Surface ozone measurements in the Venezuelan tropical savannah     

Eugenio Sanhueza  Kathleen H. Octavio  Alfonso Arrocha 《Journal of Atmospheric Chemistry》1985,2(4):377-385

A one-year set of surface ozone measurements in a four-station network located in the Venezuelan savannah is reported. The diurnal ozone variation is typical of continental stations with a maximum in the afternoon, when vertical turbulent mixing is strongest. The annual O₃ average concentration, based on the monthly averages of daily maxima, was 17±2 ppb, which is in good agreement with values reported for similar latitudes. The boundary-layer ozone levels did not fall below 8 ppb, in contrast with previous sporadic measurements made in tropical latitudes. No evidence was found that mesoscale O₃ downdrafts in the ITCZ in the South American continent are an important source of surface ozone. Finally, it is suggested that the relatively high ozone levels observed at the end of the dry season are probably of photochemical origin.  相似文献   

Geomagnetic secular variation of Bransfield Strait (Western Antarctica) from analysis of marine crossover data     

M. Catalán  L. M. Agudo  Alfonso Muñoz 《Geophysical Journal International》2006,165(1):73-86

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Effects of the baroclinic adjustment on the tropopause in the NCEP–NCAR reanalysis     

Alessandro Dell’Aquila  Paolo M. Ruti  Alfonso Sutera 《Climate Dynamics》2007,28(2-3):325-332

In this work, we study the mean tropopause structure from the National Center for Environmental Prediction–National Center for Atmospheric Research reanalysis in the framework of baroclinic adjustment theories, focusing on the impact of baroclinic eddies on the mean tropopause height. In order to measure the effects of such perturbations, we introduce an appropriate global index that selects events of high baroclinic activity and allows us to distinguish the phases of growth and decay of baroclinic waves. We then composite the tropopause mean structure before and after baroclinic events, finding that baroclinic disturbances cause the zonally averaged midlatitude winter tropopause height to rise. Our results establish the importance of baroclinic adjustment processes for midlatitude tropopause dynamics.  相似文献   

The thin and medium filters of the EPIC camera on-board XMM-Newton: measured performance after more than 15 years of operation     

Marco Barbera  Fabio Gastaldello  Luisa Sciortino  Simonpietro Agnello  Gianpiero Buscarino  Alfonso Collura  Nicola La Palombara  Ugo Lo Cicero  Nicola Sartore  Andrea Tiengo  Salvatore Varisco  Anna Maria Venezia 《Experimental Astronomy》2016,42(2):179-197

After more than 15 years of operation of the EPIC camera on board the XMM-Newton X-ray observatory, we have reviewed the status of its Thin and Medium filters. We have selected a set of Thin and Medium back-up filters among those still available in the EPIC consortium and have started a program to investigate their status by different laboratory measurements including: UV/VIS transmission, Raman scattering, X-Ray Photoelectron Spectroscopy, and Atomic Force Microscopy. Furthermore, we have investigated the status of the EPIC flight filters by performing an analysis of the optical loading in the PN offset maps to gauge variations in the optical and UV transmission. We both investigated repeated observations of single optically bright targets and performed a statistical analysis of the extent of loading versus visual magnitude at different epochs. We report the results of the measurements conducted up to now. Most notably, we find no evidence for change in the UV/VIS transmission of the back-up filters in ground tests spanning a 2 year period and we find no evidence for change in the optical transmission of the thin filter of the EPIC-pn camera from 2002 to 2012. We point out some lessons learned for the development and calibration programs of filters for X-ray detectors in future Astronomy missions.  相似文献   

The concentrations of selected trace elements in clams, Trivela mactroidea along the Venezuelan coast in the state of Miranda     

LaBrecque JJ  Benzo Z  Alfonso JA  Cordoves PR  Quintal M  Gomez CV  Marcano E 《Marine pollution bulletin》2004,49(7-8):664-667

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The Gulf of California: Review of ecosystem status and sustainability challenges     

Salvador E. Lluch-Cota  Eugenio A. Aragón-Noriega  David Aurioles-Gamboa  Richard C. Brusca  Roberto Cortés-Altamirano  Alfonso Esquivel-Herrera  Michel E. Hendrickx  Hugo Herrera-Cervantes  Miguel Lavín  Daniel B. Lluch-Cota  Silvio G. Marinone  Sofia Ortega-García  Alejandro Parés-Sierra  Mauricio Ramírez-Rodríguez  Richard A. Schwartzlose  Arturo P. Sierra-Beltrán 《Progress in Oceanography》2007,73(1):1-26

The Gulf of California is unique because of its geographical location and conformation. It hosts diverse ecosystems and important fisheries that support industry and provide livelihood to coastal settlements. It is also the site of interests and problems, and an intense interaction among managers, producers, and conservationists. In this report, we scrutinize the abiotic (hydrography, climate, ocean circulation, and chemistry) and biotic (phyto- and zooplankton, fish, invertebrates, marine mammals, birds, and turtles) components of the marine ecosystem, and some particular aspects of climate variability, endemisms, harmful algal blooms, oxygen minimum layer, and pollution. We also review the current conditions and conflicts around the main fisheries (shrimp, small and large pelagic fishes, squid, artisanal and sportfishing), the most important human activity in the Gulf of California. We cover some aspects of management and conservation of fisheries, especially the claimed overexploitation of fish resources and the ecosystems, and review proposals for creating networks of marine protected areas. We conclude by identifying main needs for information and research, particularly the integration of data bases, the implementation of models and paleoreconstructions, establishment of monitoring programs, and the evaluation of fishing impacts and management actions.  相似文献   

The solubility of Pt and Pd sulfides and Au in bisulfide solutions     

S. A. Wood  P. Pan  Y. Zhang  A. Mucci 《Mineralium Deposita》1994,29(4):309-317

Two sets of measurements of the solubility of Pt and Pd in bisulfide solutions have been carried out at low temperatures. The first involved the equilibration of Pt metal with bisulfide solutions at 25 °C and pH = 6–12 for periods up to five years. These experiments yielded Pt concentrations on the order of tens of g/L at sulfide concentrations as low as 0.001 molal under conditions too reducing to permit significant contributions from hydroxide complexes. The second set of experiments consisted of reacting PtS, PdS and Au with H₂S-saturated solutions having pH values of 3–4 at 25°, 50° and 90 °C. These experiments showed that the solubilities of all three metals increased with temperature. The observed order of solubility was Au > Pt Pd. Solubilities ranged from 10 to 75 g/L Au, 4 to 20 g/L Pt and 0.5 to 10 g/L Pd. The data do not permit definitive identification of the Pt and Pd species present in either set of experiments, but do strongly suggest that the species present under acidic and basic conditions are different. The measured solubility of gold at 25° and 50 °C is consistent with that measured in previous studies.Although the measured Pt and Pd solubilities are not as high as those estimated by theoretical methods, it is nevertheless evident that bisulfide complexation can lead to the remobilization of Pt and Pd over a wide range of pH under reducing conditions at geologically reasonable sulfide concentrations, at low as well as high temperatures. Such conditions are characteristic of a wide variety of geological environments where Pt and Pd have been inferred to have been affected by hydrothermal transport. In these cases, bisulfide complexation is far more effective than chloride or hydroxide complexes in transporting the PGE. On leave from: Shenyang Laboratory of Rock and Mineral Resources, Ministry of Geology and Mineral Resources, People's Republic of China  相似文献   

Subsurface formation of oxidants on Mars and implications for the preservation of organic biosignatures     

Alfonso F. Davila  Alberto G. Fairn  Luis Gago-Duport  Carol Stoker  Ricardo Amils  Rosalba Bonaccorsi  Jhony Zavaleta  Darlene Lim  Dirk Schulze-Makuch  Christopher P. McKay 《Earth and Planetary Science Letters》2008,272(1-2):456-463

Hydrogen peroxide can form through the interaction of pyrite and anoxic water. The oxidation of pyrite results in the precipitation of sulfates and iron oxides, high redox potentials (~ 1000 mV) and acidic pH (3–4). The oxidative potential of the resultant solution may be responsible for the oxidation of organic compounds, as observed in the subsurface of the Rio Tinto Mars analog. On Mars subsurface migration of groundwater interacting with volcanogenic massive pyrite deposits would have mobilized acidic and oxidizing fluids through large portions of the crust, resulting in the widespread deposition of sulfates and iron oxides. This groundwater could have leached substantial volumes of aquifer material and crustal rocks, thereby erasing any organic compounds possibly down to depths of hundreds of meters. Therefore, the preservation of organic biosignatures must have been severely constrained in the portions of the ancient Martian crust that were exposed to aqueous processes, calling for a redefinition of the future targets in the search for biomolecular traces of life on Mars.  相似文献   

Multifrequency observations of the interacting galaxy NGC 4922 (UCM 1259 + 2934)     

Almudena Alonso-Herrero  Martin J. Ward  Alfonso Aragón-Salamanca  Jaime Zamorano 《Monthly notices of the Royal Astronomical Society》1999,302(3):561-570

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Aptian bio-events—an integrated biostratigraphic analysis of the Almadich Formation, Inner Prebetic Domain, SE Spain     

Roque Aguado  Jos Manuel Castro  Miguel Company  Gins Alfonso De Gea 《Cretaceous Research》1999,20(6):663

The Upper Barremian to Aptian Almadich Formation (Inner Prebetic Domain of the Betic Cordillera) is composed of hemipelagic sediments deposited on a distal carbonate ramp in the southern Iberian Palaeomargin. Within this facies we have found a thick interval of blue to black shales and marls that is interpreted as deposited under oxygen-depleted conditions. We think that this interval, dated as early Aptian, represents the local record of Ocean Anoxic Event 1a. The integrated biostratigraphic analysis of a section in the Almadich Formation, by means of planktonic foraminifera, calcareous nannofossils and ammonites, enables us to recognize most of the biostratigraphic units based on these three fossil groups and to correlate between them. The Sartousiana, Sarasini, Weissi, Deshayesi and Furcata (ammonite) Zones were identified for the Upper Barremian–Lower Aptian interval. By means of calcareous nannofossil biostratigraphy the Micrantholithus hoschulzii, Hayesites irregularis and Rhagodiscus angustus Zones, plus several additional biohorizons, were identified. A quantitative study performed on a set of 27 Lower Aptian samples has enabled the precise identification of the ‘nannoconid crisis’, the lower limit of which clearly precedes the main anoxic event, and its correlation with other bioevents. Planktonic foraminifera occur consistently throughout the Lower to Upper Aptian of the Cau section and are moderately well preserved. This fact allows us to use the most recent taxonomic framework, based on wall texture, to identify the Blowiella blowi, Schackoina cabri, Globigerinelloides ferreolensis, Globigerinelloides algerianus, Hedbergella trocoidea andTicinella bejaouaensis Zones. Coincident with the anoxic episode, the planktonic foraminiferal assemblages are composed of a significant number of forms with elongated chambers and/or tubulospines assigned to the genera Claviblowiella,Lilliputianella , Leupoldina and Schackoina. Most of the planktonic foraminiferal and nannofossil taxa are illustrated.  相似文献