Silicon isotopic fractionation of CAI-like vacuum evaporation residues     

Kim B. Knight  Noriko T. Kita  Frank M. Richter  Andrew M. Davis  John W. Valley 《Geochimica et cosmochimica acta》2009,73(20):6390-5891

Calcium-, aluminum-rich inclusions (CAIs) are often enriched in the heavy isotopes of magnesium and silicon relative to bulk solar system materials. It is likely that these isotopic enrichments resulted from evaporative mass loss of magnesium and silicon from early solar system condensates while they were molten during one or more high-temperature reheating events. Quantitative interpretation of these enrichments requires laboratory determinations of the evaporation kinetics and associated isotopic fractionation effects for these elements. The experimental data for the kinetics of evaporation of magnesium and silicon and the evaporative isotopic fractionation of magnesium is reasonably complete for Type B CAI liquids (Richter F. M., Davis A. M., Ebel D. S., and Hashimoto A. (2002) Elemental and isotopic fractionation of Type B CAIs: experiments, theoretical considerations, and constraints on their thermal evolution. Geochim. Cosmochim. Acta66, 521-540; Richter F. M., Janney P. E., Mendybaev R. A., Davis A. M., and Wadhwa M. (2007a) Elemental and isotopic fractionation of Type B CAI-like liquids by evaporation. Geochim. Cosmochim. Acta71, 5544-5564.). However, the isotopic fractionation factor for silicon evaporating from such liquids has not been as extensively studied. Here we report new ion microprobe silicon isotopic measurements of residual glass from partial evaporation of Type B CAI liquids into vacuum. The silicon isotopic fractionation is reported as a kinetic fractionation factor, α_Si, corresponding to the ratio of the silicon isotopic composition of the evaporation flux to that of the residual silicate liquid. For CAI-like melts, we find that α_Si = 0.98985 ± 0.00044 (2σ) for ²⁹Si/²⁸Si with no resolvable variation with temperature over the temperature range of the experiments, 1600-1900 °C. This value is different from what has been reported for evaporation of liquid Mg₂SiO₄ (Davis A. M., Hashimoto A., Clayton R. N., and Mayeda T. K. (1990) Isotope mass fractionation during evaporation of Mg₂SiO₄. Nature347, 655-658.) and of a melt with CI chondritic proportions of the major elements (Wang J., Davis A. M., Clayton R. N., Mayeda T. K., and Hashimoto A. (2001) Chemical and isotopic fractionation during the evaporation of the FeO-MgO-SiO₂-CaO-Al₂O₃-TiO₂-REE melt system. Geochim. Cosmochim. Acta65, 479-494.). There appears to be some compositional control on α_Si, whereas no compositional effects have been reported for α_Mg. We use the values of α_Si and α_Mg, to calculate the chemical compositions of the unevaporated precursors of a number of isotopically fractionated CAIs from CV chondrites whose chemical compositions and magnesium and silicon isotopic compositions have been previously measured.  相似文献   

The ‘war for talent’: The gatekeeper role of executive search firms in elite labour markets     

James R. Faulconbridge  Jonathan V. Beaverstock  Andrew Hewitson 《Geoforum》2009,40(5):800-808

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Proximity and power within investment relationships: The case of the UK private equity industry     

Andrew Jones  Paul Search 《Geoforum》2009,40(5):809-819

The role of power in economic activity has been researched across the social sciences but there has been little engagement with the spatialities of power relations. This paper thus draws on a recent reinvigorated interest in power within economic geography to develop an approach for understanding how the spatiality of power relations in economic practices are constituted through different forms of proximity. It argues that proximity needs to be conceptualised as multi-dimensional including physical, cultural, virtual and organizational proximity between firms and actors. It further contends that the development of different forms of proximity shape the agency of empowered actors in industry clusters and regional economies. This general proposition is explored by presenting research into a case study: the UK-based private equity industry. The research focuses on the nature, role and development of different forms of proximity between private equity firms and the investee firms that are the subject of investments.  相似文献   

Plesiosaur remains from the Jurassic-Cretaceous Purbeck Limestone Group of southern England     

Benjamin P. Kear  Andrew R. Milner  Paul M. Barrett 《Proceedings of the Geologists' Association. Geologists' Association》2009,120(2-3):121-125

Plesiosaur fossils from the uppermost Tithonian (Upper Jurassic) to lower Valanginian (Lower Cretaceous) Purbeck Limestone Group of Dorset, England are important because they constitute a rare record from around the Jurassic-Cretaceous boundary. Where diagnostic, the remains are referred to indeterminate plesiosauroids (Cryptocleidoidea) and represent relatively small animals including a previously undescribed juvenile individual. This observation accords with the lagoonal-lacustrine (with periodic marine influx) depositional setting of the Purbeck Limestone Group strata, a palaeoenvironment that is often associated with juvenile plesiosaur occurrences.  相似文献   

Mineralogical control of rare earth elements in acid sulfate soils     

Susan A. Welch  Andrew G. Christy  Lloyd Isaacson  Dirk Kirste 《Geochimica et cosmochimica acta》2009,73(1):44-177

Major, trace and rare earth element concentrations were measured in porewater, surface water and sediments at an acid sulfate soil site. The concentrations of La and Ce in porewater are up to 1-3 ppm. There is a strong correlation between REE concentration and acidity, except that the maximum concentrations were consistently found below the horizon of maximum acidity, associated with an increase in pH (to ca. 4) and change in mineralogy from jarosite-dominated to goethite-dominated mottles. Jarosite replacement by goethite is as expected with the rise in pH, which in turn is due to the occurrence of a fossil shell bed just below. The rare earth element patterns in the porewaters are enriched in the MREE with respect to Post-Archaean Australian Shale (PAAS). Measurements and calculations show that this is in accord with experiments on low-degree partial dissolution of jarosite, even when the jarosite itself is highly enriched in LREE. There is a clear fractionation in the patterns between the clay-rich soil matrix, which is slightly depleted in the LREE when normalized to PAAS (La/Yb_PAAS ∼0.5), and the secondary mineral phase jarosite, which is enriched in the LREE (La/Yb_PAAS = 15-50). The REE pattern in the porewater changes with the transition from jarosite- to goethite-rich mottles, becoming relatively more enriched in the LREE compared to the HREE, which is consistent with the incongruent dissolution of jarosite to form goethite and the release of greater amounts of jarosite REE to solution, including proportionately more of the jarosite-compatible LREE.Maximum surface water REE concentrations in acidic water were 100-200 ppb La and Ce. REE patterns in surface water were very similar to the porewater transition zone, enriched in the MREE, but asymmetric, relatively enriched in the LREE compared to the HREE.  相似文献   

Bioreduction of hematite nanoparticles by the dissimilatory iron reducing bacterium Shewanella oneidensis MR-1     

Saumyaditya Bose  Michael F. Hochella Jr.  David W. Kennedy  Andrew S. Madden 《Geochimica et cosmochimica acta》2009,73(4):962-976

We examined the reduction of different size hematite (α-Fe₂O₃) nanoparticles (average diameter of 11, 12, 30, 43, and 99 nm) by the dissimilatory iron reducing bacteria (DIRB), Shewanella oneidensis MR-1, to determine how S. oneidensis MR-1 may utilize these environmentally relevant solid-phase electron acceptors. The surface-area-normalized-bacterial Fe(III) reduction rate for the larger nanoparticles (99 nm) was one order of magnitude higher than the rate observed for the smallest nanoparticles (11 nm). The Fe(III) reduction rates for the 12, 30, and 43 nm nanoparticles fell between these two extremes. Whole-cell TEM images showed that the mode of Fe₂O₃ nanoparticle attachment to bacterial cells was different for the aggregated, pseudo-hexagonal/irregular and platey 11, 12, and 99 nm nanoparticles compared to the non-aggregated 30 and 43 nm rhombohedral nanoparticles. Due to differences in aggregation, the 11, 12, and 99 nm nanoparticles exhibited less cell contact and less cell coverage than did the 30 and 43 nm nanoparticles. We hypothesize that S. oneidensis MR-1 employs both indirect and direct mechanisms of electron transfer to Fe(III)-oxide nanoparticles and that the bioreduction mechanisms employed and Fe(III) reduction rates depend on the nanoparticles’ aggregation state, size, shape and exposed crystal faces.  相似文献   

Detecting inter-aquifer leakage in areas with limited data using hydraulics and multiple environmental tracers,including <Superscript>4</Superscript>He, <Superscript>36</Superscript>Cl/Cl, <Superscript>14</Superscript>C and <Superscript>87</Superscript>Sr/<Superscript>86</Superscript>Sr     

Stacey C. Priestley  Daniel L. Wohling  Mark N. Keppel  Vincent E. A. Post  Andrew J. Love  Paul Shand  Lina Tyroller  Rolf Kipfer 《Hydrogeology Journal》2017,25(7):2031-2047

The investigation of regionally extensive groundwater systems in remote areas is hindered by a shortage of data due to a sparse observation network, which limits our understanding of the hydrogeological processes in arid regions. The study used a multidisciplinary approach to determine hydraulic connectivity between the Great Artesian Basin (GAB) and the underlying Arckaringa Basin in the desert region of Central Australia. In order to manage the impacts of groundwater abstraction from the Arckaringa Basin, it is vital to understand its connectivity with the GAB (upper aquifer), as the latter supports local pastoral stations and groundwater-dependent springs with unique endemic flora and fauna. The study is based on the collation of available geological information, a detailed analysis of hydraulic data, and data on environmental tracers. Enhanced inter-aquifer leakage in the centre of the study area was identified, as well as recharge to the GAB from ephemeral rivers and waterholes. Throughout the rest of the study area, inter-aquifer leakage is likely controlled by diffuse inter-aquifer leakage, but the coarse spatial resolution means that the presence of additional enhanced inter-aquifer leakage sites cannot be excluded. This study makes the case that a multi-tracer approach along with groundwater hydraulics and geology provides a tool-set to investigate enhanced inter-aquifer leakage even in a groundwater basin with a paucity of data. A particular problem encountered in this study was the ambiguous interpretation of different age tracers, which is attributed to diffusive transport across flow paths caused by low recharge rates.  相似文献   

Calcite twinning strain variations across the Proterozoic Grenville orogen and Keweenaw-Kapuskasing inverted foreland,USA and Canada     

John P. Craddock  Suzanne D. Craddock  Alex Konstantinou  Andrew R.C. Kylander-Clark  David H. Malone 《地学前缘(英文版)》2017,8(6):1357-1384

We report the calcite twinning strain results of a traverse across the Grenville orogen from Parry Sound, Ontario (NW) to Ft. Ann, New York (SE), including the younger, adjacent Ordovician Taconic allochthon. Fifty four carbonates (marbles, calcite veins, Ordovician limestone) were collected resulting in 68 strain analyses on mechanically twinned calcite (n = 2337 grains) across the Central Gneiss Belt (CGB; 3 samples), the Central Metasedimentary Belt (CMB; 27 samples), the Central Granulite Terrane (CGT; Adirondack's; 13 samples) and the Ottawan Orogenic Lid (OOL; 11 samples). Twinning strains in the greenschist-grade OOL marbles preserve N–S shortening and U-Pb titanite ages (～1150 Ma; n = 4) document these marbles formed during the Shawinigan (1190–1140 Ma) part of the Grenville orogen. From northwest to southeast, the Ottawan (1095–1020 Ma) twinning strain is dominantly a layer-parallel shortening fabric oriented N–S (Parry Sound), then becomes parallel to the Grenville thrust direction (NW–SE) across the CMB to the Adirondack Highlands where the sub-horizontal shortening strain becomes margin-parallel (SW–NE). Within the regional sample suite there are two areas studied in detail, the Bancroft shear zone (n = 11) and a roadcut on the southeast side of the Adirondack Mountains (Ft. Ann, NY; n = 8). Marbles from the Bancroft shear zone contain calcite grains with 2 sets of twin lamellae (e₁ and e₂). The better-developed e₁ sets (n = 406) record a horizontal fabric oriented NW–SE whereas the younger e₂ lamellae (n = 146) preserve a margin-parallel (SW–NE) horizontal fabric. Both the e₁ and e₂ strains record an overprint vertical shortening strain (NEV), perhaps related to extensional orogenic collapse. We also report an Ottawan orogen-aged granoblastic mylonite (1093 Ma, U-Pb zircon; 1102 Ma Ar-Ar biotite) in the Keweenaw thrust hanging wall 500 km inboard of the Grenville front and interpret the relations of Grenville-Keweenaw far-field dynamics.  相似文献   

Effect of diffuse recharge and wastewater on groundwater contamination in Douala,Cameroon     

Mengnjo Jude Wirmvem  Takeshi Ohba  Linus Anye Nche  Brice Tchakam Kamtchueng  Wiylahnyuy Edith Kongnso  Mumbfu Ernestine Mimba  Tasin Godlove Bafon  Muga Yaguchi  Gloria Eneke Takem  Wilson Yetoh Fantong  Ako Andrew Ako 《Environmental Earth Sciences》2017,76(9):354

High water demand for domestic use in Douala with over 3 million inhabitants is met mainly by shallow groundwater. Field measurements and water sampling in January 2015 were carried out to examine the major controls on the groundwater composition and spatial view of ions in the water, timing of recharge and link between the recharge process and quality of the water. Fifty-two water samples were analysed for major ions and stable hydrogen and oxygen isotopes. Low pH values (3.61–6.92) in the groundwater indicated an acidic aquifer; thus, prone to acidification. The dominant water type was Na–Cl. Nitrate, which exceeded the WHO guide value of 50 mg/l in 22% of the groundwater, poses a health problem. Mass ratios of Cl^?/Br^? in the water ranged from 54 to 3249 and scattered mostly along the mixing lines between dilute waters, septic-tank effluent and domestic sewage. A majority of the samples, especially the high NO₃ ^? shallow wells, clustered around the septic-tank effluent-end-member indicating high contamination by seepage from pit latrines; hence, vulnerable to pollution. Stable isotopes in the groundwater indicated its meteoric origin and rapid infiltration after rainfall. The δ¹⁸O values showed narrow ranges and overlaps in rivers, springs, open wells and boreholes. These observations depict hydraulic connectivity, good water mixing and a homogeneous aquifer system mainly receiving local direct uniform areal recharge from rainfall. The rapid and diffused recharge favours the leaching of effluent from the pit toilets into the aquifer; hence, the high NO₃ ^? and Cl^? in shallow wells. Silicate weathering, ion exchange and leaching of waste from pit toilets are the dominant controls on the groundwater chemistry. Drilling of deep boreholes is highly recommended for good-quality water supply. However, due the hydraulic connection to the shallow aquifer, geochemical modelling of future effects of such an exploitation of the deeper aquifer should support groundwater management and be ahead of the field actions.  相似文献   

Fold crest degradation and slump deposition in the deepwater Niger Delta,Nigeria     

Byami Andrew Jolly  Jeremiah Ayok  Okwudiri A Anyiam 《Arabian Journal of Geosciences》2017,10(2):34

This study uses 3D seismic reflection dataset to investigate the time-integrated growth and degradation of fault-propagation folds and associated slump deposits in the deepwater Niger Delta. The results of the analysis showed that slump deposits are sourced almost entirely from the degradation of growing fold crests—resulting in the development of seaward-facing scarps on the forelimbs of these folds. The scarps develop parallel to fold axes and have dips that range between 4° SW and 20° SW. The constant presence of fan-shaped slump deposits downdip of these scarps suggests a direct relationship to fold crest degradation. Moreover, the spatio-temporal distribution of the slumps also shows a direct relationship with the heights of seabed scarps along the strike of growing folds. Slumps have short run-out distances (generally less than 5 km); however, they also travel long distances downslope (up to 10 km) across growing structures by exploiting relay areas between growing scarps.  相似文献