Fluid inclusion and stable isotope (O, H, C, and S) constraints on the genesis of the Serrinha gold deposit, Gurupi Belt, northern Brazil   总被引：1，自引：0，他引：1  

Evandro L. Klein  Chris Harris  Christophe Renac  André Giret  Candido A. V. Moura  Kazuo Fuzikawa 《Mineralium Deposita》2006,41(2):160-178

The Serrinha gold deposit of the Gurupi Belt, northern Brazil, belongs to the class of orogenic gold deposits. The deposit is hosted in highly strained graphitic schist belonging to a Paleoproterozoic (∼2,160 Ma) metavolcano-sedimentary sequence. The ore-zones are up to 11 m thick, parallel to the regional NW–SE schistosity, and characterized by quartz-carbonate-sulfide veinlets and minor disseminations. Textural and structural data indicate that mineralization was syn- to late-tectonic and postmetamorphic. Fluid inclusion studies identified early CO₂ (CH₄-N₂) and CO₂ (CH₄-N₂)-H₂O-NaCl inclusions that show highly variable phase ratios, CO₂ homogenization, and total homogenization temperatures both to liquid and vapor, interpreted as the product of fluid immiscibility under fluctuating pressure conditions, more or less associated with postentrapment modifications. The ore-bearing fluid typically has 18–33mol% of CO₂, up to 4mol% of N₂, and less than 2mol% of CH₄ and displays moderate to high densities with salinity around 4.5wt% NaCl equiv. Mineralization occurred around 310 to 335°C and 1.3 to 3.0 kbar, based on fluid inclusion homogenization temperatures and oxygen isotope thermometry with estimated oxygen fugacity indicating relatively reduced conditions. Stable isotope data on quartz, carbonate, and fluid inclusions suggest that veins formed from fluids with δ¹⁸O_H2O and δD_H2O (310–335°C) values of +6.2 to +8.4‰ and −19 to −80‰, respectively, which might be metamorphic and/or magmatic and/or mantle-derived. The carbon isotope composition (δ¹³C) varies from −14.2 to −15.7‰ in carbonates; it is −17.6‰ in fluid inclusion CO₂ and −23.6‰ in graphite from the host rock. The δ³⁴S values of pyrite are −2.6 to −7.9‰. The strongly to moderately negative carbon isotope composition of the carbonates and inclusion fluid CO₂ reflects variable contribution of organic carbon to an originally heavier fluid (magmatic, metamorphic, or mantle-derived) at the site of deposition and sulfur isotopes indicate some oxidation of the originally reduced fluid. The deposition of gold is interpreted to have occurred mainly in response to phase separation and fluid-rock interactions such as CO₂ removal and desulfidation reactions that provoked variations in the fluid pH and redox conditions.  相似文献   

Comparison between tomographic structures and models of convection in the upper mantle   总被引：1，自引：0，他引：1  

Pierre Vacher  Antoine Mocquet  Christophe Sotin 《Geophysical Journal International》1996,124(1):45-56

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The aging of gypsum in underground mines   总被引：1，自引：0，他引：1  

Christophe Auvray  Franoise Homand  Claudia Sorgi 《Engineering Geology》2004,74(3-4):183-196

The aging properties of gypsum extracted from two underground mines in France (Livry–Gargan and Grozon) have been highlighted by means of observation performed using scanning electron microscopy on samples taken along horizontal boreholes drilled through to the middle of several pillars. The aging process is exhibited by the presence of traces of dissolution (edges of the dissolved crystals, corroded crystalline surfaces, important intra- and intercrystalline space). These dissolution figures decrease in number and in intensity from the wall heading towards the middle of the pillar. The “older” pillars display a greater number of dissolution traces than the “more recent” pillars. Then, the role of the aging has been assessed by determining various physical and mechanical parameters on cylindrical samples of 38 mm in diameter and 76 mm in height, machined from the set of drilled boreholes. The following parameters have been quantified: density, grains density, total porosity, porosity accessible to water, intrinsic permeability to nitrogen, velocity of ultrasonic compression and shear waves, dynamic Young's modulus, dynamic Poisson's ratio, uniaxial compressive strength and static Young's modulus. Significant variations in parameter values between the wall and the middle of the pillar were recorded and recognized as being strongly correlated with the intensity of dissolution traces, and hence with gypsum aging.  相似文献   

Variability of the ice export through Fram Strait in 1993–98: the winter 1994/95 anomaly     

Marie-Noëlle Houssais  Christophe Herbaut 《Polar research》2003,22(1):99-106

The origin of the large positive anomaly of the Fram Strait sea ice export which occurred in winter 1994/95 is analysed on the basis of a model simulation of the Arctic sea ice cover over the period 1993-98. The overall intra-annual and interannual variability in the model is in good agreement with observational estimates and the 1994/95 anomaly is well reproduced with an amplitude amounting to half of the mean winter value. Model results suggest that, concomitant to anomalous export velocities, larger than usual ice thickness in the strait contributes to the outstanding amplitude of the anomaly. Analysis on the ice thickness evolution in the strait indicates that the thick ice advected in Fram Strait at the end of the fall of 1994 originates in the anomalous cyclonic wind stress which prevailed during the preceding summer. This anomalous wind stress resulted in persistent convergence of the ice flow against the northern coasts of Canada and Greenland and in the formation of a large thickness anomaly north of Greenland. The anomaly then feeds the Fram Strait ice flow during those following winter months when the local wind forcing in the strait favours ice drift from the north-west. Our results suggest that short-term wind stress variations resulting in local thickness changes to the north of Fram Strait can lead to substantial variability of the Fram Strait ice export.  相似文献   

Traceurs sédimentaires des variations du niveau marin et de la mousson sud-est asiatique depuis 450 ka en mer de Chine du Sud     

Sbastien Boulay  Christophe Colin  Alain Trentesaux 《Comptes Rendus Geoscience》2008,340(6):367-378

In order to reconstruct the past variations of the Southeast Asian monsoon intensity and estimate the sedimentary system reactivity to climatic changes in Southeast Asia over the last 450 kyr, mineralogical and sedimentological analyses have been performed on the terrigenous fraction of the South China Sea sediment. End-member modelling coupled with grain size data discriminates three end-members that determine the nature and intensity of the main sediment transport vectors. Low sea-level stands are characterized by sediment reworking that allows transportation of a coarse end-member (20–40 μm) to the deep-basin. By contrast, the other end-members (4–6 μm; 9–13 μm) are controlled by the shoreline position (sea level) and/or by changes of the rivers capacity transport (monsoon). Finally, aeolian input to the northern margin of the South China Sea can be considered negligible compared to the massive fluvial input and the reworking of the sediments.  相似文献   

Tracking past mining activity using trace metals,lead isotopes and compositional data analysis of a sediment core from Longemer Lake,Vosges Mountains,France     

Anne-Lise Mariet  Fabrice Monna  Frédéric Gimbert  Carole Bégeot  Christophe Cloquet  Simon Belle  Laurent Millet  Damien Rius  Anne-Véronique Walter-Simonnet 《Journal of Paleolimnology》2018,60(3):399-412

A 157-cm-long sediment core from Longemer Lake in the Vosges Mountains of France spans the past two millennia and was analyzed for trace metal content and lead isotope composition. Trace metal accumulation rates highlight three main input phases: Roman Times (cal. 100 BC–AD 400), the Middle Ages (cal. AD 1000–1500), and the twentieth century. Atmospheric contamination displays a pattern that is similar to that seen in peat bogs from the region, at least until the eighteenth century. Thereafter, the lake sediment record is more precise than peat records. Some regional mining activity, such as that in archaeologically identified eighteenth-century mining districts, was detected from the lead isotope composition of sediment samples. Compositional data analysis, using six trace metals (silver, arsenic, cadmium, copper, lead and zinc), enabled us to distinguish between background conditions, periods of mining, and of other anthropogenic trace metal emissions, such as the recent use of leaded gasoline.  相似文献   

Towards a microzonation of the Greater Beirut area: an instrumental approach combining earthquake and ambient vibration recordings     

Marleine Brax  Pierre-Yves Bard  Anne-Marie Duval  Etienne Bertrand  Muhsin-Elie Rahhal  Rachid Jomaa  Cécile Cornou  Christophe Voisin  Alexandre Sursock 《Bulletin of Earthquake Engineering》2018,16(12):5735-5767

Lebanon is situated on the 1000 km long Levant transform fault that separates the Arabic from the African tectonic plates. In Lebanon, the Levant fault splits up into a set of ramifications that had, in the past, generated major destructive earthquakes causing a lot of destruction and thousands of casualties. The most devastating one was the 551 A.D. offshore earthquake that destroyed Beirut, the capital of Lebanon. This paper presents a site effect study in Beirut, aimed at proposing a framework for future microzonation works in the city. It includes two complementary parts. A 6-month, temporary seismological experiment was first conducted to estimate the site response at 10 sites sampling the main geological units of Beirut on the basis of local and regional earthquake recordings. This spatially sparse information was then complemented by a large number (615) of microtremor measurements covering the Beirut municipality and part of its suburbs with a 400 m dense grid. The recordings were analysed with the standard site-to-reference and horizontal-to-vertical spectral ratio methods for earthquake recordings, and the horizontal-to-vertical ratio for ambient noise recordings. Significant ground motion amplification effects (up to a factor of 8) are found in a few areas corresponding to recent deposits. The consistency between results from earthquake and microtremor recordings allows proposing a map of the resonance frequencies within the city and its suburbs, with frequencies ranging from 0.5 to 5 Hz for the deepest deposits, and 5–10 Hz for shallow areas. Finally, the results are discussed and a way to combine the results obtained from the temporary stations to the great number of recordings coming from the permanent Lebanese network is proposed.  相似文献   

Net rainfall estimation by the inversion of a geomorphology-based transfer function and discharge deconvolution     

Houda Boudhraâ  Christophe Cudennec  Hervé Andrieu  Mohamed Slimani 《水文科学杂志》2018,63(2):285-301

The assessment of net rainfall, defined as the intermediate hydrological variable linked in between the hillslope and the river network, is a challenge. This paper presents a method for net rainfall estimation, using inverse modelling associated to a geomorphology-based transfer function. The analysis is carried out in semi-arid Tunisia, with a dataset from event discharges in a mesoscale dryland basin. A complete sensitivity analysis is developed, along with a discussion of validity limits for simplifying assumptions and the identification of paths for improvement. This work could be relevant for data-scarce areas, thanks to the use of simple dynamic conceptualization and being based on observable geomorphological features, adjusted to the available data and knowledge.  相似文献   

Identification and Explanation of a Change in the Groundwater Regime using Time Series Analysis     

Christophe Obergfell  Mark Bakker  Kees Maas 《Ground water》2019,57(6):886-894

Time series analysis is applied to identify and analyze a transition in the groundwater regime in the aquifer below the sand ridge of Salland in the Netherlands, where groundwater regime refers to the range of head variations throughout the seasons. Standard time series analysis revealed a discrepancy between modeled and observed heads in several piezometers indicating a possible change in the groundwater regime. A new time series modeling approach is developed to simulate the transition from the initial regime to the altered regime. The transition is modeled as a weighted sum of two responses, one representing the initial state of the system, the other representing the altered state. The inferred timing and magnitude of the change provided strong evidence that the transition was the result of significant dredging works that increased the river bed conductance of the main river draining the aquifer. The plausibility of this explanation is corroborated by an analytical model. This case study and the developed approach to identify a change in the groundwater regime are meant to stimulate a more systematic application of time series analysis to detect and understand changes in groundwater systems which may easily go unnoticed in groundwater flow modeling.  相似文献   

Changes in carbon and nutrient fluxes from headwaters to ocean in a mountainous temperate to subtropical basin          下载免费PDF全文

Macdex Mutema  Pauline Chivenge  Fantine Nivet  Christophe Rabouille  Vincent Thieu  Vincent Chaplot 《地球表面变化过程与地形》2017,42(13):2038-2053

Water erosion provides major links in global cycles of carbon (C), nitrogen (N) and phosphorus (P). Although significant research on erosion mechanisms has been done, there is still little knowledge on C, N and P fluxes across landscapes to the ocean and their controlling factors in subtropical climates. A four‐year study quantifying and comparing particulate and dissolved C, N and P from multiple scales (microplot, plot, microcatchment, subcatchment, catchment, sub‐basin and basin) was performed in Thukela basin (≈30 000 km²), South Africa. The basin climate was largely subtropical‐humid [mean annual precipitation (MAP) > 980 mm yr^‐1], but temperate (MAP >2000 mm yr^‐1) on the highlands. Open grassland, cropland and bushland were the major land uses. On average, 65, 24 and 4 g m^‐2 yr^‐1 C, N and P were displaced from original topsoil positions, but only 0.33, 0.005 and 0.002 mg m^‐2 yr^‐1 were, respectively, exported to the ocean. The fluxes decreased by 95, 97 and 84%, respectively, from plot to microcatchment outlet; and decreased further in downstream direction by >99% from microcatchment to basin outlet. The hillslope (microplot to microcatchment) fluxes correlated strongly with rainfall parameters. Particulate contributions dominated hillslope fluxes at 73, 81 and 76% of total annual C, N and P, respectively. Although particulate C dominated in the microcatchment‐catchment reach (55%), N (54%) and P (69%) were dominated by dissolved forms. The lower basin zone was dominated by dissolved flux contributions at 93, 81 and 78% for C, N and P for the sub‐basin outlet. These results suggested spatially varying drivers of C, N and P losses from the landscape to the ocean, via the river network. Deposition was envisaged the dominant hillslope level loss process, which gradually gave way to mineralization and biotic uptake in the river network as flux contributions shifted from being predominantly particulate to dissolved forms. Copyright © 2017 John Wiley & Sons, Ltd.  相似文献