Laboratory Kinetic Studies of the Reactions of Cl Atoms with Species of Biogenic Origin: δ3-Carene, Isoprene, Methacrolein and Methyl Vinyl Ketone     

Carlos E. Canosa-Mas  Hilary R. Hutton-Squire  Martin D. King  David J. Stewart  Katherine C. Thompson  Richard P. Wayne 《Journal of Atmospheric Chemistry》1999,34(1):163-170

The rate coefficients for the reaction between atomic chlorine and a number of naturally occurring species have been measured at ambient temperature and atmospheric pressure using the relative rate technique. The values obtained were (4.0 ± 0.8) × 10^-10, (2.1 ± 0.5) × 10^-10, (3.2 ± 0.5) × 10^-10, and (4.9 ± 0.5) × 10^-10 cm³ molecule^-1 s^-1, for reactions with isoprene, methyl vinyl ketone, methacrolein and ³-carene, respectively. The value obtained for isoprene compares favourably with previously reported values. No values have been reported to date for the rate constants of the other reactions.  相似文献   

An old old friend revisited     

Carlos L. Aiken  John R. Sturgul 《Mathematical Geosciences》1971,3(4):381-381

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Construction of a high-resolution gridded rainfall dataset for Peru from 1981 to the present day     

Cesar Aybar  Carlos Fernández  Adrian Huerta  Waldo Lavado  Fiorella Vega  Oscar Felipe-Obando 《水文科学杂志》2020,65(5):770-785

ABSTRACT

A new gridded rainfall dataset available for Peru is introduced, called PISCOp V2.1 (Peruvian Interpolated data of SENAMHI’s Climatological and Hydrological Observations). PISCOp has been developed for the period 1981 to the present, with an average latency of eight weeks at 0.1° spatial resolution. The merging algorithm is based on geostatistical and deterministic interpolation methods including three different rainfall sources: (i) the national quality-controlled and infilled raingauge dataset, (ii) radar-gauge merged precipitation climatologies and (iii) the Climate Hazards Group Infrared Precipitation (CHIRP) estimates. The validation results suggest that precipitation estimates are acceptable showing the highest performance for the Pacific coast and the western flank of the Andes. Furthermore, a meticulous quality-control and gap-infilling procedure allowed us to reduce the formation of inhomogeneities (non-climatic breaks). The dataset is publicly available at https://piscoprec.github.io/ and is intended to support hydrological studies and water management practices.  相似文献   

Metamorphic rocks of the Araya Peninsula,Eastern Venezuela     

Dr. Carlos Schubert 《International Journal of Earth Sciences》1971,60(4):1571-1600

Two grades of metamorphism, both subfacies of the greenschist facies of regional metamorphism, were mapped on the Araya Peninsula: 1. the quartzalbite-epidote-almandine subfacies, consisting mainly of a sequence of garnet and kyanite quartz-mica schists, interlayered with quartzites; and 2. the quartzalbite-muscovite-chlorite subfacies, which consists of chloritic phyllites, quartzmica schists and phyllites, metaconglomerates, calcareous quartz-mica schists, limestones and marbles, and calcareous epidote schists of volcanic origin. The two subfacies are separated by faults. The probable age of these rocks ranges from Triassic(?)-Jurassic to Lower and Middle Cretaceous. Serpentinites intrude rocks of the lower metamorphic grade, and are interpreted as tectonically emplaced. The foliation of these rocks is highly folded by mesoscopic folds, whose axes trend east-northeast and which are overturned to the south-southeast. Lineations parallel to the fold axes and thrusting to the south-southeast are common. These structures reflect a macroscopic structure of antiforms and synforms, all affected by a dominant north-northwest to south-southeast tectonic transport. A system of high-angle or vertical longitudinal faults crosses the peninsula from west-southwest to east-northeast. Evidence of recent strike-slip movement was found, although vertical movement has also been important along these faults. Two tectonic styles exist in the metamorphic rocks. The older one is characterized by compression and thrusting in a south-southeast direction. The younger one is represented by longitudinal faults oriented in an east-northeast direction, with vertical and strike-slip movement. They probably reflect the eastward movement of the Caribbean region with respect to South America.  相似文献   

Geological development and mineralization in the Atacama segment of the South American Andes,northern Chile (26°15′–27°25′S)     

Carlos M. Palacios  Brian C. Townley  Alfredo A. Lahsen  Antonio M. Egaña 《International Journal of Earth Sciences》1993,82(4):652-662

Between the Late Jurassic and the Middle Miocene, widespread magmatism, tectonic events and hydrothermal mineralization characterized the geological evolution of the Atacama segment of the South American Andes. A characteristic feature of this zone is the coincidence in time and space between subduction-generated igneous activity, crustal deformation and mineralization in the magmatic arcs, which formed longitudinal belts migrating eastward.Mineralization in the last 140 Ma is generally restricted to four longitudinal metallogenic belts, in which hydrothermal activity was channelled along crustal-scale faults (1) the Atacama Fault System, along which Early Cretaceous Cu-Au-bearing breccia pipes, veins and stockwork were formed; (2) the Inca do Oro Belt, which contains Upper Cretaceous low sulphur precious metal epithermal mineralization, and Middle Eocene Cu-Mo-Au-bearing breccia pipes; (3) the West Fissure System, which hosts Upper Eocene to Early Oligocene porphyry copper deposits and high sulphur precious metal epithermal mineralization; and (4) the Maricunga Belt, when contains Upper Oligocene to Middle Miocene high sulphur precious metal epithermal deposits and Au-rich porphyry mineralization.  相似文献   

Volcanic emissions and atmospheric pollution:A study of nanoparticles     

Erika M.Trejos  Luis F.O.Silva  James C.Hower  Eriko M.M.Flores  Carlos Mario González  Jorge E.Pachón  Beatriz H.Aristizábal 《地学前缘(英文版)》2021,12(2):746-755

The influence of emissions of an active volcano on the composition of nanoparticles and ultrafine road dust was identified in an urban area of the Andes.Although many cities are close to active volcanoes,few studies have evaluated their influence in road dust composition.Air quality in urban areas is significantly affected by nonexhaust emissions(e.g.road dust,brake wear,tire wear),however,natural sources such as volcanoes also impact the chemical composition of the particles.In this study,elements from volcanic emissions such as Si>Al>Fe>Ca>K>Mg,and Si-Al with K were identified as complex hydrates.Similarly,As,Hg,Cd,Pb,As,H,Cd,Pb,V,and salammoniac were observed in nanoparticles and ultrafine material.Mineral composition was detected in the order of quartz>mullite>calcite>kaolinite>illite>goethite>magnetite>zircon>monazite,in addition to salammoniac,a tracer of volcanic sources.The foregoing analysis reflects the importance of carrying out more studies relating the influence of volcanic emissions in road dust in order to protect human health.The road dust load(RD₁₀)ranged between 0.8 and 26.8 mg m^?2in the city.  相似文献   

Phase equilibrium modelling of the amphibolite facies metamorphism in the Yelapa-Chimo Metamorphic Complex,Mexico     

Fabian Gutierrez-Aguilar  Peter Schaaf  Gabriela Solís-Pichardo  Gerardo F.Arrieta-García  Teodoro Hernandez-Trevino  Carlos Linares-Lopez 《地学前缘(英文版)》2021,12(1):293-312

The Yelapa-Chimo Metamorphic Complex forms part of the Jalisco Block in western Mexico and exposes a wide range of Early Cretaceous metamorphic rocks;such as paragneiss,orthogneiss,amphibolites,and migmatites.However,the pressure-temperature(P-T)conditions of metamorphism and partial melting remain poorly studied in the region.To elucidate metamorphic P-T conditions,phase equilibrium modelling was applied to two sillimanite-garnet paragneisses,one amphibole-orthogneiss,and one amphibolite.Sillimanite-garnet paragneisses exhibit a lepidoblastic texture with a biotite+sillimanite+kyanite+garnet+quartz+plagioclase+K-feldspar mineral assemblage.Amphibole-orthogneiss and amphibolite display a nematoblastic texture with an amphibole+(1)plagioclase+quartz+(1)titanite assemblage and an amphibole+(2)plagioclase+(2)titanite+ilmenite retrograde mineral assemblage.Pseudosections calculated for the two sillimanite-garnet paragneiss samples show P-T peak conditions at~6-7.5 kbar and~725-740℃.The results for amphibole-orthogneiss and the amphibolite yield P-T peak conditions at~8.5-10 kbar and~690-710℃.The mode models imply that metasedimentary and metaigneous units can produce up to~20 vol%and~10 vol%of melt,respectively.Modelling within a closed system during isobaric heating suggests that melt compositions of metasedimentary and metaigneous units are likely to have direct implications for the petrogenesis of the Puerto Vallarta Batholith.Our new data indicate that the Yelapa-Chimo Metamorphic Complex evolved through a metamorphic gradient between~23-33℃km^-1and the metamorphic rocks formed at depths between~22 km and~30 km with a burial rate of~2.0 km Ma^-1.Finally,the P-T data for both metasedimentary and metaigneous rocks provide new constraints on an accretionary framework,which is responsible for generating metamorphism and partial melting in the YelapaChimo Metamorphic Complex during the Early Cretaceous.  相似文献   

Using probabilistic analysis to improve greenhouse gas baseline forecasts in developing country contexts: the case of Chile     

Raul O’ Ryan  Carlos Benavides  Juan Pablo San Martín  Javier Mallea 《Climate Policy》2019,19(3):299-314

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Bacterially mediated mineralization of vaterite   总被引：1，自引：0，他引：1  

Carlos Rodriguez-Navarro  Concepcion Jimenez-Lopez  Maria Teresa Gonzalez-Muñoz 《Geochimica et cosmochimica acta》2007,71(5):1197-1213

Myxococcus xanthus, a common soil bacterium, plays an active role in the formation of spheroidal vaterite. Bacterial production of CO₂ and NH₃ and the transformation of the NH₃ to and OH⁻, thus increasing solution pH and carbonate alkalinity, set the physicochemical conditions (high supersaturation) leading to vaterite precipitation in the microenvironment around cells, and directly onto the surface of bacterial cells. In the latter case, fossilization of bacteria occurs. Vaterite crystals formed by aggregation of oriented nanocrystals with c-axis normal to the bacterial cell-wall, or to the core of the spherulite when bacteria were not encapsulated. While preferred orientation of vaterite c-axis appears to be determined by electrostatic affinity (ionotropic effect) between vaterite crystal (0001) planes and the negatively charged functional groups of organic molecules on the bacterium cell-wall or on extracellular polymeric substances (EPS), analysis of the changes in the culture medium chemistry as well as high resolution transmission electron microscopy (HRTEM) observations point to polymorph selection by physicochemical (kinetic) factors (high supersaturation) and stabilization by organics, both connected with bacterial activity. The latter is in agreement with inorganic precipitation of vaterite induced by NH₃ and CO₂ addition in the protein-rich sterile culture medium. Our results as well as recent studies on vaterite precipitation in the presence of different types of bacteria suggest that bacterially mediated vaterite precipitation is not strain-specific, and could be more common than previously thought.  相似文献   

Electrooxidation Combined with Ozonation in Hospital Laundry Effluents Treatment          下载免费PDF全文

Carlos Alexandre Lutterbeck  Rômulo de Oliveira Schwaickhardt  Alexandre Straatmann  Lourdes Teresinha Kist  Eduardo A. Lobo  Ênio Leandro Machado 《洁净——土壤、空气、水》2014,42(5):601-608

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