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331.
The Sørfjord has a long history of agriculture and industry, and environmental monitoring has been conducted for decades, comprising analyses of contaminants in mussel, fish and sediments. DDT was used as an insecticide in orchards surrounding the fjord between World War II and 1970. Since the early 1990s, elevated concentrations of DDT were found in mussels and fish. Unexpectedly, DDT-concentrations increased towards present day, despite the discontinuation of use. The highest concentrations in mussels (in 2006) corresponded to about two orders of magnitude higher than background. Analyses of sediment core sections also indicated increased input towards present day. Shifts in climatic parameters, as well as increased amounts of soil dissolved organic carbon following a decline in atmospheric sulphate deposition may have contributed to this phenomenon. We warrant the need for increased knowledge of the effects of alterations in variables acting regionally and globally on the disposition of contaminants in ecosystems.  相似文献   
332.
Significant attention has been given to hyporheic water fluxes induced by hydromorphologic processes in streambeds and the effects they have on stream ecology. However, the impact of hyporheic fluxes on regional groundwater flow discharge zones as well as the interaction of these flows are much less investigated. The groundwater-hyporheic interactive flow not only governs solute mass and heat transport in streams but also controls the retention of solute and contamination following the discharge of deep groundwater, such as naturally occurring solutes and leakage from geological waste disposal facilities. Here, we applied a physically based modeling approach combined with extensive hydrologic, geologic and geographical data to investigate the effect of hyporheic flow on groundwater discharge in the Krycklan catchment, located in a boreal landscape in Sweden. Regional groundwater modeling was conducted using COMSOL Multiphysics by considering geologic heterogeneity and infiltration constraint of the groundwater circulation intensity. Moreover, the hyporheic flow was analyzed using an exact spectral solution accounting for the fluctuating streambed topography and superimposed with the regional groundwater flow. By comparing the discharge flow fields with and without consideration of hyporheic flows, we found that the divergence of the discharge was substantially enhanced and the distribution of the travel times of groundwater was significantly shifted toward shorter times due to the presence of hyporheic flow. Particularly important is that the groundwater flow paths contract near the streambed interface due to the hyporheic flow, which leads to a phenomenon that we name “fragmentation” of coherent areas of groundwater upwelling in pinhole-shaped stream tubes.  相似文献   
333.
334.
We investigate the sensitivity of a coarse resolution coupled climate model to the representation of the overflows over the Greenland–Scotland ridge. This class of models suffers from a poor representation of the water mass exchange between the Nordic Seas and the North Atlantic, a crucial part of the large-scale oceanic circulation. We revisit the explicit representation of the overflows using a parameterisation by hydraulic constraints and compare it with the enhancement of the overflow transport by artificially deepened passages over the Greenland–Scotland ridge, a common practice in coarse resolution models. Both configurations increase deep water formation in the Nordic Seas and represent the large-scale dynamics of the Atlantic realistically in contrast to a third model version with realistic sill depths but without the explicit overflow transport. The comparison of the hydrography suggests that for the unperturbed equilibrium the Nordic Seas are better represented with the parameterised overflows. As in previous studies, we do not find a stabilising effect of the overflow parameterisation on the Atlantic meridional overturning circulation but merely on the overflow transport. As a consequence the surface air temperature in the Nordic Seas is less sensitive to anomalous surface fresh water forcing.Special attention is paid to changes in the subpolar gyre circulation. We find it sensitive to the overflow transport and the density of these water masses through baroclinic adjustments. The analysis of the governing equations confirms the presence of positive feedbacks inherent to the subpolar gyre and allows us to isolate the influence of the overflows on its dynamics.  相似文献   
335.
In this study we have investigated protein changes in plasma of juvenile Atlantic cod (Gadus morhua) induced by crude North Sea oil and North Sea oil spiked with alkyl phenols and polycyclic aromatic hydrocarbons, a surrogate produced water composition. Using a proteomic approach, we identified 137 differentially expressed proteins at different levels of crude oil exposure. Many of the induced protein changes occurred at low levels of exposure. The results obtained with protein expression profiles after exposure to oil and surrogate produced water indicate effects on fibrinolysis and the complement cascade, the immune system, fertility-linked proteins, bone resorption, fatty acid metabolism as well as increased oxidative stress, impaired cell mobility and increased levels of proteins associated with apoptosis. Although the number of individuals and samples in this study is limited within each treatment group, the protein changes observed in this study represent a first screening for potential biomarker candidates in cod plasma reflecting potential effects of crude oil and produced water exposure on fish.  相似文献   
336.
The possibility of using the pyrene metabolite 1-hydroxypyrene as a biomarker of polycyclic aromatic hydrocarbons (PAHs) exposure was investigated by exposure of the marine polychaete Nereis diversicolor to several PAHs in the laboratory. Animals were exposed to pyrene alone and to five different PAHs – phenanthrene, anthracene, pyrene, benzo[a]pyrene and benzo[k]flouranthene. After five days of exposure the concentrations of parent PAHs and 1-hydroxypyrene were identified using three different analytical methods, high-performance liquid chromatography with fluorescence detection (HPLC/F), synchronous fluorescence spectroscopy (SFS) and gas chromatography with mass spectrometric detection (GC/MS). The SFS measurements of 1-hydroxypyrene were validated by the more sensitive method HPLC/F. The positive correlation between total PAHs and 1-hydroxypyrene concentrations in the polychaete tissues observed in experiments, suggests the feasibility of 1-hydroxypyrene as a suitable biomarker for total PAH exposure assessment. Furthermore, the possibility of employment of the simple and rapid SFS method instead of HPLC/F for biomarker analysis has been confirmed by the positive and significant correlation between results achieved by these two analytical methods.  相似文献   
337.
The Wilson–Devinney program is used to model 27 light curves (our own and others) for CF Tuc. We find new parameters for the binary system, and estimate the longitudes and radii of the spots on the cooler secondary star. We also find a strong tendency for spots on the cooler star to appear in a limited range of longitudes, rather than to migrate fairly rapidly as for other RS CVn systems. There is evidence that the mean light level of the cooler star is varying cyclically.
The orbital period clearly changes discontinuously. We discuss this, and the apparently cyclic variations in mean light level, in relation to the model proposed by Applegate.  相似文献   
338.
Metop-GRAS in-orbit instrument performance   总被引:2,自引:1,他引:1  
The GRAS instrument on the Metop-A satellite provides more than 600 radio occultation measurement profiles per day. The instrument is characterized by its wide antenna coverage, high signal-to-noise ratio and an ultra-stable clock reference. The conventional dual-frequency tracking of GPS signals is under dynamic atmosphere conditions complemented by open loop tracking with sampling of the signal at a 1 kHz rate, providing an unprecedented view of the signal spectral environment. This paper presents the instrument performance as derived from analysis of in-orbit measurement data. We show that the noise figure is low enough to enable mapping of external radio noise variations over the earth’s surface. An error propagation model is presented to relate instrument characteristics to bending angle performance. This model is also used to illustrate the relation between filter bandwidth, resolution and measurement noise. The Doppler model, guiding open loop measurements, is found to be accurate to better than 20 Hz with a possibility for improvement to 10 Hz. The high performance at low altitudes enables the presence of surface reflections at the −20-dB level to be identified in more than 50% of the occultations. The potential performance improvements for next generation receivers are discussed.  相似文献   
339.
Biotransformation of polycyclic aromatic hydrocarbons in marine polychaetes   总被引:2,自引:0,他引:2  
Deposit-feeding polychaetes constitute the dominant macrofauna in marine environments that tend to be depositional centers for organic matter and contaminants. Polychaetes are known to accumulate polycyclic aromatic hydrocarbons (PAHs) from both particulate and dissolved phases but less is known about the mechanisms underlying elimination of accumulated PAHs. An important pathway of elimination is through biotransformation which results in increased aqueous solubility of the otherwise hydrophobic PAHs. Biotransformation in marine polychaetes proceeds in a two phased process similar to those well studied in vertebrates, phase I enzymes belonging to the Cytochrome P450 (CYP) enzyme family, along with a few phase II enzymes have been identified in marine polychaetes. In this review we aim at highlighting advances in the mechanistic understanding of PAH biotransformation in marine polychaetes by including data obtained using analytical chemistry and molecular techniques. In marine polychaetes induction of CYP enzyme activity after exposure to PAHs and the mechanism behind this is currently not well established. Conflicting results regarding the inducibility of CYP enzymes from polychaetes have led to the suggestion that induction in polychaetes is mediated through a different mechanistic pathway, which is corroborated by the apparent lack of an AhR homologous in marine polychaetes. Also, none of the currently identified CYP genes from marine polychaetes are isoforms of those regulated by the AhR in vertebrates. Relatively few studies of phase II enzymes in marine polychaetes are currently available and most of these studies have not measured the activity of specific phase II enzymes and identified phase II metabolites but used an extraction technique only allowing determination of the overall amount of phase II metabolites. Studies in insects and various marine invertebrates suggest that in invertebrates, enzymes in the important phase II enzyme family, UDP-glucuronosyl transferases primarily use glucoside as co-substrate as opposed to the vertebrate cosubstrate glucuronic acid. Recent studies in marine polychaetes have however identified glucuronidation of PAHs indicating no mechanistic difference in co-substrate preference among UDP-glucuronosyl transferases between vertebrates and marine polychaetes but it might suggest a mechanistic difference between marine polychaetes and insects.  相似文献   
340.
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