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11.
Speciation of Hg and conversion to methyl-Hg were evaluated in stream sediment, stream water, and aquatic snails collected downstream from the Bonanza Hg mine, Oregon. Total production from the Bonanza mine was >1360 t of Hg, during mining from the late 1800s to 1960, ranking it as an intermediate sized Hg mine on an international scale. The primary objective of this study was to evaluate the distribution, transport, and methylation of Hg downstream from a Hg mine in a coastal temperate climatic zone. Data shown here for methyl-Hg, a neurotoxin hazardous to humans, are the first reported for sediment and water from this area. Stream sediment collected from Foster Creek flowing downstream from the Bonanza mine contained elevated Hg concentrations that ranged from 590 to 71,000 ng/g, all of which (except the most distal sample) exceeded the probable effect concentration (PEC) of 1060 ng/g, the Hg concentration above which harmful effects are likely to be observed in sediment-dwelling organisms. Concentrations of methyl-Hg in stream sediment collected from Foster Creek varied from 11 to 62 ng/g and were highly elevated compared to regional baseline concentrations (0.11–0.82 ng/g) established in this study. Methyl-Hg concentrations in stream sediment collected in this study showed a significant correlation with total organic C (TOC, R2 = 0.62), generally indicating increased methyl-Hg formation with increasing TOC in sediment. Isotopic-tracer methods indicated that several samples of Foster Creek sediment exhibited high rates of Hg-methylation. Concentrations of Hg in water collected downstream from the mine varied from 17 to 270 ng/L and were also elevated compared to baselines, but all were below the 770 ng/L Hg standard recommended by the USEPA to protect against chronic effects to aquatic wildlife. Concentrations of methyl-Hg in the water collected from Foster Creek ranged from 0.17 to 1.8 ng/L, which were elevated compared to regional baseline sites upstream and downstream from the mine that varied from <0.02 to 0.22 ng/L. Aquatic snails collected downstream from the mine were elevated in Hg indicating significant bioavailability and uptake of Hg by these snails. Results for sediment and water indicated significant methyl-Hg formation in the ecosystem downstream from the Bonanza mine, which is enhanced by the temperate climate, high precipitation in the area, and high organic matter.  相似文献   
12.
Mercury concentrations in stomach contents and muscle tissue are reported for five fish species: herring (Clupea harengus), whiting (Merlangius merlangus), roker (Raja clavata), plaice (Pleuronectes platessa) and dab (Limanda limanda) collected in summer 1992 off the mouth of the River Tyne, North East England. Median muscle mercury concentrations in the area increase in the order plaice < herring < roker < dab < whiting. Absolute mercury concentrations and muscle mercury-length relationships indicate that the environmental availability of mercury in the study area is low. Stomach contents were recovered from dab, plaice and roker only. Median mercury concentrations in stomach contents increased in the order plaice < roker < dab. The variability of the ratio (muscle mercury/stomach content mercury) has been examined for these three species. In dab the variation is relatively low (39.7% RSD), whereas in plaice and roker it is considerably higher (128.4% and 184.6%, respectively). If stomach content mercury concentrations accurately reflect local mercury availability then dab muscle tissue would make a more reliable availability index than muscle tissue of plaice or roker.  相似文献   
13.
We have discovered a new type of galaxy in the Fornax Cluster: `ultra-compact' dwarfs (UCDs). The UCDs are unresolved in ground-based imaging and have spectra typical of old stellar systems. Although the UCDs resemble overgrown globular clusters, based on VLT UVES echelle spectroscopy, they appear to be dynamically distinct systems with higher internal velocity dispersions and M/L ratios for a given luminosity than Milky Way or M31 globulars. Our preferred explanation for their origin is that they are the remnant nuclei of dwarf elliptical galaxies which have been tidally stripped, or `threshed' by repeated encounters with the central cluster galaxy, NGC1399. If correct, then tidal stripping of nucleated dwarfs to form UCDs may, over a Hubble time, be an important source of the plentiful globular cluster population in the halo of NGC1399, and, by implication, other cD galaxies. In this picture, the dwarf elliptical halo contents, up to 99% of the original dwarf luminosity, contribute a significant fraction of the populations of intergalactic stars, globulars, and gas in galaxy clusters. This revised version was published online in July 2006 with corrections to the Cover Date.  相似文献   
14.
The Kwakshua Watersheds Observatory (KWO) is an integrative watersheds observatory on the coastal margin of a rain-dominated bog-forest landscape in British Columbia (BC), Canada. Established in 2013, the goal of the KWO is to understand and model the flux of terrestrial materials from land to sea – the origins, pathways, processes and ecosystem consequences – in the context of long-term environmental change. The KWO consists of seven gauged watersheds and a network of observation sites spanning from land to sea and along drainage gradients within catchments. Time-series datasets include year-round measurements of weather, soil hydrology, streamflow, aquatic biogeochemistry, microbial ecology and nearshore oceanographic conditions. Sensor measurements are recorded every 5 min and water samples are collected approximately monthly. Additional observations are made during high-flow conditions. We used remote sensing to map watershed terrain, drainage networks, soils and terrestrial ecosystems. The watersheds range in size from 3.2 to 12.8 km2, with varying catchment characteristics that influence hydrological and biogeochemical responses. Despite local variation, the overall study area is a global hotspot for yields of dissolved organic carbon, dissolved organic nitrogen and dissolved iron at the coastal margin. This observatory helps fill an important gap in the global network of observatories, in terms of spatial location (central coast of BC), climate (temperate oceanic), hydrology (very high runoff, pluvial regime), geology (igneous intrusive, glacially scoured), vegetation (bog rainforest) and soils (large stores of organic carbon).  相似文献   
15.
Carbonate flat‐pebble conglomerate is an important component of Precambrian to lower Palaeozoic strata, but its origins remain enigmatic. The Upper Cambrian to Lower Ordovician strata of the Snowy Range Formation in northern Wyoming and southern Montana contain abundant flat‐pebble conglomerate beds in shallow‐water cyclic and non‐cyclic strata. Several origins of flat‐pebble conglomerate are inferred for these strata. In one case, all stages of development of flat‐pebble conglomerate are captured within storm‐dominated shoreface deposits of hummocky cross‐stratified (HCS) fine carbonate grainstone. A variety of synsedimentary deformation structures records the transition from mildly deformed in situ stratification to buckled beds of partially disarticulated bedding to fully developed flat‐pebble conglomerate. These features resulted from failure of a shoreface and subsequent brittle and ductile deformation of compacted to early cemented deposits. Failure was induced by either storm or seismic waves, and many beds failed along discrete slide scar surfaces. Centimetre‐scale laminae within thick amalgamated HCS beds were planes of weakness that led to the development of platy clasts within partly disarticulated and rotated bedding of the buckled beds. In some cases, buckled masses accelerated downslope until they exceeded their internal friction, completely disarticulated into clasts and transformed into a mass flow of individual cm‐ to dm‐scale clasts. This transition was accompanied by the addition of sand‐sized echinoderm‐rich debris from local sources, which slightly lowered friction by reducing clast–clast interactions. The resulting dominantly horizontal clast orientations suggest transport by dense, viscous flow dominated by laminar shear. These flows generally came to rest on the lower shoreface, although in some cases they continued a limited distance beyond fairweather wave base and were interbedded with shale and grainstone beds. The clasts in these beds show no evidence of extensive reworking (i.e. not well rounded) or condensation (i.e. no rinds or coatings). A second type of flat‐pebble conglomerate bed occurs at the top of upward‐coarsening, metre‐scale cycles. The flat‐pebble conglomerate beds cap these shoaling cycles and represent either lowstand deposits or, in some cases, may represent transgressive lags. The clasts are well rounded, display borings and have iron‐rich coatings. The matrix to these beds locally includes glauconite. These beds were considerably reworked and represent condensed deposits. Thrombolites occur above the flat‐pebble beds and record microbial growth before initial transgression at the cycle boundaries. A third type of flat‐pebble conglomerate bed occurs within unusual metre‐scale, shale‐dominated, asymmetric, subaqueous cycles in Shoshone Canyon, Wyoming. Flat‐pebble beds in these cycles consist solely of clasts of carbonate nodules identical to those that are in situ within underlying shale beds. These deeper water cycles can be interpreted as either upward‐shoaling or ‐deepening cycles. The flat‐pebble conglomerate beds record winnowing and reworking of shale and carbonate nodules to lags, during either lowstand or the first stages of transgression.  相似文献   
16.
Moraines that dam proglacial lakes pose an increasing hazard to communities in the Andes and other mountain ranges. The moraines are prone to failure through collapse, overtopping by lake waters or the effect of displacement waves resulting from ice and rock avalanches. Resulting floods have led to the loss of thousands of lives in the Cordillera Blanca mountains of Peru alone in the last 100 years. On 22 April 2002 a rock avalanche occurred immediately to the south‐west of Laguna Safuna Alta, in the Cordillera Blanca. The geomorphic evidence for the nature, magnitude and consequences of this event was investigated in August 2002. Field mapping indicated that the avalanche deposited 8–20 × 106 m3 of rock into the lake and onto the surface of the frontal region of Glaciar Pucajirca, which flows into the lake. Repeated bathymetric surveying indicated that ~5 × 106 m3 of this material was deposited directly into the lake. The immediate effect of this event was to create a displacement wave that gained in height as it travelled along the lake basin, overtopping the impounding moraine at the lake's northern end. To achieve overtopping, the maximum wave height must have been greater than 100 m. This, and subsequent seiche waves, caused extensive erosion of both the proximal and distal faces of the impounding terminal moraine. Further deep gullying of the distal face of this moraine resulted from the supply of pressurized water to the face via a relief overflow tunnel constructed in 1978. Two‐dimensional, steady‐state analysis of the stability of the post‐avalanche moraine rampart indicates that its proximal face remains susceptible to major large‐scale rotational failure. Copyright © 2005 John Wiley & Sons, Ltd.  相似文献   
17.
Geotechnical and Geological Engineering - Clean drinking water is a necessity and recycling stormwater and greywater has been more appealing in the recent decades to provide filtered water for...  相似文献   
18.
19.
14C AMS-dated gravity cores reveal that the Trænadjupet Slide offshore Norway occurred about 4,000 14C years B.P. (ca. 4,000 cal. years ago). From 4,000 to 3,000 years B.P., minor areas of the newly formed slide scar were probably eroded, the result of smaller episodes of mass wasting caused by delayed collapse of part of the western, upper sidewall or by bottom currents. From about 3,000 years B.P. to the present, sediments were derived from alongslope-flowing, north-eastward-oriented ocean currents carrying sediments in suspension. These results demonstrate that large-scale mass wasting during sea-level highstand is rather common on passive continental margins.  相似文献   
20.
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