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101.
Eric H. Oelkers Sergey V. Golubev Claire Chairat Oleg S. Pokrovsky Jacques Schott 《Geochimica et cosmochimica acta》2009,73(16):4617-6554
The surface chemistry of natural wollastonite, diopside, enstatite, forsterite, and albite in aqueous solutions was characterized using both electrokinetic techniques and surface titrations performed for 20 min in batch reactors. Titrations performed in such reactors allow determination of both proton consumption and metal release from the mineral surface as a function of pH. The compositions, based on aqueous solution analysis, of all investigated surfaces vary dramatically with solution pH. Ca and Mg are preferentially released from the surfaces of all investigated divalent metal silicates at pH less than ∼8.5-10 but preferentially retained relative to silica at higher pH. As such, the surfaces of these minerals are Si-rich and divalent metal poor except in strongly alkaline solutions. The preferential removal of divalent cations from these surfaces is coupled to proton consumption. The number of protons consumed by the preferential removal of each divalent cation is pH independent but depends on the identity of the mineral; ∼1.5 protons are consumed by the preferential removal of each Ca atom from wollastonite, ∼3 protons are consumed by the preferential removal of each Mg or Ca atom from diopside or enstatite, and ∼4 protons are consumed by the preferential removal of each Mg from forsterite. These observations are interpreted to stem from the creation of additional ‘internal’ adsorption sites by the preferential removal of divalent metal cations which can be coupled to the condensation of partially detached Si. Similarly, Na and Al are preferentially removed from the albite surface at 2 > pH > 11; mass balance calculations suggest that three protons are consumed by the preferential removal of each Al atom from this surface over this entire pH range. Electrokinetic measurements on fresh mineral powders yield an isoelectric point (pHIEP) 2.6, 4.4, 3.0, 4.5, and <1, for wollastonite, diopside, enstatite, forsterite, and albite, respectively, consistent with the predominance of SiO2 in the surface layer of all of these multi-oxide silicates at acidic pH. Taken together, these observations suggest fundamental differences between the surface chemistry of simple versus multi-oxide minerals including (1) a dependency of the number and identity of multi-oxide silicate surface sites on the aqueous solution composition, and (2) the dominant role of metal-proton exchange reactions on the reactivity of multi-oxide mineral surfaces including their dissolution rate variation with aqueous solution composition. 相似文献
102.
Jean-Alix Barrat Akira Yamaguchi Richard C. Greenwood Claire Bollinger Marcel Bohn Ian A. Franchi 《Geochimica et cosmochimica acta》2009,73(19):5944-5958
The howardite–eucrite–diogenite (HED) achondrites are a group of meteorites that probably originate from the asteroid Vesta. Howardites are complex polymict breccias that sometimes contain, in addition to various rock debris, impact melt glasses which show an impressive range of compositions. In this paper we report on the geochemistry and O isotopes of a series of 6 Saharan polymict breccias (4 howardites and 2 polymict eucrites), and on the trace element abundances of high-K impact spherules found in two of them, Northwest Africa (NWA) 1664 and 1769, which are likely paired.The high-K impact spherules found in the howardites NWA 1664 and NWA 1769 display remarkable trace element patterns. Compared to eucrites or howardites, they all show prominent enrichments in Cs, Rb, K, Li and Ba, strong depletion in Na, while the REE and other refractory elements are unfractionated. These features could not have been generated during impact melting of their host howardites, nor other normal HED target materials. The involvement of Na-poor rocks, and possibly rocks of granitic composition, appears likely. Although these lithologies cannot be well constrained at present, our results demonstrate that the surface of Vesta is certainly more diverse than previously thought. Indeed, despite the large number of available HED meteorites (about 1000 different meteorites), the latter are probably not sufficient to describe the whole surface of their parent body. 相似文献
103.
The Pacific oyster (Crassostrea gigas) was introduced into Strangford Lough, Northern Ireland in the 1970s. It was assumed that local environmental conditions would not facilitate successful reproduction. However, in the 1990s there were reports of C. gigas outside licensed aquaculture sites and this investigation set out to ascertain the current distribution, years of likely recruitment and population structure of the species. C. gigas were found distributed widely throughout the northern basin during surveys; the frequency distribution suggesting C. gigas is not recruiting every year. Establishment of feral populations of C. gigas elsewhere have linked to habitat change. A pilot cull was initiated to assess the success rate of early intervention. This paper demonstrates the potential benefits of responding rapidly to initial reports of non-native species in a way that may curtail establishment and expansion. The method advocated in simple and can be recommended to the appropriate regulatory authorities. 相似文献
104.
Francesca Cigna Hannah Jordan Luke Bateson Harry McCormack Claire Roberts 《Pure and Applied Geophysics》2015,172(11):2965-2995
105.
A detailed field study was carried out on a tidal bore to document the turbulent processes and sediment entrainment which occurred. The measured bore, within the Arcins Channel of the Garonne River (France), was undular in nature and was followed by well‐defined secondary wave motion. Due to the local river geometry a collision between the Arcins channel tidal bore and the bore which formed within the main Garonne River channel was observed about 800 m upstream of the sampling site. This bore collision generated a transient standing wave with a black water mixing zone. Following this collision the bore from the main Garonne River channel propagated ‘backward’ to the downstream end of the Arcins channel. Velocity measurements with a fine temporal resolution were complemented by measurements of the sediment concentration and river level. The instantaneous velocity data indicated large and rapid fluctuations of all velocity components during the tidal bore. Large Reynolds shear stresses were observed during and after the tidal bore passage, including during the 'backward' bore propagation. Large suspended sediment concentration estimates were recorded and the suspended sediment flux data showed some substantial sediment motion, consistent with the murky appearance of the flood tide waters. Copyright © 2015 John Wiley & Sons, Ltd. 相似文献
106.
Eric Bardou Guillaume Favre‐Bulle Claire Faucheux Nicolas Jeannée Pascal Ornstein 《地球表面变化过程与地形》2015,40(9):1191-1201
Complex para‐glacial systems may show signs of destabilization leading to frequent and potentially hazardous debris‐flows. Understanding creeping permafrost displacement over a period of time is therefore crucial for hazard management and risks assessment. This paper presents our methodology for estimating creeping permafrost displacement based upon data derived from various survey methods and demonstrates its relevance on the Glacier Bonnard system in southern Switzerland. Geostatistical processing allowed estimation of the displacement intensity over the area of interest, as well as assessment of the interpolation quality. Although the local measurement network needs to be refined, the results largely improve the understanding of the Bonnard para‐glacial system, though highlighting the need to locally refine the measurement network. In the present case, the destabilized front advances at ~1 m/a and the upstream creeping part at ~0.4 m/a. Variance analysis also provide objective thresholds that could be used to distinguish underlying physical processes. Copyright © 2015 John Wiley & Sons, Ltd. 相似文献
107.
William F. Kenney Mark Brenner Jason H. Curtis Claire L. Schelske 《Journal of Paleolimnology》2010,44(4):1039-1052
We analyzed 210Pb-dated sediment cores from four relatively shallow lakes (zmax < 10 m) in the Upper Ocklawaha River Basin, Florida, USA to compare primary producer community structure before and after
anthropogenic impacts. We measured physical and chemical sediment variables including density, organic matter (OM), water-soluble
phosphorus, polyphosphate (Poly-P), total P (TP), total carbon to total nitrogen mass ratios of OM (TC:TN), biogenic silica
(diatoms, sponge spicules), total amorphous silica, and stable carbon and nitrogen isotope ratios of bulk OM. Principal component
analysis showed that diatom biogenic silica, TC:TN, Poly-P and TP displayed discernible stratigraphic changes associated with
the shift in the primary producer community. We applied k-means cluster analysis to these variables to identify macrophyte-derived,
transitional, and phytoplankton-derived sediments. Our approach provides an objective method for identifying sediment sources
that may be applied to shallow lakes in other regions. The four study lakes shifted from a macrophyte-dominated state to a
transitional state before major anthropogenic disturbances, and became phytoplankton-dominated after ~1950. 相似文献
108.
Catherine O. de Burgh-Day Claire M. Spillman Craig Stevens Oscar Alves Graham Rickard 《新西兰海洋与淡水研究杂志》2019,53(2):201-221
We present a first assessment of the Sea Surface Temperature (SST) and 300m Heat Content (HC) ensemble mean skill of the Australian Community Climate and Earth-System Simulator-Seasonal v1.0 (ACCESS-S1) around New Zealand on seasonal timescales, using a set of retrospective ensemble forecasts for 1990-2012. This was verified against Reynolds AVHRR analysis and Bluelink ReANalysis 3.5 (BRAN3.5). For inshore areas with depth <300m, the model shows skill forecasting for summer at a lead time of 0 months, with 66% and 65% of model grid cells having correlation coefficients exceeding 0.6 for SST and 300m HC respectively. Regions of lower skill seem to be associated with the model representation of the complex and variable frontal systems around New Zealand, and an overly-strong response to the El Niño Southern-Oscillation (ENSO). Nevertheless, the skill of ACCESS-S1 around New Zealand suggests there is potential for the development of useful seasonal forecast products for the region. 相似文献
109.
110.
We present the first demonstration of hydraulic tomography (HT) to estimate the three-dimensional (3D) hydraulic conductivity (K) distribution of a fractured aquifer at high-resolution field scale (HRFS), including the fracture network and connectivity through it. We invert drawdown data collected from packer-isolated borehole intervals during 42 pumping tests in a wellfield at the former Naval Air Warfare Center, West Trenton, New Jersey, in the Newark Basin. Five additional tests were reserved for a quality check of HT results. We used an equivalent porous medium forward model and geostatistical inversion to estimate 3D K at high resolution (K blocks <1 m3), using no strict assumptions about K variability or fracture statistics. The resulting 3D K estimate ranges from approximately 0.1 (highest-K fractures) to approximately 10−13 m/s (unfractured mudstone). Important estimated features include: (1) a highly fractured zone (HFZ) consisting of a sequence of high-K bedding-plane fractures; (2) a low-K zone that disrupts the HFZ; (3) several secondary fractures of limited extent; and (4) regions of very low-K rock matrix. The 3D K estimate explains complex drawdown behavior observed in the field. Drawdown tracing and particle tracking simulations reveal a 3D fracture network within the estimated K distribution, and connectivity routes through the network. Model fit is best in the shallower part of the wellfield, with high density of observations and tests. The capabilities of HT demonstrated for 3D fractured aquifer characterization at HRFS may support improved in situ remediation for contaminant source zones, and applications in mining, repository assessment, or geotechnical engineering. 相似文献