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Eocene shales metamorphosed by a naturally ignited coal seam in the Powder River Basin, Wyoming record a continuum of mineralogic and textural changes from relatively unaltered shale to melt developed during pyrometamorphism. Samples collected along a section 2 m in length, corresponding to a temperature range of approximately 1300°C, were examined optically and by XRD, SEM, and STEM. The low temperature samples are comprised primarily of silt-sized quartz, K-feldspar, and minor amounts of other detrital minerals in a continuous matrix of illite/smectite (I/S). Delamination of phyllosilicates due to dehydroxylation occurs early in the sequence with curling of individual layers from rim to core. Within one-half meter of melted areas, phyllosilicates have undergone an essentially isochemical reconstitution with nucleation and growth of mullite crystals with maximum diameters of 50 nm, randomly distributed within a non-crystalline phase that replaces I/S. Large detrital grains remain for the most part unaffected except for the inversion of quartz to tridymite/cristobalite. Within 1 mm of the solid/melt interface, the mullitebearing clay mineral matrix is essentially homogeneous in composition with obscure grain boundaries, caused by apparent homogenization of poorly crystalline material. This material is similar in composition to parent clays and acts as a matrix to angular, remnant tridymite/cristobalite grains. Rounded, smaller silica grains have reaction rims with the non-crystalline matrix; K-feldspar is no longer present (apparently reacted with the matrix) and the matrix contains abundant pore space due to shrinkage upon dehydroxylation. As isolated pods of paralava (glass) or fractures are approached, Fe–Ti–Al oxides become abundant. Vesicular glass is separated from clinker by a well-defined interface and contains numerous phenocrysts. XRF analyses and reduced area rastering using EDS imply enrichment of the melt phase in Fe, Ca, Mg and Mn, apparently due to vapor transport from other layers lower in the sedimentary sequence.Contribution No. 490, the Mineralogical Laboratory, Department of Geological Sciences, The University of Michigan  相似文献   
124.
The present work is a follow-up of the investigation on the decomposition reaction of kaolinite as a function of the defectivity of the starting material and the temperature of reaction. In the present work we study the high temperature reaction of mullite synthesis from kaolinite, from the starting point of the results obtained in the first part.Time resolved energy-dispersive powder diffraction patterns have been measured using synchrotron radiation in isothermal conditions. The apparent activation energy for mullite nucleation and growth is found to be related to the defective structure of the starting kaolinite, which thus must have an influence on the chemical homogeneity of the amorphous intermediate phase.  相似文献   
125.
The decomposition reaction of kaolinite has been investigated as a function of the defectivity of the starting material and the temperature of reaction. Time resolved energy-dispersive powder diffraction patterns have been measured using synchrotron radiation, both under a constant heating rate (heating rates from 10 to 100° C/min) and in isothermal conditions (in the temperature range 500 to 700° C). The apparent activation energy of the dehydroxylation process is different for kaolinites exhibiting a different degree of stacking fault density. The results of the analysis of the kinetic data indicate that the starting reaction mechanism is controlled by diffusion in the kaolinite particle. The diffusion process is dependent on the defective nature of both kaolinite and metakaolinite. At high temperatures, and at higher heating rates, the reaction mechanism changes and the resistance in the boundary layer outside the crystallites becomes the rate-limiting factor, and nucleation begins within the reacting particle. During the final stage of the dehydroxylation process the reaction is limited by heat or mass transfer, and this might be interpreted by the limited diffusion between the unreacted kaolinite domains and the metakaolinite matrix.  相似文献   
126.
A radiative-conductive model for the prediction of radiation fog   总被引:2,自引:0,他引:2  
A conductive-radiative model is used to predict the formation and growth of radiation fog. This is accomplished by solving numerically the heat and mass transport equations in conjunction with an approximate form of the radiative transfer equation. The equations of motion in simplified form are included in the physical system to make use of Blackadar's (1962) formulation of the exchange coefficient of the boundary layer.It is found for a number of hypothetical test cases that the model gives results which appear to represent real physical conditions. One actual situation is tested. Results show that the model reproduces better than qualitatively those parameters which are obtained from routine observations.  相似文献   
127.
Sand and sandstone   总被引:1,自引:0,他引:1  
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Zusammenfassung Die Sierra Leone unterteilt sich in zwei Haupteinheiten. Die östliche ist ein Teil des festen präkambrischen westafrikanischen Kratons und besteht aus hochgradig metamorphem Gestein und Granitgneisen. Die Strukturen verlaufen in vorherrschend NE-Richtung. Der westliche Teil enthält Elemente eines orogenen Gürtels, nämlich der Rokeliden, die entweder im späten Präkambrium oder frühen Paläozoikum entstanden sind und nach NNW streichen. Die Gesteinsserien, die den orogenen Gürtel bilden, setzen sich aus dem Kasila-System, einer unbenannten Gneisgruppe östlich davon, den Rokel River Series und den Marampa Schists zusammen. Die sich an das Kasila-System, umbenannt in Kasila-Gruppe, anschließenden Gneise und wahrscheinlich auch die Kasila-Gruppe selbst können mit dem Gestein des Kratons verglichen werden, sind jedoch während der Entstehung der Rokeliden neu überprägt worden. Sie bilden die Basis der Mulde, die Sedimente und vulkanisches Gestein aus den Rokel River Series und den Marampa Schists enthält. Die Rokel River Series sind neu benannt und unterteilen sich in die Rokel River Gruppe mit sechs Formationen und in die Taban Formation, die aus nach-orogener Molasse besteht. Die Marampa Schists sind neu benannt in Marampa Formation. Das Ausmaß der Metamorphose steigert sich über die Rokeliden nach WSW, und die Marampa Formation ist der am stärksten metamorphisierte Teil der geosynklinalen Ausfüllung.
Sierra Leone is divisible into two major structural units. The eastern one is part of the stable Precambrian West African craton and consists of high grade metamorphic rocks and granitic gneisses. The foliation has a dominantly NE trend. The western unit contains the elements of an orogenic belt named the Rokelides, which formed in either late Precambrian or early Palaeozoic, and trends NNW. The rock groups which comprise the orogenic belt are the Kasila System, an unnamed group of gneisses on the east of it, the Rokel River Series and the Marampa Schists. The gneisses adjacent to the Kasila System, renamed Kasila Group, and also, probably, the Kasila Group can be correlated with rocks in the craton, but were refoliated during the Rokelide orogenesis. They constituted the basement to the geosyncline which contained sediments and volcanic rocks of the Rokel River Series and Marampa Schists. The Rokel River Series is renamed, and divided into Rokel River Group which contains six formations, and the Taban Formation which is post-orogenic molasse. The Marampa Schists are renamed the Marampa Formation. The intensity of metamorphism and deformation increases across the Rokelides towards the WSW and the Marampa Formation is the most highly metamorphosed part of the geosynclinal infilling.

Résumé Le Sierra Leone peut se diviser en deux principales sections structurales. La section orientale fait partie du craton stable précambrien de l'Afrique occidentale, formé de roches métamorphiques de haute qualité et de gneiss de granit. La foliation a principalement une direction NE. La section occidentale contient les éléments d'une ceinture orogénique appelée les Rokelides qui ont été formées soit vers la fin de la période précambrienne, soit au début de la période paléozoique et en direction NNW. Les groupes rocheux qui comprennent la ceinture orogénique sont le Kasila System, un groupe de gneiss sans nom situé à son côté est, la Rokel River Series et les Marampa Schists. Les gneiss avoisinant le Kasila System, renommé Kasila Group et en toute probilité le Kasila Group également peuvent être rattachés aux roches du craton mais auraient été refoliés pendant l'orogenèse Rokelide. Ils ont formé la base du géosynclinal qui contient des sédiments et des roches volcaniques de la Rokel River Series et des Marampa Schists. La Rokel River Series a été renommée et divisée en Rokel River Group qui contient six formations et la Taban Formation qui est la mollasse post-orogénique. Les Marampa Schists ont été renommés la Marampa Formation. L'intensité du métamorphisme et de la déformation augmente vers WSW à travers les Rokelides, et la Marampa Formation est la partie la plus métamorphosée de l'accumulation géosynclinale.

. — - . , NE. (), -, NNW. : 1) , 2) , 3) , 4) . , , , . ; peopa , . , , , . . WSW, — , .
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130.
This paper explains how modern analytical techniques can be used to detect hydrocarbons in marine organisms at extremely low concentrations, below those detectable by taste or smell.  相似文献   
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