Distribution of platinum-group elements in the Platreef at Overysel,northern Bushveld Complex: a combined PGM and LA-ICP-MS study   总被引：1，自引：0，他引：1  

D. A. Holwell  I. McDonald 《Contributions to Mineralogy and Petrology》2007,154(2):171-190

Detailed mineralogical and laser ablation-inductively coupled plasma-mass spectrometry studies have revealed the physical manifestation of the platinum-group elements (PGE) within the Platreef at Overysel, northern Bushveld Complex, South Africa. The PGE in the Platreef were originally concentrated in an immiscible sulfide liquid along with semi-metals such as Bi and Te. As the sulfide liquid began to crystallize, virtually all the Os, Ir, Ru and Rh partitioned into monosulfide solid solution (mss), which on further cooling, exsolved to form pyrrhotite and pentlandite with Os, Ir and Ru remaining in solid solution in both phases with Rh prefentially partitioning into pentlandite. Platinum, some Pd and Au were concentrated in the residual sulfide liquid after mss crystallization, and were then concentrated in an immiscible late stage melt along with semi metals, which was expelled to the grain boundaries during crystallization of intermediate solid solution (iss) to form Pt and Pd tellurides and electrum around the margins of the sulfide grains. Tiny droplets of this melt trapped in the crystallizing mss and iss cooled to form Pt–Bi–Te microinclusions in all sulfide phases, whilst the excess Pd was accommodated in solid solution in pentlandite. Minor redistribution and recrystallization by hydrothermal fluids occurred around xenoliths and at the very base of the mineralized zone within the footwall, however, the overall lack of secondary alteration coupled with the volatile-poor nature of the gneissic footwall have allowed the preservation of what may be the most ‘primary’ style of Platreef mineralization. The lack of PGM inclusions within early liquidus phases suggests very early sulfur saturation in the Platreef, lending support to theories involving S saturation occurring prior to intrusion of the Platreef, possibly within a staging chamber.  相似文献   

Strain localization as a key to reconciling experimentally derived flow-law data with dynamic models of continental collision     

Susan Ellis  Silke Wissing  Adrian Pfiffner 《International Journal of Earth Sciences》2001,90(1):168-180

Published strength profiles predict strength discontinuities within and/or at the base of continental crust during compression. We use finite element models to investigate the effect of strength discontinuities on continental collision dynamics. The style of deformation in model crust during continued subduction of underlying mantle lithosphere is controlled by: (1) experimental flow-law data; (2) the crustal geotherm; (3) strain localization by erosion; (4) strain-softening and other localization effects. In the absence of erosion and other factors causing strain localization, numerical models with typical geothermal gradients and frictional/ductile rheologies predict diffuse crustal deformation with whole-scale detachment of crust from mantle lithosphere. This prediction is at odds with earlier model studies that only considered frictional crustal rheologies and showed asymmetric, focused crustal deformation. Without localization, model deformation is not consistent with that observed in small collisional orogens such as the Swiss Alps. This suggests that strain localization by a combination of erosion and rheological effects such as strain softening must play a major role in focusing deformation, and that strength profiles derived under constant strain rates and uniform material properties cannot be used to infer crustal strength during collision dynamics.  相似文献   

Cyclic strength and deformation of crushable carbonate sand     

Masayuki Hyodo  Noritaka Aramaki  Masayuki Itoh  Adrian F.L. Hyde 《Soil Dynamics and Earthquake Engineering》1996,15(5):331-336

Cyclic triaxial tests have been carried out on a skeletal carbonate sand from the west coast of Eire. Results are presented for undrained cyclic shear tests on samples with 80% of relative density consolidated under both isotropic and anisotropic conditions. Failure was defined as a 5% double amplitude cyclic strain and a 5% peak axial strain for stress-reversal and non-reversal stress conditions, respectively. Using this definition the cyclic strength for isotropically consolidated samples was affected by the confining pressure although the angular platey nature of the sand resulted in higher cyclic strengths than for a comparable silica sand. For anisotropically consolidated samples the cyclic strength increased with increasing initial static shear stress while on the other hand the cyclic strength normalised in the usual way with respect to the initial confining pressure decreased as this pressure increased.  相似文献   

Evidence of polycyclic aromatic hydrocarbon (PAH) exposure in fish from the Antarctic peninsula     

Susanne J. McDonald  Mahlon C. Kennicutt  II  James M. Brooks 《Marine pollution bulletin》1992,25(9-12):313-317

PAH exposure was assessed in fish from Arthur Harbor, Antarctica and sites remote from human activities by measuring the concentrations of polycyclic aromatic hydrocarbon (PAH) metabolites in bile and PAH in tissues and stomach contents. The highest concentrations of biliary metabolites and tissue PAH were present in fish captured near an Argentine supply ship (Bahia Paraiso) that ran aground in Arthur Harbor in 1989. The presence of biliary PAH metabolites in fish collected near Palmer Station, a small US scientific station in Arthur Harbor, suggests low level exposure to contaminants. However, PAH tissue concentrations in fish from Palmer Station were similar to those from remote sites. Both tissue PAH and metabolite concentrations were low in fish captured at sites remote from human activities. The confirmation of PAH metabolites in the bile of fish from Arthur Harbor is direct evidence that the presence of humans has resulted in Antarctic fish being exposed to petroleum-derived PAH.  相似文献   

Metasomatic overprinting by juvenile igneous fluids,Igdlerfigsalik, South Greenland     

Adrian Finch 《Contributions to Mineralogy and Petrology》1995,122(1-2):11-24

The late Igdlerfigsalik centre, part of the Igaliko nepheline syenite complex in the Gardar Province, S Greenland, is bounded to the N and E by compositionally similar, earlier syenites forming the early Igdlerfigsalik and South Qôroq centres. In a circa 1 km wide zone parallel to its contact with late Igdlerfigsalik, the South Qôroq centre shows recrystallisation and alteration of mafic phases. South Qôroq therefore comprises two zones, termed the “unaltered” and the “recrystallised” zones. A study of the biotites from the rocks of the area of the present study has demonstrated variations in biotite chemistry, notably variations in elements inferred to reside on the octahedral and hydroxyl sites. Samples were chosen to provide a representative selection from each centre, avoiding pegmatites and late-stage veins. Electron probe microanalyses demonstrate little Cl in these biotites. Fluorine contents of some biotites can be demonstrated to vary with Fe/(Fe+Mg) and ∑(octahedral Al and Ti). Statistical analysis of the data sets as a whole, however, does not demonstrate simple relationships between fluorine content and these parameters and more complex crystallographic controls over fluorine uptake are inferred. Despite these variations, the relative fluorine contents characteristic of each centre can be determined, which, it is believed, reflect the characteristic F activity of fluids associated with each period of magmatism. In South Qôroq, the unaltered zone has a distinctive F-content in biotite, reflecting the original F-content of fluids associated with South Qôroq magmatism. However in the recrystallised zone, the F-contents are distinct, more closely resembling F-contents characteristic of late Igdlerfigsalik rocks. Reaction between a fluorine-rich, younger fluid and older fluorine-poor rocks is inferred. Despite evidence in the micas for fluid-rock interaction, whole-rock chemical changes are irregular in nature and appear not to conform to simple trends. Mass-balance equations are therefore unable to predict the levels of fluid-rock interaction. Similar exchange between late-stage fluids from younger centres and pre-existing rocks may be commonplace in igneous plutonic environments, and fluorine in micas may provide a relatively sensitive guide to fluid-rock interactions.  相似文献   

Compressional angles of isallo stress theory for a circular-cylindrical,spherical and elliptic-cylindrical elastic inhomogeneity in an elastic medium     

Hans Pulpan  Adrian E. Scheidegger 《Pure and Applied Geophysics》1969,76(1):147-152

Summary The compressional angle of isallo stress theory for the case of a cylindrical (circular and elliptic) and spherical subsurface inhomogeneity, assuming that the conjugate fracture surfaces are inclined at a Mohr angle of 30° toward the largest compression, has been calculated. The solution for a spherical and cylindrical inclusion in an infinite medium subject to a uniform stress field (at infinity) were taken as the basis for the stress analysis. The stress angle was then calculated for the mentioned types of inclusions.  相似文献   

Directional permeability of porous media to homogeneous fluids     

Dr. Adrian E. Scheidegger 《Pure and Applied Geophysics》1954,28(1):75-90

Summary Investigations have shown that in groundwater- and oil-bearing strata there are preferential directions of flow that are often maintained over wide areas.Johnson & Hughes (1948, see Ref.) analysed a series of oil well cores by cutting them into small horizontal plugs and they obtained directional permeabilities which they plotted in the form of polar graphs. They were not able to give a physical explanation of this phenomenon. On the other hand, there exists a theory of permeability in which the latter is represented as a symmetric tensor. This theory has been developed byFerrandon (1948, see Ref.), but no experimental substantiation of it seems ever to have been attempted.In the present paper, the author undertakes to compare the two sets of findings. FromFerrandon's theory, the directional permeabilities (denoted byk) corresponding to the experiments ofJohnson & Hughes are calculated and it is shown thatk ^–1/2 if plotted as polar graph, should form an ellipse. The data ofJohnson & Hughes are then are drawn. In this manner, a substantiation of the tensor theory ofFerrandon is obtained.

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Zusammenfassung Untersuchungen der Permeabilität von Grundwasser und Erdöl führenden Gesteinsschichten haben gezeigt, dass dieselbe in vielen Fällen richtungsabhängig ist. Hierbei bleibt die Richtung extremaler Permeabilität oft über weite Gebiete konstant.Johnson & Hughes untersuchten eine Reihe von Bohrkernen von Oelquellen auf Richtungsabhängigkeit der Permeabilität. Hierzu schnitten sie aus denselben kleine, waagrechte Stücke, bestimmten deren Permeabilität und stellten das Ergebnis ihrer Messungen in der Form von Permeabilitätspolardiagrammen dar. Sie waren nicht im Stande, eine theoretische Erklärung der erhaltenen Kurven zu geben. Auf der anderen Seite existiert eine Theorie der Permeabilität, wobei die letztere als symmetrischer Tensor behandelt wird. Diese Theorie wurde vonFerrandon vorgeschlagen; es scheint aber, dass keine experimentelle Bestätigung davon je versucht worden ist.In der vorliegenden Arbeit vergleicht der Verfasser die zwei Typen von Untersuchungen. Nach derFerrandon'schen Theorie wird die «gerichtete» Permeabilität (mitk bezeichnet), die den Experimenten vonJohnson & Hughes entspricht, berechnet. Es wird gezeigt, dassk ^–1/2, als Polardiagramm dargestellt, die Gestalt einer Ellipse haben sollte. Die Resultate vonJohnson & Hughes werden dann in die Form vonk ^–1/2 umgerechnet und als entsprechende Polardiagramme dargestellt. In dieser Weise wird eine experimentelle Bestätigung der Tensortheorie vonFerrandon erhalten.

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Published by Permission of Imperial Oil Limited, Calgary, Alberta (Canada).  相似文献   

Relativistic electrons from solar flares     

T. L. Cline  F. B. McDonald 《Solar physics》1968,5(4):507-530

Observations of interplanetary relativistic electrons from several solar-flare events monitored through 1964 to mid-1967 are presented. These are the first direct spectral measurements and time histories, made outside the magnetosphere, of solar-flare electrons having relativistic velocities. The 3- to 12-MeV electrons detected have kinetic energies about two orders of magnitude higher than those solar electrons previously studied in space, and measurements of both the time histories and energy spectra for a number of events in the present solar cycle were carried out. These measurements of interplanetary electrons are also directly compared with solar X-ray data and with measurements of related interplanetary solar protons.The time histories of at least four electron events show fits to the typical diffusion picture. A demonstrated similarity between the electron and the medium-energy proton fits for the event of 7 July, in particular, indicates that at these electron energies, but over several orders of magnitude of rigidity, whatever diffusion does take place is very nearly on a velocity, rather than a rigidity or an energy, basis. Diffusion-fit time histories varied as a function of T ₀ also indicate that the electrons in certain flare events originate at times near the X-ray and microwave burst, establishing their likely identity as the same electrons which cause the impulsive radiations. Also, the energy spectra and total numbers of the interplanetary electrons, compared with those of the flare-site electrons calculated from X-ray and microwave measurements, indicate that probably a small fraction of flare electrons escape into interplanetary space.  相似文献   

Meteorological monitoring of an active volcano: Implications for eruption prediction     

Jenni Barclay  Jade E. Johnstone  Adrian J. Matthews   《Journal of Volcanology and Geothermal Research》2006,150(4):241-358

Rainfall data collected on and around the Soufriere Hills Volcano, Montserrat between 1998 and 2003 were analysed to assess the impact on primary volcanic activity, defined here as pyroclastic flows, dome collapses, and explosions. Fifteen such rainfall-triggered events were identified. If greater than 20 mm of rain fell on a particular day, the probability of a dome collapse occurring on that day increased by a factor of 6.3% to 9.2%, compared to a randomly chosen day. Similarly, the probability of observing pyroclastic flows and explosions on a day with > 20 mm of rainfall increased by factors of 2.6 and 5.4, respectively. These statistically significant links increased as the rainfall threshold was increased. Seventy percent of these rainfall-induced dome collapse episodes occurred on the same calendar day (most within a few hours) as the onset of intense rainfall, but an extra 3 occurred one or two calendar days later. The state of the volcano was important, with the rainfall–volcanic activity link being strongest during periods of unstable dome growth and weakest during periods of no dome growth or after a recent major collapse.Over 50% of the heavy rain days were associated with large-scale weather systems that can potentially be forecast up to a few days ahead. However, the remaining heavy rain days were associated with small-scale, essentially unpredictable weather systems. There was significant variability in the amount of rainfall recorded by different rain gauges, reflecting topographic variations around the volcano but also the inherent small-scale variability within an individual weather system. Hence, any monitoring/warning program is recommended to use a network, rather than just a single gauge. The seasonal cycle in rainfall was pronounced, with nearly all the heavy rain days occurring in the May–December wet season. Hence, the dome was at its most vulnerable at the beginning of the wet season after a period of uninterrupted growth. Interannual variability in rainfall was related to tropical Pacific and Atlantic sea surface temperature anomalies, and holds out the prospect of some limited skill in volcanic hazard forecasts at even longer lead times.  相似文献   

Modeling long-period noise in kinematic GPS applications     

Adrian A. Borsa  Jean-Bernard Minster  Bruce G. Bills  Helen A. Fricker 《Journal of Geodesy》2007,81(2):157-170

We develop and test an algorithm for modeling and removing elevation error in kinematic GPS trajectories in the context of a kinematic GPS survey of the salar de Uyuni, Bolivia. Noise in the kinematic trajectory ranges over 15 cm and is highly autocorrelated, resulting in significant contamination of the topographic signal. We solve for a noise model using crossover differences at trajectory intersections as constraints in a least-squares inversion. Validation of the model using multiple realizations of synthetic/simulated noise shows an average decrease in root-mean-square-error (RMSE) by a factor of four. Applying the model to data from the salar de Uyuni survey, we find that crossover differences drop by a factor of eight (from an RMSE of 5.6 to 0.7 cm), and previously obscured topographic features are revealed in a plan view of the corrected trajectory. We believe that this algorithm can be successfully adapted to other survey methods that employ kinematic GPS for positioning.  相似文献