Hydrological and geomorphological criteria to evaluate the dispersion risk of waste sludge generated by the Aznalcollar mine spill (SW Spain)   总被引：2，自引：0，他引：2  

G. Benito  Alfonso Benito-Calvo  Francesc Gallart  Juan Pedro Martín-Vide  David Regües  Ernest Bladé 《Environmental Geology》2001,40(4-5):417-428

Following the Aznalcóllar pyrite mine disaster (Seville, Spain) which caused the spilling of some 4.5?hm³ of acid water, the floodplains of the rivers Agrio and Guadiamar were rapidly cleaned of waste sludge. However, despite the efficiency of cleaning activities, there is still evidence of a fine superficial layer of sludge and some soil contamination, with the consequent risk of remobilisation of the pollutants by water erosion. There is much concern that these contaminated sediments may affect the precious ecosystems of the Doñana National Park and the Guadalquivir marshlands. This report describes the evaluation of the risk of mobilisation of the waste sludge through (1) detailed geomorphological analysis, indicating potential areas of erosion-sedimentation on the floodplains of the rivers Agrio and Guadiamar, and predicted dynamics of the waste sludge, and (2) evaluation of the potential dispersion of the waste sludge provoked by future flood events, including hydraulic calculations to model channel flow and the analysis of the texture of the sludge to obtain critical transport and sedimentation values. Findings suggest that the waste sludge is likely to be transported and deposited within the Doñana National Park during future flood events.  相似文献   

How to improve attribution of changes in drought and flood impacts     

Heidi Kreibich  Veit Blauhut  Jeroen C.J.H. Aerts  Laurens M. Bouwer  Henny A.J. Van Lanen  Alfonso Mejia 《水文科学杂志》2020,65(Z2):1-18

ABSTRACT

For the development of sustainable, efficient risk management strategies for the hydrological extremes of droughts and floods, it is essential to understand the temporal changes of impacts, and their respective causes and interactions. In particular, little is known about changes in vulnerability and their influence on drought and flood impacts. We present a fictitious dialogue between two experts, one in droughts and the other in floods, showing that the main obstacles to scientific advancement in this area are both a lack of data and a lack of commonly accepted approaches. The drought and flood experts “discuss” available data and methods and we suggest a complementary approach. This approach consists of collecting a large number of single or multiple paired-event case studies from catchments around the world, undertaking detailed analyses of changes in impacts and drivers, and carrying out a comparative analysis. The advantages of this approach are that it allows detailed context- and location-specific assessments based on the paired-event analyses, and reveals general, transferable conclusions based on the comparative analysis of various case studies. Additionally, it is quite flexible in terms of data and can accommodate differences between floods and droughts.  相似文献   

A tertiary fold and thrust belt in the Valle del Cauca Basin, Colombian Andes     

C.A. Alfonso  P.E. Sacks  D.T. Secor  J. Rine  V. Perez 《Journal of South American Earth Sciences》1994,7(3-4)

Surface geology and heophysical data, supplemented by regional structural interpretations, indicate that the Valle del Cauca basin and adjacent areas in west-central Colombia form a west-vergent, basement-involved fold and thrust belt. This belt is part of a Cenozoic orogen developed along the west side of the Romeral fault system. Structural analysis and geometrical constraints show that the Mesozoic ophiolitic basement and its Cenozoic sedimentary cover are involved in a “thick-skinned” west-vergent foreland style deformation. The rocks are transported and shortened by deeply rooted thrust faults and stacked in imbricate fashion. The faults have a NE---SW regional trend, are listric in shape, developed as splay faults which are interpreted as joining a common detachment at over 10 km depth. The faults carry Paleogene sedimentary strata and Cretaceous basement rocks westward over Miocene strata of the Valle del Cauca Basin. Fold axes trend parallel or sub parallel to the thrust faults. The folds are westwardly asymmetrical with parallel to kink geometry, and are interpreted to be fault-propagation folds stacked in an imbricate thrust system. Stratigraphic evidence suggests that the Valle del Cauca basin was deformed between Oligocene and upper Miocene time. The kinematic history outlined above is consistent with an oblique convergence between the Panama and South American plates during the Cenozoic.A negative residual Bouguer anomaly of 20–70 mgls in the central part of the Valle del Cauca basin indicates that a substantial volume of low density sedimentary rocks is concealed beneath the thrust sheets exposed at the land surface. The hydrocarbon potential of the Valle del Cauca should be reevaluated in light of the structural interpretations presented in this paper.  相似文献   

Comment on “The solubility of aragonite in seawater”     

Alfonso Mucci  Frank J. Millero  John W. Morse 《Geochimica et cosmochimica acta》1982,46(1):105-107

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The incorporation of Mg²⁺ and Sr²⁺ into calcite overgrowths: influences of growth rate and solution composition     

Alfonso Mucci  John W Morse 《Geochimica et cosmochimica acta》1983,47(2):217-233

The concentrations of Mg²⁺ and Sr²⁺ incorporated within calcite overgrowths precipitated from seawater and related solutions, determined at 25°C, were independent of the precipitation rate over approximately an order of magnitude. The saturation states used to produce this range of precipitation rates varied from 3 to 17 depending on the composition of the solution.The amount of Mg²⁺ incorporated in the overgrowths was not directly proportional to $\text{Mg}{}^{\mathrm{2+}}\text{Ca}{}^{\mathrm{2+}}$ in solution over the entire range (1–20) of ratios studied. Below a ratio of 7.5, the overgrowth was enriched in MgCO₃ relative to what is predicted by the constant distribution coefficient measured above a ratio of 7.5. This increased MgCO₃ correlates with the relative enrichment of adsorbed Mg²⁺. Above a ratio of 7.5 the concentration of MgCO₃ in the calcite overgrowths followed a classical thermodynamic behavior characterized by a constant distribution coefficient of 0.0123 (±0.008 std dev).The concentration of SrCO₃ incorporated in the overgrowths was linearly related to the MgCO₃ content of the overgrowths, and is attributed to increased solubility of SrCO₃ in calcite due to the incorporation of the smaller Mg²⁺ ions.The kinetic data indicate that the growth mechanism involves the adsorption of the cations on the surface of the calcite prior to dehydration and final incorporation. It is suggested that dehydration of cations at the surface is the rate controlling step.  相似文献   

DFT study of the cation arrangements in the octahedral and tetrahedral sheets of dioctahedral 2:1 phyllosilicates     

Alfonso Hernández-Laguna  Elizabeth Escamilla-Roa  Vicente Timón  Martin T. Dove  C. Ignacio Sainz-Díaz 《Physics and Chemistry of Minerals》2006,33(10):655-666

Quantum mechanical calculations based on the density functional theory (DFT) are used to study the crystal structures of dioctahedral 2:1 phyllosilicates. The isomorphous cation substitution is investigated by exploring different substitutions of octahedral Al³⁺ by Mg²⁺ or Fe³⁺, tetrahedral substitution of Si⁴⁺ by Al³⁺, and different interlayer cations (IC) (Na⁺, K⁺, Ca²⁺, and Mg²⁺). Samples with different kinds of layer charges are studied: only tetrahedrally charged, only octahedrally charged, or mixed octahedral/tetrahedral charged. The effect of the relative arrangements of these substitutions on the lattice parameters and total energy is studied. The experimental observation of segregation tendency of Fe³⁺ and dispersion tendency of Mg²⁺ in the octahedral sheet is reproduced and explained with reference to the relative energies of the octahedral cation arrangements. These energies are higher than those due to the IC/tetrahedral and IC/octahedral relative arrangements. The tetrahedral and octahedral substitutions that generate charged layers also tend to be dispersed. The octahedral cation exchange potentials change with the IC-charge/ionic radius value.  相似文献   

Late Neoproterozoic crustal growth in the European Variscides: Nd isotope and geochemical evidence from the Sierra de Córdoba Andesites (Ossa-Morena Zone, Southern Spain)     

Christian Pin  Eladio Lin  Emilio Pascual  Teodosio Donaire  Alfonso Valenzuela 《Tectonophysics》2002,352(1-2)

Because the Hercynian overprint was extremely weak, the Sierra de Córdoba (southeastern Ossa-Morena Zone, OMZ) provides an excellent opportunity to study the tectonic evolution of sequences deposited close to the Late Neoproterozoic–Early Palaeozoic boundary. In order to put constraints on the sources and geodynamic significance of the Late Proterozoic magmatism, a representative set of 18 igneous rocks, and 3 interbedded sedimentary rocks from the San Jerónimo Formation have been studied for major and trace element geochemistry and for the Sm–Nd isotopic systematics. The igneous rocks are generally porphyritic to microporphyritic andesites, with abundant plagioclase (±amphibole) phenocrysts. With the exception of two intrusive rocks, possibly not related to the Late Proterozoic episode, all the samples display positive _{Nd550 Ma} values, ranging from +2.9 to +7.6. Most of them, with +4<_{Nd550 Ma}<+6, exhibit LREE enrichment, high La/Nb ratios, and elevated Zr/Nb ratios ranging from 21 to 32. There is no obvious correlation between the shape of REE patterns, La/Nb ratios and _{Nd550 Ma} values, precluding simple models of late-stage interaction with typical crustal components having low _Nd and high LREE/HREE and La/Nb ratios. Based on their major element composition and enriched, continental crust-like trace element characteristics, combined with distinctly positive _Nd initial values, the Córdoba andesites document an episode of crustal growth through the addition of calc-alkaline magmas, extracted from a mantle reservoir which was strongly depleted in LREE on a time-integrated basis. The occurrence of interlayered sediments of continental provenance (negative _Nd values) does not favour a purely ensimatic arc setting, remote from continental land masses, for this subduction-related magmatism, but the geochemical data suggest an active margin environment located on relatively juvenile crust. In any case, the Córdoba andesites document the addition of materials chemically similar to the bulk continental crust which were extracted from mantle sources with strong time-integrated LREE depletion. Therefore, they provide evidence for crustal growth related to Cadomian orogenic events during Late Proterozoic times.  相似文献   

Geophysical Survey and Archaeological Data at Masseria Grasso (Benevento,Italy)     

Enzo Rizzo  Alfonso Santoriello  Luigi Capozzoli  Gregory De Martino  Cristiano Benedetto De Vita  Daniela Musmeci  Felice Perciante 《Surveys in Geophysics》2018,39(6):1201-1217

The use of geophysical methods in metrology is a significant tool within the wide research topic of landscape archaeology context. Since 2011, the Ancient Appia Landscapes Project aims to recognize dynamics, shapes and layout of the ancient settlement located along the Appia road east of Benevento, and cyclical elements and human activities that influenced the choice of landscapes. The integration of geophysical data with an archaeological infra-site analysis allowed us to investigate the area of Masseria Grasso, about 6 km from Benevento (Campania region, Italy). In this framework, an archaeogeophysical approach (Geomagnetic and Ground Penetrating Radar) was adopted for detecting anomalies potentially correlated with buried archaeological evidences. The geomagnetic results have given a wide knowledge of buried features in a large survey highlighting significant anomalies associated with the presence of buildings, roads and open spaces. These geophysical results permitted us to define the first archaeological excavations and, successively, a detailed Ground Penetrating Radar approach has been provided highlighting the rooms and paved spaces. The overlap between archaeological dataset and geophysical surveys has also allowed recognizing the path of the ancient Appia road near the city of Benevento and hypothesize the settlement organization of the investigated area, which has been identified with the ancient Nuceriola.  相似文献   

The Differential Geochemical Behavior of Arsenic and Phosphorus in the Water Column and Sediments of the Saguenay Fjord Estuary, Canada     

Alfonso Mucci  Louis-Filip Richard  Marc Lucotte  Constance Guignard 《Aquatic Geochemistry》2000,6(3):293-324

The distribution and partitioning of dissolved andparticulate arsenic and phosphorus in the water columnand sediments of the Saguenay Fjord in Quebec, Canada,are compared. In addition, selective and/or sequentialextractions were carried out on the suspendedparticulate matter (SPM) and solid sediments tocontrast their geochemical behaviors in this naturalaquatic system.Results of our analyses show that both arsenic andsoluble reactive phosphate are actively scavenged fromthe water column by settling particles. Upon theiraccumulation at the sediment-water interface some Asand P may be released to porewaters following thedegradation of organic matter to which they areassociated. The porewater concentrations are, however,limited by their strong affinity for authigenic,amorphous iron oxyhydroxides which accumulate in theoxic sediments near the sediment-water interface.The geochemical behavior of arsenic and phosphorusdiverge most strikingly upon the development of anoxicconditions in the sediments. Following their burial inthe anoxic zone, amorphous iron oxyhydroxides arereduced and dissolved, releasing phosphate and arsenicto the porewaters. We observed, however, thatporewater arsenic concentrations increase at shallowerdepths than phosphate in the sediments. The reductionof arsenate, As(V), to arsenite, As(III), and itsdesorption prior to the reductive dissolution of thecarrier phase(s) may explain this observation.Driven by the strong concentration gradientestablished in the suboxic zone, phosphate diffuses uptowards the oxic layer where it is readsorbed byauthigenic iron oxyhydroxides. In the organic-rich andrapidly accumulating sediments at the head of theFjord, porewater sulfate depletion and the resultingabsence of a sulfide sink for Fe(II), may lead to theformation of vivianite in the fermentation zone, apotential sink for phosphate. Arsenite released to theporewaters in the suboxic and anoxic zones of thesediments diffuses either down, where it is adsorbedto or incorporated with authigenic iron sulfides, orup towards the oxic boundary. Arsenite appears tomigrate well into the oxic zone where it may beoxidized by authigenic manganese oxides before beingadsorbed by iron oxyhydroxides present at the samedepth. Whereas, in the absence of authigenic carbonatefluorapatite precipitation, the ability of oxicsediments to retain mineralized phosphate is afunction of their amorphous iron oxyhydroxide content,arsenic retention may depend on the availability ofmanganese oxides, the thickness of the oxic layer and,its co-precipitation with iron sulfides at depth.  相似文献   

Projected bispectrum in spherical harmonics and its application to angular galaxy catalogues     

Licia Verde  Alan F. Heavens  Sabino Matarrese 《Monthly notices of the Royal Astronomical Society》2000,318(2):584-598

We present a theoretical and exact analysis of the bispectrum of projected galaxy catalogues. The result can be generalized to evaluate the projection in spherical harmonics of any 3D bispectrum and therefore has applications to cosmic microwave background and gravitational lensing studies.
By expanding the 2D distribution of galaxies on the sky in spherical harmonics, we show how the three-point function of the coefficients can be used in principle to determine the bias parameter of the galaxy sample. If this can be achieved, it would allow a lifting of the degeneracy between the bias and the matter density parameter of the Universe, which occurs in linear analysis of 3D galaxy catalogues. In previous papers, we have shown how a similar analysis can be done in three dimensions, and we show here through an error analysis and by implementing the method on a simulated projected catalogue that ongoing three-dimensional galaxy redshift surveys (even with all the additional uncertainties introduced by partial sky coverage, redshift-space distortions and smaller numbers) will do far better than all-sky projected catalogues with similar selection function.  相似文献