Dehydration reactions and micro/nanostructures in experimentally-deformed serpentinites     

Cecilia Viti  Takehiro Hirose 《Contributions to Mineralogy and Petrology》2009,157(3):327-338

High-T torsion experiments on lizardite + chrysotile serpentinites produced mineralogical and micro/nanostructural changes, with important implications in rheological properties. High-resolution TEM showed that specimens underwent ductile [by microkinking and (001) interlayer glide] and brittle deformation (by microfracturing), together with dehydration and break-down reactions. Lizardite is affected by polytypic disorder and microkinking [kink axial planes at high angle with respect to (001) planes], that were not present in the initial ordered 1T-lizardite. Chrysotile fibres are deformed, resulting in elliptical cross-sections, with strong loss of interlayer cohesion. Both lizardite and chrysotile break down to a fine intergrowth of olivine (up to 200 nm), talc (up to 30 nm) and poorly-crystalline material. Lizardite-out reaction preferentially occurs at kink axial planes, representing sites of preferential strain and enhanced reactivity; conversely, chrysotile break-down is a bulk process, resulting in large healed olivine aggregates, up to micrometric in size. Overall observations suggest that dehydration and break-down reactions are more advanced in chrysotile than in lizardite.  相似文献   

Three-Dimensional Reconstruction and Thermal Modeling of Observed Loops     

Nuevo  Federico A.  Mac Cormack  Cecilia  López Fuentes  Marcelo C.  Vásquez  Alberto M.  Mandrini  Cristina H. 《Solar physics》2020,295(12):1-22

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Melting and cataclastic features in shatter cones in basalt from the Vista Alegre impact structure,Brazil          下载免费PDF全文

Lidia Pittarello  Fabrizio Nestola  Cecilia Viti  Alvaro Penteado Crósta  Christian Koeberl 《Meteoritics & planetary science》2015,50(7):1228-1243

Shatter cones are one of the most widely recognized pieces of evidence for meteorite impact events on Earth, but the process responsible for their formation is still debated. Evidence of melting on shatter cone surfaces has been rarely reported in the literature from terrestrial impact craters but has been recently observed in impact experiments. Although several models for shatter cones formation have been proposed, so far, no one can explain all the observed features. Shatter cones' from the Vista Alegre impact structure, Brazil, formed in fine‐grained basalt of the Jurassic‐Cretaceous Serra Geral Formation (Paraná large igneous province). A continuous quenched melt film, consisting of a crystalline phase, mica, and amorphous material, decorates the striated surface. Ultracataclasites, containing subrounded pyroxene clasts in an ultrafine‐grained matrix, occur subparallel to the striated surface. Several techniques were applied to characterize the crystalline phase in the melt, including Raman spectroscopy and transmission electron microscopy. Results are not consistent with any known mineral, but they do suggest a possible rare or new type of clinopyroxene. This peculiar evidence of melting and cataclasis in relation with shatter cone surfaces is interpreted as the result of tensile fracturing at the tip of a fast propagating shock‐induced rupture, which led to the formation of shatter cones at the tail of the shock front, likely during the early stage of the impact events.  相似文献   

Paleomagnetic and rock-magnetic survey of eocene dike swarms from the Tecalitlan area (Western Mexico): Tectonic implications     

Jose Rosas-Elguera  Bertha Aguilar Reyes  Avto Goguitchaichvili  Macario Rocha  Margarita López Martínez  Miriam M. Tostado-Plascencia  Luis M. Alva Valdivia  Cecilia Caballero Miranda 《Studia Geophysica et Geodaetica》2011,55(2):265-278

For long time the western-central Mexico has been affected by oblique subduction caused by Farallon plate beneath North America. As result, smaller plates (e.g. Cocos Plate), several fault systems outlining crustal blocks (e.g. Michoacán block) and magmatic arcs (e.g. Paleocene-Early Oligocene magmatism and the Trans-Mexican Volcanic Belt) were developed. Still, no paleomagnetic data are available for Oligocene and Miocene. The principal aim of this study is to evaluate whether the tectonic rotations and relative motions of these blocks occurred before the Miocene. Here, we report a detailed rock-magnetic and paleomagnetic results from Tecalitlan area, located in the Michoacán block. Sixteen sites (about 150 oriented samples) were collected including one radiometrically dated diabase dike (35.0 ± 1.8 Ma). Rock-magnetic experiments permitted identification of magnetic carriers and assessment of the paleomagnetic stability. Continuous susceptibility measurements vs temperature in most cases yield reasonably reversible curves with Curie points close to that of magnetite. Reliable paleomagnetic directions were obtained for 12 sites. Inclination I and declination D of the mean paleomagnetic direction obtained in this study are I = 33.1°, D = 345.0°, and Fisherian statistical parameters are k = 25, α₉₅ = 8.9°. The corresponding mean paleomagnetic pole position is P_lat = 75.7°, P_long = 166.6°, K = 31, A₉₅ = 8.0°. The mean inclination is in reasonably good agreement with the expected value, as derived from reference poles for the stable North America. Magnetic declination is not significantly different from that expected which is in disagreement with a counterclockwise tectonic rotation of about 20° previously reported for the studied area. Based on paleomagnetic results obtained in this study compiled with those currently available from the Michoacán Block, we propose a simple model suggesting that sometime in Eocene epoch the convergence vector of the Farallon plate relative to North America plate was normal to the trench before reaching an actual oblique convergence.  相似文献   

Shifts in an epibenthic trophic web across a marine frontal area in the Southwestern Atlantic (Argentina)     

A. Cecilia Mauna  Florencia Botto  Barbara Franco  J. Matías Schwartz  E. Marcelo Acha  Mario L. Lasta  Oscar O. Iribarne 《Journal of Sea Research》2011,66(3):248-255

Marine benthic trophic relationships and food web structures may be influenced by benthic–pelagic coupling processes, which could also be intensified by the physical dynamics of marine fronts. In this work, we employed stable isotope (δ¹³C and δ¹⁵N) analysis to investigate the influence of the Southwest (SW) Atlantic shelf-break front (SBF; 38–39°S, 55–56°W; Argentina) on an epibenthic trophic web. Epibenthic organisms were sampled, at depths of ~ 100 m, with a non-selective dredge from a sandy bottom community located in frontal (F) and marginal (M) areas. The SBF position and the chlorophyll-a (chl-a) concentrations were inferred using satellite data of the sea surface temperature (SST) and satellite chl-a concentration, respectively. The most noticeable shifts in stable isotopes between the sampled areas were those of the Patagonian scallop, Zygochlamys patagonica (δ¹³C), and those of the sea urchin, Sterechinus agassizi (δ¹⁵N). Diet analyses inferred from stable isotopes and mixing models demonstrated that the dominant component of this community, Z. patagonica, had variable contributions to higher trophic levels between areas. More importantly, the epibenthic assemblage in F areas showed δ¹³C-enriched and δ¹⁵N-depleted isotopic signatures with respect to the M areas. Collectively, this evidence suggests that frontal dynamics promotes the accumulation of δ¹³C-enriched phytoplankton in the seabed in F areas, while in M areas the more degraded organic matter becomes more important in the trophic web, decreasing the δ¹⁵N isotopic signature of the assemblage. Therefore, the trophic web was sustained by fresher food in F areas than in M areas, demonstrating the role of frontal dynamics in the shaping of these communities.  相似文献   

PCBs and chlorinated pesticides in the atmosphere and aquatic organisms of Ross Island, Antarctica     

Per Larsson  Cecilia Jrnmark  Anders Sdergren 《Marine pollution bulletin》1992,25(9-12):281-287

PCBs, p,p′-DDT, p,p′-DDE and lindane (γ-hexachlorocyclohexane) were monitored in the lower atmosphere of Ross Island, in Antarctica for 2 yr. Geometrical means were 15.2 pg m⁻³ for PCBs, 2.0 pg m⁻³ for p,p′-DDT, 1.0 pg m⁻³ for p,p′-DDE and 25.8 pg m⁻³ for lindane. Atmospheric levels of lindane were positively correlated with temperature, and a significant difference was found between spring-summer and summer-winter concentrations. No season related differences were found for the other chlorinated hydrocarbons, possibly owing to their lower vapour pressure and the cold climate. Periods with increased atmospheric levels of PCBs and DDT compounds were recorded. Lindane, p,p′-DDE and PCBs were present in fish and zooplankton sampled close to Ross Island. Pollutant levels in the zooplankton (on an extractable fat basis) were highest during the Antarctic spring and autumn and were inversely correlated to their fat content.  相似文献   

Is net ecosystem production higher in natural relative to constructed wetlands?     

Cecilia Español  Belinda Gallardo  M. Rosa Pino  Ana Martín  Francisco A. Comín 《Aquatic Sciences - Research Across Boundaries》2013,75(3):385-397

Ecosystem metabolism is an important measure of wetland restoration efficiency, and serves to indicate if the system is capable of processing energetic resources. Despite its value, ecosystem metabolism has rarely been included in monitoring programs. In this study, we aimed to achieve the following objectives: (i) compare net ecosystem production (NEP) rates of constructed vs. natural wetlands; (ii) identify the highest NEP rate habitats; and (iii) define the main environmental factors regulating NEP in different wetland types. Pelagic and benthic NEP rates and physicochemical features were measured in three natural and five constructed wetlands in the middle Ebro River floodplain (NE Spain). Statistical analyses showed pelagic NEP rates peaked in natural wetlands, which produced up to 187.5 mg C m^?3 h^?1 compared to lower rates in constructed wetlands (up to 46.2 mg C m^?3 h^?1). Pelagic NEP responded positively to temperature, total dissolved solids, and nutrients. Benthic NEP rates were 3 to 30-fold greater than pelagic in natural (up to 994.9 mg C m^?3 h^?1) and constructed (up to 1,551.5 mg C m^?3 h^?1) wetlands, and were heavily influenced by habitat type, with NEP peaking in areas dominated by submerged vegetation and fine organic sediment. Rapid recovery in aquatic communities (i.e. macroinvertebrate diversity) has been previously reported for the studied wetlands; however, our study suggests a slower recovery of functional processes (i.e. pelagic NEP) in constructed habitats. We therefore strongly advocate the inclusion of ecosystem function in the design and evaluation of restoration projects to optimise long-term wetland ecosystem sustainability.  相似文献   

A Geometric Interpretation of Integrable Motions     

Cecilia Clementi  Marco Pettini 《Celestial Mechanics and Dynamical Astronomy》2002,84(3):263-281

Integrability, one of the classic issues in galactic dynamics and in general in celestial mechanics, is here revisited in a Riemannian geometric framework, where Newtonian motions are seen as geodesics of suitable -mechanical- manifolds. The existence of constants of motion that entail integrability is associated with the existence of Killing tensor fields on the mechanical manifolds. Such tensor fields correspond to hidden symmetries of non-Noetherian kind. Explicit expressions for Killing tensor fields are given for the N = 2 Toda model, and for a modified Hénon-Heiles model, recovering the already known analytic expressions of the second conserved quantity besides energy for each model respectively.  相似文献   

Rights to carbon and payments for services rendered under REDD+: Options for the case of Mexico     

Margaret Skutsch  Cecilia Simon  Alejandro Velazquez  José Carlos Fernández 《Global Environmental Change》2013,23(4):813-825

Mexico is relatively advanced in its preparation for international policy on Reduced Emissions from Deforestation and forest Degradation (REDD+) and has many of the pre-conditions needed to support a community approach in the implementation of a national REDD+ programme, particularly as regards tenure of forests and experience with community forest management and PES schemes, although these conditions do not pertain everywhere. One critical issue that is yet to be resolved concerns rights to carbon credits and distribution of the financial benefits flowing from REDD+. We demonstrate that attribution of carbon credits from reduced deforestation and degradation at the community level is virtually impossible from a technical viewpoint, since these credits are counterfactual. Payments based on assessment of performance of each community in terms of such reductions would moreover be inequitable and inefficient. Flat rate payments in return for agreed improvements in management are likely to be more motivating and much easier to administer. However, increases in carbon stock (forest enhancement) can be physically measured on site, and could be more easily attributed to each individual community. We therefore propose a system in which reduced deforestation and degradation are considered environmental services, with credits accruing to national government. The financial value of the credits may be used to finance flat rate payments to communities who agree to implement improved management. On the other hand, credits for forest enhancement, which reflect measurable increases in carbon in the communities’ trees, would be considered environmental goods. These should be considered the direct property of the owners of the forest (in the same sense as wood or poles) and it would be possible for communities to sell these credits themselves. We acknowledge however that many other problems face implementation of REDD+ in Mexico, and provide a number of important examples.  相似文献   

The Mediterranean intercalibration exercise on soft‐bottom benthic invertebrates with special emphasis on the Italian situation     

Anna Occhipinti Ambrogi  Giulia Forni  Cecilia Silvestri 《Marine Ecology》2009,30(4):495-504

The intercalibration exercise is an important step in the building process of the surface water ecological quality assessment, which is required by the Water Framework Directive (WFD). Its aim is to apply the water quality classification in a uniform manner to all the Member States belonging to the same eco‐region. Cyprus, France, Greece, Italy, Slovenia and Spain participated in the soft‐bottom benthic invertebrate subgroup for the Mediterranean coastal region. The methodologies proposed by Member States were applied and tested; the results were compared and harmonized to establish agreed and comparable boundaries for the benthic invertebrate ecological status classes. The national methods used in the intercalibration process were: for Cyprus and Greece, the Bentix Index; for Slovenia, a combination of AZTI Marine Biotic Index (AMBI), richness and diversity with the use of factor and discriminant analysis (Multimetric AMBI); for Spain, a new index, named MEDOCC, which is an adaptation of the AMBI index to the Western Mediterranean area. Italy and France tested different methods, none of which have been officially adopted. Final class boundary values for the different official classification systems were obtained and compared. Besides describing methods and results obtained by the different countries, the Italian situation is examined in more detail. All the above methods have been applied to Italian data, but the results were not conclusive. Major causes for concern are related to insufficient sites and data, to the lack of real non‐impacted reference sites, and to the difficulties in validating the ecological status classification in sites not showing a pollution gradient.  相似文献