Assessment of alternative adsorption models and global sensitivity analysis to characterize hexavalent chromium loss from soil to surface runoff          下载免费PDF全文

Chuan‐An Xia  Juxiu Tong  Bill X. Hu  Xiujie Wu  Alberto Guadagnini 《水文研究》2018,32(20):3140-3157

We investigate our ability to assess transfer of hexavalent chromium, Cr(VI), from the soil to surface runoff by considering the effect of coupling diverse adsorption models with a two‐layer solute transfer model. Our analyses are grounded on a set of two experiments associated with soils characterized by diverse particle size distributions. Our study is motivated by the observation that Cr(VI) is receiving much attention for the assessment of environmental risks due to its high solubility, mobility, and toxicological significance. Adsorption of Cr(VI) is considered to be at equilibrium in the mixing layer under our experimental conditions. Four adsorption models, that is, the Langmuir, Freundlich, Temkin, and linear models, constitute our set of alternative (competing) mathematical formulations. Experimental results reveal that the soil samples characterized by the finest grain sizes are associated with the highest release of Cr(VI) to runoff. We compare the relative abilities of the four models to interpret experimental results through maximum likelihood model calibration and four model identification criteria (i.e., the Akaike information criteria [AIC and AIC_C] and the Bayesian and Kashyap information criteria). Our study results enable us to rank the tested models on the basis of a set of posterior weights assigned to each of them. A classical variance‐based global sensitivity analysis is then performed to assess the relative importance of the uncertain parameters associated with each of the models considered, within subregions of the parameter space. In this context, the modelling strategy resulting from coupling the Langmuir isotherm with a two‐layer solute transfer model is then evaluated as the most skilful for the overall interpretation of both sets of experiments. Our results document that (a) the depth of the mixing layer is the most influential factor for all models tested, with the exception of the Freundlich isotherm, and (b) the total sensitivity of the adsorption parameters varies in time, with a trend to increase as time progresses for all of the models. These results suggest that adsorption has a significant effect on the uncertainty associated with the release of Cr(VI) from the soil to the surface runoff component.  相似文献   

基于噪声谱比法的内蒙古西部地区台站场地响应研究     

张珂  王鑫  王树波  张红才  宋晓燕 《大地测量与地球动力学》2020,40(6):646-651

利用内蒙古西部12个台站的地脉动噪声数据，采用噪声谱比法研究台站的场地响应情况。分析表明，台站场地响应按曲线形态可分为3类，且可能受地形地貌、局部构造和台基状况等条件影响。对比分析噪声谱比法与Moya方法的场地响应结果发现，场地响应曲线形态基本一致，只有极少数台站存在明显差异。结果表明，内蒙古西部区域大部分台站的台基状况总体较好，场地响应曲线较为平坦，无明显频率放大点。  相似文献   

从商务日语课程设置谈高职教育课程改革     

张奚渝 《广东海洋大学学报》2003,23(5):134-136

本科院校办高职学院是我国 2 0世纪末出现的一个新生事物 ,如何设置专业课程 ,提高教学质量 ,使学生一出校门就能容纳到直接为经济服务当中去 ,结合商务日语专业的具体情况对这个问题进行了思考。  相似文献   

青藏高原隆升的非线性动态有限元仿真研究   总被引：7，自引：4，他引：3  

杨红心  王乘  张秋文  郑文衡 《大地测量与地球动力学》2002,22(2):75-81

根据青藏高原的地质特征建立分析模型，采用3维动态有限元方法，在计算仿真板块速度场的基础上，计算在青藏高原的隆升过程中该地区地壳岩石的等效应力和位移随时间的变化，计算仿真得到的速度场与1998年GPS观测的速度场吻合良好；与过去一贯的假设相反，计算结果反映出地壳应力场不是静态的，而是此起彼伏，不断变化的，应力值最大且变化最剧烈的地区在克什米尔地区、鄂尔多斯地区和鲜水河－小江断裂带，与地震多发区域吻合。  相似文献   

大同—阳高Ms6.1地震前兆综合加权信息熵的变化     

张昭栋  刘章增  赵会蓬 《大地测量与地球动力学》2002,22(1):51-55

利用“地震预报计算机专家系统”的思想对大同 -阳高 Ms6 .1地震前每一前兆异常事件进行综合评估 ,以每一异常的最可能发震时间来计算发震概率 ,利用地震前兆综合加权信息熵研究了系统熵值与地震的关系。对华北地区的地震前兆综合加权信息熵研究表明 ,在大同 -阳高 Ms6 .1地震前 ,信息熵出现了明显的减熵有序变化  相似文献   

对青藏东北缘现今块体划分、运动及变形的初步研究   总被引：19，自引：9，他引：10  

张晓亮  江在森  陈兵  李辉 《大地测量与地球动力学》2002,22(1):63-67

利用2维非连续变形分析方法（DDA），以位移代替围压作为边界约束力，研究青藏东北缘现今块体划分及其运动变形。根据该地区地质构造及地震活动，以GPS点测量位移作为模拟结果约束点，得出了较合理的块体划分模型和随时间演化的主应变分布图，并把应变高值区与近几年来发生的5级以上地震作对比，得出了研究区内地震危险性可能较大的区域。另外，对模拟的甘青块体与阿拉善块体的边缘带断裂左旋运动做了大概计算。  相似文献   

抽油机悬点投影测量仪     

文志雄  戚克军  李明  曾南志 《大地测量与地球动力学》2002,22(1):110-113

油田抽油机的抽油杆幌动幅度过大，是引起抽油杆断裂的一个重要因素，检测这种幌动幅度是防止抽油杆断裂的一种有效手段。设计了一种基于面阵CCD和普通半导体激光器（LD）测量这种幌动的悬点投影测量方法，通过数字卷积滤波，达到了范围为0－40mm，误差＜0.2mm的技术检测指标。  相似文献   

Influence of the Choice of Core-Envelope Transition Point on the Binary Merger of Two Main-sequence Components     

Xue-Fei Chen  Zhan-Wen HanNational Astronomical Observatories  Yunnan Observatory  Chinese Academy of Sciences. Kunming  Graduate School of the Chinese Academy of Sciences  Beijing 《中国天文和天体物理学报》2005,5(1):65-76

We have studied the influence of different choices of core-envelope transition point on the final merger of contact binaries with two main-sequence components. A binary of 1.00 + 0.90M⊙ with an initial orbital period of 0.35d is examined. The mass fraction of the primary mixed with the matter of the secondary, qmix, determined by the chosen core-envelope transition point, ranges from 0.04 to 1.00 in our analysis. If as qmix< 0.8, none of the  相似文献   

中国1∶100万景观生态制图设计   总被引：5，自引：0，他引：5  

程维明  柴慧霞龙恩  刘海江张旸 《地球信息科学学报》2004,6(4):19-24

中国1∶100万景观生态图系借鉴国内外传统景观制图方法和制图规范,在遥感、地理信息系统先进技术的支持下,设计研制其制图方法、制图内容、样图和技术流程,同时提出初步的景观分类系统,为今后编制中国1∶100万景观生态图奠定基础。  相似文献   

Bacterial productivity in the Prydz Bay and its adjacent waters,Antarctic     

邱雨生  黄奕普  陈敏  刘广山 《极地研究(英文版)》2004,15(1):14-27

1　IntroductionBacteriaandtheiractivitiesplayanimportantroleintheelementalbiogeochemicalcyclesandenergytransformingintheocean (Zhenetal.1 997) .DortchandPackard(1 989) proposedthatfoodwebsintheeutrophicwatersaredominatedbythebiomassofprimaryproducerswhilefoodwebsintheoligotrophicwatersaredominatedbythebiomassofmicrobes.Heterotrophicbacteriahadbeenshowntoplayanimportantroleinthedecompositionoflarge ,rapidlysinkingorganicparticleswithinandbelowtheeuphot iczone ,andfurthertoaffecttheelementaldyn…  相似文献