Quantitative antimony speciation in shooting-range soils by EXAFS spectroscopy   总被引：1，自引：0，他引：1  

Andreas C. Scheinost  Andre Rossberg  Irene Xifra  Ann-Kathrin Leuz  C. Annette Johnson 《Geochimica et cosmochimica acta》2006,70(13):3299-3312

The Sb speciation in soil samples from Swiss shooting ranges was determined using Sb K-edge X-ray absorption spectroscopy (XAS) and advanced statistical data analysis methods (iterative transformation factor analysis, ITFA). The XAS analysis was supported by a spectral data set of 13 Sb minerals and 4 sorption complexes. In spite of a high variability in geology, soil pH (3.1-7.5), Sb concentrations (1000-17,000 mg/kg) and shooting-range history, only two Sb species were identified. In the first species, Sb is surrounded solely by other Sb atoms at radial distances of 2.90, 3.35, 4.30 and 4.51 Å, indicative of metallic Sb(0). While part of this Sb(0) may be hosted by unweathered bullet fragments consisting of PbSb alloy, Pb L_III-edge XAS of the soil with the highest fraction (0.75) of Sb(0) showed no metallic Pb, but only Pb²⁺ bound to soil organic matter. This suggests a preferential oxidation of Pb in the alloy, driven by the higher standard reduction potential of Sb. In the second species, Sb is coordinated to 6 O-atoms at a distance of 1.98 Å, indicative of Sb(V). This oxidation state is further supported by an edge energy of 30,496-30,497 eV for the soil samples with <10% Sb(0). Iron atoms at radial distances of 3.10 and 3.56 Å from Sb atoms are in line with edge-sharing and bidentate corner-sharing linkages between Sb(O,OH)₆ and Fe(O,OH)₆ octahedra. While similar structural units exist in tripuhyite, the absence of Sb neighbors contradicts formation of this Fe antimonate. Hence the second species most likely consists of inner-sphere sorption complexes on Fe oxides, with edge and corner-sharing configuration occurring simultaneously. This pentavalent Sb species was present in all samples, suggesting that it is the prevailing species after weathering of metallic Sb(0) in oxic soils. No indication of Sb(III) was found.  相似文献   

Fluid geochemistry of natural manifestations from the Southern Poroto–Rungwe hydrothermal system (Tanzania): Preliminary conceptual model     

Manuëlla Delalande  Laurent Bergonzini  Fabrizio Gherardi  Massimo Guidi  Luc Andre  Issah Abdallah  David Williamson 《Journal of Volcanology and Geothermal Research》2011,199(1-2):127-141

The South Poroto–Rungwe geothermal field, in the northern part of the Malawi rift, Tanzania divides in two main areas. The relatively high altitude northern area around the main Ngozi, Rungwe, Tukuyu and Kyejo volcanoes, is characterised by cold and gas-rich springs. In contrast, hot springs occur in the southern and low-altitude area between the Kyela and Livingstone faults. The isotopic signature of the almost stagnant, cold springs of the Northern district is clearly influenced by H₂O–CO_2(g) exchange as evidenced from negative oxygen-shifts in the order of few deltas permil. In contrast, the isotopic signature of waters discharged from the hot springs of the Southern district is markedly less affected by the H₂O–CO_2(g) interaction. This evidence is interpreted as an effect of the large, permanent outflow of these springs, which supports the hypothesis of a regional-scale recharge of the major thermal springs. Measurements of carbon isotope variations of the dissolved inorganic carbon of waters and CO_2(g) from the Northern and Southern springs support a model of CO_2(g)-driven reactivity all over the investigated area. Our combined chemical and isotopic results show that the composition of hot springs is consistent with a mixing between (i) cold surface fresh (SFW) and (ii) Deep Hot Mineralised (DHMW) Water, indicating that the deep-originated fluids also supply most of the aqueous species dissolved in the surface waters used as local potable water. Based on geothermometric approaches, the temperature of the deep hydrothermal system has been estimated to be higher than 110 °C up to 185 °C, in agreement with the geological and thermal setting of the Malawi rift basin. Geochemical data point to (i) a major upflow zone of geothermal fluids mixed with shallow meteoric waters in the Southern part of the province, and (ii) gas absorption phenomena in the small, perched aquifers of the Northern volcanic highlands.  相似文献   

Natural and forced air temperature variability in the Labrador region of Canada during the past century     

Robert G. Way  Andre E. Viau 《Theoretical and Applied Climatology》2015,121(3-4):413-424

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The sources of geogenic arsenic in aquifers at Datong basin,northern China: Constraints from isotopic and geochemical data     

Xianjun Xie  Yanxin Wang  Andre Ellis  Chunli Su  Junxia Li  Mengdi Li 《Journal of Geochemical Exploration》2011

Mineralogical, geochemical and zircon U–Pb dating studies were carried out to identify the sources of arsenic in the shallow aquifers of Datong Basin in northern China. A sediment sample from 18 m depth containing 10.3 mg/kg arsenic showed a Zircon U–Pb concordant age of 2528 ± 20 to 271 ± 4 Ma that can be divided into two groups (2528 ± 20 to 1628 ± 21 Ma and 327 ± 4 to 271 ± 4 Ma) and is comparable to that of the sedimentary rocks of Taiyuan (upper Carboniferous) and Shanxi Formation (lower Permian) outcropping to the west of Datong Basin. In contrast, a sediment sample from 22.5 m depth containing 5.7 mg/kg arsenic displayed a Zircon U–Pb concordant age ranging from 2561 ± 21 to 1824 ± 26 Ma that is comparable to that of the Hengshan Complex (Ne-Archaean Precambrian) outcropping to the east of .  相似文献   

Spatial distribution and general population characteristics of mysid shrimps in the Westerschelde estuary (SW Netherlands)     

Karen Rappé  Nancy Fockedey  Carl Van Colen  Andre Cattrijsse  Jan Mees  Magda Vincx 《Estuarine, Coastal and Shelf Science》2011

The distribution and general population characteristics of five mysid shrimps were investigated in the period 2003–2005 in the Westerschelde estuary, a tidal temperate estuary situated along the Dutch–Belgian border. Multivariate analyses revealed that salinity predominantly governs the spatial distribution of Neomysis integer, Gastrosaccus spinifer, Schistomysis kervillei and Schistomysis spiritus while temperature, and to a lesser extent turbidity, control the distribution of Mesopodopsis slabberi. N. integer is a resident species in the mesohaline zone of the estuary, i.e. all life stages of the species are present in the estuary throughout the year. For the first time since decades N. integer inhabits the oligohaline zone of the estuary supposedly as a consequence of improved oxygen conditions in the upstream reaches. M. slabberi, the most abundant mysid in the Westerschelde, dominates the hyperbenthos of the mesohaline zone of the estuary. The polyhaline zone of the estuary is, most abundantly inhabited by M. slabberi, G. spinifer, S. kervillei and to a lesser extent by S. spiritus. The abundance of the latter four species is low in winter, probably due to a migration towards coastal waters to avoid colder temperatures in the estuary combined with an increased mortality after breeding. The sex ratio of all the mysid populations corresponds to the expected 1:1 female:male ratio and no salinity governed segregation is found between the different life stages of each mysid population. A seasonal variation exists in brood size in the N. integer population regardless of the body size, with a larger number of broods during winter and spring compared to the summer. In the other mysid populations the brood sizes vary only with the length of the ovigerous females.  相似文献   

Uraniferous bitumen nodules in the Talvivaara Ni–Zn–Cu–Co deposit (Finland): influence of metamorphism on uranium mineralization in black shales     

Andreï Lecomte  Michel Cathelineau  Etienne Deloule  Marc Brouand  Chantal Peiffert  Kirsti Loukola-Ruskeeniemi  Esa Pohjolainen  Hannu Lahtinen 《Mineralium Deposita》2014,49(4):513-533

In the central part of the Fennoscandian Shield, the Talvivaara Ni–Zn–Cu–Co deposit, hosted by Palaeoproterozoic metamorphosed black schists, contains low uranium concentrations ranging from 10 to 30 ppm. The Talvivaara black schists were deposited 2.0–1.9 Ga ago and underwent subsequent metamorphism during the 1.9–1.79 Ga Svecofennian orogeny. Anhedral uraninite crystals rimmed by bitumen constitute the main host of uranium. U–Pb secondary ion mass spectrometry dating indicates that uraninite crystals were formed between 1,878?±?17 and 1,871?±?43 Ma, during peak metamorphism. Rare earth element patterns and high Th content (average 6.38 wt%) in disseminated uraninite crystals indicate that U was concentrated during high temperature metamorphism (>400 °C). The formation of bitumen rims around uraninite may be explained by two distinct scenarios: (a) a transport of U coincident with the migration of hydrocarbons or (b) post-metamorphic formation of bitumen rims, through radiolytic polymerization of gaseous hydrocarbons at the contact with uraninite.  相似文献   

Correction to: Evaluation of a multi-model approach to estimate leaf wetness duration: an essential input for disease alert systems     

Gama  Andre B.  Perondi  Daniel  Dewdney  Megan M.  Fraisse  Clyde W.  Small  Ian M.  Peres  Natalia A. 《Theoretical and Applied Climatology》2022,149(1-2):101-101

Theoretical and Applied Climatology -  相似文献   

Geochemical indicators of interbasin groundwater flow within the southern Rio Grande Valley, southwestern USA     

Jeff B. Langman  Andre S. Ellis 《Environmental Earth Sciences》2013,68(5):1285-1303

Increased groundwater withdrawals for the growing population in the Rio Grande Valley and likely alteration of recharge to local aquifers with climate change necessitates an understanding of the groundwater connection between the Jornada del Muerto Basin and the adjoining and more heavily used aquifer in the Mesilla Basin. Separating the Jornada and Mesilla aquifers is a buried bedrock high from Tertiary intrusions. This bedrock high or divide restricts and/or retards interbasin flow from the Jornada aquifer into the Mesilla aquifer. The potentiometric surface of the southern Jornada aquifer near part of the bedrock high indicates a flow direction away from the divide because of a previously identified damming effect, but a groundwater outlet from the southern Jornada aquifer is necessary to balance inputs from the overall Jornada aquifer. Differences in geochemical constituents (major ions, δD, δ¹⁸O, δ³⁴S, and ⁸⁷Sr/⁸⁶Sr) indicate a deeper connection between the two aquifers through the Tertiary intrusions where Jornada water is geochemically altered because of a geothermal influence. Jornada groundwater likely is migrating through the bedrock high in deeper pathways formed by faults of the Jornada Fault Zone, in addition to Jornada water that overtops the bedrock high as previously identified as the only connection between the two aquifers. Increased groundwater withdrawals and lowering of the potentiometric surface of the Jornada aquifer may alter this contribution ratio with less overtopping of the bedrock high and a continued deeper flowpath contribution that could potentially increase salinity values in the Mesilla Basin near the divide.  相似文献   

Limitation of fluid flow at the Nankai Trough megasplay fault zone     

Sebastian B. Hammerschmidt  Earl E. Davis  Andre Hüpers  Achim Kopf 《Geo-Marine Letters》2013,33(5):405-418

Along the Nankai Trough megasplay fault off SE Japan, the effect of fluid migration on subduction-related seismogenesis and tsunamigenesis remains unresolved. To investigate the existence and role of fluid flow, a SmartPlug borehole observatory was installed at Site C0010 of the Integrated Ocean Drilling Program NanTroSEIZE Kumano transect, where a shallow branch of the fault was intersected and in situ fluid pressure monitored from August 2009 to November 2010. The tidal signal in the formation showed no phase shift relative to seafloor loading. The attenuation of 0.73 reflects the loading efficiency accurately, and enabled calculation of a formation compressibility of 1.0×10^–9 Pa^–1 and a hydraulic diffusivity (HD) of 1.5×10^–5 m² s^–1. A similar HD is predicted by a tidal response model based on SmartPlug pressure data. By contrast, permeability measurements on intact samples from Site C0004 SE along-strike the splay fault and from Site C0006 in the frontal thrust zone were found to be similar and one magnitude smaller respectively, despite having a higher porosity. This is explained by the presence of fractures, which are covered by the larger scale of in situ measurements at Site C0010. Consequently, HD can be set to be at least 10^–5 m² s^–1 for the splay fault and 10^–6 m² s^–1 for the frontal thrust fault zone. Considering recent publications makes fluid flow at the splay fault unlikely, despite the presence of fractures. If the influence of fractures is limited, then processes leading to fault weakening may be enhanced.  相似文献   

First recorded evidence in the fossil record of snipe flies (Diptera: Rhagionidae) in Cretaceous amber, France     

Mnica Morayma Solrzano Kraemer  Andre Nel 《Cretaceous Research》2009,30(6):1367-1375

Novelaria, a new genus of rhagionid of late Albian age with three new species, is the first record of this family from Charentes amber (southwestern France). The new genus is probably closely related to the recent genus Chrysopilus. However its relationship with the other fossils in amber is discussed. A key for separation of the new species is provided and the diversity of the family during the Cretaceous is also briefly discussed.  相似文献