Comparing field and laboratory breakdown rates of coarse particulate organic matter: Sediment dynamics mask the impacts of dissolved nutrients on CPOM mass loss in streams     

Bernd Spänhoff  Clemens Augspurger  Kirsten Küsel 《Aquatic Sciences - Research Across Boundaries》2007,69(4):495-502

  相似文献   

Heat capacity of wadeite-type K2Si4O9 and the pressure-induced stable decomposition of K-feldspar     

Detlef W. Fasshauer  Bernd Wunder  Niranjan D. Chatterjee  Günther W. H. Höhne 《Contributions to Mineralogy and Petrology》1998,131(2-3):210-218

The heat capacity of synthetic, stoichiometric wadeite-type K₂Si₄O₉ has been measured by DSC in the 195≤T(K)≤598 range. Near the upper temperature limit of our data, the heat capacity observed by DSC agrees with that reported by Geisinger et al. (1987) based on a vibrational model of their infrared and Raman spectroscopic data. However, with decreasing temperature, the Cp observed by DSC is progressively higher than that predicted from the vibrational model, suggesting that the standard entropy of K₂Si₄O₉ is likely to be larger than 198.9 ± 4.0 J/K · mol computed from the spectroscopic data. A fit to the DSC data gave: Cp(T) = 499.13 (±1.87) − 4.35014 · 10³(±3.489 · 10¹) · T ^−0.5, with T in K and average absolute percent deviation of 0.37%. The room-temperature compressibilities of kalsilite and leucite, hitherto unknown, have been measured as well. The data, fitted to the Murnaghan equation of state, gave K _o = 58.6 GPa, K _o ^′ = 0.1 for kalsilite and K _o = 45 GPa, K _o ^′ = 5.7 for α-leucite. Apart from the above mentioned data on the properties of the individual phases, we have also obtained reaction-reversals on four equilibria in the system K₂O-Al₂O₃-SiO₂. The Bayesian method has been used simultaneously to process the properties of 13 phases and 15 reactions between them to derive an internally consistent thermodynamic dataset for the K₂O-Al₂O₃-SiO₂ ternary. The enthalpy of formation of K₂Si₄O₉ wadeite is in perfect agreement with its revised calorimetric value, the standard entropy is 232.1 ± 10.4 J/K · mol, ∼15% higher than that implied by vibrational modeling. The phase diagram, generated from our internally consistent thermodynamic dataset, shows that for all probable P-T trajectories in the subduction regime, the stable pressure-induced decomposition of K-feldspar will produce coesite + kalsilite rather than coesite + kyanite + K₂Si₄O₉ (cf. Urakawa et al. 1994). Received: 11 June 1997 / Accepted: 2 December 1997  相似文献   

The role of gravity in the WEGENER project     

Iginio Marson  Bernd Richter   《Journal of Geodynamics》1998,25(3-4)

Variations in the gravity field are introduced by mass or density redistribution in the vicinity of the measuring point as well as far field or global effects but also any crustal process which involves a height variation has a direct implication on the temporal variation of the gravity field.The measuring techniques involved in the WEGENER project include absolute and high precision relative gravity measurements and stationary measurements with superconducting gravity meters. The state of the art for both techniques is discussed and shown that systematic errors or the measurement of their changes can be detected by inter-comparison with other absolute gravimeters and frequently repeated measurements at a reference station monitored by a superconducting gravimeter. In the combination of the available gravity techniques it is possible to achieve a precision at the micro-Gal level for secular trends and a higher accuracy for period events which enable improvements in the modelling of environmental effects induced by ocean, atmospheric and ground water loading effects from the long term processes.  相似文献   

Geothermal resource assessment of the United States     

L. J. Patrick Muffler  Robert L. Christiansen 《Pure and Applied Geophysics》1978,117(1-2):160-171

Geothermal resource assessment is the broadly based appraisal of the quantities of heat that might be extracted from the earth and used economically at some reasonable future time. In the United States, the Geological Survey is responsible for preparing geothermal assessments based on the best available data and interpretations. Updates are required every few years owing to increasing knowledge, enlarging data base, improving technology, and changing economics. Because geothermal understanding is incomplete and rapidly evolving, the USGS complements its assessments with a broad program of geothermal research that includes (1) study of geothermal processes on crustal and local scales, (2) regional evaluations, (3) intensive study of type systems before and during exploitation (4) improvement of exploration techniques, and (5) investigation of geoenvironmental constraints.  相似文献   

Schallgeschwindigkeit und Impedanz des oberen Meeresbodens in Gebieten der Nordsee,des Skagerraks,des Kattegats und der Ostsee     

Dr. Florian Schirmer  Dr. Bernd Schmalfeldt  Dipl.-Phys. Jürgen Siebert 《Ocean Dynamics》1979,32(6):279-288

  相似文献   

Hydraulic Properties of Coal and Related Materials, Northern Great Plains   总被引：1，自引：0，他引：1  

Bernd W. Rehm  Gerald H. Groenewold  Kevin A. Morin 《Ground water》1980,18(6):551-561

  相似文献   

Pyrolysis-high resolution gas chromatography and pyrolysis gas chromatography-mass spectrometry of kerogens and kerogen precursors     

Dik van de Meent  Stephen C. Brown  R.Paul Philp  Bernd R.T. Simoneit 《Geochimica et cosmochimica acta》1980,44(7):999-1013

A series of kerogens and kerogen precursors isolated from DSDP samples, oil shales and Recent algal mats have been examined by Curie point pyrolysis-high resolution gas chromatography and gas chromatography-mass spectrometry. This study has shown that the three main types of kerogens (marine, terrestrial and mixtures of both) can be characterized using these techniques. The marine (algal) kerogens yield principally aliphatic products and the terrestrial kerogens yield more aromatic and phenolic products with some n-alkanes and n-alkenes. The yields of n-alkanes and n-alkenes increase and phenols decrease with increasing geologic age, however, pyrolysis-GC cannot be used to characterize the influence of short term diagenesis on the kerogen structure.  相似文献   

Determination of vertical temperature profiles for the atmospheric boundary layer by ground-based microwave radiometry     

Bernd Schönwald 《Boundary-Layer Meteorology》1978,15(4):453-464

A useful method for remote sensing of vertical temperature profiles in the atmospheric boundary layer is described. From angular measurements of brightness temperature at 58 GHz, profiles have been inferred up to an altitude of 700 m. Calculations were done with an iterative inversion procedure (Smith et al., 1972) using Twomey-type smoothing (Twomey, 1963). It is shown how an initial-guess profile can be directly derived from the radiation measurements using, a nomogram.  相似文献   

Diterpenoid compounds and other lipids in deep-sea sediments and their geochemical significance     

Bernd R.T Simoneit 《Geochimica et cosmochimica acta》1977,41(4):463-476

Cyclic diterpenoid compounds have been found by various investigators in the geosphere (e.g. fossil resins, coals, soil, shale and deep-sea sediments). These compounds occur in significant amounts only in higher plants and are therefore potential markers of terrigenous plant lipids.Diterpenoids with the abietane skeleton (mainly dehydroabietic acid) have been identified in the lipids of sediment samples from the northeast Pacific Ocean, Black Sea and North Atlantic Ocean. The presence of these resin-derived compounds correlated with the terrigenous clay components and with the presence of pollen. The presence of polycyclic diterpenoids was also correlated with the distribution patterns and inferred sources of other sediment lipid constituents (e.g. n-alkanes, n-fatty acids, etc.).Potamic transport, followed by turbidite redistribution are the probable input mechanisms of these resin-derived compounds to the deep-sea sediments. These diterpenoids appear to be excellent biological markers of resinous higher plants.  相似文献   

Paleo-redox boundaries in fractured granite     

K. Dideriksen  B.C. Christiansen  T. Balic-Zunic  S.L.S. Stipp 《Geochimica et cosmochimica acta》2010,74(10):2866-5573

At the Earth’s surface, Fe(II) often oxidises and forms insoluble Fe(III)-(oxyhydr)oxides, whose particle size and structure depend on solution composition and temperature during formation and afterwards. Bacterial processes and exposure to reducing environments reduces them again, releasing dissolved iron to the groundwater. During such cycling, the Fe isotopes fractionate to an extent that is expected to depend on temperature. In this study, we report on the use of Fe-oxides as paleo-redox indicators, using their structure, morphology and Fe-composition as a clue for formation conditions. In samples taken from ∼120 m drill cores in granite from SE Sweden, X-ray amorphous, superparamagnetic, nanometre-sized Fe-oxides are confined to fractures of the upper ∼50 m, whereas well-crystalline Fe-oxides, with particle sizes typical for soils, occur down to ∼110 m. We also identified hematite with a particle size of 100 nm, similar to hematite of hydrothermal origin. The Fe isotope composition of the fine-grained Fe-oxides (−1‰ < δ⁵⁶Fe < 1‰, IRMM-14 referenced) scatter significantly compared to the distribution previously observed for hydrothermal material (−0.26‰ < δ⁵⁶Fe < 0.12‰) and they are dominantly heavier than Fe-bearing silicates from fractures (−0.56‰ < δ⁵⁶Fe < −0.35‰). This is consistent with formation by low-temperature weathering, where Fe-silicates dissolve, Fe(II) oxidises and Fe(III)-oxides precipitate. The X-ray amorphous, nanometre-sized nature of near-surface Fe-oxides suggests recent formation. The deeper situated, well-crystalline Fe-oxides are more mature and we interpret that they record earlier oxidising events. They exist in fractures that are not significantly altered, indicating formation during periods of oxidation. Our results show that oxygenated water may reach depths of ∼110 m in fractured granite. The absence of natural, low-temperature Fe-oxides from deeper drill cores suggests that oxygenated waters do not readily penetrate beyond about 100 m and suggests that radioactive waste repositories located at a depth of ∼500 m should be well-protected from oxygenated waters.  相似文献