland water area variability at Thirlmere Lakes using Landsat time-series data     

B. P. Banerjee  S. Raval  W. Timms 《International Journal of Environmental Science and Technology》2016,13(7):1781-1792

Thirlmere Lakes is a group of five freshwater wetlands in the southwest fringe of Sydney, Australia, that is subject to cyclic wetting and drying. The lakes are surrounded by activities that have led to increasing pressure on the local surface and groundwater supply including farming and mining. The mine has been operating for more than 30 years, and in recent times, there has been speculation that the surface subsidence and underground pumping may have some impact on surface water and groundwater hydrology. A study was undertaken using satellite imagery to examine the relation between water area changes and rainfall variability. The study utilised Landsat time-series data during the period 1982–2014 to calculate changes in the lake water area (LA), through the normalised difference water index (NDWI) threshold. High classification accuracy was achieved using NDWI against high-resolution data that are available for the years 2008 (88.4 %), 2010 (92.8 %), and 2013 (96.9 %). The LA measurement was correlated against 11 historic observations that occurred in 2009, 2010, and 2011 during drier wetland conditions. Correlation analysis of the LA with the residual rainfall mass spread across the past 30 years has found that rainfall variability is a major dominant factor associated with the wetland changes. The underground mining operations, if verified by independent investigations, probably play a minor or negligible contributor to variations in total wetland area during the study period. This study has demonstrated that remote sensing is a technique that can be used to augment limited historic data.  相似文献   

Activated sludge acclimation for toluene and DEHP degradation in a two-phase partitioning bioreactor     

I. Béchohra  J. B. Le Menn  A. Couvert  A. Amrane 《International Journal of Environmental Science and Technology》2016,13(8):1883-1890

The effect of activated sludge acclimation on the biodegradation of toluene in the presence of a biodegradable non-aqueous phase liquid, di (2-ethylhexyl) phthalate (DEHP), in a two-phase partitioning bioreactor was characterized. The influence of the presence of DEHP, at a ratio of 0.1 % (volume ratio), and of the acclimation of activated sludge (AS) on the biodegradation of hydrophobic VOC was studied. AS was acclimated to both toluene and DEHP simultaneously. Using acclimated cells, 73 and 96 % improvement of the mean biodegradation rates was recorded for toluene and the organic solvent (DEHP), respectively, if compared to the values recorded in the absence of acclimation, during tests performed in Erlenmeyer flasks. Degradation rates were further improved by the use of acclimated AS in a reactor with a large head space; degradation yields for toluene and DEHP were above 99 and 89 %, respectively.  相似文献   

Way forward to achieve sustainable and cost-effective biofuel production from microalgae: a review     

N. Misra  P. K. Panda  B. K. Parida  B. K. Mishra 《International Journal of Environmental Science and Technology》2016,13(11):2735-2756

Driven by policies aimed at enhancing energy security and mitigating greenhouse gas emissions, the production and use of biofuels have significantly increased in recent years. Microalgae owing to its multiple advantages which include high lipid content, sustainable biomass production, effective land and water utilization are the most potential biofuel feedstock that can provide drop-in fossil fuel replacements without stimulating competition for agricultural resources and are considered to be more environmentally benign than the first- and second-generation biofuel feedstocks. However, there are many existing technical and scientific impediments that are yet to be resolved. Keeping this in view, the present review provides a concise account of the microalgal species known to accumulate high levels of lipid and describes the main factors that should be taken into consideration while selecting suitable algal strains for mass cultivation. The underlining advantages and limitations of raceway pond and photobioreactor cultivation systems are also examined. The recent advances in genetic engineering of microalgae to improve biomass and lipid productivity are then highlighted, which include the ongoing debate over the biosafety issues pertinent to the use of genetically modified algae. Furthermore, a wide range of high-value products that can be co-produced from microalgae have been discussed. The review concludes with a comprehensive summary of the major techno-economic constraints to commercialization of algal-derived biofuels along with promising methods for overcoming these challenges in order to produce cost-competitive and environmentally sustainable biofuel.  相似文献   

Influence of varying nitrogen levels on lipid accumulation in <Emphasis Type="Italic">Chlorella</Emphasis> sp.     

B. Kiran  K. Pathak  R. Kumar  D. Deshmukh  N. Rani 《International Journal of Environmental Science and Technology》2016,13(7):1823-1832

Microalgal lipids can be enhanced through varying nitrogen (N) content, and limited supply of nitrogen source seems to be valuable approach for increased lipid accumulation in microalgae. In this study, Chlorella sp. IM-02 was observed under fluorescence microscope for increased number of lipid bodies under nitrogen scarcity. Fourier transform infrared spectroscopy was used to determine spectral changes due to varying lipid content under nitrogen-starved (N₀, without sodium nitrate), nitrogen-limited (N_0.1, N_0.25, N_0.5 and N_1.0 representing 0.1, 0.25, 0.5 and 1.0 g/L of sodium nitrate, respectively) and nitrogen-sufficient (N_1.5, i.e., 1.5 g/L sodium nitrate) setting. Chlorophyll content was also monitored under these conditions as growth indicator. Various biochemical components viz. total carbohydrates, total proteins and total lipids were also estimated under varying nitrogen levels spectrophotometrically. On fourth day itself, maximum lipid productivity was observed in case of N_0.5, which is having one-third of nitrogen concentration present in original growth media, BG-11. This concludes N_0.5 as suitable nitrogen provision for better production of lipids in Chlorella sp. IM-02 without much compromising the biomass production as both growth and lipid quantity are key parameters affecting the lipid productivity of any microalgal strain.  相似文献   

Experimental study of pure and mixtures of CO<Subscript>2</Subscript> and CH<Subscript>4</Subscript> adsorption on modified carbon nanotubes     

E. Molyanyan  S. Aghamiri  M. R. Talaie  N. Iraji 《International Journal of Environmental Science and Technology》2016,13(8):2001-2010

In this work 3-[2-(2-aminoethylamino)ethylamino]propyl trimethoxysilane (TRI) was employed to functionalize MWCNT containing hydroxyl groups (OH-MWCNT), and the XRD, FTIR, TGA and CHNS elemental analysis techniques were used to characterize the resulted adsorbents. The characterization results for amine-MWCNT showed amine groups effectively attached to the surface of the MWCNT. The equilibrium adsorption capacity of pure CO₂ and CH₄ and their binary mixture on the pristine MWCNT, OH-MWCNT and amine-MWCNT was measured through a set of equilibrium adsorption experiments at 303.2 and 318.2 K. Capacities of all three types of adsorbents for CO₂ adsorption were higher than those for methane adsorption. Also, amine-MWCNT demonstrated better performance on CO₂ adsorption than the other two adsorbents, especially at low partial pressures. The capacity of amine-MWCNT for pure CO₂ adsorption was 2.5 and 4 times as much as those for pristine MWCNT and OH-MWCNT, respectively, at the temperature of 303.2 K and the pressure of 0.2 bar. The binary adsorption experiment revealed that CO₂/CH₄ selectivity for pristine MWCNT and amine-MWCNT in all molar fractions of CO₂ is about 1.77 and 7, respectively.  相似文献