Rare earth and trace element geochemistry of a fragment of jurassic seafloor,Point Sal,California     

Martin Menzies  Douglas Blanchard  Joyce Brannon  Randy Korotev 《Geochimica et cosmochimica acta》1977,41(10):1419-1430

A suite of rocks from the Point Sal ophiolite, California, were analyzed for rare earth elements (REE), Sc, Co, Na₂O, Cr, Zn and FeO. The lavas all have either flat or slightly light REE (LREE) depleted profiles relative to chondrites. The lavas contain smectite or greenschist facies mineralogy and some have radiogenically enriched ${}^{87}\text{Sr}{}^{86}\text{Sr}$ ratios. This is interpreted as evidence of basaltseawater interaction (Hopsonet al., 1975; Davis and Lass, 1975). The smectite and zeolite bearing lavas that have been exposed to seawater for prolonged periods have anomalous Ce abundances. At higher grades of metamorphism, the lavas show no marked changes in light REE. The plutonic igneous rocks vary from early cumulus dunite to late stage, noncumulus diorite. All the plutonic rocks are light REE depleted with total REE abundance varying by a factor of 100 × between the dunites and diorites. Analyses of clinopyroxene and hornblende separates indicate that these two minerals strongly influence the REE characteristics of the early cumulates and late stage fractionates, respectively.In general, REE contents are: hornblende > clinopyroxene > plagioclase > orthopyroxene > olivine. Estimates of the REE compositions of parental lavas were obtained by calculating the REE contents of liquids in equilibrium with early cumulate clinopyroxenes. This reveals that the parent to the stratiform sequence was more depleted in light REE than the parent to the lava pile.  相似文献   

Inhibition of estuarine bacteria by metal refinery effluent     

R Goulder  Anne S Blanchard  P.J Metcalf  B Wright 《Marine pollution bulletin》1979,10(6):170-173

Water samples from the Humber Estuary adjacent to a discharge of metal refinery effluent were found to have high dissolved metal concentrations and low pH. Bacterial activities and concentrations of viable bacteria were low, indicating inhibition of bacteria and reduction in self-purification. Toxicity tests demonstrated that acid conditions and copper and arsenic amongst metals probably contributed to bacterial inhibition.  相似文献   

Un nouveau critere de sens de mise en place dans une caisse filonienne: Le “pincement” des mineraux aux epontes : Orientation des minéraux dans un magma en écoulement     

Jean-Philippe Blanchard  Pierre Boyer  Claude Gagny 《Tectonophysics》1979,53(1-2)

The flow of a magma into a dike, sill, laccolite, pipe or batholith leads to a preferential orientation of crystals in the magma. A study by computer simulation has brought to light certain types of fabric for oblate and prolate minerals in the case of a plane deformation, on the one hand by pure shear, and on the other hand by simple shear. Theoretical and practical studies suggest a new method for determining the direction of injection (“injection axis”) in a dike, based on the angular relations of minerals near the walls.New developments are proposed on the relations between plane and linear flow-lines, on the distinction between “apparent flow-lines” and the transport-plane of the magma (“real flow-lines”) and on the amount of magma deformation.

Résumé

La mise en place d'un magma dans une caisse filonienne (ou dans des sills, dykes, laccolites, batholites, etc.) s'accompagne d'une orientation préférentielle des minéraux déjà formés. Une étude par simulation sur ordinateur a mis en évidence certains types de fabrique pour les minéraux phylliteux et les minéraux aciculaires dans le cas d'une déformation plane, d'une part par aplatissement pur et d'autre part, par cisaillement simple.En application théorique puis pratique, un nouveau critère de sens de mise en place (axe d'injection) dans une caisse filonienne est défini: le pincement des minéraux aux épontes; en effet, à chacune d'elles, les fluidalités apparentes, observées sur les minéraux, font un angle avec la paroi du filon.Des développements nouveaux sont proposés concernant les relations entre fluidalités planaire et linéaire, la distinction entre fluidalité apparente et plan de transport du magma (fluidalité réelle), le taux de déformation subi par le magma,....  相似文献   

Major,minor, and trace element compositions of peridotitic and basaltic komatiites from the precambrian crust of Southern Africa     

A. Günter Herrmann  Douglas P. Blanchard  Larry A. Haskin  Jeffrey W. Jacobs  Doris Knake  Randy L. Korotev  Joyce C. Brannon 《Contributions to Mineralogy and Petrology》1976,59(1):1-12

Major and trace element compositional data are reported for nine mafic and ultramafic rock samples from the Barberton greenstone belt. Rocks from this province are among the oldest fragments of the Earth's crust (3.5 b.y.). The data are consistent with an oceanic crust related origin for these rocks. The high abundances of Ni in these samples make their origin by fractional crystallization of a primitive magma unlikely but are consistent with their generation by partial melting of an upper mantle source. The basaltic samples from the Komati formation can be related by small degrees of partial melting of a primitive upper mantle source to the peridotitic komatiite which probably derived from much more extensive partial melting of a similar source. REE and especially Ni abundances limit the proportion of olivine that is permitted in the residue.  相似文献   

Rare earths,other trace elements and iron in Luna 20 samples     

Philip A. Helmke  Douglas P. Blanchard  Jeffrey W. Jacobs Larry  A. Haskin 《Geochimica et cosmochimica acta》1973,37(4):869-874

The results of the analysis by neutron activation of six samples from the Luna 20 mission and one sample of < 1 mm fines from Apollo 16 are reported. The concentrations of the rare-earth elements (REE) in the samples of fines from Luna 20 and Apollo 16 are less than those found for corresponding materials from the mare areas but a negative Eu anomaly is still present. The concentrations of the REE in fines from Luna 20 are only about two-thirds as great as in the sample of Apollo 16 fines, but the concentrations of Co, Sc and Cr are greater by factors ranging from 1.5 to 2.3.  相似文献   

The ejection of drops from the sea and their enrichment with bacteria and other materials: A review     

Duncan C. Blanchard 《Estuaries and Coasts》1989,12(3):127-137

This paper is a review of work done on the production of an aerosol by the sea, and on the mechanisms by which bacteria might be enriched on the aerosol. Air bubbles produced in the sea, primarily by breaking waves, burst at the surface to eject both film and jet drops into the atmosphere. These drops are mixed upward by turbulence to produce the well-known marine sea-salt aerosol. In rising through the water, the bubbles may scavenge bacteria which, when the bubble burst, are skimmed off the bubble and ejected upward with the jet drops. Depending on drop size, the distance the bubble moves through the water, and other factors, the concentration of bacteria in jet drops can be several hundred times that in the bulk water film drops can also be enriched with bacteria. The enrichment of jet and film drops with bacteria, viruses, or toxins may at times produce a health hazard for those living along the shore.  相似文献   

Water for Texas by Jim Norwine,John R. Giardino,and Sushma Krishnamurthy,eds.     

R. Denise Blanchard‐Boehm 《The Professional geographer》2006,58(3):362-365

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Arsenic incorporation into FeS₂ pyrite and its influence on dissolution: A DFT study   总被引：3，自引：0，他引：3  

Marc Blanchard  Maria Alfredsson  Kate Wright 《Geochimica et cosmochimica acta》2007,71(3):624-630

FeS₂ pyrite can incorporate large amounts of arsenic (up to ca. 10 wt%) and hence has a strong impact on the mobility of this toxic metalloid. Focussing on the lowest arsenic concentrations for which the incorporation occurs in solid solution, the substitution mechanisms involved have been investigated by assuming simple incorporation reactions in both oxidising and reducing conditions. The solution energies were calculated by Density Functional Theory (DFT) calculations and we predict that the formation of AsS dianion groups is the most energetically favourable mechanism. The results also suggest that the presence of arsenic will accelerate the dissolution and thus the generation of acid drainage, when the crystal dissolves in oxidising conditions.  相似文献   

Power of monitoring surveys to detect abundance trends in depleted populations: the effects of density-dependent habitat use, patchiness, and climate change   总被引：1，自引：0，他引：1  

Blanchard  Julia L.; Maxwell  David L.; Jennings  Simon 《ICES Journal of Marine Science》2008,65(1):111-120

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First-principles study of OH defects in zircon     

Etienne Balan  Haohao Yi  Marc Blanchard 《Physics and Chemistry of Minerals》2013,40(7):547-554

The infrared spectroscopic properties of selected OH defects in zircon are investigated by first-principles calculations. The explicit treatment of the coupled nature of OH motions in the stretching modes, together with the calculation of the intensity and polarization of absorption bands, makes it possible to directly compare theoretical and experimental data. The bands observed at 3,420 cm^?1 (polarization parallel to c axis) and 3,385 cm^?1 (polarization perpendicular to c axis) in natural and synthetic samples correspond to the IR-active vibrational modes of the hydrozircon defect, that is, fully protonated Si vacancy. The broad band observed at 3,515 cm^?1 in the spectrum of zircon crystals grown in F-rich environments is consistent with the occurrence of composite (OH,F) tetrahedral defects. Calculations also show that the band observed at 3,200 cm^?1 in the spectrum of synthetic undoped samples can be ascribed to fully protonated Zr vacancies. The theoretical values of integrated absorption coefficients indicate that general correlations can be reasonably used to determine the concentration of OH groups in zircon.  相似文献