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191.
The gravimetric parameters of the gravity pole tide are the amplitude factor δ, which is the ratio of gravity variations induced by polar motion for a real Earth to variations computed for a rigid one, and the phase difference κ between the observed and the rigid gravity pole tide. They can be estimated from the records of superconducting gravimeters (SGs). However, they are affected by the loading effect of the ocean pole tide. Recent results from TOPEX/Poseidon (TP) altimeter confirm that the ocean pole tide has a self-consistent equilibrium response. Accordingly, we calculate the gravity loading effects as well as their influence on the gravimetric parameters of gravity pole tide at all the 26 SG stations in the world on the assumption of a self-consistent equilibrium ocean pole tide model. The gravity loading effect is evaluated between 1 January 1997 and 31 December 2006. Numerical results show that the amplitude of the gravity loading effect reaches 10−9 m s−2, which is larger than the accuracy (10−10 m s−2) of a SG. The gravimetric factor δ is 1% larger at all SG stations. Then, the contribution of a self-consistent ocean pole tide to the pole tide gravimetric parameters cannot be ignored as it exceeds the current accuracy of the estimation of the pole tide gravity factors. For the nine stations studied in Ducarme et al. [Ducarme, B., Venedikov, A.P., Arnoso, J., et al., 2006. Global analysis of the GGP superconducting gravimeters network for the estimation of the pole tide gravimetric amplitude factor. J. Geodyn. 41, 334–344.], the mean of the modeled tidal factors δm = 1.1813 agrees very well with the result of a global analysis δCH = 1.1816 ± 0.0047 in that paper. On the other hand, the modeled phase difference κm varies from −0.273° to 0.351°. Comparing to the two main periods of the gravity pole tide, annual period and Chandler period, κm is too small to be considered. Therefore, The computed time difference κL induced by a self-consistent ocean pole tide produces a negligible effect on κm. It confirms the results of Ducarme et al., 2006, where no convincing time difference was found in the SG records.  相似文献   
192.
Papandayan is a stratovolcano situated in West Java, Indonesia. Since the last magmatic eruption in 1772, only few hydrothermal explosions have occurred. An explosive eruption occurred in November 2002 and ejected ash and altered rocks. The altered rocks show that an advanced argillic alteration took place in the hydrothermal system by interaction between acid fluids and rocks. Four zones of alteration have been defined and are limited in extension and shape along faults or across permeable structures at different levels beneath the active crater of the volcano.  相似文献   
193.
194.
Debris avalanches associated with volcanic sector collapse are usually high-volume high-mobility phenomena. Debris avalanche deposit remobilisation by cohesive debris flows and landslides is common, so they can share textural characteristics such as hummocks and jigsaw cracks. Distinguishing original deposits from reworked products is critical for geological understanding and hazard assessment because of their different origin, frequency and environmental impact. We present a methodology based on field evidence to differentiate such epiclastic breccias. Basal contact mapping constrained by accurate altitude and location data allows the reconstruction of deposit stratigraphy and geometry. Lithological analysis helps to distinguish the different units. Incorporation structures, kinematic indicators and component mingling textures are used to characterise erosion and transport mechanisms. We apply this method to the enigmatic sequence at Perrier (French Massif Central), where four units (U1–U4) have been interpreted either as debris flow or debris avalanche deposits. The sequence results from activity on the Monts Dore Volcano about 2 Ma ago. The epiclastic units are matrix supported with an almost flat top. U2 and U3 have clear debris flow deposit affinities such as rounded clasts and intact blocks (no jigsaw cracks). U1 and U4 have jigsaw cracked blocks with matrix injection and stretched sediment blocks. U1 lacks large blocks (>10 m wide) and has a homogenous matrix with an upward increase of trapped air vesicle content and size. This unit is interpreted as a cohesive debris flow deposit spawned from a debris avalanche upstream. In contrast, U4 has large mega-blocks (up to 40 m wide), sharp contacts between mixed facies zones with different colours and numerous jigsaw fit blocks (open jigsaw cracks filled by monogenic intra-clast matrix). Mega-blocks are concentrated near the deposit base and are spatially associated with major substratum erosion. This deposit has a debris avalanche distal facies with local debris flow affinities due to partial water saturation. We also identify two landslide deposits (L1 and L2) resulting from recent reworking that has produced a similar facies to U1 and U4. These are distinguishable from the original deposits, as they contain blocks of mixed U1/U4 facies, a distinctly less consolidated and more porous matrix and a fresh hummocky topography. This work shows how to differentiate epiclastic deposits with similar characteristics, but different origins. In doing so, we improve understanding of present and past instability of the Monts Dore and identify present landslide hazards at Perrier.  相似文献   
195.
A two-dimensional semi-analytical heat transfer solution is developed and a parameter sensitivity analysis performed to determine the relative importance of rock material properties (density, thermal conductivity and heat capacity) and hydrogeological properties (hydraulic gradient, fracture aperture, fracture spacing) on the ability to heat fractured rock using thermal conductive heating (TCH). The solution is developed using a Green’s function approach in which an integral equation is constructed for the temperature in the fracture. Subsurface temperature distributions are far more sensitive to hydrogeological properties than material properties. The bulk ground water influx (q) can provide a good estimate of the extent of influx cooling when influx is low to moderate, allowing the prediction of temperatures during heating without specific knowledge of the aperture and spacing of fractures. Target temperatures may not be reached or may be significantly delayed when the groundwater influx is large.  相似文献   
196.
U-series systematics as well as Sr isotopes were measured on young seamount lavas from the Pitcairn hotspot collected during the Polynaut cruise. The combined U-series and Sr isotope data reveal typical mixing relationships between two endmembers. One typical ‘plume’ endmember with radiogenic 87Sr/86Sr and relatively low 230Th/238U and a ‘lithosphere’ endmember with less radiogenic 87Sr/86Sr and relatively larger 230Th/238U. Remarkably, all the lavas, except for a few arguably older samples, are characterized by 226Ra deficits relative to 230Th. On the basis of water content and trace element systematics, we argue that this is due to melting in the presence of phlogopite, which is only stable at lithosphere temperatures. A melting model including the diffusive exchange of elements among phlogopite, garnet and melt is used to constrain melting conditions of the lithosphere. These unusual 226Ra–230Th signatures can be explained by relatively slow melting rates at low matrix porosity. Our model also demonstrates that the effective partitioning behavior is dependent on the melting rate. A simple thermal model for lithosphere heating and melting is in good agreement with predicted melting rates.  相似文献   
197.
New technologies for distributed object computing (DOC) challenge new approaches to integrate Geographical Information Systems (GIS) and simulation tools for spatio-temporal modeling. Several standardization initiatives work on specifying interfaces and defining service architectures for appropriate components. Currently, the most promising attempts are represented by the OpenGIS and the High Level Architecture. This paper gives a brief survey of the current state of the emerging standards, highlights the advantages and shortcomings of these attempts, and defines a possible framework for GIS-integrated simulation of spatio-temporal processes. Two abstraction layers provide interfaces for different GIS kernels and allow the integration of different simulation models. A prototype implementation of the specified interfaces shows the integration of analysis tools and two different simulation strategies: a mesoscale boundary layer model based on the Navier-Stokes equation and a cellular automata to simulate air pollutant dispersion.  相似文献   
198.
Garnet–melt trace element partitioning experiments were performed in the system FeO–CaO–MgO–Al2O3–SiO2 (FCMAS) at 3 GPa and 1540°C, aimed specifically at studying the effect of garnet Fe2+ content on partition coefficients (DGrt/Melt). DGrt/Melt, measured by SIMS, for trivalent elements entering the garnet X-site show a small but significant dependence on garnet almandine content. This dependence is rationalised using the lattice strain model of Blundy and Wood [Blundy, J.D., Wood, B.J., 1994. Prediction of crystal–melt partition coefficients from elastic moduli. Nature 372, 452–454], which describes partitioning of an element i with radius ri and valency Z in terms of three parameters: the effective radius of the site r0(Z), the strain-free partition coefficient D0(Z) for a cation with radius r0(Z), and the apparent compressibility of the garnet X-site given by its Young's modulus EX(Z). Combination of these results with data in Fe-free systems [Van Westrenen, W., Blundy, J.D., Wood, B.J., 1999. Crystal-chemical controls on trace element partitioning between garnet and anhydrous silicate melt. Am. Mineral. 84, 838–847] and crystal structure data for spessartine, andradite, and uvarovite, leads to the following equations for r0(3+) and EX(3+) as a function of garnet composition (X) and pressure (P):
r0(3+) [Å]=0.930XPy+0.993XGr+0.916XAlm+0.946XSpes+1.05(XAnd+XUv)−0.005(P [GPa]−3.0)(±0.005 Å)
EX(3+) [GPa]=3.5×1012(1.38+r0(3+) [Å])−26.7(±30 GPa)
Accuracy of these equations is shown by application to the existing garnet–melt partitioning database, covering a wide range of P and T conditions (1.8 GPa<P<5.0 GPa; 975°C<T<1640°C). DGrt/Melt for all 3+ elements entering the X-site (REE, Sc and Y) are predicted to within 10–40% at given P, T, and X, when DGrt/Melt for just one of these elements is known. In the absence of such knowledge, relative element fractionation (e.g. DSmGrt/Melt/DNdGrt/Melt) can be predicted. As an example, we predict that during partial melting of garnet peridotite, group A eclogite, and garnet pyroxenite, r0(3+) for garnets ranges from 0.939±0.005 to 0.953±0.009 Å. These values are consistently smaller than the ionic radius of the heaviest REE, Lu. The above equations quantify the crystal-chemical controls on garnet–melt partitioning for the REE, Y and Sc. As such, they represent a major advance en route to predicting DGrt/Melt for these elements as a function of P, T and X.  相似文献   
199.
We have studied the influence of Ca-Tschermaks (Calcium Tschermaks or CaTs) content of clinopyroxene on the partitioning of trace elements between this phase and silicate melt at fixed temperature and pressure. Ion probe analyses of experiments carried out in the system Na2O–CaO–MgO–Al2O3–SiO2, at 0.1 MPa and 1218°C, produced crystal-melt partition coefficients (D) of 36 trace elements (Li, Cl, Sc, Ti, V, Cr, Fe, Co, Ge, Sr, Y, Zr, Nb, Mo, Ru, Rh, In, Sn, Sb, Ba, La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu, Hf, Ta and W), for clinopyroxene compositions between 10 and 32 mol% CaTs. Partition coefficients for 2+ to 5+ cations show, for each charge, a near parabolic dependence of log D on ionic radius of the substituting cation, for partitioning into both the M1 and M2 sites of clinopyroxene. Fitting the results to the elastic strain model of Blundy and Wood [Blundy, J.D., Wood, B.J., 1994. Prediction of crystal-melt partition coefficients from elastic moduli. Nature 372, 452–454] we obtain results for the strain-free partition coefficients of theoretical cations (D0), with site radius r0, and for the site's Young's Modulus (E).

In agreement with earlier data our results show that increasing ivAl concentration in cpx is matched by increasing D, EM1, EM2 and D0 for tri-, tetra- and pentavalent cations. The degree of fractionation between chemically similar elements (i.e. Ta/Nb, Zr/Hf) also increases. In contrast, D values for mono-, di- and hexavalent cations decrease with increasing ivAl in the cpx. The large suite of trace elements used has allowed us to study the effects of cation charge on D0, r0 and E. We have found that D0 and r0 decrease with increasing cation charge, e.g. r0=0.66 Å for 4+ cations and 0.59 Å for 5+ cations substituting into M1. Values of EM1 and EM2 increase with cation charge as well as with increasing ivAl content. The increase in EM2 is linear and close to the trend set by Hazen and Finger [Hazen, R.M., Finger, L.W., 1979. Bulk modulus-volume relationship for cation–anion polyhedra. J. Geophys. Res. 84 (10) 6723–6728] for oxides. EM1 values are much higher and do not fit the trend predicted by the Hazen and Finger relationship.  相似文献   

200.
The crater lake of Kawah Ijen volcano contains extremely low pH (<0.4) waters with high SO4 (70000 mg/kg), Cl (21000 mg/kg), F (1500 mg/kg), Al (5000 mg/kg), Fe (2000 mg/kg) and trace metal (Cu 0.5, Zn 4, Pb 3 mg/kg) contents. These brines seep outward through the western crater rim and reappear on the other side as streamlets, which form the headwaters of the Banyupahit stream. The Banyupahit first mixes with fresh rivers and thermal springs in the Ijen caldera and then irrigates a coastal agricultural plain which is 30 km from the summit crater.We discuss the downstream composition changes affecting the Banyupahit waters by using stable isotope, chemical and mineralogical data collected from sites along the stream length. The saturation of the stream waters with respect to minerals was evaluated with SOLVEQ and WATEQ4F and compared with the geochemical observations. An aluminous mineralogy (alunogen, pickeringite, tamarugite and kalinite) develops in the upper part of the Banyupahit due to concentration of the headwaters by evaporation. Downstream attenuation of dissolved element concentrations results principally from dilution and from mineral precipitation. The stream pH changes from 0 at the source to >4 close to the mouth. The δD and δ18O values and the relative SO4–Cl–F contents of the Banyupahit waters indicate that the tributaries are mostly meteoric. Dissolved SO4 in the acidic stream come only from the crater lake seepages and are not involved later in microbially mediated reactions, as shown by their δ34S and δ18O values. Re-equilibration of the stream SO4 oxygen-isotope composition with H2O from tributaries does not occur.Calcium, SiO2, Al, Fe, K and SO4 behave non-conservatively in the stream waters. Gypsum, silica (amorphous or poorly ordered), a basic aluminum hydroxysulfate (basaluminite?), K-jarosite and amorphous ferric hydroxide may exert a solubility control on these elements along the entire stream length, or in certain stream sections, consistent with the thermochemical model results. Downstream concentration trends and mineral saturation levels suggest that precipitation of Sr-, Pb-rich barite and celestite consume Ba, Sr and Pb, whereas dissolved Cu, Pb and Zn may adsorb onto solid particles, especially after the junctions of the acidic stream with non-acidic rivers. We calculated that significant fluxes of SO4, F, Cl, Al, SiO2, Ti, Mn and Cu may reach the irrigation system, possibly causing serious environmental impacts such as soil acidification and induration.  相似文献   
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