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291.
We present a study of the spatial distribution of δ18O and δD values of lake and river waters from 144 locations in Ireland. Before we can gain a better understanding of paleoclimate records derived from lacustrine carbonate minerals we must understand mechanisms that produce variation in isotope values of modern surface waters. The focus of this study is to provide insight into the behavior of lakes and rivers in Ireland, including source, recycling and loss through evapotranspiration. The short duration of sampling in this project provides a snapshot of modern isotope variability to be applied towards long-term climate change in Ireland and provides a basis of comparison for other proxy records.Electronic supplementary material to this article is available at and accessible for authorized users.  相似文献   
292.
Increased nutrient loadings have resulted in low dissolved oxygen (DO) concentrations in bottom waters of the Patuxent River, a tributary of Chesapeake Bay. We synthesize existing and newly collected data to examine spatial and temporal variation in bottom DO, the prevalence of hypoxia-induced mortality of fishes, the tolerance of Patuxent River biota to low DO, and the influence of bottom DO on the vertical distributions and spatial overlap of larval fish and fish eggs with their gelatinous predators and zooplankton prey. We use this information, as well as output from watershed-quality and water-quality models, to configure a spatially-explicit individual-based model to predict how changing land use within the Patuxent watershed may affect survival of early life stages of summer breeding fishes through its effect on DO. Bottom waters in much of the mesohaline Patuxent River are below 50% DO saturation during summer. The system is characterized by high spatial and temporal variation in DO concentrations, and the current severity and extent of hypoxia are sufficient to alter distributions of organisms and trophic interactions in the river. Gelatinous zooplankton are among the most tolerant species of hypoxia, while several of the ecologically and economically important finfish are among the most sensitive. This variation in DO tolerances may make the Patuxent River, and similar estuaries, particularly susceptible to hypoxia-induced alterations in food web dynamics. Model simulations consistently predict high mortality of planktonic bay anchovy eggs (Anchoa mitchilli) under current DO, and increasing survival of fish eggs with increasing DO. Changes in land use that reduce nutrient loadings may either increase or decrease predation mortality of larval fish depending on the baseline DO conditions at any point in space and time. A precautionary approach towards fisheries and ecosystem management would recommend reducing nutrients to levels at which low oxygen effects on estuarine habitat are reduced and, where possible, eliminated.  相似文献   
293.
This study documents the new PLACE soil hydrology model, and examines the effects of various parameterization schemes on the solution of the Richards equation. Richards equation is the basis upon which many of the land surface schemes participating in the PILPS experiments model soil water transport. Generally, the integration is carried out using a coarse model grid, which makes the solution more sensitive to particulars of the parameterization scheme. Parameterization schemes for the lower boundary condition, lateral interflow, and for moisture fluxes between model layers are tested in PLACE using both high and low resolution grids. Simulations were made using PILPS-HAPEX forcing data and soil and vegetation parameters. The soil hydrology model is validated against the annual observed HAPEX soil moisture profiles. The predicted evapotranspiration is also compared to a value computed from the PILPS-HAPEX forcing data using the Penman-Monteith equation.When testing a low-resolution soil grid typical of land surface schemes, predicted soil moisture was found to be highly sensitive to the interpolation method for computing vertical moisture fluxes between model layers. A new interpolation method for low resolution models is proposed and tested. It reproduces the high resolution model results more faithfully, over the entire range of soil moisture, than two methods commonly applied in the literature. Further tests demonstrate that by varying the parameterizations for lower boundary condition and the treatment of lateral flow (collectively called drainage), the predicted total annual evapotranspiration may range between 74% and 97% of the incident precipitation in this case. Both of these parameterizations involve one free parameter, and both are largely unconstrained by the available observations. Good overall agreement between the PLACE predicted and HAPEX observed soil moisture profiles was attained by varying these two PLACE drainage parameters over their respective ranges for a series of model simulations. Root-mean square error tests were then used to determine the set of parameters which corresponded to the best predicted soil moisture profile. However, the best predicted soil moisture profiles do not correspond with the best predicted evapotranspiration. This inconsistency occurs not only for PLACE, but, to varying degrees, for all of the land-surface schemes participating in PILPS-HAPEX.  相似文献   
294.
The Woodroffe thrust, central Australia, is a > 1.5-km-wide mylonitized shear zone marked by large volumes of mm- to cm-scale pseudotachylyte veins. The pseudotachylytes display typical melt-origin features, including rounded and embayed clasts, spherulitic and dentritic microlites, and flow structures within a fine-grained matrix. Three types of pseudotachylyte are identified on the basis of deformation texture, vein morphology, and host-rock lithology: cataclasite-related (C-Pt), mylonite-related (M-Pt), and ultramylonite-related (Um-Pt). The M-Pt and Um-Pt veins intrude into mylonite and ultramylonite and are themselves overprinted by subsequent mylonitization. These pseudotachylytes contain an internal foliation defined by flattened porphyroclasts and layering of the fine-grained vein matrix, and the foliation is generally oriented parallel to foliation in the surrounding mylonite and ultramylonite. These observations constrain the timing and environment of M-Pt and Um-Pt pseudotachylyte formation to a protracted period of deformation and mylonitization within the ductile regime of the crust. The M-Pt and Um-Pt veins, as well as the host mylonite, are overprinted by cataclasis and multiple generations of late-stage C-Pt veins that were generated in the brittle-dominated regime of the upper crust during uplift and exhumation of the shear zone.The coexistence of multiple generations of voluminous C-Pt, M-Pt, and Um-Pt veins indicates that the pseudotachylyte veins represent a large number of large earthquakes and accompanying seismic slip over an extended period of seismicity on the Woodroffe thrust. The timing and distribution of pseudotachylyte indicate that the earthquakes nucleated at the base of the brittle-dominated seismogenic zone and propagated down through the brittle–ductile transition into the ductile-dominated regime of the crust.  相似文献   
295.
The Malanjkhand Cu–Mo–Au deposit, located near the northwest margin of the Malanjkhand batholith (terrane), is a strategic and significant porphyry-style deposit that experienced a protracted 50 m.y. deformational history shortly after its formation at 2,490±8 Ma (Stein et al. 2004). In a recent study, Panigrahi et al. (2004) averaged U–Pb SHRIMP zircon data from a pooled set of samples from the Malanjkhand batholith to advocate a meaningless intermediate age of ~2,476 Ma for the Malanjkhand granitoid and its Cu–Mo–Au deposit. In the northwest part of the Malanjkhand batholith, Re–Os dating of occurrence-specific molybdenite captures not only the age of porphyry-style mineralization and associated magmatism, but also elucidates a complex deformational history that extends to ~2,450 Ma. In the central part of the Malanjkhand batholith, Re–Os dating of delicate spindles of accessory molybdenite occurring with pristine muscovite in miarolitic cavities within the undeformed microgranitoid at the Devgaon Mo prospect unequivocally shows that deformation ceased at this location no later than 2,470–2,465 Ma. The deformational history recorded at the Malanjkhand deposit in the northwest most likely reflects prolonged transpressive convergence and docking of the Malanjkhand terrane with units in the poorly understood (proto) Central Indian Tectonic Zone (CITZ) along its southern margin, the Central Indian shear zone. The timing for this convergence is Late Archean–Early Paleoproterozoic.Comment on “Age of granitic activity associated with copper–molybdenum mineralization at Malanjkhand, Central India” by Panigrahi MK et al. (Mineralium Deposita 39:670–677)  相似文献   
296.
Chironomid remains from a mid-elevation lake in the Sierra Nevada, California, were used to estimate quantitative summer surface water temperatures during the past ∼15,000 yr. Reconstructed temperatures increased by ∼3°C between lake initiation and the onset of the Holocene at ∼10,600 cal yr BP (calibrated years before present). Temperatures peaked at 6500 cal yr BP, displayed high variability from 6500 to 3500 cal yr BP, and stabilized after 3500 cal yr BP. This record generally tracks reconstructed Santa Barbara Basin sea surface temperatures (SSTs) through much of the Holocene, highlighting the correspondence between SST variability and California land temperatures during this interval.  相似文献   
297.
Hydrogeology Journal - Ancient river channels or subglacial drainage networks infilled with younger sediments can include significant deposits of highly permeable sands and gravels. Despite being...  相似文献   
298.
Magnetite from hydrothermal ore deposits can contain up to tens of thousands of parts per million (ppm) of elements such as Ti, Si, V, Al, Ca, Mg, Na, which tend to either structurally incorporate into growth and sector zones or form mineral micro- to nano-sized particles. Here, we report micro- to nano-structural and chemical data of hydrothermal magnetite from the Los Colorados iron oxide–apatite deposit in Chile, where magnetite displays both types of trace element incorporation. Three generations of magnetites (X–Z) were identified with concentrations of minor and trace elements that vary significantly: SiO2, from below detection limit (bdl) to 3.1 wt%; Al2O3, 0.3–2.3 wt%; CaO, bdl–0.9 wt%; MgO, 0.02–2.5 wt%; TiO2, 0.1–0.4 wt%; MnO, 0.04–0.2 wt%; Na2O, bdl–0.4 wt%; and K2O, bdl–0.4 wt%. An exception is V2O3, which is remarkably constant, ranging from 0.3 to 0.4 wt%. Six types of crystalline nanoparticles (NPs) were identified by means of transmission electron microscopy in the trace element-rich zones, which are each a few micrometres wide: (1) diopside, (2) clinoenstatite; (3) amphibole, (4) mica, (5) ulvöspinel, and (6) Ti-rich magnetite. In addition, Al-rich nanodomains, which contain 2–3 wt% of Al, occur within a single crystal of magnetite. The accumulation of NPs in the trace element-rich zones suggest that they form owing to supersaturation from a hydrothermal fluid, followed by entrapment during continuous growth of the magnetite surface. It is also concluded that mineral NPs promote exsolution of new phases from the mineral host, otherwise preserved as structurally bound trace elements. The presence of abundant mineral NPs in magnetite points to a complex incorporation of trace elements during growth, and provides a cautionary note on the interpretation of micron-scale chemical data of magnetite.  相似文献   
299.
The Atmospheric Radiation Measurement (ARM) Program Southern Great Plains (SGP) site has a rich history of actively sensed cloud observations. Fourteen years (1997–2010) of observations from the Millimeter Cloud Radar (MMCR), Micropulse Lidar (MPL), and Belfort/Vaisala Ceilometers are used to understand how instrument selection and sampling impacts estimates of Cloud Fraction (CF) at this location. Although all instruments should be used in combination for the best estimates of CF, instrument downtime limits available samples and increases observational errors, demanding that users make sacrifices when calculating CF at longer intervals relevant to climate studies. Selection of MMCR or MMCR + MPL cloud masks changes very little in the overall understanding of total CF. Addition of the MPL increases the 14-year average CF by 9 %, mainly through an increase in optically thin high clouds year-round, and mid-level clouds during the summer months. Splitting the period into two equal 7-year periods reveals negligible change in MMCR + MPL CF. For the MMCR, however, CF deceases by 6.1 %. This sudden change in CF occurs around the time the radar was upgraded, suggesting that this decrease is tied to hardware sensitivity or scanning strategy changes. Users must be cognizant of this and other issues when calculating CF from the variety of observations available at the ARM SGP site.  相似文献   
300.
We report δ7Li, Li abundance ([Li]), and other trace elements measured by ion probe in igneous zircons from TTG (tonalite, trondhjemite, and granodiorite) and sanukitoid plutons from the Superior Province (Canada) in order to characterize Li in zircons from typical Archean continental crust. These data are compared with detrital zircons from the Jack Hills (Western Australia) with U–Pb ages greater than 3.9 Ga for which parent rock type is not known. Most of the TTG and sanukitoid zircon domains preserve typical igneous REE patterns and CL zoning. [Li] ranges from 0.5 to 79 ppm, typical of [Li] in continental zircons. Atomic ratios of (Y + REE)/(Li + P) average 1.0 ± 0.7 (2SD) for zircons with magmatic composition preserved, supporting the hypothesis that Li is interstitial and charge compensates substitution of trivalent cations. This substitution results in a relatively slow rate of Li diffusion. The δ7Li and trace element data constrain the genesis of TTGs and sanukitoids. [Li] in zircons from granitoids is significantly higher than from zircons in primitive magmas in oceanic crust. TTG zircons have δ7Li (3 ± 8‰) and δ18O in the range of primitive mantle-derived magmas. Sanukitoid zircons have average δ7Li (7 ± 8‰) and δ18O higher than those of TTGs supporting genesis by melting of fluid-metasomatized mantle wedge. The Li systematics in sanukitoid and TTG zircons indicate that high [Li] in pre-3.9-Ga Jack Hills detrital zircons is a primary igneous composition and suggests the growth in proto-continental crust in magmas similar to Archean granitoids.  相似文献   
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