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991.
992.
Bacterially mediated mineralization of vaterite   总被引:1,自引:0,他引:1  
Myxococcus xanthus, a common soil bacterium, plays an active role in the formation of spheroidal vaterite. Bacterial production of CO2 and NH3 and the transformation of the NH3 to and OH, thus increasing solution pH and carbonate alkalinity, set the physicochemical conditions (high supersaturation) leading to vaterite precipitation in the microenvironment around cells, and directly onto the surface of bacterial cells. In the latter case, fossilization of bacteria occurs. Vaterite crystals formed by aggregation of oriented nanocrystals with c-axis normal to the bacterial cell-wall, or to the core of the spherulite when bacteria were not encapsulated. While preferred orientation of vaterite c-axis appears to be determined by electrostatic affinity (ionotropic effect) between vaterite crystal (0001) planes and the negatively charged functional groups of organic molecules on the bacterium cell-wall or on extracellular polymeric substances (EPS), analysis of the changes in the culture medium chemistry as well as high resolution transmission electron microscopy (HRTEM) observations point to polymorph selection by physicochemical (kinetic) factors (high supersaturation) and stabilization by organics, both connected with bacterial activity. The latter is in agreement with inorganic precipitation of vaterite induced by NH3 and CO2 addition in the protein-rich sterile culture medium. Our results as well as recent studies on vaterite precipitation in the presence of different types of bacteria suggest that bacterially mediated vaterite precipitation is not strain-specific, and could be more common than previously thought.  相似文献   
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This paper aims to apply statistical procedures to analyse the ozone weekend effect (OWE) in three European urban areas: Lisbon, Oporto and London. Seasonal variations of surface ozone (O3) and total oxidant species (Ox) concentrations are presented. The studied period was from January 2007 to December 2009. The O3 annual average profile in London was significantly different from the ones achieved for Lisbon and Oporto, due to the high emissions of nitrogen oxides and low temperatures (associated with low solar radiations). The influence of nitrogen oxides in atmospheric chemistry of London was analysed by linear correlations between O3 concentrations and NO2/NO ratio. High values during almost all period showed that O3 concentrations are mainly influenced by NO? NO2? O3 chemical reaction. On the other hand, the linear correlations between O3 and NO2 concentrations only presented positive values in Lisbon and Oporto. This behaviour is associated with photo‐dissociation of NO2, producing O3 during the spring and summer periods. Additionally, cluster analysis was applied to group the days of week according the correspondent O3 behaviour. The weekend and some weekdays (immediately after or before) were grouped in the same cluster, showing that OWE occurs in all urban areas selected in this study. These findings suggest that the applied statistical procedures should be used to analyse the OWE and that the causes for the different O3 behaviours during the week may be influenced by meteorological variables.  相似文献   
996.
The electric and magnetic fields generated by an individual horizontal current ring induced inside a homogeneous conductive half‐space, originating from an external large circular loop source of current in the presence of a flat half‐space, are deduced. A check of self‐consistency for these expressions led to the known general functions for these fields due to the same external source in the presence of that medium. The current rings’ mutual coupling related to the magnetic field's radial component is thoroughly analysed and its specific members are presented. The existence of a relatively small zone inside the half‐space responsible for the main contribution for the signal measured at the observation point, with the source and receiver on the ground surface, is made evident. For increasing values of frequency, at a given transmitter‐receiver (T–R) configuration, this zone shrinks and its central point moves away from a maximum depth of about 30% and horizontal distance of nearly 85%, of the T–R separation, to a point very close to the receiver position. The coordinates of the central point of this zone of main contribution are provided as approximated functions in terms of the induction number .  相似文献   
997.
Uncertainty analyses allow the identification and quantification of the factors that contribute to the potential misclassification of the ecological status of water bodies, helping to improve the sampling design used in monitoring. Here we used a Posidonia oceanica multivariate index (POMI) bio-monitoring dataset covering a total of 81 sites distributed throughout 28 water bodies from the coast of Catalonia, Balearic Islands and Croatia to determine the levels of uncertainty associated with each region and how they change according to the quality status of water bodies. Overall, variability among sites (meadows) within water bodies was the factor that generated the greatest risk of misclassification among the three regions, within which the Balearic Islands had the lowest uncertainty, followed by Croatia and Catalonia. When water bodies classified in good/high quality were separated from those in moderate/poor status classes, we found that the latter displayed higher levels of uncertainty than the former.  相似文献   
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In seismic interpretation and seismic data analysis, it is of critical importance to effectively identify certain geologic formations from very large seismic data sets. In particular, the problem of salt characterization from seismic data can lead to important savings in time during the interpretation process if solved efficiently and in an automatic manner. In this work, we present a novel numerical approach that is able to automatically segmenting or identifying salt structures from a post‐stack seismic data set with a minimum intervention from the interpreter. The proposed methodology is based on the recent theory of sparse representation and consists in three major steps: first, a supervised learning assisted by the user which is performed only once, second a segmentation process via unconstrained ?1 optimization, and finally a post‐processing step based on signal separation. Furthermore, since the second step only depends upon local information at each time, the whole process greatly benefits from parallel computing platforms. We conduct numerical experiments in a synthetic 3D seismic data set demonstrating the viability of our method. More specifically, we found that the proposed approach matches up to 98.53% with respect to the corresponding 3D velocity model available in advance. Finally, in appendixes A and B, we present a convergence analysis providing theoretical guarantees for the proposed method.  相似文献   
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