Gas phase reactions of alkyl nitrates with hydroxyl radicals under tropospheric conditions in comparison with photolysis     

K. H. Becker  K. Wirtz 《Journal of Atmospheric Chemistry》1989,9(4):419-433

Rate constants for the reaction of OH radicals with some branched alkyl nitrates have been measured applying a competitive technique. Methyl nitrite photolysis in synthetic air was used as OH radical source at 295±2 K and 1000 mbar total pressure. Using a rate constant of 2.53×10^-12 cm³ s^-1 for the reaction of OH radicals with n-butane as reference, the following rate constants were obtained (units: 10^-12 cm³ s^-1): isopropyl nitrate, 0.59±0.22; isobutyl nitrate, 1.63±0.20; 3-methyl-2-butyl nitrate, 1.95±0.15; 2-methyl-1-butyl nitrate, 2.50±0.15; 3-methyl-1-butyl nitrate, 2.55±0.35. These values have been combined with the literature data to recalculate the substituent factors F(X) for the different nitrate groups which can be used to predict OH rate constants for organic nitrates for which experimental data are not available.Preliminary measurements of the photolysis frequency of isopropyl nitrate have shown that for this nitrate as a model substance, OH reactions and direct photolysis are of equal importance under tropospheric conditions.  相似文献   

Significance of the remotely sensed thermal infrared measurements obtained over a citrus orchard   总被引：1，自引：0，他引：1  

J.A. Sobrino  V. Caselles  F. Becker 《ISPRS Journal of Photogrammetry and Remote Sensing》1990,44(6)

In this work we have developed a theoretical model that helps the interpretation of the remotely sensed thermal infrared measurements carried out over citrus orchards. A detailed analysis of the different factors which take part in the definition of the effective emissivity and temperature (observation height, viewing angle, type of soil, dimensions and separation between orange trees) is made. The model was validated under vertical observation in a citrus orchard during seven nights. In this situation we have determined that the model performs to an accuracy of about 1%.  相似文献   

Spatial variability in soil moisture as predicted from airborne thematic mapper (ATM) data     

Donald A. Davidson  Alistair I. Watson 《地球表面变化过程与地形》1995,20(3):219-230

In the first part of this project, the extent to which moisture content of alluvial soils could be predicted from imagery derived from an airborne thematic mapper (ATM) was investigated. From sampling done on the same day as the flight, it was found that digital numbers derived from the thermal channel (waveband 11) were strongly correlated with gravimetric moisture content. From sampling three fields of contrasting land cover, the relationship between waveband 11 values and moisture content was found to be independent of land cover type. Spatial variation in waveband 11 values and thus moisture content were related to palaeochannel patterns on the alluvial land. This was investigated by deriving variograms for long transects from each of the three investigated fields. The range and sills of the variograms are shown to express the nature and pattern of palaeochannels. By the application of such geostatistical techniques, high resolution imagery can thus be used to quantify palaeochannel characteristics on alluvial land.  相似文献   

Geochemical Indicators of Intrinsic Bioremediation   总被引：19，自引：0，他引：19  

Robert C. Borden  Carlos A. Gomez  Mark T. Becker 《Ground water》1995,33(2):180-189

A detailed field investigation has been completed at a gasoline-contaminated aquifer near Rocky Point, NC, to examine possible indicators of intrinsic bioremediation and identify factors that may significantly influence the rate and extent of bioremediation. The dissolved plume of benzene, toluene, ethylbenzene, and xylene (BTEX) in ground water is naturally degrading. Toluene and o-xylene are most rapidly degraded followed by m-, p-xylene, and benzene. Ethylbenzene appears to degrade very slowly under anaerobic conditions present in the center of the plume. The rate and extent of biodegradation appears to be strongly influenced by the type and quantity of electron acceptors present in the aquifer. At the upgradient edge of the plume, nitrate, ferric iron, and oxygen are used as terminal electron acceptors during hydrocarbon biodegradation. The equivalent of 40 to 50 mg/I of hydrocarbon is degraded based on the increase in dissolved CO₂ relative to background ground water. Immediately downgradient of the source area, sulfate and iron are the dominant electron acceptors. Toluene and o-xylene are rapidly removed in this region. Once the available oxygen, nitrate, and sulfate are consumed, biodegradation is limited and appears to be controlled by mixing and aerobic biodegradation at the plume fringes.  相似文献   

Carbon,hydrogen and nitrogen isotopes in solvent-extractable organic matter from carbonaceous chondrites     

Richard H Becker  Samuel Epstein 《Geochimica et cosmochimica acta》1982,46(1):97-103

Solvent extractions were done on the carbonaceous chondrites Murray, Murchison, Orgueil and Renazzo, using CCl₄ and CH₃OH. Between 2 and 10% of the total carbon in these meteorites is extractable by ordinary techniques, most of it in CH₃OH. After demineralization with HF, perhaps as much as 30% of the total carbon in Murray may be extractable with CH₃OH. The extracts from Renazzo have isotopic ratios which suggest that they are mainly terrestrial organic matter, with lesser contributions from indigenous organics. The CH₃OH-soluble organic matter from Murchison and both untreated and HF-treated Murray has δ¹³C values of about +5 to + 10%. and δ¹⁵N values of about +90 to +100%., both of which are significantly higher than the bulk meteorite values. The Orgueil CH₃OH-extract also has a δ¹⁵N value well above the value in residual organic matter. Values for δD of +300 to +500%. are found for the CH₃OH-soluble organic matter. The combined data for C, H and N isotopes makes it highly unlikely that the CH₃OH-soluble components are derivable from, or simply related to, the insoluble organic polymer found in the same meteorites. A relationship is suggested between the event that formed hydrous minerals in CI1 and CM2 meteorites and the introduction of water-soluble (methanol-soluble) organic compounds. Organic matter soluble in CCl₄ has essentially no nitrogen, and δ³C and δD values are lower than for CH₃OH-soluble phases. Either there are large isotopic fractionations for carbon and hydrogen between different soluble organic phases, or the less polar components are partially of terrestrial origin.  相似文献   

Exploring the influence of the non-dipole field on magnetic records for field reversals and excursions     

Maxwell C. Brown  Richard Holme  Alistair Bargery 《Geophysical Journal International》2007,168(2):541-550

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Calibrate yourself to your data! A vital first step in seismic interpretation     

Alistair R. Brown 《Geophysical Prospecting》2001,49(6):729-733

Stratigraphic, reservoir and fluid interpretation demands a thorough understanding of the seismic-to-well tie. Data phase, polarity and tuning effects significantly influence this tie and are often poorly understood. By relating seismic character to known subsurface geology, the interpreter should gain better understanding and be able to calibrate himself to his data. This is an important preliminary stage in any seismic interpretation beyond structure.  相似文献   

Use of deuterated water as a conservative artificial groundwater tracer     

Matthew W. Becker  Tyler B. Coplen 《Hydrogeology Journal》2001,9(5):512-516

Conservative tracers are necessary to obtain groundwater transport velocities at the field scale. Deuterated water is an effective tracer for this purpose due to its similarity to water, chemical stability, non-reactivity, ease of handling and sampling, relatively neutral buoyancy, and reasonable price. Reliable detection limits of 0.1 mg deuterium/L may be obtained in field tests. A field example is presented in which deuterated water, bromide, and pentafluorobenzoic acid are used as groundwater tracers. Deuterated water appeared to be transported conservatively, producing almost identical breakthrough curves as that of other soluble tracers. Electronic Publication  相似文献   

Impacts of afforestation on groundwater resources and quality   总被引：4，自引：0，他引：4  

Alistair Allen  Deborah Chapman 《Hydrogeology Journal》2001,9(4):390-400

Plans to double the proportion of land under forest cover in Ireland by the year 2035 have been initiated. The plan, primarily financially driven, ignores potential environmental impacts of forestry, particularly impacts on groundwater resources and quality. Since groundwater supplies almost 25% of Ireland's total potable water, these impacts are important. Field investigations indicate that afforestation leads to a reduction in runoff by as much as 20%, mainly due to interception of rainfall by forest canopies. Clearfelling has the opposite impact. Implications are that uncoordinated forestry practices can potentially exacerbate flooding. Groundwater recharge is affected by forestry, largely due to greater uptake of soil water by trees and to increased water-holding capacity of forest soils, arising from higher organic contents. Recharge rates under forests can be reduced to one tenth that under grass or heathland. Groundwater quality may be affected by enhanced acidification and nitrification under forests, due partly to scavenging of atmospheric pollutants by forest canopies, and partly to greater deposition of highly acid leaf litter. The slower recharge rates of groundwater under forests lead to significant delays in manifestation of deterioration in groundwater quality. Electronic Publication  相似文献   

Decadal variability on the northwest european shelf     

Jürgen Sündermann  Gerd Becker  Peter Damm  Dries van den Eynde  Alexander Frohse  Remi Laane  Wim van Leussen  Thomas Pohlmann  Wim van Raaphorst  Günther Radach  Helga Schultz  Marijke Visser 《Ocean Dynamics》1996,48(3-4):365-400

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