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101.
Sulfur cycling in a stratified euxinic lake with moderately high sulfate: Constraints from quadruple S isotopes 总被引:1,自引:0,他引:1
Aubrey L. Zerkle Alexey Kamyshny Jr. Lee R. Kump James Farquhar Harry Oduro Michael A. Arthur 《Geochimica et cosmochimica acta》2010,74(17):4953-154
We present a 3-year study of concentrations and sulfur isotope values (δ34S, Δ33S, and Δ36S) of sulfur compounds in the water column of Fayetteville Green Lake (NY, USA), a stratified (meromictic) euxinic lake with moderately high sulfate concentrations (12-16 mM). We utilize our results along with numerical models (including transport within the lake) to identify and quantify the major biological and abiotic processes contributing to sulfur cycling in the system. The isotope values of sulfide and zero-valent sulfur across the redox-interface (chemocline) change seasonally in response to changes in sulfide oxidation processes. In the fall, sulfide oxidation occurs primarily via abiotic reaction with oxygen, as reflected by an increase in sulfide δ34S at the redox interface. Interestingly, S isotope values for zero-valent sulfur sampled at this time still reflect production and recycling by phototrophic S-oxidation. In the spring, sulfide S isotope values suggest an increased input from phototrophic oxidation, consistent with a more pronounced phototroph population at the chemocline. This trend is associated with smaller fractionations between sulfide and zero-valent sulfur, suggesting a metabolic rate control on fractionation similar to that for sulfate reduction. Comparison of our data with previous studies indicates that the S isotope values of sulfate and sulfide in the deep waters are remarkably stable over long periods of time, with consistently large fractionations of up to 58‰ in δ34S. Models of the δ34S and Δ33S trends in the deep waters (considering mass transport via diffusion and advection along with biological processes) require that these fractionations are a consequence of sulfur compound disproportionation at and below the redox interface in addition to large fractionations during sulfate reduction. The large fractionations during sulfate reduction appear to be a consequence of the high sulfate concentrations and the distribution of organic matter in the water column. The occurrence of disproportionation in the lake is supported by profiles of intermediate sulfur compounds and by lake microbiology, but is not evident from the δ34S trends alone. These results illustrate the utility of including minor S isotopes in sulfur isotope studies to unravel complex sulfur cycling in natural systems. 相似文献
102.
Relations between integrable systems in plane and curved spaces 总被引:1,自引:0,他引:1
We consider trajectory isomorphisms between various integrable systems on an n-dimensional sphere S
n
and a Euclidean space . Some of the systems are classical integrable problems of Celestial Mechanics in plane and curved spaces. All the systems
under consideration have an additional first integral quadratic in momentum and can be integrated analytically by using the
separation of variables. We show that some integrable problems in constant curvature spaces are not essentially new from the
viewpoint of the theory of integration, and they can be analyzed using known results of classical Celestial Mechanics. 相似文献
103.
中蒙俄高铁建设是促进中蒙俄交通基础设施互联互通、打造国际陆上交通走廊的重要举措,是中蒙俄经济走廊建设的重要突破口。科学合理地布局中蒙俄高铁线路、规避高铁建设面临的不利影响和风险,急需理清高铁建设的影响因子,揭示其作用机理和空间分布格局,制定针对性强的防控对策。本文分析了中蒙俄高铁建设的主要影响因子,阐明了各类因子对高铁建设的影响机理,通过构建一种综合集成的影响指数评估模型(IIIEM),量化评估了不同地区各类影响因子的影响指数,揭示了其空间分布格局,并据此制定了消除影响的中蒙俄高铁东线和西线的线路布局建议方案。提出通过“高铁换资源、高铁换市场”等互利共赢创新合作模式,消除经济影响;加强沟通和技术展示,降低社会影响;通过设置缓冲区及高科技手段,规避生态风险;构建中蒙俄跨境地区三大生态风险跨国联合防控体系,加强政策对接,促进中蒙俄经济一体化等防控对策及保障措施。本研究将为中蒙俄高铁建设线路科学合理布局、风险防控提供科技支撑和决策参考。 相似文献
104.
This article provides an overview of the recent modelling results on Russia's GHG emission trends, and reviews the success of mitigation policies in order to establish whether Russia's domestic target seems feasible. Various Russian GHG emission scenarios indicate that Russia's domestic target – emissions 25% below the 1990 level by 2020 – is not far from the business-as-usual emissions trajectory. In particular, two factors could deliver the required emissions reductions: the currently declining gross domestic product (GDP) growth and ongoing domestic mitigation policies. The former is more likely to secure the target level of emissions, because GDP growth has been contracting significantly in comparison to earlier forecasts of 3–5% annual growth, and this trend is expected to continue. The latter option – success with domestic mitigation measures – seems less likely, given the various meta-barriers to policy implementation, and the marginality of mitigation policies, problems with law-making processes, bureaucratic tradition, and informality of legislative and implementation systems.Policy relevanceThis article provides an assessment of the stringency of Russia's domestically set emissions limitation target by 2020 and the chances of Russia, the fourth largest GHG emitter in the world, achieving it. We base our assessment on a number of recent key sources that analyse Russia's GHG emission paths by applying socio-economic models, which have only been available in the Russian language prior to this publication. This knowledge is applicable for use by other negotiation parties to compare Russia's efforts to mitigate climate change to their own, and thus makes a contribution to facilitating a more equal burden-sharing of climate commitments under the future climate change agreement. 相似文献
105.
106.
107.
Nikolay Bonev Maria Ovtcharova-Schaltegger Robert Moritz Peter Marchev Alexey Ulianov 《Geodinamica Acta》2013,26(3-4):207-229
Field, geochemical, and geochronologic data of high-grade basement metamafic and evolved rocks are used to identify the nature and timing of pre-Alpine crustal growth of the Rhodope Massif. These rocks occur intrusive into clastic-carbonate metasedimentary succession. Petrography and mineral chemistry show compositions consistent with Alpine amphibolite-facies metamorphism that obliterated the original igneous textures of the protoliths. Bulk-rock geochemistry identifies low-Ti tholeiitic to calc-alkaline gabbroic-basaltic and plagiogranite precursors, with MORB-IAT supra-subduction zone signature and trace elements comparable to modern back-arc basalts. The U-Pb zircon dating revealed a mean age of 455 Ma for the magmatic crystallization of the protoliths that contain inherited Cambrian (528–534 Ma) zircons. Carboniferous, Jurassic, and Eocene metamorphic events overprinted the Ordovician protoliths. The radiometric results of the metamorphic rocks demonstrate that Ordovician oceanic crust was involved in the build-up of the Rhodope high-grade basement. Dating of Eocene-Oligocene volcanic rocks overlying or cross-cutting the metamorphic rocks supplied Neoproterozoic, Ordovician and Permo-Carboniferous xenocrystic zircons that were sampled en route to the surface from the basement. The volcanic rocks thus confirm sub-regionally present Neoproterozoic and Paleozoic igneous and metamorphic basement. We interpret the origin of the Middle-Late Ordovician oceanic magmatism in a back-arc rift-spreading center propagating along peri-Gondwanan Cadomian basement terrane related to the Rheic Ocean widening. The results highlight the presence of elements of Cadomian northern Gondwana margin in the high-grade basement and record of Rheic Ocean evolution. The eastern Rhodope Massif high-grade basement compared to adjacent terranes with Neoproterozoic and Cambro-Ordovician evolution shares analogous tectono-magmatic record providing a linkage among basement terranes incorporated in the Alpine belt of the north Aegean region. 相似文献
108.
A report by Soviet delegates to the 15th Congress of the International Society for Photogrammetry and Remote Sensing provides a forum for a Soviet assessment of foreign achievements in the practical application of remote sensing in various fields of economic activity, particularly oil and gas exploration, prospecting for metallic minerals, forestry, and oceanography. Special emphasis is given to digital image processing for land-use classification, a field in which Soviet researchers are becoming increasingly involved. The Congress is described as contributing greatly to the development of common data processing methodologies and the exchange of information and opinions on common problems. Translated from: Geodeziya i kartografiya, 1985, No. 4, pp. 53-58. 相似文献
109.
Dmitri V. Alexandrov Irina A. Bashkirtseva Alexey P. Malygin Lev B. Ryashko 《Pure and Applied Geophysics》2013,170(12):2273-2282
The influence of stochastic fluctuations in the atmosphere and in the ocean caused by different occasional phenomena (noises) on dynamic processes of sea ice growth with a mushy layer is studied. It is shown that atmospheric temperature variances substantially increase the sea ice thickness, whereas dispersion variations of turbulent flows in the ocean to a great extent decrease the ice content produced by false bottom evolution. 相似文献
110.
Kolguev Island in the Russian Arctic has a unique tundra ecosystem and an indigenous Nenets population whose livelihood is traditionally based on reindeer herding. The Nenets faced a major crisis in 2013–2014 when the reindeer population collapsed. Widely different explanations for this collapse were put forward. This lack of a shared perspective points at the failure of genuine joint knowledge production (JKP) in the island’s UNEP–GEF’s ECORA project (2004–2009). The ECORA project aimed to achieve integrated ecosystem management by stimulating dialog and mutual learning among indigenous people, state agencies, and scientists. This paper analyses the failure of ECORA’s JKP, using a recently developed framework of conditions for successful JKP. The results suggest that ECORA met none of these conditions. It failed at bringing the scientific and indigenous knowledge systems together, and the produced knowledge did not resonate with indigenous people’s perception of living in Kolguev. 相似文献