Erratum     

D.J. Barber 《Geochimica et cosmochimica acta》1981,45(12):2520

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Matrix phyllosilicates and associated minerals in C2M carbonaceous chondrites     

D.J. Barber 《Geochimica et cosmochimica acta》1981,45(6):945-970

TEM, HRTEM, HVEM and SEM methods, coupled with energy dispersive X-ray analysis, have been used to study the microstructure and the phases comprising the matrix of carbonaceous chondrites Murchison, Cold Bokkeveld, Nawapali and Cochabamba. A wide variety of phyllosilicate morphologies occurs in each. Very small crystals and clasts of olivine, pyroxene and other unhydrated minerals are mixed intimately with the phyllosilicates. Intergrowths of carbonates and Sulfides within the phyllosilicates also occur, as well as a ubiquitous spongey material which is difficult to characterize, but contains elementary phyllosilicate units and embryo crystals. The identifiable large crystalline phyllosilicates are principally Fe-rich serpentine-group minerals and intermediate more Mg-rich chrysotilelike group members, with characteristic ~ 7.0–7.4 Å basal layer spacings. Complex interlayered and intergrown hydrous minerals also occur associated with the spongey material, and other poorly crystalline silicates and finely divided Fe-Ni sulphides. Fe/Si and Mg/Si ratios vary on a sub-micron scale, and the morphologies of the larger phyllosilicate crystals correlate broadly with these variations. Small crystals of sodium chloride and potassium chloride have been identified, occluded within a predominantly organic mass.The matrix minerals have a multistage history of formation in which the effects of aqueous alteration are dominant. Few, if any, of matrix minerals can be unmodified nebular condensates, although some clasts and inclusions have escaped alteration and predate the alteration process.  相似文献   

Electron petrography of shock effects in a gas-rich enstatite-achondrite     

J. R. Ashworth  D. J. Barber 《Contributions to Mineralogy and Petrology》1975,49(2):149-162

The enstatite-achondrite Khor Temiki has been studied by high-voltage electron microscopy. The normal Khor Temiki lithology has a fine-grained matrix in which individual grains show the well-known effects of unshielded solar irradiation. Intensity of deformation varies greatly from grain to grain; this material has a varied history of impact deformation, and must have formed in an environment similar to that of the lunar regolith. The meteorite is traversed by veins of extra-dark material. This was produced in situ from the normal lithology by intense shock, sufficient to erase its irradiation record almost completely. Instead of the enstatite that dominates the bulk meteorite, optically twinned clinoenstatite is found to be the major mineral in such a shock-vein. It is highly defective, and its electron diffraction patterns contain diffuse orthopyroxene maxima. It is interpreted in terms of inversion of protoenstatite produced by the thermal effect of the shock. Recrystallization phenomena, and the occurrence of enstatite in close association with the clinoenstatite, are described. This occurrence of twinned clinoenstatite is contrasted with those due to quenching of primary protopyroxene in small bodies such as chondrules. The effects of shock have eliminated porosity from the vein material, and indurated it. Less severe such effects, outside the veins themselves, must have contributed to the lithification of the meteorite.  相似文献   

Electron petrography of shock-deformed olivine in stony meteorites     

J.R. Ashworth  D.J. Barber 《Earth and Planetary Science Letters》1975,27(1):43-50

We have studied olivine by high-voltage electron microscopy in meteorites showing shock effects, namely the ordinary chondrites Olivenza and Hedjaz, the ureilite Goalpara and the carbonaceous chondrite Allende. The observations are compared with published data on experimentally deformed and annealed olivine.Olivenza and Hedjaz have suffered low-temperature shock, which has produced high densities of [001] screw dislocations and cracks. Arrays of cracks are found to correspond to planar features which can be seen optically and to be responsible for mosaicism. Goalpara has suffered very heavy shock, of which the final result is extensive recrystallization of the olivine, and the new grains have distinctive low-density distributions of dislocations. Allende has not been shocked as a whole, but individual parts have deformational and heating histories dating from before the aggregation of the meteorite.  相似文献   

Lithification of gas-rich meteorites     

J.R. Ashworth  D.J. Barber 《Earth and Planetary Science Letters》1976,30(2):222-233

High-voltage electron microscopy has been used to study the fine structure of four gas-rich meteorites, with particular reference to the cementation and compaction processes that have affected the fine-grained matrix. The observed features are compared with similar effects in lunar breccias. Lithification is attributed to the passage of shock waves through porous aggregates, causing deformation whose intensity varied spatially on a small scale, the most intense deformation and heating effects being concentrated at the edges of large grains and in the matrix between them. It is inferred that relatively mild shocks have produced amorphous cement between matrix grains in the achondrite Khor Temiki and the chondrite Weston. Relatively intense shock is inferred for specimens of the chondrites St. Mesmin and Pantar. These have non-porous, completely crystalline matrices, and fine-grained black veins which fill cracks in relatively large deformed grains. Recrystallization of some deformed material is attributed to shock-heating, which was not sustained long enough to erase the irradiation record from all the relatively large grains. Matrix recrystallization without extensive melting constitutes a metamorphic event, and the observations indicate that shock was responsible for the metamorphism experienced by these chondrites at relatively late stages of the evolution of their parent bodies.  相似文献   

The impact of land use change and check‐dams on catchment sediment yield     

Carolina Boix‐Fayos  Joris de Vente  María Martínez‐Mena  Gonzalo G. Barberá  Víctor Castillo 《水文研究》2008,22(25):4922-4935

Extensive land use changes have occurred in many areas of SE Spain as a result of reforestation and the abandonment of agricultural activities. Parallel to this the Spanish Administration spends large funds on hydrological control works to reduce erosion and sediment transport. However, it remains untested how these large land use changes affect the erosion processes at the catchment scale and if the hydrological control works efficiently reduce sediment export. A combination of field work, mapping and modelling was used to test the influence of land use scenarios with and without sediment control structures (check‐dams) on sediment yield at the catchment scale. The study catchment is located in SE Spain and suffered important land use changes, increasing the forest cover 3‐fold and decreasing the agricultural land 2·5‐fold from 1956 to 1997. In addition 58 check‐dams were constructed in the catchment in the 1970s accompanying reforestation works. The erosion model WATEM‐SEDEM was applied using six land use scenarios: land use in 1956, 1981 and 1997, each with and without check‐dams. Calibration of the model provided a model efficiency of 0·84 for absolute sediment yield. Model application showed that in a scenario without check dams, the land use changes between 1956 and 1997 caused a progressive decrease in sediment yield of 54%. In a scenario without land use changes but with check‐dams, about 77% of the sediment yield was retained behind the dams. Check‐dams can be efficient sediment control measures, but with a short‐lived effect. They have important side‐effects, such as inducing channel erosion downstream. While also having side‐effects, land use changes can have important long‐term effects on sediment yield. The application of either land use changes (i.e. reforestation) or check‐dams to control sediment yield depends on the objective of the management and the specific environmental conditions of each area. Copyright © 2008 John Wiley & Sons, Ltd.  相似文献   

Air-water distribution of hexachlorobenzene and 4,4'-DDE along a North-South Atlantic transect     

Booij K  van Bommel R  Jones KC  Barber JL 《Marine pollution bulletin》2007,54(6):814-819

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The climate of Scotland over the last 5000 years inferred from multiproxy peatland records: inter‐site correlations and regional variability     

Peter G. Langdon  Keith E. Barber 《第四纪科学杂志》2005,20(6):549-566

The mid to late‐Holocene climates of most of Scotland have been reconstructed from seven peat bogs located across north–south and east–west geographical and climatological gradients. The main techniques used for palaeoclimatic reconstruction were plant macrofossil, colorimetric humification, and testate amoebae analyses, which were supported by a radiocarbon‐based chronology, aided by markers such as tephra isochrons and recent rises in pine pollen and in spheroidal carbonaceous particles (SCPs). Field stratigraphy was undertaken at each site in order to show that the changes detected within the peat profiles were replicable. Proxy climate records were reconstructed using detrended correspondence analysis (DCA) of the plant macrofossil data and a mean water table depth transfer function on the testate amoebae data. These reconstructions, coupled with the humification data, were standardised for each site and used to produce a composite record of bog surface wetness (BSW) from each site. The results show coherent wet and dry phases over the last 5000 years and suggest regional differences in climate across Scotland, specifically between northern and southern Scotland. Distinct climatic cycles are identified, all of which record a millennial‐scale periodicity which can be correlated with previously identified marine and ice core Holocene cycles. The key role of the macrofossil remains of Sphagnum imbricatum, a taxon now extinct on many sites, is discussed in relation to the identified climatic shifts. Copyright © 2005 John Wiley & Sons, Ltd.  相似文献   

A Validation of CloudSat and CALIPSO's Temperature,Humidity, Cloud Detection,and Cloud Base Height over the Arctic Marine Cryosphere     

Lauren M. Candlish  Richard L. Raddatz  Geoffrey G. Gunn  Matthew G. Asplin  David G. Barber 《大气与海洋》2013,51(3):249-264

Abstract

This study presents a semi‐analytic non‐iterative solution for the Monin‐Obukhov similarity equations under unstable surface conditions. The solution is represented in terms of the non‐dimensional Monin‐Obukhov stability parameter z/L. This parameter is given as a function of the bulk Richardson number and other surface parameters including the heat and momentum roughness lengths which are generally assumed to be different in this formulation. The proposed formulations give results that are both quantitatively and qualitatively consistent with the fully iterated numerical solution for a wide range of surface parameters.  相似文献   

Pixel‐scale evaluation of SSM/I sea‐ice algorithms in the marginal ice zone during early fall freeze‐up     

Byong Jun Hwang  David G. Barber 《水文研究》2006,20(9):1909-1927

Observed reduction in recent sea ice areal extent and thickness has focused attention on the fact that the Arctic marine system appears to be responding to global‐scale climate variability and change. Passive microwave remote‐sensing data are the primary source underpinning these reports, yet problems remain in geophysical inversion of information on ice type and concentration. Uncertainty in sea‐ice concentration (SIC) retrievals is highest in the summer and fall, when water occurs in liquid phase within the snow–sea‐ice system. Of particular scientific interest is the timing and rate of new ice formation due to the control that this form of sea ice has on mass, energy and gas fluxes across the ocean–sea‐ice–atmosphere interface. In this paper we examine the critical fall freeze‐up period using in situ data from a ship‐based and aerial survey programme known as the Canadian Arctic Shelf Exchange study combined with microwave and optical Earth observations data. Results show that: (1) the overall physical conditions observed from aerial survey photography were well matched with coincident moderate‐resolution imaging spectroradiometer data and Radarsat ScanSAR imagery; (2) the shortwave albedo was linearly related to old ice concentration derived from survey photography; (3) the three SSM/I SIC algorithms (NASA Team (NT), NASA Team 2 (NT2), and Bootstrap (BT)) showed considerable discrepancies in pixel‐scale comparison with the Radarsat ScanSAR SICs well calibrated by the aerial survey data. The major causes of the discrepancies are attributed to (1) the inherent inability to detect the new thin ice in the NT and BT algorithms, (2) mismatches of the thin‐ice tie point of the NT2 algorithm, and (3) sub‐pixel ambiguity between the thin ice and the mixture of open water and sea ice. These results suggest the need for finer resolution of passive microwave sensors, such as AMSR‐E, to improve the precision of the SSM/I SIC algorithms in the marginal ice zone during early fall freeze‐up. Copyright © 2006 John Wiley & Sons, Ltd.  相似文献