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991.
Wolfgang Kiesl Christian Koeberl Wilfried Körner 《International Journal of Earth Sciences》1990,79(2):327-335
The major and trace element geochemistry of magnesite and dolomite samples from alternating rock masses at the Oberdorf/Laming (Styria, Austria) mineralization has been studied. The rare earth elements (REE) are considered to be of importance for the discussion of the origin of sparry magnesite deposits. The Al and REE contents are positively correlated, indicating a clay component as the main source for REE in the magnesites and their precursor rocks. Our data support the view that the Oberdorf and probably other magnesite mineralizations in the Eastern Alps have been formed by metasomatism. Through this process calcite (which was deposited by sedimentation in a marine environment) underwent dolomitization. Subsequently, Mg-rich solutions circulating through the rock masses formed the magnesite bodies.During the formation of the dolomites and the conversion to magnesites, the REE patterns of the original carbonates remained unchanged. The magnesites exhibit patterns that are very similar to sedimentary carbonates (which contain a REE-bearing clay component). Magnesites of purely sedimentary origin, formed in a predominantly evaporitic environment, should have lower total REE contents and different patterns due to the short residence times of these elements in seawater. Analyses of talc pseduomorphs after magnesite indicate as well that the REE patterns are not significantly altered during the talcification. The Mg-rich solutions that led to the formation of the magnesites have probably been derived from serpentinites below the gneiss complexes of eastern Styria and the South Penninic units of the Tauern window.
Zusammenfassung Die Haupt- und Spurenelementgeochemie von Magnesit- und Dolomitproben, die aus alternierenden Gesteinsstöcken in der Magnesitmine von Oberdorf/Laming (Steiermark, Österreich) stammen, wurde untersucht. Besonderes Augenmerk wurde dabei auf die Geochemie der Seltenen Erdelemente (REE) gelegt, da diese für Aussagen über die Entstehung der Magnesitlagerstätten von besonderer Bedeutung sind. Eine positive Korrelation zwischen den Al und REE-Gehalten deutet darauf hin, daß der Hauptteil der REE einer Tonkomponente entstammt. Die Daten unterstützen eine metasomatische Entstehung der Spatmagnesite der Oberdorfer Lagerstätte und anderer Ostalpiner Lagerstätten. Sedimentär angelegter Kalzit wird dabei über Dolomit mit Mg-reichen Lösungen in Magnesit umgewandelt.Während der Metasomatose bleiben die chondritnormierten REE-Verteilungen der Ausgangskarbonate relativ unverändert erhalten. Die so entstandenen Spatmagnesite weisen Verteilungsmuster auf, die jenen der sedimentären Karbonate, aus denen sie entstanden sind, entsprechen. Rein sedimentär entstandene Magnesite werden praktisch nur in evaporitischem Milieu gebildet und sollten infolge der kurzen Verweilzeit dieser Elemente im Meerwasser wesentlich niedrigere REE-Gehalte und andere Verteilungsmuster aufweisen. Analysen einer Talkpseudomorphose zeigen, daß sich die REE-Verteilungsmuster auch bei der metasomatischen Talk-bildung nicht wesentlich ändern. Die Mg-reichen Lösungen, die zur Bildung der Magnesite notwendig waren, entstammen vermutlich tiefliegenden Sepentiniten, auf die es Hinweise im Untergrund der oststeirischen Gneisskomplexe und des südpenninischen Tauernfensters gibt.
Résumé Cette note présente les résultats d'une étude géochimique des éléments majeurs et en trace d'échantillons de magnésite et de dolomite qui se présentent en masses alternées dans la mine de magnésite de Oberdorf/Laming (Steiermark, Autriche). Une attention particulière a été apportée aux terres rares, considérées comme fournissant des arguments importants dans la discussion de l'origine des gisements. Les teneurs en Al et en terres rares montrent une corrélation positive, ce qui permet de rapporter à un composant argileux la source principale des terres rares. Les résultats obtenus plaident en faveur d'une origine métasomatique des minéralisations en magnésite d'Oberdorf et d'autres endroits des Alpes orientales. Au cours de ce processus, la calcite, d'origine sédimentaire marine, a été le siège d'une dolomitisation avec, subséquemment, formation de corps de magnésite grâce à la circulation de solutions riches en Mg.Au cours de la métasomatose, la distribution des terres rares des carbonates originels n'est pas modifiée: les magnésites montrent des répartitions très semblables à celles des carbonates sédimentaires (lesquels renferment un constituant argileux porteur des terres rares). Des magnésites d'origine purement sédimentaires, formées en milieu évoporitique, doivent présenter un contenu total en terres rares moins élevé et une distribution différente de ces éléments, eu égard à la brièveté de leur séjour dans l'eau de mer. Des analyses de pseudomorphoses de magnésite en talc montrent de même que la distribution des terres rares n'est pas modifiée de manière significative au cours de la talcification. Les solutions riches en Mg responsables de la formation de la magnésite sont probablement dérivées de serpentines situées sous les complexes gneissiques de Styrie et les unités penniques méridionales de la fenêtre des Tauern.
dorf/Laming'a (, ) . , . , . , , - . . . .. , , . , , , , ; . , . , , , , , - - .相似文献
992.
We have re-investigated the earlier calculations of Sharp and Höfflich (1989) for the first overtone of CO as observed in SN 1987A. The cooling effect of CO has been included in the models. We found a similar but slightly lower CO-enrichment. The sensitivity of the band structure on temperature is also demonstrated.Paper presented at the 11th European Regional Astronomical Meetings of the IAU on New Windows to the Universe, held 3–8 July, 1989, Tenerife, Canary Islands, Spain. 相似文献
993.
A model for second-step electron acceleration in impulsive solar flares is presented. We have extended the theory of stochastic particle acceleration to include Coulomb energy losses which become important at low coronal heights. This inclusion successfully explains the observed steepening of interplanetary electron spectra below 3 MeV following impulsive solar flares taking place at low coronal heights. It also explains the observed spectral differences of relativistic electrons in long-duration and impulsive flares. 相似文献
994.
The interaction of interstellar pick-up ions with the solar wind is studied by comparing a model for the velocity distribution function of pick-up ions with actual measurements of He+ ions in the solar wind. The model includes the effects of pitch-ang'e diffusion due to interplanetary Alfvén waves, adiabatic deceleration in the expanding solar wind and the radial variation of the source function. It is demonstrated that the scattering mean free path is in the range 0.1 AU and that energy diffusion can be neglected as compared with adiabatic deceleration. The effects of adiabatic focusing, of the radial variation of the neutral density and of a variation of the solar wind velocity with distance from the Sun are investigated. With the correct choice of these parameters we can model the measured energy spectra of the pick-up ions reasonably well. It is shown that the measured differential energy density of the pick-up ions does not vary with the solar wind velocity and the direction of the interplanetary magnetic field for a given local neutral gas density and ionization rate. Therefore, the comparison of the model distributions with the measurements leads to a quantitative determination of the local interstellar gas density.Paper dedicated to Professor Hannes Alfvén on the occasion of his 80th birthday, 30 May 1988. 相似文献
995.
Gabriel Katul Olli Peltola Tiia Grönholm Samuli Launiainen Ivan Mammarella Timo Vesala 《Boundary-Layer Meteorology》2018,169(2):163-184
The three turbulent velocity components, water vapour (\(\text {H}_2\text {O}\)), carbon dioxide (\(\text {CO}_{2}\)), and methane (\(\text {CH}_{4}\)) concentration fluctuations are measured above a boreal peatland and analyzed using conditional sampling and quadrant analysis. The overarching question to be addressed is to what degree lower-order cumulant expansion methods describe transport efficiency and the relative importance of ejections and sweeps to momentum, \(\text {CH}_{4}\), \(\text {CO}_{2}\) and \(\text {H}_2\text {O}\) fluxes across a range of atmospheric flow regimes. The patchy peatland surface creates distinctly different source and sink distributions for the three scalars in space and time thereby adding to the uniqueness of the set-up. The measured and modelled fractional contributions to the momentum flux show that sweep events dominate over ejections in agreement with prior studies conducted in the roughness sublayer. For scalar fluxes, ejections dominate the turbulent fluxes over sweeps. While ejective motions persist longer for momentum transport, sweeping events persist longer for all three scalars. Third-order cumulant expansions describe many of the results detailed above, and the results are surprising given the highly non-Gaussian distribution of \(\text {CH}_{4}\) turbulent fluctuations. Connections between the asymmetric contributions of sweeps and ejections and the flux-transport term arising in scalar turbulent-flux-budget closure are derived and shown to agree reasonably well with measurements. The proposed model derived here is much simpler than prior structural models used to describe laboratory experiments. Implications of such asymmetric contributions on, (i) the usage of the now proliferating relaxed-eddy-accumulation method in turbulent flux measurements, (ii) the constant-flux assumption, and (iii) gradient-diffusion closure models are presented. 相似文献
996.
David T. Y. Wong William S. Osborne Stephen D. Sarre Bernd Gruber 《International journal of geographical information science》2018,32(5):1006-1025
The geographical distribution of a species is limited by factors such as climate, resources, disturbances and species interactions. Environmental niche models attempt to encapsulate these limits and represent them spatially but do not always incorporate disturbance factors. We constructed MaxEnt models derived from a remotely sensed vegetation classification with, and without, an agricultural modification variable. Including agricultural modification improved model performance and led to more sites with native vegetation and fewer sites with exotic or degraded native vegetation being predicted suitable for A. parapulchella. Analysis of a relatively well-surveyed sub-area indicated that including agricultural modification led to slightly higher omission rates but markedly fewer likely false positives. Expert assessment of the model based on mapped habitat also suggested that including agricultural modification improved predictions. We estimate that agricultural modification has led to the destruction or decline of approximately 30–35% of the most suitable habitat in the sub-area studied and approximately 20–25% of suitable habitat across the entire study area, located in the Australian Capital Territory, Australia. Environmental niche models for a range of species, particularly habitat specialists, are likely to benefit from incorporating agricultural modification. Our findings are therefore relevant to threatened species planning and management, particularly at finer spatial scales. 相似文献
997.
A new method was developed for the inversion reconstruction of gravity potential. This method offers the possibility to determine
the potential function and all of its important derivatives using the common inversion of gravity gradients and the first
derivatives of potential. Gravity gradients can be originated from Torsion balance measurements, while the first derivatives
of potential can be derived from the deflections of the vertical data. Different fields having great importance can be originated
from this reconstructed potential function at any points of the investigated area. The advantage of this method is that the
solution can be performed by a significantly over-determined inverse problem. Test computations were performed for the inversion
reconstruction of gravity potential. There were 248 torsion balance measurements and 13 points where the deflections of the
vertical are known in our test area. This inversion algorithm is rather stable. Gravity potential, the first and the second
derivatives of the potential were determined for the test area by this suggested method. This method gives a good possibility
for a useful geodetic application; deflections of the vertical based on torsion balance measurements can be determined for
the whole area for each torsion balance stations. 相似文献
998.
Erin F. Owen Alan D. Wanamaker Jr. Bernd R. Schöne 《Geochimica et cosmochimica acta》2008,72(19):4687-4698
The relationship between stable isotope composition (δ13C and δ18O) in seawater and in larval shell aragonite of the sea scallop, Placopecten magellanicus, was investigated in a controlled experiment to determine whether isotopes in larval shell aragonite can be used as a reliable proxy for environmental conditions. The linear relationship between δ13CDIC and δ13Caragonite (r2 = 0.97, p < 0.0001, RMSE = 0.18) was:
δ13CDIC=1.15(±0.05)∗δ13Caragonite-0.85(±0.04) 相似文献
999.
Rainer Grün Maxime Aubert Marie-Hélène Moncel 《Geochimica et cosmochimica acta》2008,72(21):5278-5290
We have mapped U (238U) and Th (232Th) elemental concentrations as well as U-series isotope distributions in a Neanderthal tooth from the Middle Palaeolithic site of Payre using laser ablation ICP-MS. The U-concentrations in an enamel section varied between 1 and 1500 ppb. The U-concentration maps show that U-migration through the external enamel surface is minute, the bulk of the uranium having migrated internally via the dentine into the enamel. The uranium migration and uptake is critically dependent on the mineralogical structure of the enamel. Increased U-concentrations are observed along lineaments, some of which are associated with cracks, and others may be related to intra-prismatic zones or structural weaknesses reaching from the dentine into the enamel. The uranium concentrations in the dentine vary between about 25,000 and 45,000 ppb. Our systematic mapping of U-concentration and U-series isotopes provides insight into the time domain of U-accumulation. Most of the uranium was accumulated in an early stage of burial, with some much later overprints. None of the uranium concentration and U-series profiles across the root of the tooth complied with a single stage diffusion-adsorption (D-A) model that is used for quality control in U-series dating of bones and teeth. Nevertheless, in the domains that yielded the oldest apparent U-series age estimates, U-leaching could be excluded. This means that the oldest apparent U-series ages of around 200 ka represent a minimum age for this Neanderthal specimen. This is in good agreement with independent age assessments (200-230 ka) for the archaeological layer, in which it was found.The Th elemental concentrations in the dental tissues were generally low (between about 1 and 20 ppb), and show little relationship with the nature of the tissue. 相似文献
1000.
Petrogenesis of Permian alkaline lamprophyres and diabases from the Spanish Central System and their geodynamic context within western Europe 总被引：1，自引：1，他引：0
D. Orejana C. Villaseca K. Billström B. A. Paterson 《Contributions to Mineralogy and Petrology》2008,156(4):477-500
Basic to ultrabasic alkaline lamprophyres and diabases intruded within the Spanish Central System (SCS) during Upper Permian.
Their high LREE, LILE and HFSE contents, together with positive Nb–Ta anomalies, link their origin with the infiltration of
sublithospheric K-rich fluids. These alkaline dykes may be classified in two distinct groups according to the Sr–Nd isotope
ratios: (1) a depleted PREMA-like asthenospheric component, and (2) a BSE-like lithospheric component. A slight enrichment
in radiogenic 207Pb and 208Pb allows the contribution of a recycled crustal or lithospheric component in the mantle sources. The intrusion of this alkaline
magmatism is likely to have occurred due to adiabatic decompression and mantle upwelling in the context of the widespread
rifting developed from Carboniferous to Permian in western Europe. The clear differences in the geochemical affinity of Lower
Permian basic magmas from north-western and south-western Europe might be interpreted in terms of a more extensive separation
of both regions during that period, until they were assembled during Upper Permian.
Electronic supplementary material The online version of this article (doi:) contains supplementary material, which is available to authorized users. 相似文献