Inventory of nonvolatile fatty acids and hydrocarbons in the oceans     

Adam Zsolnay 《Marine Chemistry》1977,5(4-6)

A survey of the distribution of nonvolatile fatty acids and hydrocarbons in the oceans is given. The results represent more a “feel” from the literature rather than a mathematical analysis and are given in Table III. Fatty acid concentration appears to show a greater variation, presumably because they are more prone to biological influences than the hydrocarbons.  相似文献   

Atomic spectrometric analysis of heavy-metal pollutants in water: David C. Burrel. Ann Arbor Science Publishers,Mich., 1974, 331 pp., £ 13.00     

Klaus Kremling 《Marine Chemistry》1976,4(1):101-102

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Bringing GPS into harsh environments for fully automated deformation monitoring     

Jason Bond  Adam Chrzanowski  Don Kim 《GPS Solutions》2008,12(1):1-11

Engineering projects that require deformation monitoring frequently utilize geodetic sensors to measure displacements of target points located in the deformation zone. In situations where control stations and targets are separated by a kilometer or more, GPS can offer higher precision position updates at more frequent intervals than can normally be achieved using total station technology. For large-scale deformation projects requiring the highest precision, it is therefore advisable to use a combination of the two sensors. In response to the need for high precision, continuous GPS position updates in harsh deformation monitoring environments, a software has been developed that employs triple-differenced carrier-phase measurements in a delayed-state Kalman filter. Two data sets were analyzed to test the capabilities of the software. In the first test, a GPS antenna was displaced using a translation stage to mimic slow deformation. In the second test, data collected at a large open pit mine were processed. It was shown that the delayed-state Kalman filter developed could detect millimeter-level displacements of a GPS antenna. The actual precision attained depends upon the amount of process noise infused at each epoch to accommodate the antenna displacements. Higher process noise values result in quicker detection times, but at the same time increase the noise in the solutions. A slow, 25 mm displacement was detected within 30 min of the full displacement with sigma values in E, N and U of ±10 mm or better. The same displacement could also be detected in less than 5 h with sigma values in E, N and U of ±5 mm or better. The software works best for detecting long period deformations (e.g., 20 mm per day or less) for which sigma values of 1–2 mm are attained in all three solution components. It was also shown that the triple-differenced carrier-phase observation can be used to significantly reduce the effects of residual tropospheric delay that would normally plague double-differenced observations in harsh GPS environments.

Don KimEmail:

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Provenance of the Bosnian Flysch     

Tamás Mikes  Dominik Christ  Rüdiger Petri  István Dunkl  Dirk Frei  Mária Báldi-Beke  Joachim Reitner  Klaus Wemmer  Hazim Hrvatović  Hilmar von Eynatten 《Swiss Journal of Geoscience》2008,101(1):31-54

Sandwiched between the Adriatic Carbonate Platform and the Dinaride Ophiolite Zone, the Bosnian Flysch forms a c. 3000 m thick, intensely folded stack of Upper Jurassic to Cretaceous mixed carbonate and siliciclastic sediments in the Dinarides. New petrographic, heavy mineral, zircon U/Pb and fission-track data as well as biostratigraphic evidence allow us to reconstruct the palaeogeology of the source areas of the Bosnian Flysch basin in late Mesozoic times. Middle Jurassic intraoceanic subduction of the Neotethys was shortly followed by exhumation of the overriding oceanic plate. Trench sedimentation was controlled by a dual sediment supply from the sub-ophiolitic high-grade metamorphic soles and from the distal continental margin of the Adriatic plate. Following obduction onto Adria, from the Jurassic–Cretaceous transition onwards a vast clastic wedge (Vranduk Formation) was developed in front of the leading edge, fed by continental basement units of Adria that experienced Early Cretaceous synsedimentary cooling, by the overlying ophiolitic thrust sheets and by redeposited elements of coeval Urgonian facies reefs grown on the thrust wedge complex. Following mid-Cretaceous deformation and thermal overprint of the Vranduk Formation, the depozone migrated further towards SW and received increasing amounts of redeposited carbonate detritus released from the Adriatic Carbonate Platform margin (Ugar Formation). Subordinate siliciclastic source components indicate changing source rocks on the upper plate, with ophiolites becoming subordinate. The zone of the continental basement previously affected by the Late Jurassic–Early Cretaceous thermal imprint has been removed; instead, the basement mostly supplied detritus with a wide range of pre-Jurassic cooling ages. However, a c. 80 Ma, largely synsedimentary cooling event is also recorded by the Ugar Formation, that contrasts the predominantly Early Cretaceous cooling of the Adriatic basement and suggests, at least locally, a fast exhumation.  相似文献   

Micromechanical approach to unsaturated water flow in structured geomaterials by two-scale computations     

Adam Szymkiewicz  Jolanta Lewandowska 《Acta Geotechnica》2008,3(1):37-47

This article presents a micromechanical approach to the problem of unsaturated water flow in heterogeneous porous media in transient conditions. The numerical formulation is based on the two-scale model obtained previously by periodic homogenization. It allows for a coupled solution of the non-linear flow equations at macroscopic and microscopic scales and takes into account the macroscopic anisotropy of the medium and the local non-equilibrium of the capillary pressure. The model was applied to simulate two-dimensional water infiltration at constant flux into an initially dry medium containing inclusions of square and rectangular shapes. The numerical results showed the influence of the inclusion–matrix conductivity ratio and the local geometry on the macroscopic behavior. The influence of the conductivity ratio manifested itself by the acceleration or retardation of the onset of the macroscopic water flux at the outlet, while the local geometry (anisotropy) significantly affected the macroscopic spatial distribution of the water flux. Such type of approach can be extended to simulate coupled phenomena (for example hydro-mechanical problems) with evolving local geometry.  相似文献   

Bayes estimation: A novel approach to derivation of internally consistent thermodynamic data for minerals,their uncertainties,and correlations. Part II: Application     

Niranjan D. Chatterjee  Klaus Miller  Walter Olbricht 《Physics and Chemistry of Minerals》1994,21(1-2):50-62

Internally consistent thermodynamic data, including their uncertainties and correlations, are reported for 22 phases of the quaternary system CaO-Al₂O₃-SiO₂-H₂O. These data have been derived by simultaneous evaluation of the appropriate phase properties (PP) and reaction properties (RP) by the novel technique of Bayes estimation (BE). The thermodynamic model used and the theory of BE was expounded in Part I of this paper. Part II is the follow-up study illustrating an application of BE. The input for BE comprised, among others, the a priori values for standard enthalpy of formation of the i-th phase, Δ_f H _i ⁰ , and its standard entropy, S _i ⁰ , in addition to the reaction reversal constraints for 33 equilibria involving the relevant phases. A total of 269 RP restrictions have been processed, of which 107 turned out to be non-redundant. The refined values for Δ_f H _i ⁰ and S _i ⁰ obtained by BE, including their 2σ-uncertainties, appear in Table 4; the Appendix reproduces the corresponding correlation matrix. These data permit generation of computed phase diagrams with 2σ-uncertainty envelopes based on conventional error propagation; Fig. 3 depicts such a phase diagram for the system CaO-Al₂O₃-SiO₂. It shows that the refined dataset is capable of yielding phase diagrams with uncertainty envelopes narrow enough to be geologically useful. The results in Table 4 demonstrate that the uncertainties of the prior values for Δ_f H _i ^Emphasis>0 , given in Table 1, have decreased by up to an order of magnitude, while those for S _i ⁰ improved by a factor of up to two. For comparison, Table 4 also lists the refined Δ_f H _i ⁰ and S _i ⁰ data obtained by mathematical programming (MAP), minimizing a quadratic objective function used earlier by Berman (1988). Examples of calculated phase diagrams are given to demonstrate the advantages of BE for deriving internally consistent thermodynamic data. Although P-T curves generated from both MAP and BE databases will pass through the reversal restrictions, BE datasets appear to be better suited for extrapolations beyond the P-T range explored experimentally and for predicting equilibria not constrained by reversals.  相似文献   

Non-radial stellar oscillations: a perspective from potential scattering (I)     

John A. Adam 《Astrophysics and Space Science》1994,220(2):179-233

This article is the first in a series designed to gain insight into the stellar oscillation problem from a somewhat novel point of view: that of potential scattering, well-known in the quantum mechanical literature. In this paper the known theoretical foundations are developed and applied in the context of the astrophysical problem, wherein the star itself (rather than any portion of it) is the potential which scatters waves and traps them. The basis for the identification of a precisely defined scattering problem is the existence of a linear Schrödinger equation associated both globally (Section 2) and locally (Section 8) with the nonlinear eigenvalue equation for nonradial stellar pulsations. The paper is also designed to be a fairly complete account of the relevant mathematical topics that are germane to a study of this kind. This paper is dedicated to the memory of Professor Zdenèk Kopal, who was a great source of professional encouragement to me during the last fifteen years of his life.  相似文献   

GGR Critical Review of Analytical Developments in 2004–2005     

Janet M. Hergt  L. Paul Bédard  Etienne Deloule  Klaus Peter Jochum  Kathryn L. Linge  Paul J. Sylvester  Matthias Willbold  Jon D. Woodhead 《Geostandards and Geoanalytical Research》2006,30(3):141-142

In 2005 Geostandards and Geoanalytical Research embarked upon a new initiative for its readers. Key researchers in various fields of geoanalytical technique development and their application were identified and invited to provide reviews pertinent to their expertise. As noted in the first of these publications "…instead of revisiting the historical context or decades of development in each analytical technique, the goal here has been to capture a snapshot of "hot topics" across a range of fields as represented in the… literature" (Hergt et al . 2005). Rather than prepare an annual review, a decision was taken earlier this year to provide a biennial summary of progress and accomplishments, in this case for the years 2004–2005. The principal techniques employed in Earth and environmental sciences are covered here, and include laser ablation and multicollector ICP-MS, ICP-AES, thermal ionisation and secondary ion mass spectrometry, as well as neutron activation analysis, X-ray fluorescence and atomic absorption spectrometry. A comprehensive review of the development of reference materials, often essential to these techniques, is also provided. The contributions assembled serve both to keep readers informed of advances they may be unfamiliar with, but also as a means of showcasing examples of the breadth and depth of work being conducted in these fields.  相似文献   

Reference Materials in Geoanalytical Research -Review for 2004 and 2005     

Klaus Peter Jochum  Matthias Willbold 《Geostandards and Geoanalytical Research》2006,30(3):143-156

This review gives an overview of the use and development of reference materials of geochemical and environmental interest in the literature of the years 2004 and 2005. In these years the performance of existing methods has been improved and new geochemical applications using new techniques have been developed. Accordingly, there was an increasing need for new reference materials, especially for in situ microanalysis and for precise stable isotope measurements. In addition, there was a notable trend for further characterisation of existing reference materials, mainly for the platinum-group elements. This review focuses on five topics: reference materials for platinum-group elements, reference glasses for in situ microanalysis, zircon reference materials, isotopic reference materials, and the development and certification of reference materials.  相似文献   

Precambrian fluvial deposits: Enigmatic palaeohydrological data from the c. 2–1.9 Ga Waterberg Group, South Africa     

Patrick G. Eriksson  Adam J. Bumby  Jacobus J. Brümer  Markus van der Neut 《Sedimentary Geology》2006,190(1-4):25-46

Precambrian fluvial systems, lacking the influence of rooted vegetation, probably were characterised by flashy surface runoff, low bank stability, broad channels with abundant bedload, and faster rates of channel migration; consequently, a braided fluvial style is generally accepted. Pre-vegetational braided river systems, active under highly variable palaeoclimatic conditions, may have been more widespread than are modern, ephemeral dry-land braided systems. Aeolian deflation of fine fluvial detritus does not appear to have been prevalent. With the onset of large cratons by the Neoarchaean–Palaeoproterozoic, very large, perennial braided river systems became typical. The c. 2.06–1.88 Ga Waterberg Group, preserved within a Main and a smaller Middelburg basin on the Kaapvaal craton, was deposited largely by alluvial/braided-fluvial and subordinate palaeo-desert environments, within fault-bounded, possibly pull-apart type depositories.

Palaeohydrological data obtained from earlier work in the Middelburg basin (Wilgerivier Formation) are compared to such data derived from the correlated Blouberg Formation, situated along the NE margin of the Main basin. Within the preserved Blouberg depository, palaeohydrological parameters estimated from clast size and cross-bed set thickness data, exhibit rational changes in their values, either in a down-palaeocurrent direction, or from inferred basin margin to palaeo-basin centre. In both the Wilgerivier and Blouberg Formations, calculated palaeoslope values (derived from two separate formulae) plot within the gap separating typical alluvial fan gradients from those which characterise rivers (cf. [Blair, T.C., McPherson, J.G., 1994. Alluvial fans and their natural distinction from rivers based on morphology, hydraulic processes, sedimentary processes, and facies assemblages. J. Sediment. Res. A64, 450–489.]). Although it may be argued that such data support possibly unique fluvial styles within the Precambrian, perhaps related to a combination of major global-scale tectono-thermal and atmospheric–palaeoclimatic events, a simpler explanation of these apparently enigmatic palaeoslope values may be pertinent. Of the two possible palaeohydrological formulae for calculating palaeoslope, one provides results close to typical fluvial gradients; the other formula relies on preserved channel-width data. We suggest that the latter will not be reliable due to problematic preservation of original channel-widths within an active braided fluvial system. We thus find no unequivocal support for a unique fluvial style for the Precambrian, beyond that generally accepted for that period and discussed briefly in the first paragraph.  相似文献