Hydrochemical dynamics of TOC and NO3 − contents as natural tracers of infiltration in karst aquifers     

Matías Mudarra  Bartolomé Andreo  Juan Antonio Barberá  Jacques Mudry 《Environmental Earth Sciences》2014,71(2):507-523

Analysis of Total Organic Carbon (TOC) and NO₃ ^? contents in the water at six springs in the province of Malaga (Southern Spain), sampled under different hydrologic conditions, revealed two different hydrochemical behaviour patterns for these natural tracers of infiltration. TOC content increased during every recharge period, following the rapid arrival of water infiltrating through the soil. On the other hand, NO₃ ^? content only rose during the first flood episodes (normally in autumn), and fell during the winter and spring ones. This difference is consequence of the distinctive biogeochemical kinetics of nitrogen with respect to organic carbon, both in the soil and within the aquifer. Unlike the mineralisation undergone by TOC from the surface to the spring, the NO₃ ^? ion remains in the aquifer almost unaffected, due to the oxidizing conditions prevailing within the karst medium, which do not allow its denitrification and favour its preservation within the saturated zone. In non-polluted aquifers, TOC and NO₃ ^? have a common origin in the soil and can be used to determine infiltration processes and the hydrogeological functioning of karst aquifers. Their different hydrochemical evolution provides information about mineralization and degradation processes of organic matter within karst aquifers, which can be used to validate the vulnerability to contamination in this type of medium.  相似文献   

Using non-conservative tracers to characterise karstification processes in the Merinos-Colorado-Carrasco carbonate aquifer system (southern Spain)     

J. A. Barberá  B. Andreo  C. Almeida 《Environmental Earth Sciences》2014,71(2):585-599

The systematic sampling of the chemical composition of the groundwater from five karst springs (including an overflow spring) and one outflowing borehole have permitted to determine distinctive chemical changes in the waters that reflect the geochemical processes occurring in a carbonate aquifer system from southern Spain. The analysis of the dissolution parameters revealed that geochemical evolution of the karst waters basically depends on the availability of the minerals forming aquifer rocks and the residence time within the aquifers. In the three proposed scenarios in the aquifers, which include the preferential flow routines, the more important geochemical processes taking place during the groundwater flow from the recharge to the discharge zones are: CO₂ dissolution and exsolution (outgassing), calcite net dissolution, calcite and dolomite sequential dissolution, gypsum/anhydrite and halite dissolution, de-dolomitization and calcite precipitation. A detailed analysis of the hydrochemical data set, saturation indices of the minerals and partial pressure of CO₂ in the waters joined to the application of geochemical modelling methods allowed the elaboration of a hydrogeochemical model of the studied aquifers. The developed approach contributes to a better understanding of the karstification processes and the hydrogeological functioning of carbonate aquifers, the latter being a crucial aspect for the suitable management of the water resources.  相似文献   

Geophysical characterization of the complex dynamics of groundwater and seawater exchange in a highly stressed aquifer system linked to a coastal lagoon (SE Spain)   总被引：1，自引：0，他引：1  

J. Rey  J. Martínez  G. G. Barberá  J. L. García-Aróstegui  J. García-Pintado  D. Martínez-Vicente 《Environmental Earth Sciences》2013,70(5):2271-2282

Anthropogenic pressure influences the two-way interactions between shallow aquifers and coastal lagoons. Aquifer overexploitation may lead to seawater intrusion, and aquifer recharge from rainfall plus irrigation may, in turn, increase the groundwater discharge into the lagoon. We analyse the evolution, since the 1950s up to the present, of the interactions between the Campo de Cartagena Quaternary aquifer and the Mar Menor coastal lagoon (SE Spain). This is a very heterogeneous and anisotropic detrital aquifer, where aquifer–lagoon interface has a very irregular geometry. Using electrical resistivity tomography, we clearly identified the freshwater–saltwater transition zone and detected areas affected by seawater intrusion. Severity of the intrusion was spatially variable and significantly related to the density of irrigation wells in 1950s–1960s, suggesting the role of groundwater overexploitation. We distinguish two different mechanisms by which water from the sea invades the land: (a) horizontal advance of the interface due to a wide exploitation area and (b) vertical rise (upconing) caused by local intensive pumping. In general, shallow parts of the geophysical profiles show higher electrical resistivity associated with freshwater mainly coming from irrigation return flows, with water resources mostly from deep confined aquifers and imported from Tagus river, 400 km north. This indicates a likely reversal of the former seawater intrusion process.  相似文献   

Comparing and cross-validating lake and bog palaeoclimatic records: a review and a new 5,000 year chironomid-inferred temperature record from northern England     

Keith Barber  Alastair Brown  Peter Langdon  Paul Hughes 《Journal of Paleolimnology》2013,49(3):497-512

This paper reviews the past history of comparisons between lacustrine records of chironomid-inferred summer temperatures (CI-T) and peat bog-derived records of surface wetness (BSW), and develops a new summer temperature record for the mid-late Holocene for Northern Britain from Bigland Tarn, Cumbria. The CI-T reconstruction is well dated, and corresponds well with the only two other CI-T records for Britain. Comparisons are made with BSW records from northern Britain, which show consistent similarities over centennial to millennial timescales, demonstrating that at this resolution cooler summers equated with a wetter climate, at least during the mid- to late-Holocene.  相似文献   

Spectrum of hot water in the 4750–13 000 cm⁻¹ wavenumber range (0.769–2.1 μm)     

Nikolai F. Zobov  Sergei V. Shirin  Roman I. Ovsyannikov  Oleg L. Polyansky  Robert J. Barber  Jonathan Tennyson  Peter F. Bernath  Michel Carleer  Reginald Colin  Pierre-François Coheur 《Monthly notices of the Royal Astronomical Society》2008,387(3):1093-1098

The high resolution laboratory spectrum of hot water vapour has been recorded in the 500–13 000 cm⁻¹ wavenumber range and we report on the analysis of the 4750–13 000 cm⁻¹ (0.769–2.1 μm) portion. The emission spectrum was recorded using an oxy-acetylene welding torch and a Fourier transform spectrometer. Line assignments in the laboratory spectrum as well as in an absorption spectrum of a sunspot umbra were made with the help of the BT2 line-list. Our torch spectrum is the first laboratory observation of the 9300 Å'steam bands' seen in M-stars and brown dwarfs.  相似文献   

Pine plantation bands limit seedling recruitment of a perennial grass under semiarid conditions     

J.A. Navarro-Cano  G.G. Barberá  A. Ruiz-Navarro  V.M. Castillo 《Journal of Arid Environments》2009,73(1):120-126

Pine plantations coexist with Stipa tenacissima grasslands in many semiarid western Mediterranean areas. We compared three microsites created by a 30-year-old Pinus halepensis plantation: below pine plantation line (BP), below canopy of pines (BC) and interline bare band (BA). They were evaluated in terms of soil properties, pine litter and suitability as recruitment niches for S. tenacissima. Next, in a manipulative experiment in growth chambers we tested the hypothesis that pine litter interferes with the seedling emergence of S. tenacissima. Three treatments in pots were compared: (a) soil from BA; (b) intact soil + litter from BP; and (c) soil + litter from BP, which was mixed in the laboratory (BPMX). In the field the main microsite differences were pine cover and litter cover and thickness. Seedling emergence was significantly greater in BA than in BP. Emergence and litter depth fits a linear regression model. In the growth chamber litter did not interfere with the emergence of S. tenacissima. However, seedlings grown without litter were 28% longer and their mass was 27% greater than in the litter treatments. The detected pine litter interference may be relevant for plant dynamics and might be considered in forestry management programs.  相似文献   

Change and variability in sea ice during the 2007–2008 Canadian International Polar Year program     

David G. Barber  Matthew G. Asplin  Richard L. Raddatz  Lauren M. Candlish  Scot Nickels  Stephanie Meakin  Klaus P. Hochheim  Jennifer V. Lukovich  Ryan J. Galley  Simon J. Prinsenberg 《Climatic change》2012,115(1):115-133

In this paper we describe sea ice change and variability during the Canadian International Polar Year (IPY) program and examine several regional and hemispheric causes of this change. In a companion paper (Barber et al., Climate Change 2012) we present an overview of the consequences of this observed change and variability on ecosystem function, climatically relevant gas exchange, habitats of primary and apex predators, and impacts on northern peoples. Sea ice-themed research projects within the fourth IPY were designed to be among the most diverse international science programs. They greatly enhanced the exchange of Inuit knowledge and scientific ideas across nations and disciplines. This interdisciplinary and cultural exchange helped to explain and communicate the impacts of a transition of the Arctic Ocean and ecosystem to a seasonally ice-free state, the commensurate replacement of perennial with annual sea ice types and the causes and consequences of this globally significant metamorphosis. This paper presents a synthesis of scientific sea ice research and traditional knowledge results from Canadian-led IPY projects between 2007 and 2009. In particular, a summary of sea ice trends, basin-wide and regional, is presented in conjunction with Inuit knowledge of sea ice, gathered from communities in northern Canada. We focus on the recent observed changes in sea ice and discuss some of the causes of this change including atmospheric and oceanic forcing of both dynamic and thermodynamic forcing on the ice. Pertinent results include: 1) In the Amundsen Gulf, at the western end of the Northwest Passage, open water persists longer than normal and winter sea ice is thinner and more mobile. 2) Large areas of summer sea ice are becoming heavily decayed during summer and can be broken up by long-period waves being generated in the now extensive open water areas of the Chukchi Sea. 3) Cyclones play an important role in flaw leads??regions of open water between pack ice and land-fast ice. They delay the formation of new ice and the growth of multi-year ice. 4) Feedbacks involving the increased period of open water, long-period wave generation, increased open-ocean roughness, and the precipitation of autumn snow are all partially responsible for the observed reduction in multiyear sea ice. 5) The atmosphere is observed as remaining generally stable throughout the winter, preventing vertical entrainment of moisture above the surface.  相似文献   

Stratigraphic and structural evolution of the Blue Nile Basin,Northwestern Ethiopian Plateau     

N. DS. Gani  M. G. Abdelsalam  S. Gera  M. R. Gani 《Geological Journal》2009,44(1):30-56

The Blue Nile Basin, situated in the Northwestern Ethiopian Plateau, contains ∼1400 m thick Mesozoic sedimentary section underlain by Neoproterozoic basement rocks and overlain by Early–Late Oligocene and Quaternary volcanic rocks. This study outlines the stratigraphic and structural evolution of the Blue Nile Basin based on field and remote sensing studies along the Gorge of the Nile. The Blue Nile Basin has evolved in three main phases: (1) pre‐sedimentation phase, include pre‐rift peneplanation of the Neoproterozoic basement rocks, possibly during Palaeozoic time; (2) sedimentation phase from Triassic to Early Cretaceous, including: (a) Triassic–Early Jurassic fluvial sedimentation (Lower Sandstone, ∼300 m thick); (b) Early Jurassic marine transgression (glauconitic sandy mudstone, ∼30 m thick); (c) Early–Middle Jurassic deepening of the basin (Lower Limestone, ∼450 m thick); (d) desiccation of the basin and deposition of Early–Middle Jurassic gypsum; (e) Middle–Late Jurassic marine transgression (Upper Limestone, ∼400 m thick); (f) Late Jurassic–Early Cretaceous basin‐uplift and marine regression (alluvial/fluvial Upper Sandstone, ∼280 m thick); (3) the post‐sedimentation phase, including Early–Late Oligocene eruption of 500–2000 m thick Lower volcanic rocks, related to the Afar Mantle Plume and emplacement of ∼300 m thick Quaternary Upper volcanic rocks. The Mesozoic to Cenozoic units were deposited during extension attributed to Triassic–Cretaceous NE–SW‐directed extension related to the Mesozoic rifting of Gondwana. The Blue Nile Basin was formed as a NW‐trending rift, within which much of the Mesozoic clastic and marine sediments were deposited. This was followed by Late Miocene NW–SE‐directed extension related to the Main Ethiopian Rift that formed NE‐trending faults, affecting Lower volcanic rocks and the upper part of the Mesozoic section. The region was subsequently affected by Quaternary E–W and NNE–SSW‐directed extensions related to oblique opening of the Main Ethiopian Rift and development of E‐trending transverse faults, as well as NE–SW‐directed extension in southern Afar (related to northeastward separation of the Arabian Plate from the African Plate) and E–W‐directed extensions in western Afar (related to the stepping of the Red Sea axis into Afar). These Quaternary stress regimes resulted in the development of N‐, ESE‐ and NW‐trending extensional structures within the Blue Nile Basin. Copyright © 2008 John Wiley & Sons, Ltd.  相似文献   

Representative Sampling of Ground Water from Short-Screened Boreholes   总被引：1，自引：0，他引：1  

C. Barber  G. B. Davis 《Ground water》1987,25(5):581-587

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A new titanium-bearing calcium aluminosilicate phase: III. Crystals from a mixer furnace slag     

David J. Barber  Stuart O. Agrell 《Meteoritics & planetary science》1994,29(5):691-695

Abstract Small crystals of an optically uniaxial Ti-bearing calcium aluminosilicate were discovered in a mixer furnace slag consisting mostly of åkermanitic melilite. The crystals have the same unit cell as those observed for a phase crystallized from slowly-cooled melts used to simulate the formation of aluminous inclusions in meteorites. Moreover, compositions of synthetic and meteoritic occurrences of the phase are all very similar and can be expressed in terms of a binary solid solution between the end-members Ca₃TiAl₂Si₃O₁₄ and Ca₃Ti(AlTi)(AlSi₂)O₁₄. Thus, crystallographic and crystallochemical information obtained from crystals in the mixer furnace slag can be used to constrain the origin of similar crystals found in meteoritic inclusions. We separated crystals from the mixer furnace slag by acid leaching; some were used for EPMA analysis, others were crushed for study by TEM methods or X-ray powder diffraction. Convergent beam electron diffraction shows that the crystals belong to the trigonal (rhombohedral) class and have point group symmetry 3m. X-ray powder diffraction gives the unit cell parameters a = 0.791 ± 0.009 nm, c = 0.492 ± 0.006 nm. The results suggest that the mineral has space group symmetry P3ml or P31m.  相似文献