Equilibrium H/H fractionations in organic molecules: I. Experimental calibration of ab initio calculations     

Ying Wang  Alex L. Sessions  Robert J. Nielsen  William A. Goddard III 《Geochimica et cosmochimica acta》2009,73(23):7060-7075

Carbon-bound hydrogen in sedimentary organic matter can undergo exchange over geologic timescales, altering its isotopic composition. Studies investigating the natural abundance distribution of ¹H and ²H in such molecules must account for this exchange, which in turn requires quantitative knowledge regarding the endpoint of exchange, i.e., the equilibrium isotopic fractionation factor (α_eq). To date, relevant data have been lacking for molecules larger than methane. Here we describe an experimental method to measure α_eq for C-bound H positions adjacent to carbonyl group (H_α) in ketones. H at these positions equilibrates on a timescale of days as a result of keto-enol tautomerism, allowing equilibrium ²H/¹H distributions to be indirectly measured. Molecular vibrations for the same ketone molecules are then computed using Density Functional Theory at the B3LYP/6-311G** level and used to calculate α_eq values for H_α. Comparison of experimental and computational results for six different straight and branched ketones yields a temperature-dependent linear calibration curve with slope = 1.081−0.00376T and intercept = 8.404−0.387T, where T is temperature in degrees Celsius. Since the dominant systematic error in the calculation (omission of anharmonicity) is of the same size for ketones and C-bound H in most other linear compounds, we propose that this calibration can be applied to analogous calculations for a wide variety of organic molecules with linear carbon skeletons for temperatures below 100 °C. In a companion paper (Wang et al., 2009) we use this new calibration dataset to calculate the temperature-dependent equilibrium isotopic fractionation factors for a range of linear hydrocarbons, alcohols, ethers, ketones, esters and acids.  相似文献   

Thallium isotopes as a potential tracer for the origin of cratonic eclogites     

Sune G. Nielsen  Helen M. Williams  William L. Griffin  Norman Pearson 《Geochimica et cosmochimica acta》2009,73(24):7387-6704

Cratonic eclogites are inferred to originate either from subducted ocean crust or mantle melts accreted onto the roots of continents. These models have different implications for the growth of continents, but it is currently difficult to determine the origin of individual eclogite suites.Upper ocean crust altered at low temperatures and marine sediments both display high thallium (Tl) concentrations and strongly fractionated Tl isotope signatures relative to the ambient upper mantle. In this study we carry out the first examination of the suitability of Tl isotopes as a tracer for an ocean-crust origin of cratonic eclogites. We have analysed the Tl isotope composition of clinopyroxene and garnet in six eclogites from the Kaalvallei and Bellsbank kimberlite pipes in South Africa. Minerals were pre-cleaned with an HCl leaching technique and the leachates display variably light Tl isotope ratios. These most likely reflect low-temperature hydrothermal alteration occurring after eruption of the kimberlite that carried the eclogites to the surface.The leached mineral pairs all display identical Tl isotope ratios, strongly suggesting that the source of the analysed Tl is identical for each mineral pair. It is, however, not possible to exclude the possibility that the analysed Tl originates from kimberlitic material that was not removed by the cleaning procedure.Only one of the six samples exhibits a Tl isotope composition different from ambient mantle. Assuming that the Tl isotope signatures indeed represent the eclogite minerals and not any form of contamination, the Tl isotope composition in this sample is consistent with containing a minor component (<3%) of ocean crust altered at low temperatures.Thallium isotopes may become one of the most sensitive indicators for the presence of low-T altered ocean crust because of the stark contrast in Tl concentration and isotopic composition between the mantle and altered ocean crust. In fact, no other chemical or isotopic tracer could have provided an indication that any of the samples studied here had a subduction origin. However, much work is still required before it becomes clear if Tl isotope measurements are a viable means to establish the origin of cratonic eclogites.  相似文献   

Subduction Influence on Oxygen Fugacity and Trace and Volatile Elements in Basalts Across the Cascade Volcanic Arc   总被引：2，自引：0，他引：2  

Rowe  Michael C.; Kent  Adam J. R.; Nielsen  Roger L. 《Journal of Petrology》2009,50(1):61-91

Fluids or melts derived from a subducting plate are often citedas a mechanism for the oxidation of arc magmas. What remainsunclear is the link between the fluid, oxygen fugacity, andother major and trace components, as well as the spatial distributionof the impact of those fluids. To test the potential effectsof addition of a subduction-derived fluid or melt to the sub-arcmantle, olivine-hosted melt inclusions from primitive basalticlavas sampled from across the central Oregon Cascades (43°–45°N)have been analyzed for major, trace and volatile elements andfO₂. Oxygen fugacity was determined in melt inclusions fromsulfur speciation determined by electron microprobe and fromolivine–chromite oxygen geobarometry. The overall rangein fO₂ based on sulfur speciation measurements is from <–0·25log units to + 1·9 log units (FMQ, where FMQ is fayalite–magnetite–quartzbuffer). Oxygen fugacity is positively correlated with fluid-mobiletrace element and light rare earth element contents in basaltsgenerated by relatively low-degree partial melting. Establishinga further correlation between fO₂ and fluid-mobile trace elementabundances with position along the arc requires the basaltsto be subdivided into shoshonitic, calc-alkaline, low-K tholeiiteand enriched intraplate basalt groups. Melt inclusions fromenriched intraplate and shoshonitic lavas show increasing fO₂and trace element abundances closer to the trench, whereas calc-alkalinemelt inclusions exhibit no significant across-arc variations.Low-K tholeiitic melt inclusions record an increase in incompatibletrace elements closer to the trench; however, there is no correlatedincrease in fO₂. The correlation observed in enriched intraplateand shoshonitic melt inclusions is interpreted to reflect aprogressively greater proportion of a fluid-rich, oxidized subductioncomponent in magmas generated nearer the subduction zone. Significantly,calc-alkaline melt inclusions with high ratios of large ionlithophile elements to high field strength elements, characteristicof ‘typical’ arc magmas, have oxidation states indistinguishablefrom low-K tholeiite and enriched intraplate basalt melt inclusions.The lack of across-arc geochemical variation in calc-alkalinemelt inclusions may suggest that these basalts are not necessarilythe most appropriate magmas for examining recent addition ofa subduction component to the sub-arc mantle. Flux and batchmelt model results produce a wide range of predicted amountsof melting and subduction component added to the mantle source;however, general trends characterized by increased melting andproportion of the subduction component from enriched intraplate,to low-K tholeiite, to calc-alkaline are robust. The model resultsdo not require enriched intraplate, low-K tholeiite and calc-alkalinemagmas to be produced from the same more fertile mantle source.However, enriched intraplate magmas, in contrast to calc-alkalineand low-K tholeiite magmas, cannot be generated from a depletedmantle source. Flux or batch melting of either the more fertileor depleted mantle sources used to generate the low-K tholeiite,calc-alkaline, and enriched intraplate magmas cannot reproduceshoshonitic compositions, which require a significantly depletedmantle source strongly metasomatized by a subduction component.The potential mantle source for shoshonitic basalts has a predictedfO₂ (after oxidation) from + 0·3 to + 2·4 logunits (FMQ) whereas the mantle source for low-K tholeiite, calc-alkaline,and enriched intraplate magmas may range from –1·1to + 0·7 log units (FMQ). KEY WORDS: basalt; Cascades; melt inclusions; oxidation state; volatiles  相似文献   

Objectives of fisheries management: case studies from the UK, France, Spain and Denmark     

Simon Mardle  Sean Pascoe  Jean Boncoeur  Bertrand Le Gallic  Juan J. García-Hoyo  Ins Herrero  Ramon Jimenez-Toribio  Concepcin Cortes  Nuria Padilla  Jesper Raakjaer Nielsen  Christoph Mathiesen 《Marine Policy》2002,26(6)

The main objectives of fisheries management are generally similar throughout the world. These are often stated in policy documents such as the Common Fisheries Policy and the Magnuson–Stevens Fishery Conservation and Management Act. However, at the local level often the key objectives of management are more detailed, characterised by both the overriding management structure and the status and type of fishery concerned. In this paper, we consider case study fisheries from the UK, France, Spain and Denmark to compare some of the various types of fisheries and fisheries management systems that exist in the European Union. From this, we define the key objectives for each management system.  相似文献   

SPB stars in the open SMC cluster NGC 371     

C. Karoff  T. Arentoft  L. Glowienka  C. Coutures  T. B. Nielsen  G. Dogan  F. Grundahl  H. Kjeldsen 《Monthly notices of the Royal Astronomical Society》2008,386(2):1085-1091

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A mental picture of the greenhouse effect     

Rasmus?E.?BenestadEmail author 《Theoretical and Applied Climatology》2017,128(3-4):679-688

The popular picture of the greenhouse effect emphasises the radiation transfer but fails to explain the observed climate change. An old conceptual model for the greenhouse effect is revisited and presented as a useful resource in climate change communication. It is validated against state-of-the-art data, and nontraditional diagnostics show a physically consistent picture. The earth’s climate is constrained by well-known and elementary physical principles, such as energy balance, flow, and conservation. Greenhouse gases affect the atmospheric optical depth for infrared radiation, and increased opacity implies higher altitude from which earth’s equivalent bulk heat loss takes place. Such an increase is seen in the reanalyses, and the outgoing long-wave radiation has become more diffuse over time, consistent with an increased influence of greenhouse gases on the vertical energy flow from the surface to the top of the atmosphere. The reanalyses further imply increases in the overturning in the troposphere, consistent with a constant and continuous vertical energy flow. The increased overturning can explain a slowdown in the global warming, and the association between these aspects can be interpreted as an entanglement between the greenhouse effect and the hydrological cycle, where reduced energy transfer associated with increased opacity is compensated by tropospheric overturning activity.  相似文献   

Degradation of Aromatic and Chlorinated Aliphatic Hydrocarbons in the Anaerobic Part of the Grindsted Landfill Leachate Plume: In Situ Microcosm and Laboratory Batch Experiments   总被引：2，自引：0，他引：2  

Poul L. Bjerg  Kirsten Riigge  Jesper Cortsen  Per H. Nielsen  Thomas H. Christensen 《Ground water》1999,37(1):113-121

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Data Analysis and Modeling to Optimize Thermal Treatment Cost and Performance          下载免费PDF全文

Jack C. Parker  Ungtae Kim  Alyson Fortune  Steffen Griepke  James P. Galligan  Amber Bonarrigo 《Ground Water Monitoring & Remediation》2017,37(1):51-66

The objective of in situ thermal treatment is typically to reduce the contaminant mass or average soil concentration below a specified value. Evaluation of whether the objective has been met is usually made by averaging soil concentrations from a limited number of soil samples. Results from several field sites indicate large performance uncertainty using this approach, even when the number of samples is large. We propose a method to estimate average soil concentration by fitting a log normal probability model to thermal mass recovery data. A statistical approach is presented for making termination decisions from mass recovery data, soil sample data, or both for an entire treatment volume or for subregions that explicitly considers estimation uncertainty which is coupled to a stochastic optimization algorithm to identify monitoring strategies to meet objectives with minimum expected cost. Early termination of heating in regions that reach cleanup targets sooner enables operating costs to be reduced while ensuring a high likelihood of meeting remediation objectives. Results for an example problem demonstrate that significant performance improvement and cost reductions can be achieved using this approach.  相似文献   

Comparison of abstraction scenarios simulated by SWAT and SWAT-MODFLOW     

Eugenio Molina-Navarro  Ryan T. Bailey  Hans Estrup Andersen  Hans Thodsen  Anders Nielsen  Seonggyu Park 《水文科学杂志》2019,64(4):434-454

In hydrological modelling of catchments, wherein streams are groundwater-fed, an accurate representation of groundwater processes and their interaction with surface water is crucial. With this purpose, a coupled model was recently developed linking SWAT (Soil and Water Assessment Tool) with the fully-distributed groundwater model MODFLOW (Modular Groundwater Flow). In this study, SWAT and SWAT-MODFLOW were applied to a Danish groundwater-dominant catchment, simulating groundwater abstraction scenarios and assessing the benefits and drawbacks of SWAT-MODFLOW. Both models demonstrated good performance. However, SWAT-MODFLOW provided more realistic outputs when simulating abstraction: the decrease in streamflow was similar to the volume of water abstracted, while in SWAT the impact was negligible. SWAT also showed impacts on streamflow only when abstractions were taken from the shallow aquifer, not from the deep aquifer. Overall, SWAT-MODFLOW demonstrated wider possibilities for groundwater analysis, providing more insights than SWAT in supporting decision making in relation to environmental assessment.  相似文献   

Damage localization and quantification of earthquake excited RC-frames     

P. S. Skjrbk  S. R. K. Nielsen  P. H. Kirkegaard  A. . akmak 《地震工程与结构动力学》1998,27(9):903-916

In the paper a recently proposed method for damage localization and quantification of RC-structures from response measurements is tested on experimental data. The method investigated requires at least one response measurement along the structures and the ground surface acceleration. Further, the two lowest time-varying eigenfrequencies of the structure must be identified. The data considered are sampled from a series of three RC-frame model tests performed at the structural laboratory at Aalborg University, Denmark during the autumn of 1996. The frames in the test series were exposed to two or three series of ground motions of increasing magnitude. After each of these runs the damage state of the frame was examined and each storey of the frame were classified into one of the following six classifications: undamaged, cracked, lightly damaged, damaged, severely damaged or collapse. During each of the ground motion events the storey accelerations were measured by accelerometers. After application of the last earthquake sequence to the structure the frames were cut into pieces and each of the beams and columns was statically tested and damage assessment was performed using the obtained stiffnesses. The damage in the storeys determined by the suggested method was then compared to the damage classification from the visual inspection as well as the static tests. It was found that especially in the cases where the damage is concentrated in a certain area of the structure a very good damage assessment is obtained using the suggested method. © 1998 John Wiley & Sons, Ltd.  相似文献