Comparison of Treatment Efficiency and Energy Consumption of Batch and Continuous Electrocoagulation in Urban Wastewater     

Alper Erdem Yılmaz  Yeşim Dede Sağsöz  Baybars Ali Fil  Murat Tolga Yılmaz 《洁净——土壤、空气、水》2023,51(1):2200032

In this study, domestic wastewater was used as the electrolyte. The work was carried out with an up-flow tubular reactor, made of stainless steel that was used as cathode, while the anode electrode material was aluminum and varying values of flow regime (25, 50, 75 and 100 mL/s for continuous system), initial pH value (5, 6, 7 and 7.8) and current intensity (10, 15 and 20 A) were applied. For domestic wastewater with natural pH, the effluent pH was >9 in the batch system, while in the continuous system the pH was 8–8.5. Likewise, while the effluent temperature was up to 60°C in the batch system, it was at most 35°C in the continuous system. However, the energy consumption values in the continuous system were considerably lower compared with the batch system. At a current intensity of 10 A, 80 kWh of energy per unit volume was consumed in the batch system, while it was 50 kWh for the continuous system. The present results show that the batch system can be used for small wastewater streams whereas the continuous system can be used for large wastewater streams for domestic wastewater treatment.  相似文献   

Temporal changes of soft-bottom zoobenthic communities in and around Alsancak Harbor (Izmir Bay, Aegean Sea), with special attention to the autecology of exotic species     

Melih Ertan Çinar  Tuncer Katagan  Bilal Öztürk  Özdemir Egemen  Zeki Ergen  Ahmet Kocatas  Mesut Önen  Fevzi Kirkim  Kerem Bakir  Güley Kurt  Ertan Dagli  Asli Kaymakçi  Sermin Açik  Alper Dogan  & Tahir Özcan 《Marine Ecology》2006,27(3):229-246

Temporal and spatial variation in soft‐bottom benthic communities following recovery from a pollution episode were studied between January and September 2004 in and around Alsancak Harbor, located in the polluted part of Izmir Bay (Aegean Sea, eastern Mediterranean). Samples were collected at seven stations by van Veen grab. Three additional stations were sampled by means of a beam trawl to take into account large mobile animals and for a better estimate of the local biodiversity. A total of 231 species belonging to 10 zoobenthic groups were found. Polychaetes contributed 90% of the total faunal populations and mollusks 87% of the total biomass in the area. Community parameters varied significantly among stations and sampling periods; number of species ranged from 2 to 79 per 0.1 m² grab sample; density from 20 to 81,720 ind·m^?2; biomass from 0.1 to 4190 g·m^?2; Shannon–Wiener diversity index (log₂ base) from 0.4 to 4.4; and Pielou's evenness index from 0.11 to 1.0. Collections indicate that a number of species, including those sensitive to pollution, have colonized the area where azoic conditions had been previously reported. A total of six exotic species, Streblospio gynobranchiata, Polydora cornuta, Hydroides dianthus, Hydroides elegans, Anadara demiri and Fulvia fragilis, probably transferred to the area via ballast water or hull fouling, dominated soft or hard substrata in and near Alsancak Harbor. The first two species accounted for more than 70% of the total population in the area, while A. demiri contributed the most to the biomass (93%, at station 7).  相似文献   

Synthesis and phase transformations involving scorodite, ferric arsenate and arsenical ferrihydrite: Implications for arsenic mobility   总被引：1，自引：0，他引：1  

Dogan Paktunc  John Dutrizac 《Geochimica et cosmochimica acta》2008,72(11):2649-2672

Scorodite, ferric arsenate and arsenical ferrihydrite are important arsenic carriers occurring in a wide range of environments and are also common precipitates used by metallurgical industries to control arsenic in effluents. Solubility and stability of these compounds are controversial because of the complexities in their identification and characterization in heterogeneous media. To provide insights into the formation of scorodite, ferric arsenate and ferrihydrite, series of synthesis experiments were carried out at 70 °C and pH 1, 2, 3 and 4.5 from 0.2 M Fe(SO₄)_1.5 solutions also containing 0.02-0.2 M Na₂HAsO₄. The precipitates were characterized by transmission electron microscopy, X-ray diffraction and X-ray absorption fine structure techniques. Ferric arsenate, characterized by two broad diffuse peaks on the XRD pattern and having the structural formula of FeAsO₄·4-7H₂O, is a precursor to scorodite formation. As defined by As XAFS and Fe XAFS, the local structure of ferric arsenate is profoundly different than that of scorodite. It is postulated that the ferric arsenate structure is made of single chains of corner-sharing Fe(O,OH)₆ octahedra with bridging arsenate tetrahedra alternating along the chains. Scorodite was precipitated from solutions with Fe/As molar ratios of 1 over the pH range of 1-4.5. The pH strongly controls the kinetics of scorodite formation and its transformation from ferric arsenate. The scorodite crystallite size increased from 7 to 33 nm by ripening and aggregation. Precipitates, resulting from continuous synthesis at pH 4.5 from solutions having Fe/As molar ratios ranging from 1 to 4 and resembling the compounds referred to as ferric arsenate, arsenical ferrihydrite and As-rich hydrous ferric oxide in the literature, represent variable mixtures of ferric arsenate and ferrihydrite. When the Fe/As ratio increases, the proportion of ferrihydrite increases at the expense of ferric arsenate. Arsenate adsorption appears to retard ferrihydrite growth in the precipitates with molar Fe/As ratios of 1-4, whereas increased reaction gradually transforms two-line ferrihydrite to six-line ferrihydrite at Fe/As ratios of 5 and greater.  相似文献   

High-resolution palynological analysis in Lake Sapanca as a tool to detect recent earthquakes on the North Anatolian Fault     

Suzanne A.G. Leroy  Sonay Boyraz  Alper Gürbüz 《Quaternary Science Reviews》2009,28(25-26):2616-2632

High-resolution palynological analysis of a 38-cm long core collected from Lake Sapanca, northwest Turkey, reveals large earthquakes that occurred during the second half of the 20th century along the North Anatolian Fault Zone. Four events have disturbed the lacustrine sedimentary sequence. Three of the four events are historical earthquakes in 1999 in Izmit, 1967 in Mudurnu and 1957 in Abant. These events are recorded in the core by turbiditic deposits and reworked sediment and by low overall palynomorph concentrations but high values of thick-exined pollen, fern spores and fungal spores. Palynomorphs in the event beds have been grouped based on their associations in modern moss, river and lake samples. The inferred mechanisms of transport and sources for the palynomorphs are: 1- lake sediment displaced by slump, 2- collapsed shoreline sediment owing to seiche, waves and sudden lake level changes, 3- subsidence of deltas and 4- river-transported soil and sediment from upland areas. The 1999 Izmit earthquake is only weakly recorded by palynomorphs, probably due to recent engineering control on the rivers. The 1967 Mudurnu earthquake had the strongest effect on the lake, introducing successive packages of sediment to the centre of the lake from underwater slopes, the lakeshore and rivers.  相似文献   

Biomonitoring of trace element accumulation in plants growing at Murat Mountain   总被引：2，自引：2，他引：0  

I. Ugulu  Y. Dogan  S. Baslar  O. Varol 《International Journal of Environmental Science and Technology》2012,9(3):527-534

The purpose of this study is to determine the present levels of atmospheric trace element pollution in the Murat Mountain of Aegean Region in the western part of Turkey. Therefore, 29 different plants were selected as potential biomonitors of trace elements including nickel, zinc, iron, lead, cadmium and manganese (??g/g, dry weight). The samples were collected from two different heights of Murat Mountain. Atomic absorption spectrometry was used to determine the concentrations of trace elements. The mean concentrations determined at 1,000?m altitude ranged from 0.139 to 4.518, 0.223 to 0.986, 0.359 to 6.930, 0.443 to 0.727 and 0.077 to 3.222???g/g, dry weight, for nickel, zinc, iron, lead and manganese, respectively. At 1,600?m altitude, the values ranged from 0.191 to 6.248, 0.302 to 1.008, 2.387 to 8.896, 0.345 to 0.570 and 0.195 to 3.502???g/g, dry weight, for nickel, zinc, iron, lead and manganese, respectively. No cadmium was found at both altitudes. For determination of existence of any differences between the averages of the herbaceous and woody plants, comparisons were made by the independent sample t test. In the statistical analysis, comparison of trace element pollution values of herbaceous and woody plants for nickel, lead and manganese was significant (P?<?0.05), while it was not for iron and zinc.  相似文献   

Pressure Dependence of Cymbal Transducers     

Uzgur  E. Markley  D.C. Guo  M. Snyder  B. Meyer  R.J. Dogan  A. Newnham  R.E. 《Oceanic Engineering, IEEE Journal of》2007,32(2):408-415

The hydrostatic pressure limit that a receiver can withstand without failure is of major importance in underwater sonar systems. In this paper, the hydrostatic pressure tolerance and sensitivity of cymbal receivers were investigated. The failure mode in cymbal transducers under hydrostatic pressure is described. Effects of cavity geometry and material selection on hydrostatic piezoelectric coefficients and pressure limits were evaluated using both experimental data and finite-element analysis (FEA). It was found that cavity depth has a very strong effect on the stability of underwater sensitivity and pressure tolerance of these devices. Cymbals made with soft piezoelectric transducers (PZTs) possess higher figures of merit and better pressure tolerance than those made with hard PZTs. Alternatively, the cymbal sensitivity and pressure tolerance can be improved by changing the cap material.  相似文献   

Dissipative devices for earthquake resistant composite steel structures: bolted versus welded solution     

Marco Valente  Carlo A. Castiglioni  Alper Kanyilmaz 《Bulletin of Earthquake Engineering》2016,14(12):3613-3639

This paper investigates and compares the seismic performance of two types of innovative repairable fuse devices for earthquake resistant composite steel frames through experimental tests and numerical analyses. The fuses are energy dissipating devices consisting of steel plates that can be welded or bolted to the beam web and bottom flange. The numerical analyses performed in this study are based on the results of experimental tests carried out on beam-to-column sub-assemblages equipped with both the types of fuse devices. The main differences in terms of hysteretic behavior and failure modes of the fuses are identified through the experimental campaign. Detailed three-dimensional finite element models of the beam-to-column sub-assemblages are then created to provide a deeper insight into both the response and the effectiveness of the two investigated devices. On the basis of the results of both the experimental tests and numerical analyses, simplified models of different types of fuses are developed in order to study the effects of bolted and welded devices on the seismic response of composite steel frames. The results are then extended to the case of three-dimensional building structures with different number of storeys. The experimental and numerical investigations prove the effectiveness of the fuses and highlight the main differences between the two possible solutions.  相似文献   

1-D DC Resistivity Modeling and Interpretation in Anisotropic Media Using Particle Swarm Optimization     

Ertan Pekşen  Türker Yas  Alper Kıyak 《Pure and Applied Geophysics》2014,171(9):2371-2389

We examine the one-dimensional direct current method in anisotropic earth formation. We derive an analytic expression of a simple, two-layered anisotropic earth model. Further, we also consider a horizontally layered anisotropic earth response with respect to the digital filter method, which yields a quasi-analytic solution over anisotropic media. These analytic and quasi-analytic solutions are useful tests for numerical codes. A two-dimensional finite difference earth model in anisotropic media is presented in order to generate a synthetic data set for a simple one-dimensional earth. Further, we propose a particle swarm optimization method for estimating the model parameters of a layered anisotropic earth model such as horizontal and vertical resistivities, and thickness. The particle swarm optimization is a naturally inspired meta-heuristic algorithm. The proposed method finds model parameters quite successfully based on synthetic and field data. However, adding 5 % Gaussian noise to the synthetic data increases the ambiguity of the value of the model parameters. For this reason, the results should be controlled by a number of statistical tests. In this study, we use probability density function within 95 % confidence interval, parameter variation of each iteration and frequency distribution of the model parameters to reduce the ambiguity. The result is promising and the proposed method can be used for evaluating one-dimensional direct current data in anisotropic media.  相似文献   

Mineral composite assessment of Kelkit River Basin in Turkey by means of remote sensing     

Hakan Mete Dogan 《Journal of Earth System Science》2009,118(6):701-710

Utilizing remote sensing (RS) and geographic information systems (GIS) tools, mineral composite characteristics (ferrous minerals (FM), iron oxide (IO), and clay minerals (CM)) of the Kelkit River Basin (15913.07 km²) in Turkey were investigated and mapped. Mineral composite (MC) index maps were produced from three LANDSAT-ETM+ satellite images taken in 2000. Resulting MC index maps were summarized in nine classes by using ‘natural breaks’ classification method in GIS. Employing bi-variety correlation analysis, relationships among index maps were investigated. According to the results, FM and IO index maps showed positive correlation, while CM index map is negatively correlated with FM and IO index maps. Negative correlations between iron and clay variables suggested that the dominant clay minerals of the study area might be smectite, illite, kaolinite, and chlorite, which have little or no iron content. Using field data for which their geographic coordinates had been determined by global positioning system (GPS), developed MC maps were verified, and found dependable for environmental and ecological modeling studies.  相似文献   

Microbial reduction of ferrous arsenate: Biogeochemical implications for arsenic mobilization     

Michael G. Babechuk  Christopher G. Weisener  Brian J. Fryer  Dogan Paktunc  Christian Maunders 《Applied Geochemistry》2009

In reduced aqueous environments, the presence of As in solution is a function of both biotic and abiotic mechanisms. Recent studies have demonstrated a significant release of As(III) through the microbial reduction of dissolved and mineral-bound As(V), which raises health concerns when the greater comparative mobility and toxicity of As(III) is considered. These release mechanisms do not operate in isolation but occur in concert with a number of removal processes, including secondary mineralization and sorption to other natural substrates. Thermodynamic and applied experimental studies have shown that ferrous arsenates, such as symplesite [Fe(II)₃(As(V)O₄)₂·8H₂O], may provide a significant sink for Fe(II) and As(V). In this study, the stability of a representative ferrous arsenate phase in the presence of the arsenate-reducing bacterium Shewanella sp. strain ANA-3 is examined. The reduction of ferrous arsenate by ANA-3 results in the release of aqueous As(III) and, subsequently, the progressive nucleation of a biogenic ferrous arsenite phase proximal to the microbial cells. The valence states of secondary solid-phase products were verified using X-ray absorption spectroscopy (XAS). Electron microscopy reveals that nucleation occurs on cellular exudates which may imply a role of extracellular reduction through c-type cytochromes as investigated in recent literature. These observations provide new insights into the reduction mechanisms of ANA-3 and the biogeochemical cycling of As(III) in natural systems.  相似文献