Mineralogy and geochemistry of atypical reduction spheroids from the Tumblagooda Sandstone,Western Australia     

David C. M. Fox  Samuel C. Spinks  Robert L. Thorne  Milo Barham  Mehrooz Aspandiar  Joseph G. T. Armstrong  Tonguç Uysal  Nicholas E. Timms  Mark A. Pearce  Michael Verrall  Belinda Godel  Brad Whisson 《Sedimentology》2020,67(1):677-698

Reduction spheroids are small-scale, biogenic, redox-controlled, metal enrichments that occur within red beds globally. This study provides the first analysis of the compositionally unique reduction spheroids of the Tumblagooda Sandstone. The work aims to account for their composition and consequently improve existing models for reduction spheroids generally, which presently fail to account for the mineralogy of the Tumblagooda Sandstone reduction spheroids. Interstitial areas between detrital grains contained in the cores of these reduction spheroids are dominated by microplaty haematite, in addition to minor amounts of svanbergite, gorceixite, anatase, uraninite, monazite and illite. The haematite-rich composition, along with an absence of base metal phases and the vanadiferous mica roscoelite, makes these reduction spheroids notable in comparison to other global reduction spheroid occurrences. Analyses of illite crystallinity provide values for samples of the Tumblagooda Sandstone host rock corresponding to heating temperatures of ca 200°C. Consequently, while Tumblagooda Sandstone reduction spheroids formed via the typical metabolic processes of dissimilatory metal-reducing bacteria, the combination of a unique mineralogy and illite crystallinity analysis provides evidence of more complex late-stage heating and reoxidation. This has not previously been recognised in other reduction spheroids and therefore expands the existing model for reduction spheroid genesis by also considering the potential for late-stage alteration. As such, future reduction spheroid studies should consider the potential impact of post-formation modification, particularly where they are to be used as evidence of ancient microbial processes; such as in the search for early evidence of life in the geological record on Earth or other planets. Additionally, because of their potential for modification, reduction spheroids serve as a record of the redox history of red beds and their study could provide insights into the evolution of redox conditions within a given red bed during its diagenesis. Finally, this paper also provides insights into the relatively understudied diagenetic history of the Tumblagooda Sandstone; supplying the first reliable and narrow constraints on its thermal history. This has important implications for the thermal history of the Carnarvon Basin and its petroleum prospectivity more broadly.  相似文献   

Discriminating assimilants and decoupling deep- vs. shallow-level crystal records at Mount Adams using 238U–230Th disequilibria and Os isotopes     

Brian R. Jicha  Clark M. Johnson  Wes Hildreth  Brian L. Beard  Garret L. Hart  Steven B. Shirey  Brad S. Singer 《Earth and Planetary Science Letters》2009,277(1-2):38-49

A suite of 23 basaltic to dacitic lavas erupted over the last 350 kyr from the Mount Adams volcanic field has been analyzed for U–Th isotope compositions to evaluate the roles of mantle versus crustal components during magma genesis. All of the lavas have (²³⁰Th/²³⁸U) > 1 and span a large range in (²³⁰Th/²³²Th) ratios, and most basalts have higher (²³⁰Th/²³²Th) ratios than andesites and dacites. Several of the lavas contain antecrysts (crystals of pre-existing material), yet internal U–Th mineral isochrons from six of seven lavas are indistinguishable from their eruption ages. This indicates a relatively brief period of time between crystal growth and eruption for most of the phenocrysts (olivine, clinopyroxene, plagioclase, magnetite) prior to eruption. One isochron gave a crystallization age that is ~ 20–25 ka older than its corresponding eruptive age, and is interpreted to reflect mixing of older and juvenile crystals or a protracted period of magma storage in the crust. Much of the eruptive volume since 350 ka consists of lavas that have small to moderate ²³⁰Th excesses (2–16%), which are likely inherited from melting of a garnet-bearing intraplate (“OIB-like”) mantle source. Following melt generation and subsequent migration through the upper mantle, most Mt. Adams magmas interacted with young, mafic lower crust, as indicated by ¹⁸⁷Os/¹⁸⁸Os ratios that are substantially more radiogenic than the mantle or those expected via mixing of subducted material and the mantle wedge. Moreover, Os–Th isotope variations suggest that unusually large ²³⁰Th excesses (25–48%) and high ¹⁸⁷Os/¹⁸⁸Os ratios in some peripheral lavas reflect assimilation of small degree partial melts of pre-Quaternary basement that had residual garnet or Al-rich clinopyroxene. Despite the isotopic evidence for lower crustal assimilation, these processes are not generally recorded in the erupted phenocrysts, indicating that the crystal record of the deep-level ‘cryptic’ processes has been decoupled from shallow-level crystallization.  相似文献   

Impacts of ocean acidification on marine fauna and ecosystem processes   总被引：21，自引：1，他引：21  

Fabry  Victoria J.; Seibel  Brad A.; Feely  Richard A.; Orr  James C. 《ICES Journal of Marine Science》2008,65(3):414-432

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Collateral consequences of the inhomogeneous distribution of short-lived radionuclides in the solar nebula     

Robert H. NICHOLS  Frank A. PODOSEK  Brad S. MEYER  Cristine L. JENNINGS 《Meteoritics & planetary science》1999,34(6):869-884

Abstract— The presence of several short-lived (now extinct) radionuclides in the early solar system demands that they were synthesized and added to preexisting solar system materials shortly (on a time scale on the order of the relevant radionuclide lifetime) before formation of solar system solids. For diverse reasons, it is often suggested that the solar system distributions of these radionuclides were radically heterogeneous, perhaps because of the late addition. Much attention has been given to the astrophysical circumstances that might govern the synthesis and distribution of these short-lived radionuclides, but comparatively little attention has been devoted to the distribution of cosynthesized isotopes. The focus of this paper is a systematic, quantitative evaluation of the collateral consequences in stable and long-lived isotopes that might be expected if short-lived radionuclides, in particular ²⁶Al or ⁵³Mn, were injected at their canonical levels and inhomogeneously distributed in the early solar system. We mix model massive star yields of Meyer et al. (1995) and Woosley and Weaver (1995) into a reservoir of cosmic composition, as tabulated by Anders and Grevesse (1989). To mitigate the effects of systematic deviations that may be present in these mixtures due to uncertainties in model stellar yields, we follow Timmes and Clayton (1996) and also mix into a “renormalized” proxy solar system composition computed from a galactic chemical evolution model based primarily on the stellar yields of Woosley and Weaver (1995). The results are very unfavorable to the likelihood of heterogeneously distributed ²⁶Al derived from supernova ejecta. If a massive star is invoked to account for ²⁶Al, its ejecta must have been rather uniformly distributed, as inferred from the lack of measured collateral anomalies in several elements, notably Ca, Cr, and Ni. Conversely, if ²⁶Al were indeed radically heterogeneously distributed, some other nucleosynthetic source more efficient at producing ²⁶Al is required. In principle, a similar statement applies to ⁵³Mn, but the situation is more complicated. The inferred anomalies at ⁵³Cr will depend not only on how much ⁵³Mn is added by a heterogeneous component, but also more sensitively on the contributions to the associated stable nuclides, ⁵³Cr, ⁵²Cr, and ⁵⁰Cr. Consideration of predicted collateral anomalies provides no direct support for heterogeneously distributed supernova-derived ⁵³Mn, but the required quantity of supernova contribution, and thus also the collateral anomalies, are much less for ⁵³Mn than for ²⁶Al. With allowance for model calculation uncertainties, it could be argued that anomalies collateral to heterogeneous ⁵³Mn might be small enough to have evaded detection.  相似文献   

Baseline Sediment Trace Metals Investigation: Steinhatchee River Estuary, Florida, Northeast Gulf of Mexico     

Candace A. Trimble  Ronald W. Hoenstine  A. Brad Highley  Joseph F. Donoghue  Paul C. Ragland 《Marine Georesources & Geotechnology》1999,17(2):187-197

This Florida Geological Survey U.S. Department of the Interior, Minerals Manage ment Service Cooperative Study provides baseline data for major and trace metal concentrations in the sediments of the Steinhatchee River estuary. These data are intended to provide a benchmark for comparison with future metal concentration data measurements. The Steinhatchee River estuary is a relatively pristine bay located within the Big Bend Wildlife Management Area on the North Central Florida Gulf of Mexico coastline. The river flows 55 km through woodlands and planted pines before emptying into the Gulf at Deadman Harbor. Water quality in the estuary is excellent at present. There is minimal development within the watershed. The estuary is part of an extensive system of marshes that formed along the Florida Gulf coast during the Holocene marine transgression. Sediment accretion rate measurements range from 1.4 to 4.1 mm yr on the basis of lead-210 measurements. Seventy-nine short cores were collected from 66 sample locations, representing four lithofacies: clay- and organic-rich sands, organic-rich sands, clean quartz sands, and oyster bioherms. Samples were analyzed for texture, total organic matter, total carbon, total nitrogen, clay mineralogy, and major and trace-metal content. Follow ing these analyses, metal concentrations were normalized against geochemical reference elements (aluminum and iron) and against total weight percent organic matter. Metals were also normalized granulometrically against total weight percent fines (0.062 mm). Concentrations were determined by inductively coupled plasma atomic emission spectrometry (ICP-AES) for all metals except mercury. Mercury concentrations were determined by cold-flameless atomic absorption spectrometry (AAS). Granulo metric measurements were made by sieve and pipette analyses. Organic matter was determined by two methods: weight loss upon ignition and elemental analysis (by Carlo-Erba Furnace) of carbon and nitrogen. X-ray diffraction was used to deter mine clay mineralogy. Trace-metal concentrations were best correlated when normalized with respect to sediment aluminum concentrations. Normalizations indicate that most major and trace-metal concentrations fall within 95 % prediction limits of the expected value. This finding suggests that little significant metal contamination occurred within this system prior to 1994 sediment sampling. Exceptions include lead, mercury, copper, zinc, potassium, and phosphorous. Lead and mercury are elements that generally enter this watershed through atmospheric deposition; thus, anomalous levels of these metals are not necessarily associated with activities within the watershed of the Steinhatchee River estuary. Anomalous concentrations of other metals such as zinc, copper, and phosphorous probably do originate within the Steinhatchee watershed. Copper failed to correlate well with any geochemical or granulometric normalizer, and this condition was not limited to a single facies or area within the estuary. This finding may indicate copper contamination in the system. Increased zinc and copper levels may be attributed to marine paints. Phosphorous levels also appeared to be elevated in a few locations in the two marsh facies sampled. This may be due to nutrient loading from two small communities, Jena and Steinhatchee, or from the application of this element in fertilizer to reduce moisture stress to young planted pines on tree farms within the watershed.  相似文献   

Water vapor variations in the Venus mesosphere from microwave spectra     

Brad J. Sandor  R. Todd Clancy 《Icarus》2005,177(1):129-143

Mm-wave spectra of HDO in the Venus mesosphere (65-100 km) were obtained over the period March 1998 to June 2004. Each spectrum is a measurement of the hemispheric-average H₂O vapor mixing ratio in the Venus mesosphere. Observations were conducted for wide ranges of Venus solar elongations (46° W to 47° E), and fractional disk illuminations (f=0% to 99%), yielding water vapor abundances on 17 dates and over a full range of local solar time (LST) at the sub-Earth point on Venus. Our mesopheric H₂O values are more numerous and far more precise than the earliest mm-derived H₂O measurements [Encrenaz, Th., Lellouch, E., Paubert, G., Gulkis, S., 1991. First detection of HDO in the atmosphere of Venus at radio wavelengths: An estimate of the H₂O vertical distribution. Astron. Astrophys. 246, L63-L66; Encrenaz, Th., Lellouch, E., Cernicharo, J., Paubert, G., Gulkis, S., Spilker, T., 1995. The thermal profile and water abundance in the Venus mesosphere from H₂O and HDO millimeter observations. Icarus 117, 162-172], allowing an analysis of variability that was previously impossible. Measured 65-100 km H₂O ranged from 0.0±0.06 to 3.5±0.3 ppmv, with significantly different variability than found in previous infrared (lower altitude, cloudtop) studies. Strong global variability on a 1-2 month timescale is clear and unambiguous. A limited number of excellent s/n measurements tentatively indicate the 1-2 month variability manifests most rapidly as change in the lower mesosphere, and more slowly as change in the upper mesosphere. Neither long term (1998-2004) nor diurnal variability in 65-100 km H₂O is evident. While six-year and/or diurnal variabilities are not ruled out, they are weaker than the 1-2 month timescale variation. These conclusions are supported by initial (2004) sub-mm measurements.  相似文献   

UV properties of type Ia supernova and their host galaxies     

Brad E. Tucker 《Astrophysics and Space Science》2011,335(1):223-230

Type Ia Supernova (SN Ia) are a powerful, albeit not completely understood, tool for cosmology. Gaps in our understanding of their progenitors and detailed physics can lead to systematic errors in the cosmological distances they measure. We use UV data in two context to help further our understanding of SN Ia progenitors and physics. We analyze a set of nearly 700 light curves, and find no signature of the shock heating of a red giant companion, predicted by Kasen (Astrophys. J. 708:1025, 2010), casting doubt as to frequency of this SN Ia channel. We also use UV imaging of high redshift host galaxies of SN Ia to better understand the environments which SN Ia occur. We show that some high-z elliptical galaxies have current star formation, hindering efforts to use them as low-extinction environments. We show cosmological scatter of SN distances at large effective radii in their hosts is significantly reduced, and argue this is due to the smaller amounts of dust affecting the SN Ia. Finally, we find a two component dependence of SN distance measurements as a function of their host galaxy’s FUV-V color. This indicates that both the age and metallicity/mass of the host galaxy maybe important ingredients in measuring SN Ia distances.  相似文献   

Channel evolution of Des Moines Lobe till drainage ditches in southern Minnesota (USA)   总被引：1，自引：1，他引：0  

Joe Magner  Brad Hansen  Tim Sundby  Geoff Kramer  Bruce Wilson  John Nieber 《Environmental Earth Sciences》2012,67(8):2359-2369

Some drainage ditches in the intensively managed row-crop agricultural region of southern Minnesota evolved from a trapezoidal form to multi-staged channel forms similar to natural streams. Older ditches constructed in cohesive sediment of the Des Moines Lobe till tend to follow a channel evolution model developed by Simon and Hupp. Site cross sections, longitudinal water and bed profiles and bed material particle size were determined according to Harrelson and others at 24 older ditch reaches, 5 newly constructed ditch reaches and 13 natural stream reaches. Morphological features were hypothesized to change from trapezoidal form to flat bench banks, similar to benches found in natural stream channels. All data were statistically analyzed with respect to drainage area using regression, because channel form is directly related to drainage area for a given climate, geology and land use. Results show similar regression slope and intercept for bankfull channel width and bankfull cross-sectional area (CSA) of older ditches and natural streams compared to typical trapezoidal designed ditches. Evolved ditches developed a small floodplain bench above the ditch bed and adjusted their bankfull widths similar to natural stream channels with respect to drainage area. Old ditches showed a relatively strong R ² (0.82, 0.68) for channel CSA and width, a weaker R ² (0.45) for water surface slope, and little to no correlation with bed particle size. Channel form appears to have adjusted more quickly than bed facets and/or bed particle size distribution. However, stepwise regression determined that D₈₄, width/depth ratio and mean bankfull depth explained 83?% of the variability of channel features across varying drainage areas. Findings suggest a possible reduction of long-term maintenance costs if older ditches are allowed to evolve over time. A stable ditch form similar to natural streams is typically self-sustaining, suggesting that prior to a scheduled clean-out, the ditch should be examined for hydraulic capacity, sediment transport and bank stability.  相似文献   

Reactive Transport Modeling of Subaqueous Sediment Caps and Implications for the Long-Term Fate of Arsenic, Mercury, and Methylmercury   总被引：1，自引：0，他引：1  

Brad A. Bessinger  Dimitri Vlassopoulos  Susana Serrano  Peggy A. O’Day 《Aquatic Geochemistry》2012,18(4):297-326

A 1-D biogeochemical reactive transport model with a full set of equilibrium and kinetic biogeochemical reactions was developed to simulate the fate and transport of arsenic and mercury in subaqueous sediment caps. Model simulations (50?years) were performed for freshwater and estuarine scenarios with an anaerobic porewater and either a diffusion-only or a diffusion plus 0.1-m/year upward advective flux through the cap. A biological habitat layer in the top 0.15?m of the cap was simulated with the addition of organic carbon. For arsenic, the generation of sulfate-reducing conditions limits the formation of iron oxide phases available for adsorption. As a result, subaqueous sediment caps may be relatively ineffective for mitigating contaminant arsenic migration when influent concentrations are high and sorption capacity is insufficient. For mercury, sulfate reduction promotes the precipitation of metacinnabar (HgS) below the habitat layer, and associated fluxes across the sediment–water interface are low. As such, cap thickness is a key design parameter that can be adjusted to control the depth below the sediment–water interface at which mercury sulfide precipitates. The highest dissolved methylmercury concentrations occur in the habitat layer in estuarine environments under conditions of advecting porewater, but the highest sediment concentrations are predicted to occur in freshwater environments due to sorption on sediment organic matter. Site-specific reactive transport simulations are a powerful tool for identifying the major controls on sediment- and porewater-contaminant arsenic and mercury concentrations that result from coupling between physical conditions and biologically mediated chemical reactions.  相似文献   

The Suomi National Polar-orbiting Partnership Satellite ushers in a new era of Earth observations and partnership     

Kamlesh Lulla  M. Duane Nellis  Brad Rundquist 《国际地球制图》2013,28(2)

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