Optical properties of a vertically inhomogeneous mid-latitude mid-level mixed-phase altocumulus in the infrared region   总被引：1，自引：0，他引：1  

Jianguo Niu  Lawrence D. Carey  Ping Yang  Thomas H. Vonder Haar   《Atmospheric Research》2008,88(3-4):234-242

A vertically inhomogeneous mid-latitude mixed-phase altocumulus cloud was observed around 17:26 UTC on Oct. 14, 2001 during the 9th Cloud Layer Experiment (CLEX9). In this study the microphysical and optical properties of this cloud are investigated on the basis of in-situ observed vertical profiles of particle size and habit distributions. Two cloud models, assuming that the cloud properties were vertically homogeneous and inhomogeneous, are adopted to derive the bulk optical and radiative properties of this cloud. The observed microphysical properties are combined with the theoretical solutions to the scattering and absorption properties of individual cloud particles to determine the bulk optical properties at various heights within the cloud layer. The single-scattering properties of spherical liquid water droplets and nonspherical ice crystals are obtained from the Lorenz–Mie theory and an existing database, respectively. The bulk microphysical and optical properties associated with the inhomogeneous model depend strongly on the height above the cloud-base whereas the dependence is smoothed out in the case of the homogeneous model. Furthermore, the transfer of infrared radiation is simulated in conjunction with the two cloud models. It is shown that the brightness temperatures at the top of the atmosphere in the case of the homogeneous model can be 1.5% (3.8 K) higher than their counterpart associated with the inhomogeneous cloud model. This result demonstrates that the effect of the vertical inhomogeneity of a mixed-phase cloud on its radiative properties is not negligible.  相似文献   

Towards constraining climate sensitivity by linear analysis of feedback patterns in thousands of perturbed-physics GCM simulations   总被引：2，自引：1，他引：1  

Benjamin M. Sanderson  C. Piani  W. J. Ingram  D. A. Stone  M. R. Allen 《Climate Dynamics》2008,30(2-3):175-190

A linear analysis is applied to a multi-thousand member “perturbed physics" GCM ensemble to identify the dominant physical processes responsible for variation in climate sensitivity across the ensemble. Model simulations are provided by the distributed computing project, climate prediction.net . A principal component analysis of model radiative response reveals two dominant independent feedback processes, each largely controlled by a single parameter change. The leading EOF was well correlated with the value of the entrainment coefficient—a parameter in the model’s atmospheric convection scheme. Reducing this parameter increases high vertical level moisture causing an enhanced clear sky greenhouse effect both in the control simulation and in the response to greenhouse gas forcing. This effect is compensated by an increase in reflected solar radiation from low level cloud upon warming. A set of ‘secondary’ cloud formation parameters partly modulate the degree of shortwave compensation from low cloud formation. The second EOF was correlated with the scaling of ice fall speed in clouds which affects the extent of cloud cover in the control simulation. The most prominent feature in the EOF was an increase in longwave cloud forcing. The two leading EOFs account for 70% of the ensemble variance in λ—the global feedback parameter. Linear predictors of feedback strength from model climatology are applied to observational datasets to estimate real world values of the overall climate feedback parameter. The predictors are found using correlations across the ensemble. Differences between predictions are largely due to the differences in observational estimates for top of atmosphere shortwave fluxes. Our validation does not rule out all the strong tropical convective feedbacks leading to a large climate sensitivity.  相似文献   

Attribution of twentieth century temperature change to natural and anthropogenic causes   总被引：6，自引：0，他引：6  

P. A. Stott  S. F. B. Tett  G. S. Jones  M. R. Allen  W. J. Ingram  J. F. B. Mitchell 《Climate Dynamics》2001,17(1):1-21

  We analyse possible causes of twentieth century near-surface temperature change. We use an “optimal detection” methodology to compare seasonal and annual data from the coupled atmosphere-ocean general circulation model HadCM2 with observations averaged over a range of spatial and temporal scales. The results indicate that the increases in temperature observed in the latter half of the century have been caused by warming from anthropogenic increases in greenhouse gases offset by cooling from tropospheric sulfate aerosols rather than natural variability, either internal or externally forced. We also find that greenhouse gases are likely to have contributed significantly to the warming in the first half of the century. In addition, natural effects may have contributed to this warming. Assuming one particular reconstruction of total solar irradiance to be correct implies, when we take the seasonal cycle into account, that solar effects have contributed significantly to the warming observed in the early part of the century, regardless of any relative error in the amplitudes of the anthropogenic forcings prescribed in the model. However, this is not the case with an alternative reconstruction of total solar irradiance, based more on the amplitude than the length of the solar cycle. We also find evidence for volcanic influences on twentieth century near-surface temperatures. The signature of the eruption of Mount Pinatubo is detected using annual-mean data. We also find evidence for a volcanic influence on warming in the first half of the century associated with a reduction in mid-century volcanism. Received: 24 January 2000 / Accepted: 20 April 2000  相似文献   

Experimental constraints on pre-eruptive water contents and changing magma storage prior to explosive eruptions of Mount St Helens volcano   总被引：2，自引：0，他引：2  

J. E. Gardner  M. Rutherford  S. Carey  H. Sigurdsson 《Bulletin of Volcanology》1995,57(1):1-17

Compositionally diverse dacitic magmas have erupted from Mount St Helens over the last 4000 years. Phase assemblages and their compositions in these dacites provide information about the composition of the pre-eruptive melt, the phases in equilibrium with that melt and the magmatic temperature. From this information pre-eruptive pressures and water fugacities of many of the dacites have been inferred. This was done by conducting hydrothermal experiments at 850°C and a range of pressures and water fugacities and combining the results with those from experiments at temperatures of 780 and 920°C, to cover the likely range in equilibration conditions of the dacites. Natural phase assemblages and compositions were compared with the experimental results to infer the most likely conditions for the magmas prior to eruption. Water contents disolved in the melts of the dacites were then estimated from the inferred conditions. Water contents in the dacites have varied greatly, from 3.7 to 6.5 wt.%, in the last 4000 years. Between 4000 and about 3000 years ago the dacites tended to be water saturated and contained 5.5 to 6.5 wt.% water. Since then, however, the dacites have been significantly water-undersaturated and contained less than 5.0 wt.% water. These dacites have tended to be hotter and more mafic, and andesitic and basaltic magmas have erupted. These changes can be explained by variable amounts of mixing between felsic dacite and basalt, to produce hotter, drier and more mafic dacites and andesites. The magma storage region of the dacitic magmas has also varied significantly during the 4000 years, with shifts to shallower levels in the crust occurring within very short time periods, possibly even two years. These shifts may be related to fracturing of overlying roof rock as a result of magma with-drawal during larger volume eruptions.  相似文献   

Petrologic diversity in Mount St. Helens dacites during the last 4,000 years: implications for magma mixing     

James E. Gardner  Steve Carey  Malcolm J. Rutherford  Haraldur Sigurdsson 《Contributions to Mineralogy and Petrology》1995,119(2-3):224-238

Mount St. Helens has explosively erupted dacitic magma discontinuously over the last 40,000 years, and detailed stratigraphic data are available for the past 4,000 years. During this last time period the major-element composition of the dacites has ranged from mafic (62–64 wt% SiO₂) to felsic (65–67 wt% SiO₂), temperature has varied by about 150°C (770°–920°C), and crystallinity has ranged between 20% and 55%. Water content of these dacites has also fluctuated greatly. Although the source for the dacitic magmas is probably partial melting of lower crustal rocks, there is strong physical evidence, such as banded pumices, thermal heterogeneities in single pumices, phenocryst disequilibrium, contrasts between compositions of glass inclusions and host matrix glass, and amphibole reaction rims, that suggests that magma mixing has been prominent in the dacitic reservoir. Indeed, we suggest that the variations in major- and trace-element abundances in Mount St. Helens dacites indicate that magma mixing between felsic dacite and mafic magma has controlled the petrologic diversity of the dacitic magmas. Magma mixing has also controlled the composition of andesites erupted at Mount St. Helens, and thus it appears that the continuum of magmatic composition erupted at the volcano is controlled by mixing between felsic dacite, or possibly rhyodacite, and basalt. The flux of the felsic endmember to the reservior appears to have been relatively constant, whereas the flux of basalt may have increased in the past 4,000 years, as suggested by the apparently increased abundance of mafic dacite and andesite erupted in this period.  相似文献   

The heat capacity of hydrous cordierite above 295 K     

J. William Carey 《Physics and Chemistry of Minerals》1993,19(8):578-583

The heat capacity of synthetic hydrous cordierite (Mg₂Al₄Si₅O₁₈·nH₂O) has been determined by differential scanning calorimetry (DSC) from 295 to 425 K as a function of H₂O content. Six samples with H₂O contents ranging from 0 to 0.82 per formula unit were examined. The partial molar heat capacity of H₂O in cordierite over the measured temperature interval is independent of composition and temperature within experimental uncertainty and is equal to 43.3 ±0.8 J/mol/ K. This value exceeds the molar heat capacity of gaseous H₂O by 9.7 J/mol/K, but is significantly smaller than the heat capacity of H₂O in several zeolites and liquid H₂O. A statistical-mechanical model of the heat capacity of adsorbed gas species (Barrer 1978) is used to extrapolate the heat capacity of hydrous cordierite to temperatures greater than 425 K. In this model, the heat capacity of hydrous cordierite (Crd·nH₂O) is represented as follows: Cp(Crd · nH₂O) = Cp(Crd)+ n{Cp(H₂O, gas)+ R(gas constant)} (1) An examination of calorimetric data for hydrous beryl, analcime, mordenite, and clinoptilolite (Hemingway et al. 1986; Johnson et al. 1982, 1991, 1992) demonstrates the general applicability of the statistical-mechanical model for the extrapolation of heat capacity data of zeolitic minerals. The heat capacity data for cordierite are combined with the data of Carey and Navrotsky (1992) to obtain the molar enthalpy of formation and enthalpy of hydration of hydrous cordierite as a function of temperature.  相似文献   

Electron microprobe correlation of tephra layers from Eastern Mediterranean abyssal sediments and the Island of Santorini     

Alan N. Federman  Steven N. Carey 《Quaternary Research》1980,13(2):160-171

Five widespread tephra layers are found in late Quaternary sediments (0–130,000 yr B.P.) of the Eastern Mediterranean Sea. These layers have been correlated among abyssal cores and to their respective terrestrial sources by electron-probe microanalysis of glass and pumice shards. Major element variations are sufficient to discriminate unambiguously between the five major layers. Oxygen isotope stratigraphy in one of the cores studied was used to data four of the five layers. Two of the widespread layers are derived from explosive eruptions of the Santorini volcanic complex: the Minoan Ash (3370 yr B.P.) and the Acrotiri Ignimbrite (18,000 yr B.P.). An additional layer, found in one core only, is most likely correlated to the Middle Pumice Series of Santorini (approximately 100,000 yr B.P.). Two layers are correlated to deposits on the islands of Yali and Kos and date to 31,000 and 120,000 yr B.P., respectively. One layer originated from the Neapolitan area of Italy 38,000 yr B.P.  相似文献   

Sedimentology of the Krakatau 1883 submarine pyroclastic deposits     

C. W. Mandeville  S. Carey  H. Sigurdsson 《Bulletin of Volcanology》1996,57(7):512-529

The majority of tephra generated during the paroxysmal 1883 eruption of Krakatau volcano, Indonesia, was deposited in the sea within a 15-km radius of the caldera. Two syneruptive pyroclastic facies have been recovered in SCUBA cores which sampled the 1883 subaqueous pyroclastic deposit. The most commonly recovered facies is a massive textured, poorly sorted mixture of pumice and lithic lapilli-to-block-sized fragments set in a silty to sandy ash matrix. This facies is indistinguishable from the 1883 subaerial pyroclastic flow deposits preserved on the Krakatau islands on the basis of grain size and component abundances. A less common facies consists of well-sorted, planarlaminated to low-angle cross-bedded, vitric-enriched silty ash. Entrance of subaerial pyroclastic flows into the sea resulted in subaqueous deposition of the massive facies primarily by deceleration and sinking of highly concentrated, deflated components of pyroclastic flows as they traveled over water. The basal component of the deposit suggests no mixing with seawater as inferred from retention of the fine ash fraction, high temperature of emplacement, and lack of traction structures, and no significant hydraulic sorting of components. The laminated facies was most likely deposited from low-concentration pyroclastic density currents generated by shear along the boundary between the submarine pyroclastic flows and seawater. The Krakatau deposits are the first well-documented example of true submarine pyroclastic flow deposition from a modern eruption, and thus constitute an important analog for the interpretation of ancient sequences where subaqueous deposition has been inferred based on the facies characteristics of encapsulating sedimentary sequences.  相似文献   

The intensity of plinian eruptions   总被引：1，自引：2，他引：1  

Steven Carey  Haraldur Sigurdsson 《Bulletin of Volcanology》1989,51(1):28-40

Peak intensities (magma discharge rate) of 45 Pleistocene and Holocene plinian eruptions have been inferred from lithic dispersal patterns by using a theoretical model of pyroclast fallout from eruption columns. Values range over three orders of magnitude from 1.6 × 10⁶ to 1.1 × 10⁹ kg/s. Magnitudes (total erupted mass) also vary over about three orders of magnitude from 2.0 × 10¹¹ to 6.8 × 10¹⁴ kg and include several large ignimbrite-forming events with associated caldera formation. Intensity is found to be positively correlated with the magnitude when total erupted mass (tephra fall, surges and pyroclastic flows) is considered. Initial plinian fall phases with intensities in excess of 2.0 × 10⁸ kg/s typically herald the onset of major pyroclastic flow generation and subsequent caldera collapse. During eruptions of large magnitude, the transition to pyroclastic flows is likely to be the result of high intensity, whereas the generation of pyroclastic flows in small magnitude eruptions may occur more often by reduction of magmatic volatile content or some transient change in magma properties. The correlation between plinian fall intensity and total magnitude suggests that the rate of magma discharge is related to the size of the chamber being tapped. A simple model is presented to account for the variation in intensity by progressive enlargement of conduits and vents and excess pressure at the chamber roof caused by buoyant forces acting on the chamber as it resides in the crust. Both processes are fundamentally linked to the absolute size of the pre-eruption reservoir. The data suggest that sustained eruption column heights (i.e. magma discharge rates) are indicators of eventual eruption magnitude, and perhaps eruptive style, and thus are key parameters to monitor in order to assess the temporal evolution of plinian eruptions.  相似文献   

Plutonium oxidation state distributions in the Pacific Ocean during 1980–1981     

Donald M. Nelson  Anne E. Carey  Vaughan T. Bowen 《Earth and Planetary Science Letters》1984,68(3):422-430

The concentration of plutonium and its oxidation state distribution have been measured as a function of depth at three locations in the North Pacific Ocean. Concentration profiles were similar to those observed in the same area during 1974 with primary maxima at depths of a few hundred meters below the surface and secondary maxima near the bottom. Oxidation state distribution profiles were similar at the three locations with plutonium about equally divided between the reduced and oxidized forms except near the bottom. There the oxidized form was more abundant and comprised ～ 90% of the total plutonium. No major change in oxidation state occurred at the depths of the shallow concentration maxima suggesting that their formation and persistence were not dependent upon a redox change. The concentration maxima near the bottom coincided with the enhanced abundance of the poorly sorbed oxidized form suggesting that they resulted from the loss of oxidized plutonium from the sediments.  相似文献