Cations in olivine,Part 1: Calcium partitioning and calcium-magnesium distribution between olivines and coexisting melts,with petrologic applications   总被引：2，自引：0，他引：2  

Amy J. G. Jurewicz  E. Bruce Watson 《Contributions to Mineralogy and Petrology》1988,99(2):176-185

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A MEG study of the olivine and spinel forms of Mg2SiO4     

Mark D. Jackson  Roy G. Gordon 《Physics and Chemistry of Minerals》1988,15(6):514-520

In this paper we present a theoretical investigation of the structures and relative stability of the olivine and spinel phases of Mg₂SiO₄. We use both a purely ionic model, based on the Modified Electron Gas (MEG) model of intermolecular forces, and a bond polarization model, developed for low pressure silica phases, to investigate the role of covalency in these compounds. The standard MEG ionic model gives adequate structural results for the two phases but incorrectly predicts the spinel phase to be more stable at zero pressure. This is mainly because the ionic modeling of Mg₂SiO₄ only accounts for 95 percent of the lattice energy. The remainder can be attributed to covalency and many-body effects. An extension of the MEG ionic model using “many-body” pair potentials corrects the phase stability error, but predicts structures which are in poorer agreement with experiment than the standard ionic approach. In addition, calculations using these many-body pair potentials can only account for 10 percent of the missing lattice energy. This model predicts an olivine-spinel phase transition of 8 GPa, below the experimental value of 20 GPa. Therefore, in order to understand more fully the stability of these structures we must consider polarization. A two-shell bond polarization model enhances the stability of both structures, with the olivine structure being stabilized more. This model predicts a phase transition at about 80 GPa, well above the observed value. Also, the olivine and spinel structures calculated with this approach are in poorer agreement with experiment than the ionic model. Therefore, based on our investigations, to properly model covalency in Mg₂SiO₄, a treatment more sophisticated than the two-shell model is needed.  相似文献   

Limitations and feasibility of the land disposal of organic solvent-contaminated wastes     

W. R. Roy  R. A. Griffin  J. K. Mitchell  R. A. Mitchell 《Environmental Geology》1989,13(3):225-231

The limitations and feasibility of the land disposal of solid wastes containing organic solvents and refrigerants (chlorinated fluorocarbons) were investigated by evaluating the attenuation capacity of a hypothetical waste-disposal site by numerical modeling. The basic theorem of this approach was that the land disposal of wastes would be environmentally acceptable if subsurface attenuation reduced groundwater concentrations of organic compounds to concentrations that were less than health-based, water-quality criteria. Computer simulations indicated that the predicted concentrations of 13 of 33 organic compounds in groundwater would be less than their health-based criteria. Hence, solid wastes containing these compounds could be safely disposed at the site. The attenuation capacity of the site was insufficient to reduce concentrations of four compounds to safe levels without limiting the amount of mass available to leach into groundwater. Threshold masses based on time-dependent migration simulations were estimated for these compounds. The remaining 16 compounds, which consisted mainly of chlorinated hydrocarbons and fluorocarbons could not be safely landfilled without severe restrictions on the amounts disposed. These organic compounds were candidates to ban from land disposal.  相似文献   

IGU Commission on Health and Developement     

Helen Roy  Eric Wajnberg 《GeoJournal》1989,18(4):451-451

The International Geographical Union Reports

IGU Commission on Population Geography  相似文献   

Occurrence of thorite and radioactive zircon in syenite pegmatite,North of Ashwaraopet,Khammam district,Andhra Pradesh,India     

K. Surya Prakash Rao  R. S. N. Sastry  Gautam Roy 《Journal of Earth System Science》1989,98(2):183-187

This paper reports the occurrence of thorite and confirms the earlier find of radioactive zircon by Subbarao, Murali and others from syenite pegmatite in the Vinayakapuram-Kunavaram alkaline belt in the Khammam district of Andhra Pradesh, India. Thorite has also been found as residual concentrations in soil overlying the pegmatite.  相似文献   

A simplified computational approach for prediction of transient climatic conditions in underground mine airways     

T. R. Roy 《Geotechnical and Geological Engineering》1993,11(1):15-23

Summary A simplified approach for prediction of transient climatic conditions in an underground airway os presented. The dry surface temperature of the airway is calculated using a finite difference scheme, whereas the wet surface temperature is determined following the concept of pseudo-base-temperature of air and using the value of thermal gradient at the dry surface as obtained from the finite difference solution of the temperature profile in the dry rock. The air-current temperatures are regularly evaluated after a suitable time span so as to simulate a real-case situation, and the re-evaluated air-current temperatures are used for further calculations. For increasing age of the airway the wet surface temperature obtained by the finite difference scheme, with an appropriate value of thermal diffusivity, is compared with its value determined by the pseudo-base-temperature approach.  相似文献   

Characterisation of ecological parameters in tropical forest community—A remote sensing approach     

P S Roy  Sarnam Singh  M C Porwal 《Journal of the Indian Society of Remote Sensing》1993,21(3):127-149

Satellite Remote Sensing data has been used for vegetation mapping, initial stratification, distribution of sample plots and for calculating the area under different vegetation types. Primary and secondary analyses of vegetation has been done using phytosociological ground data collected from sample piots to assess the ecological importance of different species. Interrelationships among different communities have been evaluated through various available indices. The spatial distribution and vegetation analysis indicate that commercial extraction of natural forests of Andaman has set in retrogression. The evergreen forests subjected to shorter rotation of commercial exploitation are being invaded with seral deciduous species. The study highlights the status of forests (spatial and community) and stresses the need to conserve germplasm present in the natural evergreen forests.  相似文献   

Factors Affecting Efficient Aquifer Restoration at In Situ Uranium Mine Sites     

James L. Osiensky  Roy E. Williams 《Ground Water Monitoring & Remediation》1990,10(2):107-112

In situ mining of uranium typically requires the injection of a reactive leaching solution (lixiviant) such as sodium carbonate/bicarbonate, ammonium carbonate/bicarbonate, or sulfuric acid, and an oxidant such as hydrogen peroxide or oxygen into an ore-bearing, confined aquifer. It also requires the environmental restoration of the source aquifer. The stratigraphy of sandstone uranium deposits typically consists of interbedded layers of poorly consolidated sands and clays and gravels deposited in fluvial or coastal environments. The parameters that influence the migration of lixiviant during mining and restoration in these environments include induced hydraulic gradients, hydrodynamic dispersion, heterogeneity, anisotropy, physicochemical reactions, leakage into and/or through confining layers, and convergence of flow lines due to partial well penetration.
The effectiveness of the various methods of aquifer restoration is sit -specific and is dependent upon the site hydrogeology and hydrogeochemistry, and the chemistry of the lixiviant. Each method of aquifer restoration has advantages and disadvantages. Selection of the most effective and economically feasible method requires detailed knowledge of the site-specific hydrogeologic conditions.  相似文献   

Volcano hazards program in the United States     

Robert I. Tilling  Roy A. Bailey 《Journal of Geodynamics》1985,3(3-4)

Volcano monitoring and volcanic-hazards studies have received greatly increased attention in the United States in the past few years. Before 1980, the Volcanic Hazards Program was primarily focused on the active volcanoes of Kilauea and Mauna Loa, Hawaii, which have been monitored continuously since 1912 by the Hawaiian Volcano Observatory. After the reawakening and catastrophic eruption of Mount St. Helens in 1980, the program was substantially expanded as the government and general public became aware of the potential for eruptions and associated hazards within the conterminous United States. Integrated components of the expanded program include: volcanic-hazards assessment; volcano monitoring; fundamental research; and, in concert with federal, state, and local authorities, emergency-response planning.In 1980 the David A. Johnston Cascades Volcano Observatory was established in Vancouver, Washington, to systematically monitor the continuing activity of Mount St. Helens, and to acquire baseline data for monitoring the other, presently quiescent, but potentially dangerous Cascade volcanoes in the Pacific Northwest. Since June 1980, all of the eruptions of Mount St. Helens have been predicted successfully on the basis of seismic and geodetic monitoring.The largest volcanic eruptions, but the least probable statistically, that pose a threat to western conterminous United States are those from the large Pleistocene-Holocene volcanic systems, such as Long Valley caldera (California) and Yellowstone caldera (Wyoming), which are underlain by large magma chambers still potentially capable of producing catastrophic caldera-forming eruptions. In order to become better prepared for possible future hazards associated with such historically unpecedented events, detailed studies of these, and similar, large volcanic systems should be intensified to gain better insight into caldera-forming processes and to recognize, if possible, the precursors of caldera-forming eruptions.  相似文献   

Review of coking phenomena in relation to an occurrence of prismatically fractured natural coke from the Castle Mountain mine, Matanuska coal field, Alaska     

Roy D. Merritt 《International Journal of Coal Geology》1985,4(4):281-298

Brief consideration is given to the formation and characteristics of natural coke and its similarities to industrial coke. Observations relating to an occurrence of prismatically fractured natural coke at the Castle Mountain coal mine of the central Matanuska Valley, Alaska are discussed. The temperature gradient across the naturally coked seam here is estimated to have ranged from 350°C at the top to 550°C at the bottom of the seam directly adjacent to the sill. The importance of studying coal-intrusive relationships and natural coking phenomena stems from the effects that intruding dikes and sills have on coal continuity, quality, and potential minability.  相似文献