Characterisation and sediment–source linkages of intertidal sediment of the UK’s north Sefton Coast using magnetic and textural properties: findings and limitations     

Vanessa J. C. Holden  Annie T. Worsley  Colin A. Booth  Graham Lymbery 《Ocean Dynamics》2011,61(12):2157-2179

Sediment pathways and links to offshore processes are considered in the textural and magnetic characteristics of sediments of the intertidal flats and salt marshes of the north Sefton Coast, UK. In addition, sediment from a range of intertidal, marine and fluvial locations within the northwest region has similarly been characterised. Subsequently, the characteristics of these regional sediments, using a multivariate statistical approach of R- and Q-mode factor analyses, have been used to investigate the sediment transport pathways of the north Sefton Coast sediment. The benefits of fractionating sediment samples have been observed, and by using combinations of textural and isothermal remanent magnetic measurements, specific environments within the research have been successfully differentiated and characterised. Linkages between potential sediment source areas have also been established on a particle size-related basis.  相似文献   

Kinetics of neptunium(V) sorption and desorption on goethite: An experimental and modeling study     

Ruth M. Tinnacher  Mavrik Zavarin  Annie B. Kersting 《Geochimica et cosmochimica acta》2011,75(21):6584-6599

Various sorption phenomena, such as aging, hysteresis and irreversible sorption, can cause differences between contaminant (ad)sorption and desorption behavior and lead to apparent sorption ‘asymmetry’. We evaluate the relevance of these characteristics for neptunium(V) (Np(V)) sorption/desorption on goethite using a 34-day flow-cell experiment and kinetic modeling. Based on experimental results, the Np(V) desorption rate is much slower than the (ad)sorption rate, and appears to decrease over the course of the experiment. The best model fit with a minimum number of fitting parameters was achieved with a multi-reaction model including (1) an equilibrium Freundlich site (site 1), (2) a kinetically-controlled, consecutive, first-order site (site 2), and (3) a parameter ψ_2,de, which characterizes the desorption rate on site 2 based on a concept related to transition state theory (TST). This approach allows us to link differences in adsorption and desorption kinetics to changes in overall reaction pathways, without assuming different adsorption and desorption affinities (hysteresis) or irreversible sorption behavior a priori. Using modeling as a heuristic tool, we determined that aging processes are relevant. However, hysteresis and irreversible sorption behavior can be neglected within the time-frame (desorption over 32 days) and chemical solution conditions evaluated in the flow-cell experiment. In this system, desorption reactions are very slow, but they are not irreversible. Hence, our data do not justify an assumption of irreversible Np(V) sorption to goethite in transport models, which effectively limits the relevance of colloid-facilitated Np(V) transport to near-field environments. However, slow Np(V) desorption behavior may also lead to a continuous contaminant source term when metals are sorbed to bulk mineral phases. Additional long-term experiments are recommended to definitely rule out irreversible Np(V) sorption behavior at very low surface loadings and environmentally-relevant time-scales.  相似文献   

Field Tracer Test for the Design of LNAPL Source Zone Surfactant Flushing          下载免费PDF全文

Thomas Robert  Richard Martel  René Lefebvre  Jean‐Marc Lauzon  Annie Morin 《Ground Water Monitoring & Remediation》2016,36(2):68-82

A field tracer test was carried out in a light nonaqueous phase liquid (LNAPL) source zone using a well pattern consisting of one injection well surrounded by four extraction wells (5‐spot well pattern). Multilevel sampling was carried out in two observation wells located inside the test cell characterized by heterogeneous lithology. Tracer breakthrough curves showed relatively uniform flow within soil layers. A numerical flow and solute transport model was calibrated on hydraulic heads and tracer breakthrough curves. The model was used to estimate an average accessible porosity of 0.115 for the swept zone and an average longitudinal dispersivity of 0.55 m. The model was further used to optimize the relative effects of viscous forces versus capillary forces under realistic imposed hydraulic gradients and to establish optimal surfactant solution properties. Maximum capillary number (N_Ca) values between injection and extraction wells were obtained for an injection flow rate of 16 L/min, a total extraction flow rate of 20 L/min, and a surfactant solution with a viscosity of 0.005 Pa?s. The unconfined nature of the aquifer limited further flow rate or viscosity increases that would have led to unrealistic hydraulic gradients. An N_Ca range of 3.8 × 10^?4 to 7.6 × 10^?3 was obtained depending on the magnitude of the simulated LNAPL‐water interfacial tension reduction. Finally, surfactant and chase water slug sizing was optimized with a radial form of the simplified Ogata‐Banks analytical solution (Ogata and Banks 1961) so that injected concentrations could be maintained in the entire 5‐spot cell.  相似文献   

Crop area mapping in West Africa using landscape stratification of MODIS time series and comparison with existing global land products   总被引：6，自引：0，他引：6  

Elodie Vintrou  Annie DesbrosseAgnès Bégué  Sibiry TraoréChristian Baron  Danny Lo Seen 《International Journal of Applied Earth Observation and Geoinformation》2012,14(1):83-93

In Africa, food security early warning systems use satellite-derived data concerning crop conditions and agricultural production. Such systems can be improved if they are provided with a more reliable estimation of the cultivated area at national scale. This paper evaluates the potential of using time series from the MODerate resolution Imaging Spectroradiometer MOD13Q1 (16-day composite of normalized difference vegetation index at 250 m resolution) to extract cultivated areas in the fragmented rural landscapes of Mali. To this end, we first stratified Southern Mali into 13 rural landscapes based on the spatio-temporal variability of NDVI and textural indices, using an object-oriented classification scheme.The accuracy of the resulting map (MODIS_crop) and how it compares with existing coarse-resolution global land products (GLC2000 Africa, GLOBCOVER, MODIS V05 and ECOCLIMAP-II), was then assessed against six crop/non-crop maps derived from SPOT 2.5 m resolution images used as references. For crop areal coverage, the MODIS_crop cultivated map was successful in assessing the overall cultivated area at five out of the six validation sites (less than 6% of the absolute difference), while in terms of crop spatial distribution, the producer accuracy was between 33.1% and 80.8%. This accuracy was linearly correlated with the mean patch size index calculated on the SPOT crop maps (r² = 0.8). Using the Pareto boundary as an accuracy assessment method at the study sites, we showed that (i) 20-40% of the classification crop error was due to the spatial resolution of the MODIS sensor (250 m), and that (ii) compared to MODIS V05, which otherwise performed better than the other existing products, MODIS_crop generally minimized omission-commission errors. A spatial validation of the different products was carried out using SPOT image classifications as reference. In the corresponding error matrices, the fraction of correctly classified pixels for our product was 70%, compared to 58% for MODIS V05, while it ranged between 40% and 51% for the GLC2000, the ECOCLIMAP-II and the GLOBCOVER.  相似文献   

Modeling of cadmium speciation and dynamics in the Seine estuary (France)     

Jean-Louis Gonzalez  Benedicte Thouvenin  Catherine Dange  Annie Fiandrino  Jean-François Chiffoleau 《Estuaries and Coasts》2001,24(6):1041-1055

A complexation model (MOCO) was used to describe cadmium (Cd) speciation during estuarine transit in the Seine estuary. This model was developed from field data. Laboratory experiments based on the use of¹⁰⁹Cd enabled checking of certain model simplifications and hypotheses and evaluation of parameters which could not be measured directly. MOCO was coupled with a 3D multivariable hydrosedimentary model (SAM3D) to simulate Cd dynamics in the estuary. These results were compared with measurements (dissolved and particulate Cd) obtained during cruises representative of various hydrodynamic conditions. The purpose of this article is to present the modeling approach used, and its expected applications and limits.  相似文献   

238U-206Pb, 235U-207Pb,systematics on Pyrenean basement     

Annie Vitrac-Michard  Claude J. Allègre 《Contributions to Mineralogy and Petrology》1975,51(3):205-212

U-Pb ages for zircons of pyreneean gneisses and associated granites are comparable to whole rock Rb-Sr ages of 580, 320 m.y. and recent. Inherited radiogenic Pb in the granites limits the dating accuracy but points out an important contribution of crustal material in their formation.  相似文献   

Assimilation of continental crust by komatiites in the Precambrian basement of the Carswell structure (Saskatchewan,Canada)     

Martine Juteau  Maurice Pagel  Annie Michard  Francis Albarede 《Contributions to Mineralogy and Petrology》1988,99(2):219-225

The isotope geochemistry (Sm-Nd, Pb-Pb and Rb-Sr) of mafic gneisses from the basement of the Carswell structure (Saskatchewan, Canada), rich both in Mg and incompatible elements (K, Rb, REE) has been investigated. A good Sm-Nd alignment gives a slope corresponding to an age of 3.7 Ga. However, comparison with major elements data strongly suggests that this alignment is a mixing line between Mg-rich, high CaO/Al₂O₃ magmas and the local felsic crust older than 2.9 Ga. The mafic magmas were probably of komatiitic affinity (MgO > 20 percent) but, nevertheless, were extracted from a source with nearly chondritic to slightly enriched light REE distribution. The age of the komatiite emplacement (1.9–2.9 Ga) is only loosely constrained by the oldest crustal residence age in the series and the subsequent metamorphic events. The granulite facies climax is dated at ca. 1.9 Ga by concordant whole rock Pb-Pb and Sm-Nd garnet-whole rock isochrons. The Rb-Sr systematics have been disturbed by later event(s) younger than 1.5–1.7 Ga, but do not permit a more precise assessment of the perturbation age.  相似文献   

Electrochemical measurements bearing on the oxidation state of the Skaergaard Layered Intrusion     

Annie B. Kersting  Richard J. Arculus  John W. Delano  Daniel Loureiro 《Contributions to Mineralogy and Petrology》1989,102(3):376-388

The oxygen fugacities (fO₂'s) of magnetically-concentrated fractions (MCF) of three rock samples from the Skaergaard Layered Intrusion were measured between 800–1150° C using oxygen-specific, solid zirconia electrolytes at atmospheric pressure. Two of the bulk rock samples (an oxide cumulate and an oxide-bearing gabbro) are from the Middle Zone (MZ) and the other (an olivine plagioclase orthocumulate) is from the Lower Zone (LZ). All MCF define fO₂ versus T arrays that lie 1.5–0.5 log units above the fayalite-magnetite-quartz (FMQ) buffer. Experiments with different cell-imposed initial redox states (one from a reduced direction and one from an oxidized direction) were run on each sample in an attempt to achieve experimental reversibility. This was accomplished by imposing a known redox memory on the galvanic cell prior to loading each sample. Reversibility for each sample agreed to better than 0.2 of a log unit. Irreversible autoreduction of 0.2 of a log unit was observed on the two MZ samples at temperatures exceeding 1065° C. Scanning electron microscope and electron microprobe study of pre- and post-run products shows that reaction and textural re-equilibration occurred among the oxide phase assemblages under the experimental conditions employed. Careful characterization of pre- and post-run assemblages is clearly necessary before adequate interpretation of the experimental results can be made in these types of electrochemical studies. Different approaches to investigations of the fO₂ of the Skaergaard Intrusion, be it thermodynamic calculations or experimental methods, should yield concordant results or at least understandable discrepancies. Calculated fO₂'s using thermobarometry applied to the ilmenite-magnetite pairs in the post-experimental assemblages agree with the experimentally determined fO₂'s to within one log unit at a given temperature. These results are also consistent with previously calculated fO₂ values (Buddington and Lindsley 1964; Morse et al. 1980), but are considerably more oxidized than a previous electrolyte-based fO₂ study of a different sample suite from the Skaergaard (Sato and Valenza 1980) that include values close to the iron-wustite (IW) buffer from both MZ and LZ oxide separates. Differences between this electrochemical study and that of Sato and Valenza (1980) may be due to variations in the level of indigenous (or curatorially-introduced) carbon in the samples studied. Despite a number of experimental difficulties, electrochemical cells can provide an accurate and precise method of determining the oxygen fugacity of naturally occurring, complex oxide assemblages. Tight experimental reversals and reproducible values obtained in heating and cooling cycles are an indication of the precision and accuracy of the data recoverable with electrochemical cells.  相似文献   

Isotope and trace element geochemistry of Colorado Plateau volcanics   总被引：5，自引：0，他引：5  

Chantal Alibert  Annie Michard  Francis Albarde 《Geochimica et cosmochimica acta》1986,50(12):2735-2750

Basalts from the San Francisco Peaks and North Rim of Grand Canyon, nephelinites from the Hopi Buttes and Navajo minettes (Colorado Plateau) have been analyzed for trace element contents and Sr, Nd, Pb isotope compositions. The ages increase eastward from the Quaternary (basalt) to 5 Ma (nephelinite) and 30 Ma (minette) as does the depth of melt generation inferred from xenolith mineralogy and major element geochemistry.

The three rock types present an enrichment of incompatible elements (although minettes present negative concentration spikes for Nb, Zr, Ti, Ba, Sr) relative to other magma types. The chondrite-normalized Ce/Yb ratio changes from 8–22 (basalt) to 25–30 (nephelinite) and 33–60 (minette) and reflects small degrees of partial melting of a mantle source with a garnet/clinopyroxene ratio increasing with depth. The negative Eu anomaly present in minette, the low Sr/Nd and high Pb/Ce suggest the presence of a recycled continental crust component in their mantle source.

The ⁸⁷Sr/⁸⁶Sr ratio varies from 0.7032-0.7045 (basalt and nephelinite) to 0.7052-0.7071 (minette), while ε_Nd is remarkably more constant at +0.8 to +3.7 (nephelinite) and −2.6 to +2.2 (basalt and minette). Good linear correlations are observed in both ²⁰⁷Pb/²⁰⁴Pb and ²⁰⁸Pb/²⁰⁴Pb vs. ²⁰⁶Pb/²⁰⁴Pb diagrams with basalt being the least and nephelinite the most radiogenic and indicate a 2.3 ±0.1 Ga age and a Th/U of 3.4.

Three lithospheric source components are indicated: a) an OIB-type depleted mantle source, b) an end-member with unradiogenic Sr, Nd and Pb for basalt and nephelinite and c) a recycled crustal component for minette.  相似文献   

A worldwide comparison of predicted S-wave delays from a three-dimensional upper mantle model with P-wave station corrections     

Annie Souriau  John H. Woodhouse 《Physics of the Earth and Planetary Interiors》1985,39(2):75-88

This paper is a comparison, on a worldwide scale, between P-station corrections deduced from ISC residuals (Dziewonski and Anderson) and synthetic S-station corrections computed using a three-dimensional upper mantle model obtained from mantle wave data (Woodhouse and Dziewonski). The upper mantle S-velocity model is described by a spherical harmonic expansion up to degree 8; the P-station corrections are smoothed using a similar expansion, in order that the two data sets can be compared.Correlations between P-station corrections, δt_P, and synthetic S-station corrections, δt_S relevant to various depths of integration indicate that a station correction contains information about structures down to at least 670 km. For this depth of integration, the correlation coefficient of the two data sets is 0.59; the slope ‘a’ of the relation δt_S = aδt_P + b, obtained for the worldwide distribution of stations, is in good agreement with results of previous regional studies using direct readings of P and S arrival times (a = 3.61 ± 0.13).An analysis of regional variations of the relation δt_S = aδt_P + b is carried out on the basis of two published global tectonic patterns (Okal; Jodan). Results for oceanic regions are not reliable, due to the lack of data. On continental areas, a significant difference appears between mountains (a = 2.7 ± 0.3) and shields (a = 4.5 ± 0.4 for Okal's pattern, a = 5.7 ± 1.5 for Jordan's pattern). The largest a-value for shields rules out an explanation by partial melting, as proposed in previous studies. Thermal heterogeneities lead to low a-values; undulations of the lithosphere-asthenosphere boundary appear to be the most feasible explanation of the high slope beneath shields; they are also able to explain the range of variation of the station corrections; the lowest values of the station corrections correspond to a total vanishing of the low velocity zone beneath the oldest shields. For mountains, the mean values of the station corrections as well as the low a-value can be accounted for by a slight increase of Poisson's ratio together with a significant density increase.  相似文献