Betekhtinite and bi-sulfosalts from the copper mine of „La Leona“ (Argentina)     

Beatriz Melba Honnorez-Guerstein 《Mineralium Deposita》1971,6(2):111-121

The copper deposit La Leona consists of ore veins in a granite batholite which intruded into Permian sediments. In these veins the following minerals are observed: pyrite, sphalerite, chalcopyrite, galena, betekhtinite, two Bisulfosalts, electrum, bornite, chalcocite, enargite, tennantite, Zn-Fahlerz, cuprite, delafossite, molybdenite, hematite and iron hydroxides, and copper carbonates with quartz and iron carbonates as gangue. The betekhtinite, (CuFe)₁₀Pb S₆, found for the first time in Argentina, the Zn-Fahlerz and the sulfosalts (Cu_3.2Bi_1.2Pb_1.2S_8.5) and (Cu_9.3Bi_1.1S_6.8) were studied in detail under the microscope, by X-rays and by microprobe. Specifically, the paragenesis of these three minerals with galena, chalcocite and bornite is discussed.

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Résumé Le gisement de cuivre de la mine «La Leona» est formé de filons de minerais recoupant un batholite granitique qui a fait intrusion dans des sédiments permiens. Les minéraus suivants ont été observés: pyrite, blende, chalcopyrite, galène, bétekhtinite, deux sulfosels de Bi, électrum, bornite, chalcosine, énargite, tennantite, «Zn-Fahlerz», cuprite, delafossite, molybdénite, hématite et hydroxydes de fer, des carbonates de cuivre, dans une gangue de quartz et de carbonates de fer. La bétekhtinite (Cu Fe)₁₀Pb S₆, trouvée pour la première fois en Argentine, le «Zn-Fahlerz» et les sulfosels (Cu_3.2Bi_1.2Pb_1.2S_8.5) et (Cu_9.3Bi_1.1S_6.8) ont été spécialement étudiés à l'aide de la microscopie, de la diffraction des rayons-X et de la microsonde. La paragénèse formée par ces trois mineraux associés à la galène, la chalcosine et la bornite est discutée.

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First assessment of the highly contaminated harbour of Montevideo,Uruguay     

Danulat E  Muniz P  García-Alonso J  Yannicelli B 《Marine pollution bulletin》2002,44(6):554-565

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Oxidative stress in the mussel Mytella guyanensis from polluted mangroves on Santa Catarina Island,Brazil     

Torres MA  Testa CP  Gáspari C  Masutti MB  Panitz CM  Curi-Pedrosa R  de Almeida EA  Di Mascio P  Filho DW 《Marine pollution bulletin》2002,44(9):923-932

Digestive glands of the mangrove mussel Mytella guyanensis, collected at one non-polluted site (site 1) and two polluted sites (sites 2 and 3), were analysed for different antioxidant defenses, lipid peroxidation and DNA damage. Thiobarbituric acid-reactive substance (TBARS) and 8-oxo-7,8-dihydro-2'-deoxyguanosine levels were enhanced at the polluted sites. With the exception of superoxide dismutase, the activities of catalase and glutathione peroxidase were also higher at the polluted sites. Greater increases were observed in glutathione reductase, glutathione S-transferase and etoxyresorufine-O-deethylase activities at the polluted sites. Conversely, reduced glutathione content was higher at the control site. Trace metal contents in mussels collected at polluted sites were increased compared to the control site, and there were strong positive correlations between TBARS and Cu and Pb contents. M. guyanensis is routinely exposed to an oxidative stress condition at both polluted sites, and considering xenobiotic bioaccumulation in bivalve molluscs, the mangrove mussel represents an excellent bioindicator for environmental monitoring studies.  相似文献   

Late Pleistocene and Holocene Paleoenvironments of Chalco Lake, Central Mexico     

Maria Socorro Lozano-García  Beatriz Ortega-Guerrero  Margarita Caballero-Miranda  Jaime Urrutia-Fucugauchi 《Quaternary Research》1993,40(3)

In order to establish paleoenvironmental conditions during the late Quaternary, four cores from the Basin of Mexico (central Mexico) were drilled in Chalco Lake, located in the southeastern part of the basin. The upper 8 m of two parallel cores were studied, using paleomagnetic, loss-on-ignition, pollen, and diatom analyses. Based on 11 ¹⁴C ages, the analyzed record spans the last 19,000 ¹⁴C yr B.P. Volcanic activity has affected microfossil abundances, both directly and indirectly, resulting in absence or reduction of pollen and diatom assemblages. Important volcanic activity took place between 19,000 and 15,000 yr B.P. when the lake was a shallow alkaline marsh and an increase of grassland pollen suggests a dry, cold climate. During this interval, abrupt environmental changes with increasing moisture occurred. From 15,000 until 12,500 yr B.P. the lake level increased and the pollen indicates wetter conditions. The highest lake level is registered from 12,500 to ca. 9000 yr B.P. The end of the Pleistocene is characterized by an increase in humidity. From 9000 until ca. 3000 yr B.P. Chalco Lake was a saline marsh and the pollen record indicates warmer conditions. After 3000 yr B.P. the lake level increased and human disturbance dominates the lacustrine record.  相似文献   

Phytoplankton absorption spectra along the water column in deep North Patagonian Andean lakes (Argentina)     

Gonzalo Prez  Claudia Queimalios  Esteban Balseiro  Beatriz Modenutti 《Limnologica》2007,37(1):3-16

During a summer period we studied the vertical variation of in vivo and chlorophyll a specific phytoplankton absorption spectra in relation to the underwater light climate of ten deep North Patagonian Andean lakes of Argentina. The lakes were thermally stratified, and the underwater light climate was characterized by extended euphotic zones which included highly illuminated epilimnetic layers (both UVR and PAR) and metalimnia exposed to dim blue-green light. Most of the lakes presented the development of Deep Chlorophyll Maxima (DCM) at the metalimnetic layers, near 1% of surface PAR irradiance. Analyzing the fourth-derivative plots of in vivo phytoplankton absorption spectra [d^IVa_ph(λ)], we were able to identify several maxima absorption values attributed to different pigments. Considering lakes with DCM, a significant positive linear relationship was found between d^IVa_ph (495–500 nm) normalized by chlorophyll a and downward irradiance. Indeed, a negative significant relationship was found between d^IVa_ph (495–500 nm) normalized by chlorophyll a and diffuse PAR attenuation coefficients. These results point out an increase in the relative concentration of different carotenoids at surface layers indicating the role of photoprotection of these pigments. On the other hand, significant negative linear relationships were found between fourth-derivative spectra normalized by chlorophyll a at 650, 590–595, 560–565 and 520–525 nm and downward irradiance. These results indicated an increase in the relative concentration of photosynthetic accessory pigments at deep layers of the euphotic zone. Furthermore, we found a decrease in depth of specific absorption spectra at 440, 670 nm and in the ratio a_ph* (440 nm) to a_ph* (670 nm). This pattern was associated with the package effect concept. The increase in relative photosynthetic accessory pigment concentrations and the decrease in values of specific absorption spectra at the bottom of the euphotic zone were attributed to changes in phytoplankton communities between surface and deep layers. These outcomes pointed out that the underwater light climate and temperature water structure are, like in marine systems, very important factors governing the distribution of phytoplanktonic organisms. In addition, the possession of specific photosynthetic accessory pigments suggests that dominant species in the DCM are well adapted to these dim blue-green light scenarios.  相似文献   

Tebuthiuron leaching in three Brazilian soils as affected by soil pH     

Autieres Teixeira Faria  Matheus Freitas Souza  Ana Beatriz Rocha de Jesus Passos  Antonio Alberto da Silva  Daniel Valadão Silva  José Cola Zanuncio  Paulo Roberto Ribeiro Rocha 《Environmental Earth Sciences》2018,77(5):214

Underground contamination water by herbicides depends on the interactions between their molecules with physical and chemical soil characteristics and climatic conditions. Studies with columns can estimate the leaching potential of herbicides in soils. This study aimed to determine the effect of soil pH on tebuthiuron leaching, and capacity of bioindicators to detect tebuthiuron residues in three Brazilian soils. Cucumber plants (Cucumis sativus) were more negatively affected when grown in soils with lower amounts of organic matter and clay, and in these soils, the tebuthiuron levels reached greater depths in the column. There was a positive correlation between tebuthiuron concentration and cucumber intoxication, and a negative correlation between tebuthiuron concentration and dry matter cucumber in all soils. The tebuthiuron leached up to 50 cm depth even in soils with higher organic matter and clay content. The increasing of soil pH can affect the leaching of nonionic herbicides, and liming practice may elevate the environmental contamination risk by tebuthiuron. The bioindicator method using Cucumis sativus is viable and can be recommended to detect tebuthiuron concentrations above 0.2 mg kg^?1.  相似文献   

Competitive policies for commercial sea ports in the EU     

Carlos Perez-Labajos  Beatriz Blanco 《Marine Policy》2004,28(6):553-556

The globalisation of the economy and the need for sustainable growth are having a strong influence on international sea freight transport and its infrastructures. Commercial sea ports, faced with the loss in ‘loyalty’ of their traffic and the appearance of ‘new rules in the game’, are developing new strategies in order to achieve the loyalty of their clients. The present paper is a reflection on the findings generated in recent years in the area of competitive port policies. The main focus is on the formulation of commercial and technological strategies, the new legislative framework and its consequences for the European Union in the context of the future ‘Common Ports Policy’.  相似文献   

Harvest control rules for the Western horse mackerel (Trachurus trachurus) stock given paucity of fishery-independent data     

Roel  Beatriz A.; De Oliveira  Jose A. A. 《ICES Journal of Marine Science》2007,64(4):661-670

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Simulation of stratospheric ozone in global forecast model using linear photochemistry parameterization     

Gill-Ran Jeong  Beatriz M. Monge-Sanz  Eun-Hee Lee  Jerald R. Ziemke 《Asia-Pacific Journal of Atmospheric Sciences》2016,52(5):479-494

The two types of ozone, the simulation with interactive (prognostic) ozone using linear photochemistry parameterization (LPP) (INTR) and the simulation with non-interactive ozone using ozone climatology (CLIM), were used in the global forecast model. These two types of ozone were compared with ozone observations from the Aura Microwave Lim Sounder (MLS) and ozonesondes from 16-30 September 2008. The INTR is sensitive to LPP schemes while less sensitive to the time average of initial ozone data. Among three LPP schemes, CARIOLLE, COPCAT, and LINOZ, the COPCAT produces ozone profiles with least differences from MLS and ozonesondes. CLIM overestimates MLS at 200-20 hPa while INTR with COPCAT scheme underestimates MLS ozone above 5 hPa. Over the Antarctic in the lower stratosphere CLIM overestimates MLS and ozonesondes whereas INTR underestimates MLS but overestimates the ozonesonde data. Thus, COPCAT agrees better with ozonesonde data than any other LPP schemes and CLIM. Changing the ozone distribution from CLIM to INTR affects temperature profiles mainly through the modification of differential radiative fluxes. The correlations between ozone, differential radiative fluxes, and temperature are distinguished by altitude (or pressure levels). The correlations are strong or moderate between 3-1000 hPa (lower atmosphere) and weak above 3 hPa (upper atmosphere). This study demonstrates that the simulation of ozone using an appropriate LPP scheme is excellent in overcoming the drawbacks of using climatological ozone profiles that poorly agree with observations in extreme ozone hole events.  相似文献   

Cu(II) adsorption from aqueous solution using red mud activated by chemical and thermal treatment     

Fabiano T. da Conceição  Beatriz C. Pichinelli  Mariana S. G. Silva  Rodrigo Braga Moruzzi  Amauri Antonio Menegário  Maria Lucia Pereira Antunes 《Environmental Earth Sciences》2016,75(5):362

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