The Mediterranean intercalibration exercise on soft‐bottom benthic invertebrates with special emphasis on the Italian situation     

Anna Occhipinti Ambrogi  Giulia Forni  Cecilia Silvestri 《Marine Ecology》2009,30(4):495-504

The intercalibration exercise is an important step in the building process of the surface water ecological quality assessment, which is required by the Water Framework Directive (WFD). Its aim is to apply the water quality classification in a uniform manner to all the Member States belonging to the same eco‐region. Cyprus, France, Greece, Italy, Slovenia and Spain participated in the soft‐bottom benthic invertebrate subgroup for the Mediterranean coastal region. The methodologies proposed by Member States were applied and tested; the results were compared and harmonized to establish agreed and comparable boundaries for the benthic invertebrate ecological status classes. The national methods used in the intercalibration process were: for Cyprus and Greece, the Bentix Index; for Slovenia, a combination of AZTI Marine Biotic Index (AMBI), richness and diversity with the use of factor and discriminant analysis (Multimetric AMBI); for Spain, a new index, named MEDOCC, which is an adaptation of the AMBI index to the Western Mediterranean area. Italy and France tested different methods, none of which have been officially adopted. Final class boundary values for the different official classification systems were obtained and compared. Besides describing methods and results obtained by the different countries, the Italian situation is examined in more detail. All the above methods have been applied to Italian data, but the results were not conclusive. Major causes for concern are related to insufficient sites and data, to the lack of real non‐impacted reference sites, and to the difficulties in validating the ecological status classification in sites not showing a pollution gradient.  相似文献   

The spreading of eutrophication in the eastern coast of the Gulf of Bothnia,northern Baltic Sea – An analysis in time and space     

Cecilia Lundberg  Britt-Marie Jakobsson  Erik Bonsdorff 《Estuarine, Coastal and Shelf Science》2009

In the Baltic Sea, the Gulf of Bothnia is the only sub-basin with only minor effects of eutrophication mainly due to physical factors. Most evaluations of the state of the Gulf of Bothnia are based on offshore investigations. In the present study the coastal zone of the eastern Gulf of Bothnia is analysed. Long-term data (1980–2007) of total nitrogen and phosphorus, turbidity and oxygen are analysed using principal component analysis (PCA) for spatial and temporal patterns in the trophic situation. The coastal zone is divided into six regions: inner and outer areas of the Bothnian Sea and the Quark, and the outer areas of the southern and northern Bothnian Bay. The results show a degradation of water quality from north to south, and from outer to inner coastal areas. Eutrophication changes from an almost non-existing problem in the Bothnian Bay in the north to clear signs of nutrient over-enrichment in the Bothnian Sea. This shows that even if eutrophication in the Gulf of Bothnia is not serious, the increasing trends in nutrient levels should be seen as warning signals for the future, and remedies to combat eutrophication should be taken rapidly.  相似文献   

Dehydration reactions and micro/nanostructures in experimentally-deformed serpentinites     

Cecilia Viti  Takehiro Hirose 《Contributions to Mineralogy and Petrology》2009,157(3):327-338

High-T torsion experiments on lizardite + chrysotile serpentinites produced mineralogical and micro/nanostructural changes, with important implications in rheological properties. High-resolution TEM showed that specimens underwent ductile [by microkinking and (001) interlayer glide] and brittle deformation (by microfracturing), together with dehydration and break-down reactions. Lizardite is affected by polytypic disorder and microkinking [kink axial planes at high angle with respect to (001) planes], that were not present in the initial ordered 1T-lizardite. Chrysotile fibres are deformed, resulting in elliptical cross-sections, with strong loss of interlayer cohesion. Both lizardite and chrysotile break down to a fine intergrowth of olivine (up to 200 nm), talc (up to 30 nm) and poorly-crystalline material. Lizardite-out reaction preferentially occurs at kink axial planes, representing sites of preferential strain and enhanced reactivity; conversely, chrysotile break-down is a bulk process, resulting in large healed olivine aggregates, up to micrometric in size. Overall observations suggest that dehydration and break-down reactions are more advanced in chrysotile than in lizardite.  相似文献   

Consortium study of the unusual H chondrite regolith breccia,Noblesville     

Michael E. Lipschutz  Stephen F. Wolf  Stephan Vogt  Edward Michlovich  Marilyn M. Lindstrom  Michael E. Zolensky  David W. Mittlefehldt  Cecilia Satterwhite  Ludolf Schultz  Thomas Loeken  Peter Scherer  Robert T. Dodd  Derek W. G. Sears  Paul H. Benoit  John F. Wacker  Roger G. Burns  Duncan S. Fisher 《Meteoritics & planetary science》1993,28(4):528-537

Abstract— The Noblesville meteorite is a genomict, regolith breccia (H6 clasts in H4 matrix). Mössbauer analysis confirms that Noblesville is unusually fresh, not surprising in view of its recovery immediately after its fall. It resembles “normal” H4–6 chondrites in its chemical composition and induced thermoluminescence (TL) levels. Thus, at least in its contents of volatile trace elements, Noblesville differs from other H chondrite, class A regolith breccias. Noblesville's small pre-atmospheric mass and fall near Solar maximum and/or its peculiar orbit (with perihelion <0.8 AU as shown by natural TL intensity) may partly explain its levels of cosmogenic radionuclides. Its cosmic ray exposure age of ～ 44 Ma, is long, is equalled or exceeded by <3% of all H chondrites, and also differs from the 33 ± 3 Ma mean exposure age peak of other H chondrite regolith breccias. One whole-rock aliquot has a high, but not unmatched, ¹²⁹Xe/¹³²Xe of 1.88. While Noblesville is now among the chondritic regolithic breccias richest in solar gases, elemental ratios indicate some loss, especially of He, perhaps b; impacts in the regolith that heated individual grains. While general shock-loading levels in Noblesville did not exceed 4 GPa, individual clasts record shock levels of 5–10 GPa, doubtless acquired prior to lithification of the whole-rock meteoroid.  相似文献   

Silicate-silicate liquid immiscibility and graphite ribbons in Libyan desert glass     

Giovanni Pratesi  Cecilia VitiCurzio Cipriani  Marcello Mellini 《Geochimica et cosmochimica acta》2002,66(5):903-911

Transmission electron microscopic (TEM) investigation of the dark (brown or bluish) streaks occurring in Libyan Desert Glass reveals the common presence of small glass spherules. The spherules, mostly 100 nm in size, are homogeneously dispersed within the silica-glass matrix. The complete absence of electron diffraction effects confirms their amorphous nature. The spherules are Al-, Fe- and Mg-enriched with respect to the surrounding silica matrix and their (Mg + Al + Fe) : Si ratio is close to 1.The silica-glass matrix and amorphous spherules form an emulsion texture (i.e., globules of one glass in a matrix of another glass), which originates from silicate-silicate liquid immiscibility. This texture has also been observed in other impact-derived glasses.The silica glass also contains carbonaceous inclusions consisting of 5-50 nm thick, polygonalized graphite ribbons that form closed structures up to 200 nm in diameter.These observations are in agreement with an impact origin for Libyan Desert Glass.  相似文献   

Crime risk in urban neighbourhoods: the use of insurance data to analyse changing spatial forms     

Cecilia Wong 《Area》1997,29(3):228-240

Summary The recent British Crime Surveys have confirmed that there are significant spatial variations in the distribution of crime risk. However, it is notoriously difficult to represent the spatial patterns in Britain convincingly, owing to the statistical inadequacy of the official crime data. This paper discusses the use of home contents insurance data as a proxy measure of crime risk, and examines the changing spatial distribution of crime risk in the two Northern conurbations of Merseyside and Greater Manchester. The analysis provides an explicit urban focus in order to establish links between the spatial distribution of crime risk and other patterns of deprivation or inequality in the urban environment. Since insurance data is used as a proxy measure of crime risk in the Department of the Environment's Index of Local Conditions, this analysis serves as an interesting basis for both academic and policy discussion.  相似文献   

Carbon and oxygen isotopes of Maastrichtian–Danian shallow marine carbonates: Yacoraite Formation, northwestern Argentina     

Rosa Marquillas  Ignacio Sabino  Alcides Nobrega Sial  Cecilia del Papa  Valderez Ferreira  Stephen Matthews 《Journal of South American Earth Sciences》2007,23(4):304-320

The Maastrichtian–Danian limestones of the Yacoraite Formation (northwestern Argentina) show carbon and oxygen isotopic values consistent with shallow marine conditions. The members of the formation respond to different sedimentary environments and are characterised by distinctive stable isotopes and geochemistry. The basal Amblayo Member is composed of high-energy dolomitic limestones and limestones with positive isotopic values (+2‰ δ¹³C, +2‰ δ¹⁸O). The top of the member reveals an isotopic shift of δ¹³C (−5‰) and δ¹⁸O (−10‰), probably related to a descent in the sea level. The sandy Güemes Member has isotopically negative (−2‰ δ¹³C, −1‰ δ¹⁸O) limestones, principally controlled by water mixing, decreased organic productivity, and compositional changes in the carbonates. The isotopically lighter limestones are calcitic, with a greater terrigenous contribution and different geochemical composition (high Si–Mn–Fe–Na, low Ca–Mg–Sr). These isotopic and lithological changes relate to the Cretaceous–Palaeogene transition. The Alemanía Member, composed of dolomitic limestones and pelites, represents a return to marine conditions and shows a gradual increase in isotopic values, reaching values similar to those of the Amblayo Member. The Juramento Member, composed of stromatolite limestones, shows isotopic variations that can be correlated with the two well-defined, shallowing-upward sequences of the member.  相似文献   

PCBs and chlorinated pesticides in the atmosphere and aquatic organisms of Ross Island, Antarctica     

Per Larsson  Cecilia Jrnmark  Anders Sdergren 《Marine pollution bulletin》1992,25(9-12):281-287

PCBs, p,p′-DDT, p,p′-DDE and lindane (γ-hexachlorocyclohexane) were monitored in the lower atmosphere of Ross Island, in Antarctica for 2 yr. Geometrical means were 15.2 pg m⁻³ for PCBs, 2.0 pg m⁻³ for p,p′-DDT, 1.0 pg m⁻³ for p,p′-DDE and 25.8 pg m⁻³ for lindane. Atmospheric levels of lindane were positively correlated with temperature, and a significant difference was found between spring-summer and summer-winter concentrations. No season related differences were found for the other chlorinated hydrocarbons, possibly owing to their lower vapour pressure and the cold climate. Periods with increased atmospheric levels of PCBs and DDT compounds were recorded. Lindane, p,p′-DDE and PCBs were present in fish and zooplankton sampled close to Ross Island. Pollutant levels in the zooplankton (on an extractable fat basis) were highest during the Antarctic spring and autumn and were inversely correlated to their fat content.  相似文献   

Modelling surface drifting of buoys during a rapidly-moving weather front in the Gulf of Finland, Baltic Sea     

Maria Gstgifvars  Hannu Lauri  Annakaisa Sarkanen  Kai Myrberg  Oleg Andrejev  Cecilia Ambjrn 《Estuarine, Coastal and Shelf Science》2006,70(4):567

The Gulf of Finland is an elongated estuary located in the north-eastern extremity of the Baltic Sea. This semi-enclosed sea-area is subject to heavy sea traffic, and is one of the main risk areas for oil accidents in the Baltic. The continuous development and validation of operational particle drift and oil-spill forecasting systems is thus seen to be essential for this sea-area.Here, the results of a three-day drift experiment in May 2003 are discussed. The field studies were performed using GPS-positioned surface floating buoys. The aim of this paper is to evaluate how well models can reproduce the drift of these buoys. Model simulations, both in forecast and hindcast modes, were carried out by three different 3D hydrodynamic models, the results of which are evaluated by comparing the calculated drifts with observations. These models were forced by HIRLAM (High Resolution Limited Area Model) and ECMWF (European Centre for Medium-Range Weather Forecasts) meteorological forecast fields.The simulated drift of the buoys showed a good agreement with observations even when, during the study period, a rapidly-changing wind situation was observed to affect the investigation area; in this situation the winds turned about 100 degrees in half an hour. In such a case it is a very complicated task to forecast the drifters' routes: there is a need to regularly update the meteorological forcing fields and to use these regularly-updated fields throughout the simulations. It is furthermore recommended that forecasts should be made using several circulation models and several meteorological forecasts, in order to get an overview of the accuracy of the forecasted drifts and related differences in between the forecasts.  相似文献   

Spatial and temporal variability of phytoplankton and environmental factors in a temperate estuary of South America (Atlantic coast,Argentina)     

Cecilia A. Popovich  Jorge E. Marcovecchio 《Continental Shelf Research》2008

A spatial and temporal study on data collected along the longitudinal gradient of the Principal Channel of Bahía Blanca estuary, Argentina, was carried out during 1992–1993. At nine stations, phytoplankton abundance, chlorophyll a (Chl-a) concentration, inorganic nutrient levels, Secchi disk depth, euphotic depth:mixing depth ratio (Z_eu:Z_m), salinity and temperature were recorded. Phytoplankton abundance, Chl-a concentration and nutrient levels decreased towards the outer zone of the estuary. The inner zone (stations 1 and 2), which was characterized by high turbidity, high nutrient concentrations and high Z_eu:Z_m (>0.16, [critical mixing ratio]), registered the highest phytoplankton abundance and Chl-a concentrations. Temporal variability of data was also noteworthy in this zone. The highest biomass values thus corresponded to June, July, August and the beginning of spring (18 μg Chl-a L⁻¹ and 9×10⁶ cells L⁻¹) concomitantly with a diatom bloom. In the middle zone (stations 3–6), a strong phytoplankton biomass decrease was observed and it coincided with both deep-mixed depths and low Z_eu:Z_m (<0.16). The outer zone (stations 7–9), which was characterized by low phytoplankton biomass values and low nutrient levels all along the year, was the area mostly influenced by waters from the adjacent continental shelf. In view of the above, it can be concluded that the most important primary production in the Bahía Blanca would be produced in the shallow inner zone during winter, being the spatial reach of the phytoplankton biomass principally limited to estuarine waters. Presumably, less than 5% of such biomass may reach the coastal area of the estuary.  相似文献