Comparative studies of the kinetic parameters of various algaenans and kerogens via open-system pyrolyses     

Daniel Dessort  Jacques Connan  Sylvie Derenne  Claude Largeau 《Organic Geochemistry》1997,26(11-12)

Kinetic parameters were determined for the first time, via open-system pyrolyses, on algaenans (highly resistant biomacromolecules that are selectively preserved during kerogen formation) isolated from extant microalgae. Parallel studies were also carried out on 10 kerogens exhibiting, with one exception, a low level of maturity. These kerogens included samples chiefly derived from the selective preservation of the above algaenans and samples mainly, or almost exclusively, derived from the “natural vulcanization” pathway. Important differences in activation energy (E_a) distributions were observed between the four algaenans investigated and correlated with their chemical structures. The kerogens predominantly derived from algaenan-selective preservation (Pula alginite, NE 70 and BJ 248 Torbanites, Rundle Oil Shale) also exhibited pronounced differences in E_a distributions. These distributions provided: (i) information on the diversity of the source materials; and (ii) reflected the occurrence of important differences in chemical structures and thermal behaviour between three of the tested kerogens, even though they are all classified as low maturity type I. The Kimmeridge Clay samples and the Lorca Oil Shale showed broad E_a distributions shifted to low energies when compared with the above algaenans and kerogens. Such shifts reflect an important (or even almost exclusive for some of these kerogens) contribution of materials originating from sulphur incorporation into various lipids during early diagenesis. Finally, the kinetic data derived for the nine low maturity fossil samples were extrapolated to a very low, geological heating rate of 3°C Ma⁻¹ and the generation rate curves and cumulative yield curves thus obtained were compared.  相似文献   

Osmium-strontium-neodymium-lead isotopic covariations in mid-ocean ridge basalt glasses and the heterogeneity of the upper mantle   总被引：4，自引：0，他引：4  

Pierre Schiano  Jean-Louis Birck  Claude J. Allgre 《Earth and Planetary Science Letters》1997,150(3-4):363-379

Osmium, strontium, neodymium, and lead isotopic data have been obtained for 30 hand picked samples of basaltic glass from the Pacific, Atlantic and Indian mid-oceanic ridges. Large variations in Os isotopic ratios exist in the glasses, from abyssal peridotite-like values to radiogenic compositions similar to oceanic island basalts (¹⁸⁷Os/¹⁸⁶Os and ¹⁸⁷Os/¹⁸⁸Os ratios range from 1.06 to 1.36 and from 0.128 to 0.163, respectively). Os isotopic and elemental data suggest the existence of mixing correlations. This relationship might be ascribed to secondary contamination processes; however, such a hypothesis cannot account for the negative correlation observed between Os and Nd isotopes and the existence of complementary covariations between Os and SrPb isotopes. In this case, OsSrNdPb isotopic variations are unrelated to late post-eruption or shallow level contamination. These relationships provide strong evidence that the Os isotopic composition of the samples are derived from the mantle and thus implies a global chemical heterogeneity of the oceanic upper mantle. The results are consistent with the presence of recycled oceanic crust in the mantle sources of mid-ocean ridge basalts, and indicate that the unique composition of the upper mantle below the Indian ocean results from its contamination by a mantle component characterized by radiogenic Os and particularly unradiogenic Nd and Pb isotopic compositions.  相似文献   

Aerosol polarized phase function and single-scattering albedo retrieved from ground-based measurements     

Zhengqiang Li  Philippe Goloub  Claude Devaux  Xingfa Gu  Yanli Qiao  Fengsheng Zhao  Hongbin Chen 《Atmospheric Research》2004,71(4):233-241

Aerosol optical parameters, polarized phase function and single-scattering albdeo, have been retrieved from ground-based sun photometer measurements in Beijing 2003. The measured aerosol optical thickness varies from 0.12 to 0.77 with an average value of 0.39. The measured Ångström coefficient ranges from 0.75 to 1.47 with an average value of 1.21. The retrieved single-scattering albedo at 870 nm is within the 0.76–0.94 range and the average value is 0.85, suggests there are considerable aerosol absorptions in Beijing. The maximum value of retrieved polarized phase function at 870 nm ranges from 0.068 to 0.225 with an average value of 0.16, and it illustrates good correlations with the Ångström coefficient, i.e. the relative size of aerosol particles. Analyses of measurements and theoretical calculations show the polarized phase function is sensitive to aerosol size distribution and complex refractive index, especially the imaginary part of the refractive index which denotes aerosol light absorbing effects. These results suggest that the polarized phase function is an effective and unique aerosol optical parameter and is able to improve the retrieval of aerosol physical properties.  相似文献   

Effects of Greenhouse Gas Emissions on World Agriculture, Food Consumption, and Economic Welfare     

Roy Darwin 《Climatic change》2004,66(1-2):191-238

Because of many uncertainties, quantitative estimates of agriculturally related economic impacts of greenhouse gas emissions are often given low confidence. A major source of uncertainty is our inability to accurately project future changes in economic activity, emissions, and climate. This paper focuses on two issues. First, to what extent do variable projections of climate generate uncertainty in agriculturally related economic impacts? Second, to what extent do agriculturally related economic impacts of greenhouse gas emissions depend on economic conditions at the time of impacts? Results indicate that uncertainty due to variable projections of climate is fairly large for most of the economic effects evaluated in this analysis. Results also indicate that economic conditions at the time of impact influence the direction and size of as well as the confidence in the economic effects of identical projections of greenhouse gas impacts. The economic variable that behaves most consistently in this analysis is world crop production. Increases in mean global temperature, for example, cause world crop production to decrease on average under both 1990 and improved economic conditions and in both instances the confidence with respect to variable projections of climate is medium (e.g.,67%) or greater. In addition and as expected, CO₂ fertilization causesworld crop production to increase on average under 1990 and improved economic conditions. These results suggest that crop production may be a fairly robust indicator of the potential impacts of greenhouse gas emissions.A somewhat unexpected finding is that improved economic conditions are not necessarily a panacea to potential greenhouse-gas-induced damages, particularly at the region level. In fact, in some regions, impacts of climate change or CO₂ fertilization that are beneficial undercurrent economic conditions may be detrimental under improved economic conditions (relative to the new economic base). Australia plus New Zealand suffer from this effect in this analysis because under improved economic conditions they are assumed to obtain a relatively large share of income from agricultural exports. When the climate-change and CO₂-fertilization scenariosin this analysis are also included, agricultural exports from Australia plus New Zealand decline on average. The resultant declines in agricultural income in Australia plus New Zealand are too large to be completely offset by rising incomes in other sectors. This indicates that regions that rely on agricultural exports for relatively large shares of their income may be vulnerable not only to direct climate-induced agricultural damages, but also to positive impacts induced by greenhouse gas emissions elsewhere.  相似文献   

Geological controls on rock mass classification of coal from Huntly East Mine, New Zealand     

Vicki Moon  Trisha Roy 《Engineering Geology》2004,75(2):201-213

Rock Mass Rating (RMR) measurements from 65 sites within Huntly East underground coal mine are presented. All measurements are in coal, for which the dominant discontinuities are vertical cleat. Basic RMR values using two discontinuity spacings are presented: overall RMR based on the average spacing of all individual discontinuities; and cleat zone RMR based on the average spacing between zones of cleat. Cleat orientations are highly variable, but on average approximately parallel horizontal stress axes (face cleat follows maximum horizontal stress axis, butt cleat follows minimum horizontal stress axis).Contours of RMR variations throughout the mine are used to compare rock mass conditions with geological structure. It is apparent that: (1) RMR is least within downthrown fault blocks, and particularly immediately on the downthrown sides of faults, and greatest in upthrown fault blocks; and (2) RMR contours parallel horizontal stress axes within fault-bounded blocks, and bend to parallel faults at block boundaries. From similar contours for parameters contributing to RMR, the Rock Quality Designation (RQD), groundwater rating, and discontinuity condition rating create most of the observed variations in RMR. RQD is determined from the measured discontinuity frequency and hence is a measure of the degree of fracturing of the rock mass. This is interpreted as influencing the groundwater and condition parameters directly by allowing greater water ingress. Discontinuity frequency is greatest (least spacing) in the immediate vicinity of faults, and in downthrown fault blocks, generating low RMR values. Within fault blocks RQD varies little, so RMR contours align with cleat orientations.As RMR contours, faults, stress field and cleat orientation are clearly interrelated, there is unequivocally a connection between RMR and structural geology; this allows some predictive capacity in terms of ground conditions. If geological features can be accurately defined through either drilling programs or seismic surveys, then ground conditions may be predicted before panels are driven.  相似文献   

Nouvelle interprétation structurale de la « faille Nord- Pyrénéenne » en vallée d'Aspe (Pyrénées-Atlantiques). Remise en question d'un plutonisme ophitique danien dans le secteur de Bedous     

Joseph Canérot  Claude Majesté-Menjoulas  Yves Ternet 《Comptes Rendus Geoscience》2004,336(2):135-142

In the Aspe Valley (western Pyrenees), the Europe/Iberia boundary corresponds to a complex fracturing zone, called the ‘Bielle–Accous Wrench-Faulting Corridor’, which represents the classical ‘North-Pyrenean Fault’. Located between the High Primary Range and the North-Pyrenean Zone, the BAWC shows different south-verging sheets mainly composed of Triassic materials. The Bedous ophite, associated with Muschelkalk and Keuper sediments, is also Triassic in age and involved in the same Pyrenean thrusting structures. So, contrary to a recent interpretation, this magmatic rock cannot be related to a supposed Danian plutonism inducing metamorphic processes in the surrounding Mesozoic formations. To cite this article: J. Canérot et al., C. R. Geoscience 336 (2004).  相似文献   

L'archivage des activités humaines par les neiges et glaces polaires : le cas du plomb     

Claude Boutron  Kevin Rosman  Carlo Barbante  Michael Bolshov  Freddy Adams  Sungmin Hong  Christophe Ferrari 《Comptes Rendus Geoscience》2004,336(10):847-867

The investigation of the occurrence of lead in dated snow and ice from Greenland and Antarctica has played a major role in our understanding of the history of the pollution of the atmosphere of our planet by this metal. Such studies have however proved to be very demanding, mainly because of the extreme purity of polar snow and ice. Reliable measurements can be obtained only if ultra-clean and highly sensitive procedures are used, as pioneered by Clair Patterson. The Greenland data show evidence of large-scale pollution of the atmosphere of the Northern Hemisphere for lead as early as two millennia ago during Greco–Roman times, especially because of mining and smelting activities in southern Spain. It peaked at the end of the 1960s, with lead concentrations in snow about 200 times higher than natural values, before declining during recent times because of the fall in the use of leaded gasoline. Lead pollution in Antarctica was already significant at the end of the 19th century as a consequence of whaling activities, the traffic of coal-powered ships crossing the Cape Horn, and mining activities in South America, South Africa and Australia. After declining because of the opening of the Panama Canal, the great economic depression and World War II, it reached a maximum during the 1980s, with lead concentrations 20 times higher than natural values. Other studies focus on past natural variations of lead in ancient ice dated from the last climatic cycles. To cite this article: C. Boutron et al., C. R. Geoscience 336 (2004).  相似文献   

Analysis of earth dams affected by the 2001 Bhuj Earthquake   总被引：3，自引：0，他引：3  

Raghvendra Singh  Debasis Roy  Sudhir K. Jain   《Engineering Geology》2005,80(3-4):282-291

An earthquake of magnitude of 7.6 (M_w 7.6) occurred in Bhuj, India on January 26, 2001. This event inflicted damages of varying extents to a large number of small to moderate size multi-zone earth dams in the vicinity of the epicenter. Some of the distress was due to the liquefaction of saturated alluvium in foundation. Liquefaction was relatively localized for the majority of these dams because the earthquake struck in the middle of a prolonged dry season when the reservoirs behind these dams were nearly empty and shallow alluvium soils underneath the downstream portions of the dams were partly dry. Otherwise, liquefaction of foundation soils would have been more extensive and damage to these dams more significant. Six such dams have been examined in this paper. Four of these facilities, Chang, Shivlakha, Suvi, and Tapar were within the 50 km of epicenter region. These dams underwent free-field ground motion with peak ground accelerations between 0.28g to 0.52g. Of these Chang Dam underwent severe slumping, whereas Shivlakha, Suvi, and Tapar Dams were affected severely especially over the upstream sections. Fatehgadh Dam and Kaswati Dam were affected relatively less severely. Foundation conditions underneath these dams were first examined for assessing liquefaction potential. A limited amount of subsurface information available from investigations undertaken prior to the earthquake indicates that, although the foundation soils within the top 2.0 to 2.5 m underneath these dams were susceptible to liquefaction, Bhuj Earthquake did not trigger liquefaction because of lack of saturation of these layers underneath the downstream portions of these dams. These dams were then analyzed using a simple sliding block procedure using appropriate estimates of undrained soil strength parameters. The results of this analysis for these structures were found to be in general agreement with the observed deformation patterns.  相似文献   

Applications géodésiques du système DORIS à l'Institut géographique national     

Pascal Willis  Claude Boucher  Hervé Fagard  Zuheir Altamimi 《Comptes Rendus Geoscience》2005,337(7):653-662

IGN is in charge of the installation and maintenance of the DORIS orbit determination network. More recently, in collaboration with JPL, precise geodetic computations were performed. The goal of this paper is to recall the various historic contributions of IGN to the DORIS system in their international context and then to describe a new estimation technique developed for a multi-satellite mode, making full profit of a better modeling for satellites and ground clocks as well as tropospheric correction parameters. Derived geodetic results demonstrate a precision in the order of 1 cm for station positions. To cite this article: P. Willis et al., C. R. Geoscience 337 (2005).  相似文献   

Riddle of arsenic in groundwater of Bengal Delta Plain—role of non-inland source and redox traps     

D. Chatterjee  R. K. Roy  B. B. Basu 《Environmental Geology》2005,49(2):188-206

In the Bengal Delta Plain (BDP) the primary arsenic sourcing appears to be different from the global scenario. Here, the Terminal Pleistocene–Holocene depositional platform, the interactive early Holocene depositional morphology with fluvio-estuarine and marine incursions played a crucial role for arsenic sourcing and enrichment. The lenticular silt-fine sand layer between anoxic clay beds favoured entrapment of dissolved organic carbon with decayed phyto-planktons debris. The Terminal Pleistocene–Holocene transgression and regression processes may have acted as major events in the BDP. Interestingly, at the end of the last glacial maxima, the Pleistocene delta had undergone block movements, wherein some parts of the platform were raised above the level of Holocene deposition. Those blocks were found to be free from arsenic in the groundwater. The sea, during re-emerging inundation (10–7 ka BP), has witnessed a monsoon-induced environment in the BDP with the resultant oscillation of sea level leading to higher upsurge towards the north. This might have resulted in the marine incursion and inundation in pre-existing land depressions. Meanwhile arsenic entrapments through marine incursion as well as enrichment in the presence of organic carbon/DOC and/or Fe/Mn/Al catalytic agents could have developed into localised redox traps. It may be of relevance that due to the repetitive transgressive–regressive phases in Holocene, resulting in periodic exposure and weathering of iron-bearing minerals and consequent iron enrichment in the aquifer system. The iron, thus present, had free charge to host arsenic as a sink. It appears that arsenic, wherever found, would likely be of atypical localised exhaustible phenomenon, both in horizontal and vertical context. It also rationalises the cause of the absence of arsenic in the other nearby Pleistocene platform, which has not come across Holocene interaction and marine incursion, as to the likely limiting condition for the search for arsenic in the BDP or beyond.  相似文献