Laboratory kinetics of C₂H radical reactions with ethane, propane, and n-butane at T = 96-296 K: implications for Titan     

James E. Murphy  Stephen R. Leone 《Icarus》2003,163(1):175-181

The kinetics of the reactions of C₂H radical with ethane (k₁), propane (k₂), and n-butane (k₃) are studied over the temperature range of T = 96-296 K with a pulsed Laval nozzle apparatus that utilizes a pulsed laser photolysis-chemiluminescence technique. The C₂H decay profiles in the presence of both the alkane reactant and O₂ are monitored by the CH(A²Δ) chemiluminescence tracer method. The results, together with available literature data, yield the following Arrhenius expressions: k₁(T) = (0.51 ± 0.06) × 10⁻¹⁰ exp[(−76 ± 30)K/T] cm³ molecule⁻¹ s⁻¹ (T = 96-800 K), k₂(T) = (0.98 ± 0.32) × 10⁻¹⁰exp[(−71 ± 60)K/T] cm³ molecule⁻¹ s⁻¹ (T = 96-361 K), and k₃(T) = (1.23 ± 0.26) × 10⁻¹⁰ cm³ molecule⁻¹ s⁻¹ (T = 96-297 K). At T = 296 K, k₁ is measured as a function of total pressure and has little or no pressure dependence. The results from this work support a direct hydrogen abstraction mechanism for the title reactions. Implications to the atmospheric chemistry of Titan are discussed.  相似文献   

Ghosts of the Milky Way: a search for topology in new quasar catalogues     

S. J. Weatherley  S. J. Warren  S. M. Croom  R. J. Smith  B. J. Boyle  T. Shanks  L. Miller  M. P. Baltovic 《Monthly notices of the Royal Astronomical Society》2003,342(1):L9-L13

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Optical flashes and very early afterglows in wind environments     

X. F. Wu  Z. G. Dai  Y. F. Huang  T. Lu 《Monthly notices of the Royal Astronomical Society》2003,342(4):1131-1138

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Symplectic Mappings of Co-orbital Motion in the Restricted Problem of Three Bodies     

Zsolt Sándor  Bálint Érdi  Carl D. Murray 《Celestial Mechanics and Dynamical Astronomy》2002,84(4):355-368

The dynamics of co-orbital motion in the restricted three-body problem are investigated by symplectic mappings. Analytical and semi-numerical mappings have been developed and studied in detail. The mappings have been tested by numerical integration of the equations of motion. These mappings have been proved to be useful for a quick determination of the phase space structure reflecting the main characteristics of the dynamics of the co-orbital problem.  相似文献   

Stochastic modelling of groundwater flow and solute transport in aquifers     

T.-C. Jim Yeh 《水文研究》1992,6(4):369-395

This paper presents an introductory overview of recently developed stochastic theories for tackling spatial variability problems in predicting groundwater flow and solute transport. Advantages and limitations of the theories are discussed. Lastly, strategies based on the stochastic approaches to predict solute transport in aquifers are recommended.  相似文献   

Isolation of resonance in acoustic backscatter from elastic targetsusing adaptive estimation schemes     

Azimi-Sadjadi  M.R. Wilbur  J. Dobeck  G.J. 《Oceanic Engineering, IEEE Journal of》1995,20(4):346-353

It has been shown that at certain frequencies the acoustic backscatter from elastic targets exhibits certain resonance behavior which closely relates to the physical properties of the target such as dimension, thickness, and composition. The purpose of this paper is to develop an automated approach for identifying the presence of resonance in the acoustic backscatter from an unknown underwater target by isolating the resonance part from the specular contribution. An adaptive transversal filter structure is used to estimate the specular part of the backscatter and consequently the error signal would provide an estimate of the resonance part. An important aspect of this scheme lies in the fact that it does not require an underlying model for the elastic return. The adaptation rule is based upon fast recursive least squares (RLS) learning. The approach taken in this paper is general in the sense that it can be applied to targets of unknown geometry and thickness and, further, does not require any a priori information about the target and/or the environment. Test results on acoustic data are presented which indicate the effectiveness of the proposed approach  相似文献   

The MPE X-ray test facility PANTER: Calibration of hard X-ray (15–50 kev) optics     

M. J. Freyberg  H. Bräuninger  W. Burkert  G. D. Hartner  O. Citterio  F. Mazzoleni  G. Pareschi  D. Spiga  S. Romaine  P. Gorenstein  B. D. Ramsey 《Experimental Astronomy》2005,20(1-3):405-412

The Max-Planck-Institut für extraterrestrische Physik (MPE) in Garching, Germany, uses its large X-ray beam line facility PANTER for testing X-ray astronomical instrumentation. A number of telescopes, gratings, filters, and detectors, e.g. for astronomical satellite missions like Exosat, ROSAT, Chandra (LETG), BeppoSAX, SOHO (CDS), XMM-Newton, ABRIXAS, Swift (XRT), have been successfully calibrated in the soft X-ray energy range (< 15keV). Moreover, measurements with mirror test samples for new missions like ROSITA and XEUS have been carried out at PANTER. Here we report on an extension of the energy range, enabling calibrations of hard X-ray optics over the energy range 15–50 keV. Several future X-ray astronomy missions (e.g., Simbol-X, Constellation-X, XEUS) have been proposed, which make use of hard X-ray optics based on multilayer coatings. Such optics are currently being developed by the Osservatorio Astronomico di Brera (OAB), Milano, Italy, and the Harvard-Smithsonian Center for Astrophysics (CfA), Cambridge, MA, USA. These optics have been tested at the PANTER facility with a broad energy band beam (up to 50 keV) using the XMM-Newton EPIC-pn flight spare CCD camera with its good intrinsic energy resolution, and also with monochromatic X-rays between C-K (0.277 keV) and Cu-Kα (8.04 keV). PACS: 95.55.Ka, 95.55.Aq, 41 50.+h, 07.85.Fv  相似文献   

Pulsar Wind Nebulae in Egret Error Boxes     

Mallory S. E. Roberts  Crystal L. Brogan  Bryan M. Gaensler  Jason W. T. Hessels  C.-Y. Ng  Roger W. Romani 《Astrophysics and Space Science》2005,297(1-4):93-100

A remarkable number of pulsar wind nebulae (PWN) are coincident with EGRET γ-ray sources. X-ray and radio imaging studies of unidentified EGRET sources have resulted in the discovery of at least six new pulsar wind nebulae (PWN). Stationary PWN (SPWN) appear to be associated with steady EGRET sources with hard spectra, typical for γ-ray pulsars. Their toroidal morphologies can help determine the geometry of the pulsar which is useful for constraining models of pulsed γ-ray emission. Rapidly moving PWN (RPWN) with more cometary morphologies seem to be associated with variable EGRET sources in regions where the ambient medium is dense compared to what is typical for the ISM.  相似文献   

Self-regulated black hole accretion, the M–σ relation and the growth of bulges in galaxies     

Mitchell C. Begelman †  Biman B. Nath ‡ 《Monthly notices of the Royal Astronomical Society》2005,361(4):1387-1392

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A robust sample of submillimetre galaxies: constraints on the prevalence of dusty, high-redshift starbursts     

R. J. Ivison  Ian Smail  J. S. Dunlop  T. R. Greve  A. M. Swinbank  J. A. Stevens  A. M. J. Mortier  S. Serjeant  T. A. Targett  F. Bertoldi  A. W. Blain  S. C. Chapman 《Monthly notices of the Royal Astronomical Society》2005,364(3):1025-1040

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