Incidence of organochlorine pesticides in muscle and liver tissues of South African great white sharks Carcharodon carcharias     

Schlenk D  Sapozhnikova Y  Cliff G 《Marine pollution bulletin》2005,50(2):208-211

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Experimental peridotite–melt reaction at one atmosphere: a textural and chemical study     

Cliff S. J. Shaw  Donald B. Dingwell 《Contributions to Mineralogy and Petrology》2008,155(2):199-214

Sieve-textured clinopyroxene and spinel are common in mantle xenoliths and have been interpreted to be the result of partial melting, mantle metasomatism and host magma–xenolith reaction during transport. In this paper, we test the latter hypothesis with a series of reduced and oxidized experiments at 1,200 and 1,156°C at one atmosphere using a synthetic leucitite melt and discs of natural peridotite. Our results show that sieve texture development on clinopyroxene and spinel in mantle xenoliths is the result of a multistage reaction process. In the first step, orthopyroxene undergoes incongruent dissolution to produce a silica and alkali-rich melt together with olivine. As this melt migrates along grain boundaries it causes incongruent dissolution of clinopyroxene and spinel. The incongruent dissolution mechanism involves complete dissolution of the clinopyroxene or spinel followed by nucleation and growth of a secondary clinopyroxene or spinel once the reacting melt is saturated. The reaction of orthopyroxene, clinopyroxene and spinel with infiltrated host magma results in a range of melt compositions that are very similar to those interpreted to be due to very small degrees of partial melting. Electronic supplementary material The online version of this article (doi:) contains supplementary material, which is available to authorized users.  相似文献   

The High Deccan duricrusts of India and their significance for the ‘laterite’ issue   总被引：1，自引：1，他引：0  

Cliff D. Ollier  Hetu C. Sheth 《Journal of Earth System Science》2008,117(5):537-551

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Large wood distribution,mobility, and recruitment in an inter‐dam river reach: A comparison with geomorphic process on the Garrison Reach of the Missouri River pre and post the historical 2011 flood          下载免费PDF全文

Edward R. Schenk  Adam J. Benthem  Mark D. Dixon  Melissa Mittelman  Katherine J. Skalak  Cliff R. Hupp  Joel M. Galloway  Rochelle A. Nustad 《地球表面变化过程与地形》2018,43(8):1677-1688

This study assessed the effect of the largest flood since dam regulation on geomorphic and large wood (LW) trends using LW distributions at three time periods on the 150 km long Garrison Reach of the Missouri River. In 2011, a flood exceeded 4390 m³/s for a two‐week period (705% above mean flow; 500 year flood). LW was measured using high resolution satellite imagery in summer 2010 and 2012. Ancillary data including forest character, vegetation cover, lateral bank retreat, and channel capacity. Lateral bank erosion removed approximately 7400 standing trees during the flood. Other mechanisms, that could account for the other two‐thirds of the measured in‐channel LW, include overland flow through floodplains and islands. LW transport was commonly near or over 100 km as indicated by longitudinal forest and bank loss and post‐flood LW distribution. LW concentrations shift at several locations along the river, both pre‐ and post‐flood, and correspond to geomorphic river regions created by the interaction of the Garrison Dam upstream and the Oahe Dam downstream. Areas near the upstream dam experienced proportionally higher rates of bank erosion and forest loss but in‐channel LW decreased, likely due to scouring. A large amount of LW moved during this flood, the chief anchoring mechanism was not bridges or narrow channel reaches but the channel complexity of the river delta created by the downstream reservoir. Areas near the downstream dam experienced bank accretion and large amounts of LW deposition. This study confirms the results of similar work in the Reach: despite a historic flood longitudinal LW and channel trends remain the same. Dam regulation has created a geomorphic and LW pattern that is largely uninterrupted by an unprecedented dam regulation era flood. River managers may require other tools than infrequent high intensity floods to restore geomorphic and LW patterns. Copyright © 2018 John Wiley & Sons, Ltd.  相似文献   

Identification of the Bloody Creek structure,a possible impact crater in southwestern Nova Scotia,Canada     

Ian Spooner  George Stevens  Jared Morrow  Peir Pufahl  Richard Grieve  Rob Raeside  Jean Pilon  Cliff Stanley  Sandra Barr  David McMullin 《Meteoritics & planetary science》2009,44(8):1193-1202

Abstract— An approximately 0.4 km diameter elliptical structure formed in Devonian granite in southwestern Nova Scotia, herein named the Bloody Creek structure (BCS), is identified as a possible impact crater. Evidence for an impact origin is based on integrated geomorphic, geophysical, and petrographic data. A near‐continuous geomorphic rim and a 10 m deep crater that is infilled with lacustrine sediments and peat define the BCS. Ground penetrating radar shows that the crater has a depressed inner floor that is sharply ringed by a 1 m high buried scarp. Heterogeneous material under the floor, interpreted as deposits from collapse of the transient cavity walls, is overlain by stratified and faulted lacustrine and wetland sediments. Alteration features found only in rim rocks include common grain comminution, polymict lithic microbreccias, kink‐banded feldspar and biotite, single and multiple sets of closely spaced planar microstructures (PMs) in quartz and feldspar, and quartz mosaicism, rare reduced mineral birefringence, and chlorite showing plastic deformation and flow microtextures. Based on their form and crystallographic orientations, the quartz PMs consist of planar deformation features that document shock‐metamorphic pressures ≤25 GPa. The age of the BCS is not determined. The low depth to diameter ratio of the crater, coupled with anomalously high shock‐metamorphic pressures recorded at its exposed rim, may be a result of significant post‐impact erosion. Alternatively, impact onto glacier ice during the waning stages of Wisconsinian deglaciation (about 12 ka BP) may have resulted in dissipation of much impact energy into the ice, resulting in the present morphology of the BCS.  相似文献   

The golden ark: arsenopyrite crystal plasticity and the retention of gold through high strain and metamorphism          下载免费PDF全文

Denis Fougerouse  Steven Micklethwaite  Angela Halfpenny  Steven M. Reddy  John B. Cliff  Laure A. J. Martin  Matt Kilburn  Paul Guagliardo  Stanislav Ulrich 《地学学报》2016,28(3):181-187

Quantitative electron backscatter diffraction analysis and ion microprobe imaging of gold‐rich arsenopyrites provide the first insights into the crystal plasticity and element mobility behaviour of arsenopyrites through metamorphism (340°–460° and 2 kbar). Remarkably, the gold‐rich arsenopyrites remained structurally and chemically robust during high strain deformation. It was only during a superimposed lower strain deformation event, at a high angle to the preferred orientation of the arsenopyrites, that small amounts of crystal plasticity affected the arsenopyrites. During the low strain event, a dissolution–reprecipitation reaction resulted in loss of gold from the crystal lattice, facilitated by localised domains of recrystallisation, most likely due to fluid percolation along sub‐ and new grain boundaries. We suggest that the abundance and rheologically robust nature of gold‐rich arsenopyrite in giant gold deposits, affected by greenschist–amphibolite metamorphism, is actually critical in the preservation of those deposits.  相似文献   

The SOLAS air-sea gas exchange experiment (SAGE) 2004     

Mike J. Harvey  Cliff S. LawMurray J. Smith  Julie A. HallEdward R. Abraham  Craig L. StevensMark G. Hadfield  David T. Ho  Brian Ward  Stephen D. ArcherJill M. Cainey  Kim I. CurrieDawn Devries  Michael J. Ellwood  Peter HillGraham B. Jones  Dave Katz  Jorma KuparinenBurns Macaskill  William Main  Andrew MarrinerJohn McGregor  Craig McNeilPeter J. Minnett  Scott D. NodderJill Peloquin  Stuart PickmereMatthew H. Pinkerton  Karl A. SafiRona Thompson  Matthew WalkingtonSimon W. Wright  Lori A. Ziolkowski 《Deep Sea Research Part II: Topical Studies in Oceanography》2011,58(6):753-763

The SOLAS air-sea gas exchange experiment (SAGE) was a multiple-objective study investigating gas-transfer processes and the influence of iron fertilisation on biologically driven gas exchange in high-nitrate low-silicic acid low-chlorophyll (HNLSiLC) Sub-Antarctic waters characteristic of the expansive subpolar zone of the southern oceans. This paper provides a general introduction and summary of the main experimental findings. The release site was selected from a pre-voyage desktop study of environmental parameters to be in the south-west Bounty Trough (46.5°S 172.5°E) to the south-east of New Zealand and the experiment was conducted between mid-March and mid-April 2004. In common with other mesoscale iron addition experiments (FeAX’s), SAGE was designed as a Lagrangian study, quantifying key biological and physical drivers influencing the air-sea gas exchange processes of CO₂, DMS and other biogenic gases associated with an iron-induced phytoplankton bloom. A dual tracer SF₆/³He release enabled quantification of both the lateral evolution of a labelled volume (patch) of ocean and the air-sea tracer exchange at tenths of kilometer scale, in conjunction with the iron fertilisation. Estimates from the dual-tracer experiment found a quadratic dependency of the gas exchange coefficient on windspeed that is widely applicable and describe air-sea gas exchange in strong wind regimes. Within the patch, local and micrometeorological gas exchange process studies (100 m scale) and physical variables such as near-surface turbulence, temperature microstructure at the interface, wave properties and windspeed were quantified to further assist the development of gas exchange models for high-wind environments.There was a significant increase in the photosynthetic competence (F_v/F_m) of resident phytoplankton within the first day following iron addition, but in contrast to other FeAX’s, rates of net primary production and column-integrated chlorophyll a concentrations had only doubled relative to the unfertilised surrounding waters by the end of the experiment. After 15 days and four iron additions totalling 1.1 ton Fe²⁺, this was a very modest response compared to other mesoscale iron enrichment experiments. An investigation of the factors limiting bloom development considered co-limitation by light and other nutrients, the phytoplankton seed-stock and grazing regulation. Whilst incident light levels and the initial Si:N ratio were the lowest recorded in all FeAXs to date, there was only a small seed-stock of diatoms (less than 1% of biomass) and the main response to iron addition was by the picophytoplankton. A high rate of dilution of the fertilised patch relative to phytoplankton growth rate, the greater than expected depth of the surface mixed layer and microzooplankton grazing were all considered as factors that prevented significant biomass accumulation. In line with the limited response, the enhanced biological draw-down of pCO₂ was small and masked by a general increase in pCO₂ due to mixing with higher pCO₂ waters. The DMS precursor DMSP was kept in check through grazing activity and in contrast to most FeAX’s dissolved dimethylsulfide (DMS) concentration declined through the experiment. SAGE is an important low-end member in the range of responses to iron addition in FeAX’s. In the context of iron fertilisation as a geoengineering tool for atmospheric CO₂ removal, SAGE has clearly demonstrated that a significant proportion of the low iron ocean may not produce a phytoplankton bloom in response to iron addition.  相似文献   

Surface layer mixing during the SAGE ocean fertilization experiment     

Craig Stevens  Brian Ward  Cliff LawMatt Walkington 《Deep Sea Research Part II: Topical Studies in Oceanography》2011,58(6):776-785

Vessel-based observations of the oceanic surface layer during the 14-day 2004 SAGE ocean fertilization experiment were conducted using ADCP, CTD and temperature microstructure in a frame of reference moving with a patch of injected SF₆ tracer. During the experiment the mixed layer depth z_mld ranged between 50 and 80 m, with several re-stratifying events that brought z_mld up to less than 40 m. These re-stratifying events were not directly attributable to local surface-down development of stratification and were more likely associated with horizontal variation in density structure. Comparison between the CTD and a one-dimensional model confirmed that the SAGE experiment was governed by 3-d processes. A new method for estimating z_mld was developed that incorporates a component that is proportional to density gradient. This highlighted the need for well-conditioned near-surface data which are not always available from vessel-based survey CTD profiles. A centred-displacement scale, L_c, equivalent to the Thorpe lengthscale, reached a maximum of 20 m, with the eddy-centroid located at around 40 m depth. Temperature gradient microstructure-derived estimates of the vertical turbulent eddy diffusivity of scalar (temperature) material yielded bin-averaged values around 10⁻³ m² s⁻¹ in the pycnocline rising to over 10⁻² m² s⁻¹ higher in the surface layer. This suggests transport rates of nitrate and silicate at the base of the surface layer generate mixed layer increases of the order of 38 and 13 mmol/m²/day, respectively, during SAGE. However, the variability in measured vertical transport processes highlights the importance of transient events like wind mixing and horizontal intrusions.  相似文献   

Control of the phytoplankton response during the SAGE experiment: A synthesis     

Jill Peloquin  Julie HallKarl Safi  Michael Ellwood  Cliff S. LawKaren Thompson  Jorma KuparinenMichael Harvey  Stuart Pickmere 《Deep Sea Research Part II: Topical Studies in Oceanography》2011,58(6):824-838

The SOLAS Air-Sea Gas Exchange (SAGE) experiment was conducted in Sub-Antarctic waters off the east coast of the South Island of New Zealand in the late summer of 2004. This mesoscale iron enrichment experiment was unique in that chlorophyll a (chl a) and primary productivity were only 2× OUT stations values toward the end of the experiment and this enhancement was due to increased activity of non-diatomaceous species. In addition, this enhancement in activity appeared to occur without a significant build up of particulate organic carbon. Picoeukaryotes (<2 ??m) were the only members of the phytoplankton assemblage that showed a statistically significant increase, a doubling in biomass. To better understand the controls of phytoplankton growth and biomass, we present results from a series of on-deck perturbation experiments conducted during SAGE. Results suggest that the pico-dominated phytoplankton assemblage was only weakly inhibited by iron. Diatoms with high growth rates comprised a small (<1%) fraction of the phytoplankton assemblage, were likely iron limited, and potentially further limited by silicic acid and therefore did not significantly contribute to bloom dynamics. On deck experiments and comparison of SAGE with other iron addition experiments suggested that neither light availability nor deep mixed layers limited phytoplankton growth. Although no substantial increase in grazing rate or specific phytoplankton growth rate was detected, microzooplankton biomass doubled over SAGE as a result of an increase in cell size. The importance of microzooplankton grazing was highlighted by the fact that they were capable of consuming 15-49% of the total phytoplankton production per day. Removal was highest on eukaryotic picophytoplankton production with a mean value of 72% (29-143%). Patch dilution played an important role during SAGE; the mean patch net algal growth:dilution rate, 1.13 (0.4-2.2) was the lowest reported for a mesoscale iron enrichment experiment. Phytoplankton biomass, estimated by chlorophyll a, only accumulated when phytoplankton growth exceeded grazing and when net algal growth exceeded dilution rate. The SAGE results highlight the function of the smallest phytoplankton size fraction described by the ecumenical Iron Hypothesis. Thus, adding iron to HNLC-low silicic acid regions during certain times of the year may simply transfer more carbon through the microbial food web. A primary implication of this study is that any iron-mediated gain in fixed carbon with this set of environmental conditions has a high probability of being recycled in surface waters.  相似文献   

Possible extra-Solar-System cause for certain lunar seismic events     

Cliff Frohlich  Yosio Nakamura 《Icarus》2006,185(1):21-28

Reanalysis of lunar seismic data collected during the Apollo program indicates that 23 of the 28 rare events known as high-frequency teleseismic (HFT) events or shallow moonquakes occurred during one-half of the sidereal month when the seismic network on the Moon's near side faced approximately towards right ascension of 12 h on the celestial sphere. Statistical analysis demonstrates that there is about a 1% probability that this pattern would occur by chance. An alternate possibility is that high-energy objects from a fixed source outside the Solar System trigger or even cause the HFT events.  相似文献