Detrital clay grain coats in estuarine clastic deposits: origin and spatial distribution within a modern sedimentary system,the Gironde Estuary (south‐west France)     

Maxime Virolle  Benjamin Brigaud  Raphaël Bourillot  Hugues Fnis  Eric Portier  Thibault Duteil  Julius Nouet  Patricia Patrier  Daniel Beaufort 《Sedimentology》2019,66(3):859-894

Porosity and permeability may be preserved in deep sandstone reservoirs by clay coating (mainly chlorite) which limits quartz overgrowths. Chloritization around quartz grains results mainly from mineralogical transformations of pre‐existing clays. It is fundamental to study those clay precursors to better understand and predict the location and distribution of clay coatings in subsurface sandstones for petroleum or geothermal prospecting. This paper reports a high‐resolution analysis of the composition, distribution and fabric of clays along a modern estuary, the Gironde (south‐west France). The scale of the study ranges from thin sections, through sand bar bodies, up to the entire estuary. Results show that clays are detrital and deposited at the same time as sand grains despite strong hydrodynamic conditions. Clays bind to medium‐grained sands forming detrital clay grain coats. On average, 26% of detrital sand grains are coated along the entire length of the estuary. Coat thickness varies from 1 μm to more than 200 μm, and coat coverage exceeds 30% in some samples. The turbidity maximum zone position (surface water turbidity from 1 to 10 g l^?1) in the estuary, which is controlled by seasonal variations in hydrodynamic processes, significantly impacts the location of the maximum clay content and the abundance of coated grains in sandy facies along the estuary. Flocculation in the water column results in the accumulation of suspended matter and contributes to the high turbidity in the estuary. Exopolymeric substances produced by diatoms are observed both in the field and by cryo‐scanning electron microscopy, suggesting that they may play a major role in binding detrital clay around sand grains. Finally, tidal bars and heterolithic point bars in the estuary funnel and estuarine channels are prime sedimentological targets for finding clay coatings and potentially good reservoir quality in deeply buried sandstones.  相似文献   

Influence of landscape and hydrological factors on stream–air temperature relationships at regional scale     

Aurélien Beaufort  Florentina Moatar  Eric Sauquet  Pierre Loicq  David M. Hannah 《水文研究》2020,34(3):583-597

Identifying the main controlling factors of the stream temperature (Tw) variability is important to target streams sensitive to climate and other drivers of change. The thermal sensitivity (TS), based on relationship between air temperature (Ta) and Tw, of a given stream can be used for quantifying the streams sensitivity to future climate change. This study aims to compare TS for a wide range of temperate streams located within a large French catchment (110,000 km²) using 4 years of hourly data (2008–2012) and to cluster stations sharing similar thermal variabilities and thereby identify environmental key drivers that modify TS at the regional scale. Two successive classifications were carried out: (a) first based on Ta–Tw relationship metrics including TS and (b) second to establish a link between a selection of environmental variables and clusters of stations. Based on weekly Ta–Tw relationships, the first classification identified four thermal regimes with differing annual Tw in terms of magnitude and amplitudes in comparison with Ta. The second classification, based on classification and regression tree method, succeeded to link each thermal regime to different environmental controlling factors. Streams influenced by both groundwater inflows and shading are the most moderated with the lowest TS and an annual amplitude of Tw around half of the annual amplitude of Ta. Inversely, stations located on large streams with a high distance from source and not (or slightly) influenced by groundwater inflows nor shading showed the highest TS, and so, they are very climate sensitive. These findings have implications for guiding river basin managers and other stakeholders in implementing thermal moderation measures in the context of a warming climate and global change.  相似文献   

Chemical variations in assemblages including epidote and/or chlorite in the fossil hydrothermal system of Saint Martin (Lesser Antilles)     

D. Beaufort  P. Patrier  A. Meunier  M.M. Ottaviani 《Journal of Volcanology and Geothermal Research》1992,51(1-2)

Epidote and/or chlorite are common minerals in the roots of the fossil geothermal system of Saint Martin (Lesser Antilles). They appear in four distinct assemblages: (1) epidote+actinolite+quartz±magnetite near the contact between the tuffaceous host rocks (andesitic modal composition) and the quartz-diorite intrusion of Philipsburg; (2) epidote+chlorite+quartz in host rocks as far as a lateral distance of about 3 km from the intrusion; (3) epidote+chlorite+haematite+quartz locally in iron and manganese rich host rocks; (4) chlorite±phengite±magnetite appearing as late sealing of porosity in fracture-controlled quartz veins with strongly phengitized wall rocks. All these assemblages constitute a large alteration grading from propylitic alteration to thermal metamorphism (actinolite-bearing assemblage).Detailed microprobe studies of epidotes replacing plagioclases and of chlorites replacing glass and mafic minerals reveal notable compositional variations which have been studied with respect to temperature paleogradients (estimated from fluid inclusions study), distance from the thermal source and f_o2 conditions. The mean Ps+Pm [100 × (Fe³⁺ + Mn³⁺)/(Al³⁺ + Fe³⁺ + Mn³⁺)] of epidotes vary from 21 in the presence of magnetite near the intrusion to 32 in haematite-bearing iron and/or manganese volcanic and sedimentary formations. The intra-grain chemical scattering of epidotes increases with increasing distance of the pluton and decreasing temperature of crystallization. All the chlorites coexisting with epidote are Mg-rich (X_Fe<0.50). Their main compositional variation consists in a significant enrichment in magnesium (toward the chlinochlore end member) in presence of haematite. The intra-grain chemical scattering of chlorite (expressed by the aluminium content in the structural formula) increases with increasing distance of the pluton and decreasing temperature of crystallization. Chlorites associated with phengite and magnetite in vein alteration are Fe- and Al-rich. The Mössbauer spectra indicate that the Fe³⁺ content of chlorite varies between 25 and 32% of total Fe in the presence of epidote; the higher content being attained in the presence of haematite. The Fe³⁺ content of chlorite associated with magnetite and phengite is 16% of total Fe. The compositional variations of epidote and/or chlorite of the four distinct assemblages observed at Saint Martin result from the combined effects of f_O2, temperature, and time of heating. The effect of f_O2 is particularly perceptible in the control of the epidote Ps content, of the chlorite X_Fe ratio of Fe³⁺ distribution between coexisting epidotes and chlorites. Despite the fact that it may be partially canceled out by the effect of f_O2, the variation of compositional ranges of both epidotes and chlorites, which increases toward the outer part of the geothermal system in response to the combination of decreasing temperatures and decreasing time of heating of the rocks, suggests that chemical equilibrium has not been attained in the assemblages bearing epidotes and chlorites.  相似文献   

Spatial distribution and compositional variation of APS minerals related to uranium deposits in the Kiggavik-Andrew Lake structural trend,Nunavut, Canada     

Thomas Riegler  Dave Quirt  Daniel Beaufort 《Mineralium Deposita》2016,51(2):219-236

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Petrography and chemistry of SiO2 filling phases in the amethyst geodes from the Serra Geral Formation deposit,Rio Grande do Sul,Brazil     

Adriane Commin-Fischer  Gilles Berger  Mireille Polvé  Michel Dubois  Paul Sardini  Daniel Beaufort  Milton Formoso 《Journal of South American Earth Sciences》2010,29(3):751-760

The filling process of amethyst-bearing geodes from Serra Geral Formation basalts, Brazil, is investigated by different methods performed on the SiO₂ filling phases. Image analysis of quartz–amethyst deposits suggests a single growing mechanism ruled by geometric selection of randomly oriented crystals. Microthermometry of fluid inclusions reveals formation temperature lower than 100 °C, probably lower than 50 °C, and fluid salinity as high as 3 mass% NaCl eq. Composition in REE and trace-elements measured by ICP-MS on acid-digested or laser-ablated samples indicates a common genesis for amethyst, quartz and chalcedony, as well as the absence of significant variations from one geode to another. ⁸⁷Sr/⁸⁶Sr data on chalcedony shows that both the host basalt or the Botucatu sandstone are possible silica sources. These data, combined with thermo-kinetic considerations, permit us to discuss the filling process. We argue in favor of the contribution of a mineralized fluid of hydrothermal origin producing a regional silica source which decreased with time. The observed mineral sequence is related to the depletion of silica in the solution.  相似文献   

Evidence of native radiation-induced paramagnetic defects in natural illites from unconformity-type uranium deposits     

E. Morichon  T. Allard  D. Beaufort  P. Patrier 《Physics and Chemistry of Minerals》2008,35(6):339-346

This study presents the first unequivocal identification of natural radiation-induced defects in illites. Middle Proterozoic illites related to unconformity-type uranium deposits of Canada and Australia were studied using electron paramagnetic resonance (EPR) spectroscopy at X- and Q-band frequencies. The saturation behaviour of EPR spectra as a function of power demonstrates that native defects of illites are different from those known in other clays as kaolinite, dickite or smectite. Q-band spectra indicate the presence of several––at least two––native defects. The EPR signal is dominated by an axially distorted spectrum with apparent principal components as follows: g _∥ = 2.032 and g _⊥ = 1.993. The corresponding defect is named as A_i center. The study of oriented specimen confirms the strong anisotropy, and shows that the main defect has its g _∥ component perpendicular to the (ab) plane of illite. These defects in illite correspond to electron holes located on oxygen atoms of the structure and likely associated to Si, according to the lack of hyperfine structure. The A_i center in illite has similar EPR parameters to the A center in kaolinite and dickite. The isochronal annealing data suggest that illite can be used as a dosimeter in the geosphere. However, the determination of half-life and activation energy of the A_i center requires additional work.  相似文献   

The precession phase of hydrological variability in the Western Pacific Warm Pool during the past 400 ka     

Kazuyo Tachikawa  Olivier Cartapanis  Laurence Vidal  Luc Beaufort  Tatiana Barlyaeva  Edouard Bard 《Quaternary Science Reviews》2011,30(25-26):3716-3727

The low-latitude hydrological cycle is a key climate parameter on different timescales, as it contributes to various feedback processes. Modelling studies suggest that the interhemispheric insolation contrast is the major factor controlling the cycle, although the influence of glacial conditions and the phase relationships relative to insolation forcing remain undetermined. In this work, we studied precipitation variability over Papua New Guinea (PNG, 3°S) for the past 400 ka using terrigenous fractions transported by the Sepik River to the Western Pacific Warm Pool (WPWP). A multi-decadal to centennial resolution of the elemental content was obtained using X-ray fluorescence scanning of a marine sediment core using an age model based on ¹⁴C dates and benthic foraminiferal δ¹⁸O. Indicators of the coarse river particulate fraction (bulk and CaCO₃-free basis Ti concentrations, the log intensity ratios of Ti/K and Ti/Ca) displayed a dominant 23 ka periodicity without a clear glacial–interglacial trend. Our precipitation records showed a tight relationship with local summer insolation (3°S, January) with time-dependent lag of 0 to 4 ka. They were generally in anti-phase for U–Th dated Chinese speleothem δ¹⁸O records. Based on an analogy to modern climate, we propose that precipitation over PNG was primarily determined by interhemispheric insolation contrast, and the contribution of austral fall/winter precipitation added second-order variability that formed the lags. For the last four climate cycles, the WPWP hydrological cycle was closely associated with the eastern Asian monsoon, and the influence of glacial conditions on the low-latitude hydrological cycle was estimated to be limited.  相似文献   

Upper quaternary laminated sapropelic sediments from the continental slope of Baja California     

I. O. Murdmaa  G. H. Kazarina  L. Beaufort  E. V. Ivanova  E. M. Emelyanov  V. A. Kravtsov  G. N. Alekhina  V. E. Vasileva 《Lithology and Mineral Resources》2010,45(2):154-171

Core MD02-2508 retrieved from the plateau of the continental slope off Baja California recovered a 40-m-thick section of sapropel (up to 15% C_org), calcareous clay, and diatom ooze with the age of 120 ka at the core bottom. The section is subdivided into three units: Unit I (Holocene) consists of the laminated sapropel; Unit II comprising oxygen isotope stages (MIS) 2, 3, and 4 is represented by homogeneous calcareous clay with interbeds of slightly siliceous sapropelic mud; and Unit III (MIS-5) is composed of laminated sapropelic diatom ooze. Laminated intervals are characterized by the intercalation of two lamina types: (1) dark-colored organic-rich laminae containing multi-species “oceanic” diatom assemblages, as well as radiolarians, coccoliths, planktonic and benthic foraminifera; (2) lighter-colored laminae consisting of diatom ooze with the neritic colonial diatom assemblages commonly composed of one to three species of a single genera. The dark laminae are assumed to be generated within a high productivity zone over the slope, whereas light ones likely represent diatom mats produced by short-term boisterous phytoplankton blooms, possibly in the coastal upwelling.  相似文献