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71.
Paleoweathering in the Sergi Formation has been classified and analyzed to ascertain its origin and relationship with stratigraphic evolution. The Sergi Formation belongs to the pre-rift sequence of the Recôncavo Basin (northeastern Brazil) and comprises a complex association of eolian and fluvial sandstones and lacustrine mudstones. This formation can be subdivided into three depositional sequences bounded by regional unconformities. Four paleoweathering types, each one related to a distinct origin, have been described in the Sergi Formation: (1) textural mottling, which is distinguished by alternating rock colors as a result of the iron oxide mobilization within mineral phases that evolved under alternating oxidation (yellowish, brownish and reddish shades) and reduction (grayish or greenish hues) conditions; (2) non-textural mottling, which displays a discoloration pattern that is independent of the original rock texture; (3) carbonate concentrations, usually related to carbonate nodule formation, which display a massive internal structure that reveals their origin through continuous growth or crystallization; and (4) banded carbonates (silicified), associated with the beginning of regular surface formation due to the chemical precipitation of carbonates within lacustrine environments. Both mottling color motifs and carbonate accumulation usually represent groundwater oscillation rather than pedogenesis. Only carbonate intraclasts and banded carbonate (silicified) have their origin ascribed to pedogenesis sensu stricto, although the carbonate intraclasts do not represent soil deposits in situ, but calcretes eroded from areas close to channels, and the banded carbonates (silicified) have strong diagenetic modifications. Therefore, it is reasonable to assume that fluvial and meteoric water have controlled paleoweathering evolution as well as deposition, yet both aspects are ruled by the same mechanisms (relief, sedimentation rate and, above all, climate).  相似文献   
72.
Opencast mining alters surface and subsurface hydrology of a landscape both during and post‐mining. At mine closure, following opencast mining in mines with low overburden to coal ratios, a void is left in the final landform. This final void is the location of the active mine pit at closure. Voids are generally not infilled within the mines' lifetime, because of the prohibitive cost of earthwork operations, and they become post‐mining water bodies or pit lakes. Water quality is a significant issue for pit lakes. Groundwater within coal seams and associated rocks can be saline, depending on the nature of the strata and groundwater circulation patterns. This groundwater may be preferentially drawn to and collected in the final void. Surface runoff to the void will not only collect salts from rainfall and atmospheric fallout, but also from the ground surface and the weathering of fresh rock. As the void water level rises, its evaporative surface area increases, concentrating salts that are held in solution. This paper presents a study of the long term, water quality trends in a post‐mining final void in the Hunter Valley, New South Wales, Australia. This process is complex and occurs long term, and modelling offers the only method of evaluating water quality. Using available geochemical, climate and hydrogeological data as inputs into a mass‐balance model, water quality in the final void was found to increase rapidly in salinity through time (2452 to 8909 mg l−1 over 500 years) as evaporation concentrates the salt in the void and regional groundwater containing high loads of salt continues to flow into the void. Copyright © 2004 John Wiley & Sons, Ltd.  相似文献   
73.
A sedimentological and geochemical study of the Lago Enol sequence (Cantabrian Mountains, northern Spain), together with detailed geomorphological mapping, provides a first record of glacier evolution and climate change over the last 40 ka in the Picos de Europa National Park. The Enol glacier retreated from its maximum extent prior to 40 ka BP as demonstrated by the onset of proglacial lacustrine sedimentation in two glaciated depressions: the Comella hollow to the north (before 40 ka BP) and the Lago Enol (before 38 ka BP). These results support previous evidence that the maximum extent of southern European glaciers occurred earlier than in northern Europe. Alternation of homogeneous and laminated proglacial sediments during the glacier retreat illustrate a dynamic glacial evolution during the Marine Isotope Stage (MIS) 3 (40–26 ka BP). A slight warming is detected at 26 ka ago with the change from proglacial sediments (in a lake located in contact to the glacier) to glaciolacustrine sedimentation (in a non‐contact or distal lake). Finally, the onset of organic‐rich sediments took place at 18 ka ago. This last transition occurred in two phases, similarly to the North Atlantic Last Termination, suggesting a link between North Atlantic Deep Water formation oscillations and palaeohydrological variability in the Cantabrian Mountains. Copyright © 2009 John Wiley & Sons, Ltd.  相似文献   
74.
Recently, the debate surrounding the United Nations Convention in the Law of the Sea (UNCLOS) and the Exclusive Economic Zones (EEZ) has been extended to the realm of economic growth and planning. Although coastal states are making efforts to determine what resources they have in their EEZs, little is known about the exact contribution those resources are making or potentially could make to enhanced economic growth. This paper suggests an accounting framework, based on existing literature, which explicity delineates the industries that should be considered a part of the marine sector. Criteria are suggested to help determine exactly where a particular industry falls. Several methodological issues are discussed in detail.The views expressed here are those of the author and do not necessarily represent those of the United Nations.  相似文献   
75.
In the summer of 1984, a three-dimensional, high-resolution microearthquake network was operated in the vicinity of two coal mines beneath Gentry Mountain in the eastern Wasatch Plateau, Utah. During a six-week period, approximately 3,000 seismic events were observed of which the majority were impulsive, higher frequency (>10 Hz), short duration (<2–3 sec) events probably associated with the caving of the roof from a longwall operation. In contrast, 234 of the largest located events appeared to occur predominantlybeneath the mines to a depth of 2 to 3 km consistent with previous studies. The magnitudes of these events ranged from less thanM c 0 to 1.6. In addition to the unusual depths of these latter events, an anomalous aspect displayed by the events was an apparent dilatational focal mechanism suggesting a non-double-couple, possibly implosional source. Implosional events have been observed in other studies of mine seismicity; however, the generally inadequate instrumental coverage of the focal sphere has cast some doubt on the validity of such mechanisms. Previously suggested source mechanisms for such implosional events have included tensional failure through strata collapse, and a shear-implosional displacement mechanism. Shear failure must be involved in the failure process of the Gentry Mountain implosional events as evidenced by well-defined shear waves in the observed seismograms. Simultaneous monitoring in the East Mountain coal mining area to the south by the University of Utah revealed typical shear failure events mixed with implosional events. The observed double-couple, reverse focal mechanisms at East Mountain were similar to mechanisms determined in previous studies and a composite focal mechanism determined in this study for a sequence outside the mining areas. This suggested that the shear events within the mining areas are being influenced by the regional tectonic stress field. Thus in addition to the seismic events associated with caving of the roof from the longwall operation, there appear to be at least two other types of mining-induced seismic events occurring in the eastern Wasatch Plateau, both submine in origin: (1) events characterized by apparent non-double-couple possibly implosional focal mechanisms and well-defined shear waves; and (2) shear events, which are indistinguishable from tectonic earthquakes and may be considered mining triggered earthquakes. The small mining-induced stress changes that occur beyond a few hundred meters from the mine workings suggest both types of seismic events are occurring on critically stressed, pre-existing zones of weakness. Topography, overburden, method of mining, and mine configuration also appear to be significant factors influencing the occurrence of the implosional submine events.  相似文献   
76.
Rank evaluation of South Brazilian Gondwana coals according to the American (American Society for Testing and Materials, ASTM) and German (Deutsche Industrie Normen, DIN) standard specifications or on the basis of Alpern's Universal Classification has too often led to conflicting results.When any attempt is made to determine the rank of Brazilian coals by using methods established for the Northern Hemisphere coals, two sorts of difficulties arise: namely, (1) the reflectence measurements do not indicate the real degree of coalification of the organic matter because of the liptinitic impregnations of the vitrinites, and (2) random reflectance values (Rran, moisture, volatile-matter and carbon contents as well as the calorific value do not correlate when plotted on the ASTM and DIN classification schemes.In addition, when rank determinations are carried out by using fluorescence measurements and geochemical analyses the results are at variance in relation to those determined by the conventional chemical and physical parameters.It is suggested that the rank evaluation of South Brazilian coals is far more meaningful if carried out by reflectance measurements on vitrinites along with fluorescence measurements on sporinites, alginites and coal extracts.  相似文献   
77.
Evaporation and infiltration were compared for tropical rainforest and pasture, near to Manaus, Brazil from October 1990 to February 1992 using measurements of soil water storage over a depth of 2 m. The soil is a clayey oxisol of low water available capacity. In both of the dry seasons studied, the maximum change in soil water storage in the forest was 154 mm and in the pasture it was 131 and 112 mm. Similar behaviour of the soil water reservoir below forest and pasture in the wet season implied that differences in evaporation and drainage were small. In the dry season, soil water storage behaviour in the upper metre of the soil was similar but there were marked differences in the second metre. The pasture took up little water from below 1.5 m but the forest appeared to utilise all of the available water in the 2 m profile in both seasons.

The water balance of the 2 m profile showed that the pasture evaporation rate was equal to that of the forest until storage had decreased 80 mm from the maximum. There was then a decline in pasture evaporation rate to 1.2 mm day−1 as the storage decreased by a further 50 mm. In contrast, the forest uptake rate remained above 3.5 mm day−1 until storage had decreased 140 mm from the maximum (within 15 mm of the extraction limit), before declining abruptly to less than 1.5 mm day−1. There was strong evidence that the forest was able to abstract water from depths greater than 3.6 m.

Spatial variability of soil water storage was significantly greater beneath the pasture than beneath the forest, particularly following rainfall events in the dry season. This was largely the result of redistribution of rainfall as local surface runoff. There was no evidence of redistribution or runoff in the forest.  相似文献   

78.
A comparative study of blue and green beryl crystals (from the region of Governador Valadares, Minas Gerais, Brazil) using electron paramagnetic resonance (EPR) and optical absorption (OA) spectroscopy is reported. The EPR spectra show that Fe3+ in blue beryl occupies a substitutional Al3+ site and in green beryl is localized in the structural channels between two O6 planes. On the other hand the infrared spectra show that the alkali content in the blue beryl is mostly at substitutional and/or interstitial sites and in green beryl is mostly in the structural channels. The OA spectra show two types of Fe2+. Thermal treatments above 200° C in green beryl cause the reduction of Fe3+ into Fe2+ accompanied by a change of color to blue. The blue beryl color does not change on heating. The kinetics of the thermal conversion of Fe3+ into Fe2+ is composed of two first order processes; the first one has an activation energy ΔE 1=0.30 eV and the second one has an activation energy ΔE 2=0.46 eV.  相似文献   
79.
80.
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