Diffusion and partition coefficients of minor and trace elements in San Carlos olivine at 1,300°C with some geochemical implications     

Carl Spandler  Hugh St.C. O’Neill 《Contributions to Mineralogy and Petrology》2010,159(6):791-818

Lattice diffusion coefficients have been determined for 19 elements (Li, Be, Na, Ca, Sc, Ti, V, Cr, Mn, Fe, Co, Ni, Zn, Y, Zr, Eu, Gd, Lu and Hf) in a single crystal of San Carlos olivine as a function of crystallographic orientation, at 1,300°C, 1 bar and fO₂ = 10^−8.3 bars, by equilibration with a synthetic silicate melt. Results for Li, Na, V, Cr, Fe and Zn are from diffusion of these elements out of the olivine, starting from their indigenous concentrations; those for all other elements are from diffusion into the olivine, from the silicate melt reservoir. Our 25-day experiment produced diffusion profiles 50 to > 700 μm in length, which are sufficiently long that precise analyses could be achieved by scanning laser ablation inductively coupled plasma mass spectrometry, even at concentration levels well below 1 μg g⁻¹. For the divalent cations Ca, Mn, Fe and Ni, profiles were also obtained by electron microprobe analysis. The results of the two methods agree well with each other, and are consistent with divalent cation diffusion coefficients previously determined using different experimental methodologies. Olivine/melt partition coefficients retrieved from the data are also consistent with other published partitioning data, indicating that element incorporation and transport in olivine in our experiment occurred via mechanisms appropriate to natural conditions. Most of the examined trace elements diffuse through olivine at similar rates to the major octahedral cations Fe and Mg, showing that cation charge and radius have little direct influence on diffusion rates. Aluminium and P remain low and constant in the olivine, implying negligible transport at our analytical scale, hence Al and P diffusion rates that are at least two orders of magnitude slower than the other cations studied here. All determined element diffusivities are anisotropic, with diffusion fastest along the [001] axis, except Y and the REEs, which diffuse isotropically. The results suggest that element diffusivity in olivine is largely controlled by cation site preference, charge balance mechanisms and point-defect concentrations. Elements that are present on multiple cation sites in olivine (e.g. Be and Ti) and trivalent elements that are charge-balanced by octahedral site vacancies tend to diffuse at relatively fast rates.  相似文献   

阿尔金索尔库里地区元古代流纹岩锆石SHRIMP U-Pb定年及其地质意义   总被引：2，自引：1，他引：1  

张志诚  郭召杰  冯志硕  李建锋 《岩石学报》2010,26(2):597-606

阿尔金索尔库里北山彩虹沟塔什达坂群卓阿布拉克组流纹岩锆石SHRIMP U-Pb 年龄为920±20Ma (MSWD=1.50),代表流纹岩的喷出时间。岩石的SiO₂介于68.33%~70.60%,K₂O>Na₂O,K₂O/Na₂O平均值6.42,属弱过铝质(ACNK平均为1.25)钙碱性系列(σ平均为2.76),为一套典型的壳源流纹岩岩石系列。稀土元素含量高(平均为211.3×10^-6),轻稀土富集(L/H平均为6.57),Eu亏损中等(δEu平均为0.30)。微量元素以富集Rb、Th、K、Zr,而相对亏损Ba、Sr、Eu、Ti、Nb、Ta为特征。岩石微量及稀土元素具有典型的板内火山岩特征,而岩石显著的低Sr特征(25.0×10^-6~65.3×10^-6,平均值为36.8×10^-6))表明其并非源自加厚的地壳,而是起源于斜长石稳定的正常地壳。阿尔金流纹岩是由进入上地壳高位岩浆房的拉斑玄武岩浆的底侵作用直接使上地壳部分熔融,形成酸性火山岩的原始岩浆。该岩浆体系沿区域断裂构造体系上升,并经历了较强的结晶分异和演化,最终形成阿尔金索尔库里北山流纹岩系列。  相似文献   

40Ar/39Ar ages of L4, H5, EL6, and feldspathic ureilitic clasts from the Almahata Sitta polymict ureilite (asteroid 2008 TC3)     

Brent D. Turrin  Fara Lindsay  Jeremy S. Delaney  Jisun Park  Gregory F. Herzog  Carl Swisher Jr  Cyrena A. Goodrich 《Meteoritics & planetary science》2023,58(3):304-327

The Almahata Sitta (AhS) meteorite consists of disaggregated clasts from the impact of the polymict asteroid 2008 TC₃, including ureilitic (70%–80%) and diverse non-ureilitic materials. We determined the ⁴⁰Ar/³⁹Ar release patterns for 16 AhS samples (3–1500 μg) taken from three chondritic clasts, AhS 100 (L4), AhS 25 (H5), and MS-D (EL6), as well as a clast of ureilitic trachyandesite MS-MU-011, also known as ALM-A, which is probably a sample of the crust of the ureilite parent body (UPB). Based on our analyses, best estimates of the ⁴⁰Ar/³⁹Ar ages (Ma) of the chondritic clasts are 4535 ± 10 (L4), 4537–4555 with a younger age preferred (H5), and 4513 ± 17 (EL6). The ages for the L4 and the H5 clasts are older than the most published ⁴⁰Ar/³⁹Ar ages for L4 and H5 meteorites, respectively. The age for the EL6 clast is typical of older EL6 chondrites. These ages indicate times of argon closure ranging up to 50 Ma after the main constituents of the host breccia, that is, the ureilitic components of AhS, reached the >800°C blocking temperatures of pyroxene and olivine thermometers. We suggest that these ages record the times at which the clasts cooled to the Ar closure temperatures on their respective parent bodies. This interpretation is consistent with the recent proposal that the majority of xenolithic materials in polymict ureilites were implanted into regolith 40–60 Ma after calcium–aluminum-rich inclusion and is consistent with the interpretation that 2008 TC₃ was a polymict ureilite. With allowance for its 10-Ma uncertainty, the 4549-Ma ⁴⁰Ar/³⁹Ar age of ALM-A is consistent with closure within a few Ma of the time recorded by its Pb/Pb age either on the UPB or as part of a rapidly cooling fragment. Plots of age versus cumulative ³⁹Ar release for 10 of 15 samples with ≥5 heating steps indicate minor losses of ⁴⁰Ar over the last 4.5 Ga. The other five such samples lost some ⁴⁰Ar at estimated times no earlier than 3800–4500 Ma bp . Clustering of ages in the low-temperature data for these five samples suggests that an impact caused localized heating of the AhS progenitor ~2.7 Ga ago. In agreement with the published work, 10 estimates of cosmic-ray exposure ages based on ³⁸Ar concentrations average 17 ± 5 Ma but may include some early irradiation.  相似文献