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81.
Measurements of  Δ14C  in atmospheric CO2 are an effective method of separating CO2 additions from fossil fuel and biospheric sources or sinks of CO2. We illustrate this technique with vertical profiles of CO2 and  Δ14C  analysed in whole air flask samples collected above Colorado, USA in May and July 2004. Comparison of lower tropospheric composition to cleaner air at higher altitudes (>5 km) revealed considerable additions from respiration in the morning in both urban and rural locations. Afternoon concentrations were mainly governed by fossil fuel emissions and boundary layer depth, also showing net biospheric CO2 uptake in some cases. We estimate local industrial CO2:CO emission ratios using in situ measurements of CO concentration. Ratios are found to vary by 100% and average 57 mole CO2:1 mole CO, higher than expected from emissions inventories. Uncertainty in CO2 from different sources was ±1.1 to ±4.1 ppm for addition or uptake of −4.6 to 55.8 ppm, limited by  Δ14C  measurement precision and uncertainty in background  Δ14C  and CO2 levels.  相似文献   
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In three excavations in the southern Netherlands and northern Belgium, the Weichselian convolutions in fine sand, silt and clay deposits were investigated, and an attempt was made towards a semi-quantitative approach to some sediment parameters. This, together with a detailed field survey, enabled interpretation of the deformations as forms of periglacial loadcasting. They originated from the time of permafrost degradation when large quantites of water were available. The amplitude of the involutions can be related to the depth of the permafrost table at that time. During the weichselian, two periods occurred in which this involution process could have been active  相似文献   
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Debris in basal ice produced by glaciohydraulic supercooling is typically characterized by high proportions of silt. A prominent hypothesis for this silt‐dominance is that frazil ice growing in supercooled water preferentially traps silt from sediment‐laden water percolating through it. It has therefore been suggested that silt‐dominance may be diagnostic of glaciohydraulic supercooling. The aim of our work is to test this hypothesis that freezing sediment‐laden supercooled water necessarily produces ice dominated by silt. We do this by simulating two freezing processes under laboratory conditions: (1) percolation of sediment‐laden water through frazil ice; (2) turbulent supercooling and subsequent freezing of sediment‐laden water. In experiments repeated using different particle sizes (sand, silt and clay in individual experiments) both processes entrained sand most effectively and silt least effectively. In experiments using a sediment mixture dominated by medium to coarse silt, both processes produced ice facies dominated by particle sizes between fine sand and coarse silt. These results suggest that silt‐dominance should therefore not be expected for supercooled freeze‐on, and is not a reliable diagnostic signature for supercooling. The silt‐dominated character of basal ice types associated with supercooling may result from other controls such as a silt‐dominated sediment supply or subglacial water flow rates, rather than the freezing process.  相似文献   
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We have characterized the relative contributions to uncertainty in predictions of global warming amount by year 2100 in the C4MIP model ensemble ( Friedlingstein et al., 2006 ) due to both carbon cycle process uncertainty and uncertainty in the physical climate properties of the Earth system. We find carbon cycle uncertainty to be important. On average the spread in transient climate response is around 40% of that due to the more frequently debated uncertainties in equilibrium climate sensitivity and global heat capacity.
This result is derived by characterizing the influence of different parameters in a global climate-carbon cycle 'box' model that has been calibrated against the 11 General Circulation models (GCMs) and Earth system Models of Intermediate Complexity (EMICs) in the C4MIP ensemble; a collection of current state-of-the-art climate models that include an explicit representation of the global carbon cycle.  相似文献   
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In this issue, Ramonet et al. revealed a positive trend in European, atmospheric CO2 concentrations relative to a marine, North Atlantic reference baseline, for the years 2001–2006. The observed build up mainly occurred during the cold season where it reaches a 0.8 ppm yr−1 at low-altitude stations to a 0.3 ppm yr−1 at mid-altitude stations. We explore the cause of this build-up using the mesoscale model CHIMERE. We first model the observed trends, using interannually varying fluxes and transport, then suppress the interannual variability in fluxes or aspects of transport to elucidate the cause. The run with no interannual variability in fluxes still matches observed trends suggesting that transport is the major cause. Separate runs varying either boundary layer height or winds show that changes in boundary layer height explain the trends at low-altitude stations within the continents while changes in wind regimes drive changes elsewhere.  相似文献   
90.
This paper uses a refined soil gradient method to estimate soil CO2 efflux. Six different models are used to determine the relative gas diffusion coefficient (ξ). A weighted harmonic averaging is used to estimate the soil CO2 diffusion coefficient, yielding a better estimate of soil CO2 efflux. The resulting soil CO2 efflux results are then compared to the soil CO2 efflux measured with a soil chamber. Depending on the choice of ξ model used, the estimated soil CO2 efflux using the gradient method reasonably approximates the efflux obtained using the soil chamber method. In addition, the estimated soil CO2 efflux obtained by this improved method is well described by an exponential function of soil temperature at a depth of 0.05 m with the temperature sensitivity ( Q 10) of 1.81 and a linear function of soil moisture at a depth of 0.12 m, in general agreement with previous findings. These results suggest that the gradient method is a practical cost-effective means to measure soil CO2 emissions. Results from the present study suggest that the gradient method can be used successfully to measure soil CO2 efflux provided that proper attention is paid to the judicious use of the proper diffusion coefficient.  相似文献   
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