Sorption of lead by chemically modified rice bran     

T. Fatima  R. Nadeem  A. Masood  R. Saeed  M. Ashraf 《International Journal of Environmental Science and Technology》2013,10(6):1255-1264

In this work, the effectiveness of native and chemically modified rice bran to remove heavy metal Pb(II) ions from aqueous solution was examined. Chemical modifications with some simple and low-cost chemicals resulted in enhancement of the adsorption capacities and had faster kinetics than native rice bran. Experiments were conducted in shake flasks to monitor the upshot of parameters over a range of pH, initial Pb(II) concentrations and contact times using a batch model study. The sorption capacities q (mg g^?1) increased in the following order: NaOH (147.78), Ca(OH)₂ (139.08), Al(OH)₃ (127.24), esterification (124.28), NaHCO₃ (118.08), methylation (118.88), Na₂CO₃ (117.12) and native (80.24). The utmost uptake capacity q (mg g^?1) was shown by NaOH-pretreated rice bran. The results showed that, using NaOH-modified rice bran, the chief removal of Pb(II) was 74.54 % at pH 5, primary Pb(II) concentration 100 mg L^?1 and contact time 240 min. Equilibrium isotherms for the Pb(II) adsorption were analyzed by Langmuir and Freundlich isotherm models. The Langmuir isotherm model, showing Pb(II) sorption as accessible through the high value of the correlation coefficient (R ² = 0.993), showed a q _max value of 416.61 mg g^?1. The kinetic model illustrated adsorption rates well, depicted by a second order, which gives an indication concerning the rate-limiting step. Thermodynamic evaluation of the metal ion ?G ^o was carried out and led to the observation that the adsorption reaction is spontaneous and endothermic in nature. NaOH chemically modified rice bran was a superb biosorbent for exclusion of Pb(II) and proved to be excellent for industrial applications.  相似文献   

Mineralogy and microchemistry of the Egat gold deposit, South Eastern Desert of Egypt     

Ashraf Emam 《Arabian Journal of Geosciences》2013,6(12):4619-4634

Gold-bearing quartz lodes from the Egat gold mine, South Eastern Desert of Egypt, are associated with pervasively silicified, highly sheared ophiolitic metagabbro and island-arc metavolcanic rocks. The mineralized quartz veins and related alteration haloes are controlled by NNW-trending shear/fault zones. Microscopic and electron probe microanalyses (EPMA) data of the ore and gangue minerals reveal that fine-grained auriferous sulfarsenides represent early high-temperature (355–382 °C) phases, with formation conditions as (fS₂?=??10, and fO₂ around ?31). A late, low-temperature (302–333 °C) assemblage includes coarse pyrite, arsenopyrite, and free-milling gold grains (88–91 wt.% Au), with formation conditions as (fS₂?=??8 and fO₂ around ?30). Gold was impounded within early sulfarsenides, while free-milling gold blebs occur along microfractures in quartz veins and as inclusions in late sulfides. Infiltration of hydrothermal fluids under brittle–ductile shear conditions led to mobilization of refractory Au from early sulfarsenide phases and reprecipitated free gold, simultaneous with silicification of the host rocks. The positive correlation between Au and As favors and verifies the use of As as the best pathfinder for gold targets, along the NNW-trending shear zones.  相似文献   

Evidences of Holocene transgression on Domingos Petrolini Swamp, southern coastal plain, Rio Grande do Sul, Brazil     

Soraia G.Bauermann  Paulo C.P.Neves  Marleni Marques-Toigo  Abdul R.Ashraf 《东北亚地学研究》2005,(Z1)

The Domingos Petrolini Swamp, located on the Southern Coastal Plain of Rio Grande do Sul, near the town of Rio Grande, constitutes an ample holocene lagoonal deposit. Events related to the holocene transgression and their diverse phases of glacial-eustatic ocillations were found through palynological analysis. Bases on these palynological data, four distinct phases to the paleoenvironmental evolution of the ecosystem were identified. It has also shown a transgressive restricted marine sequence on the base , which suggests the existence of a coastal brackish lagoon or a marisme type of environment. Later, there was a gradation for continentality conditions along with a scarce pollinical record. The third phase is characterized by the presence of marine components and halophyte vegetation, showing another transgressive event in that place. Lastly, the end of direct marine influence over the swamp was recorded and also the vegetation development as it appears these days.  相似文献   

Hydrological and geochemical constraints on the mechanism of formation of arsenic contaminated groundwater in Sonargaon,Bangladesh     

Takaaki Itai  Harue Masuda  Ashraf A. Seddique  Muneki Mitamura  Teruyuki Maruoka  Xiaodong Li  Minoru Kusakabe  Biswas K. Dipak  Abida Farooqi  Toshiro Yamanaka  Shinji Nakaya  Jun-ichi Matsuda  Kazi Matin Ahmed 《Applied Geochemistry》2008

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Impact of desalination plants brine injection wells on coastal aquifers     

Mohamed K. K. Nassar  Reda M. El-Damak  Ashraf H. M. Ghanem 《Environmental Geology》2008,54(3):445-454

A new methodology is developed in assessing environmental impacts of desalination plants discharging brine into the ground. The main environmental problem of the desalination of seawater is the brine disposal. The brine is commonly discharged into the sea or injected into a saline aquifer. In the case of injection into the ground, it is necessary to design a disposal system in a way that respects the environment and is sustainable. Laboratory and computational methods have been utilized to simulate the unsteady three-dimensional (3D) phenomena of subsurface brine disposal. The computational software used is SEAWAT, which is a 3D unsteady variable-density flow simulation model. The model is first used to simulate the laboratory results, and good agreement is achieved. Then, hypothetical problems are designed and simulated of groundwater extraction and brine disposal by desalination stations. The major purpose of these hypothetical problems is to delineate a methodology and to create design charts for design and management of production and injection well fields for coastal desalination plants. Several design charts have been developed with 36 scenarios for two well configurations created by four design parameters: relative salt concentration (RSC), production and injection rates (Q _d , Q _r ), well spacing (S), and simulation period (T).  相似文献   

Dynamics of particle creation in relativistic viscous fluid Universe in Brans Dicke theory     

L. Ibochouba  Mohammed Ashraf Ali 《Astrophysics and Space Science》1996,241(2):227-235

The study of dynamics of the particle creation in relativistic viscous fluid in Robertson-Walker Universe is studied by using Brans-Dicke theory. The behaviour of these solutions with respect to Dirac's hypothesis are investigated along with the discussion of the physical parameters as well as the variable gravitational constant. By adopting a particular method of integration, exact solutions are obtained and physical interpretations are presented.  相似文献   

The role of blocking system in heavy precipitation of Iran (a case study: southeast of Iran January 2008)     

Tayebeh Akbari Azirani  Ghasem Azizi  Ashraf Asadi  Mahmoud Davoudi 《Arabian Journal of Geosciences》2016,9(11):591

This article concerns the analysis of the heavy precipitation, which allows investigating the effect of the blocking system on the unusual precipitation and temperature occurrence in Iran. The days of January 2008 have been the coldest days during the history of recorded data in Iran. Variation of precipitation during January 2008 compared with long-term data (30 years) shows the maximum positive anomaly in the stations located in southeast of Iran. However, the precipitation in consecutive days, 14–15 and 15–16 of January, produce a more important proportion of the heavy precipitation in this region. In order to study the role of the blocking system related to heavy precipitation in January 2008, the position and movement of the atmospheric systems including cyclones, anticyclones, fronts, and wind fields have been analyzed by the use of synoptic maps by the environment to circulation approach. Consequently, the weather maps indicated that the blocking system over the north of the Caspian Sea has caused the relatively deep low trough on January 5, 7, 14, 15, and 16, 2008, while the thermal and moisture gradients in the warm section of air masses have produced heavy precipitation. As a result, wind field of low levels (850 hPa) provided remarkable moisture fed by the Arabian Sea, Oman Sea, and Persian Gulf in the study area. Furthermore, the speed of wavelength and the position of the blocking system associated with the heavy precipitation can be clearly identified.  相似文献   

Mobilized side and tip resistances of piles in clay     

Mohamed Ashour  Gary M. Norris  Sherif Elfass  Ashraf Z. Al-Hamdan 《Computers and Geotechnics》2010,37(7-8):858-866

This paper presents a procedure to assess the mobilized pile side and tip resistance versus pile head and tip settlement under axial load in clay soil. The load transfer (t–z) curve is evaluated at any point on the loaded pile based on the combined pile tip/side resistance–displacement mechanisms along the length of the pile. Unlike current methods that assume the pile settlements as a percentage of the pile/shaft diameter, the presented technique determines the side and tip resistance of the pile and the associated pile settlement under existing load based on the current stress/strain level in the surrounding soil up to failure (excessive settlement). The technique employs the concepts of the elastic theory and Ramberg–Osgood characterization of the stress–strain behavior of the clay soil. Case studies are also presented to exhibit the capabilities of the proposed procedure. The good agreement between measured and calculated load transfer curves along the pile and pile tip resistance versus pile head, side, and tip displacements shows the consistency of the proposed procedure. A computer code is developed to employ the presented technique.  相似文献   

Assessment of the Hydrogeochemical Characteristics of Groundwater Resources at some Wadis in the East of El Minia Governorate, Eastern Desert, Egypt     

Alzahraa Abo HABIBAH  Kamal DAHAB  Ashraf SHABANA  Samir KAMH  Hekmat IBRAHIM 《《地质学报》英文版》2022,96(3):1082-1097

The El Minia governorate lies within the Nile Valley, surrounded by calcareous plateaus to the east and west. The present study focuses on the hydrogeochemistry of the Eocene limestone aquifer at some wadis in the east El Minia governorate, Eastern Desert, Egypt. Hydrogeologically, two main aquifers are encountered in the study area, namely the Maghagha marly limestone and the Samalut chalky limestone aquifers. The Maghagha aquifer is composed of alternating layers of marly limestone and shale with thicknesses ranging from 3.49 m to 177.05 m and a groundwater depth ranging from 8.5 m to 59.27 m which reflects low groundwater potentiality. The groundwater salinity representing this aquifer ranges from 603.5 mg/L to 978.5 mg/L, reflecting fresh water type. Samalut aquifer is made up of chalky, cavernous and fractured limestone with thickness ranging from 30 m to 205 m and groundwater depth ranging from 9 m to 86.77 m, which indicates good groundwater potential. The groundwater salinity of the concerned aquifer ranges from 349.7 mg/L to 2043.9 mg/L, reflecting fresh to possibly brackish water types. Groundwater in the study area is of meteoric water origin; recent recharge is mainly controlled through the presence of fractures and their densities. The majority of groundwater samples in the study area are suitable for drinking and irrigation purposes.  相似文献   

Compounding effects of human activities and climatic changes on surface water availability in Iran     

Ashraf  Samaneh  AghaKouchak  Amir  Nazemi  Ali  Mirchi  Ali  Sadegh  Mojtaba  Moftakhari  Hamed R.  Hassanzadeh  Elmira  Miao  Chi-Yuan  Madani  Kaveh  Mousavi Baygi  Mohammad  Anjileli  Hassan  Arab  Davood Reza  Norouzi  Hamid  Mazdiyasni  Omid  Azarderakhsh  Marzi  Alborzi  Aneseh  Tourian  Mohammad J.  Mehran  Ali  Farahmand  Alireza  Mallakpour  Iman 《Climatic change》2019,152(3-4):379-391

Climatic Change - By combining long-term ground-based data on water withdrawal with climate model projections, this study quantifies the compounding effects of human activities and climate change...  相似文献