Boron incorporation into mullite     

K. J. Griesser  A. Beran  D. Voll  H. Schneider 《Mineralogy and Petrology》2008,92(3-4):309-320

Summary Boron-doped mullites were synthesized using aluminium nitrate-nonahydrate, tetraethoxysilane and boric acid in a sol–gel process with subsequent annealing at 950 and 1300 °C for five hours. Two different bulk compositions with constant Al₂O₃ contents (60 and 70 mol%, respectively) and varying SiO₂ plus B₂O₃ contents were investigated. X-ray powder diffraction analyses yielded a linear decrease of the lattice parameters with increasing bulk B₂O₃ content, which was interpreted as to be due to boron incorporation. Related to the increasing boron content, corresponding infrared spectra revealed a slight and continuous shift for most of the absorption bands. These data show that mullite is able to incorporate large amounts of boron into its structure (up to about 20 mol% B₂O₃ depending on the bulk composition of the starting materials). Infrared analyses suggest that boron is incorporated into the mullite structure in form of planar three-fold coordinated BO₃ groups. Author’s address: A. Beran, Institut für Mineralogie und Kristallographie, Universit?t Wien-Geozentrum, Althanstra?e 14, 1090 Wien, Austria  相似文献   

A new occurrence of sapphirine-bearing granulite from Podur, Andhra Pradesh, India     

I. N. Sharma  D. Prakash 《Mineralogy and Petrology》2008,92(3-4):415-425

  相似文献   

Methodology of hydrogeological characterization of deep carbonate aquifers as potential reservoirs of groundwater. Case of study: the Jurassic aquifer of <Emphasis Type="Italic">El Maestrazgo</Emphasis> (Castellón,Spain)     

M. Mejías  J. Garcia-Orellana  J. L. Plata  M. Marina  E. Garcia-Solsona  B. Ballesteros  P. Masqué  J. López  C. Fernández-Arrojo 《Environmental Geology》2008,54(3):521-536

A methodology for the characterization of deep carbonate aquifers has been developed and applied to El Maestrazgo Jurassic aquifer in Castellón, Spain. Characterization of these aquifer formations, located at more than 300 m deep, consisted of a previous phase of compilation, analysis and synthesis of the existing information about the area, followed by a coordinated combination of different speciality studies: geology, stratigraphy, structural analysis, hydrogeology, hydrochemistry, geophysics and remote sensing. Geological studies included geological mapping, definition of stratigraphical units and facies and structural analysis. The aim of the hydrogeology study was to define aquifer formations, recharge area, aquifer points inventory and groundwater flow directions for the establishment of piezometric and water quality observation nets. Special techniques were applied, like thermal infrared aerial images and the evaluation of submarine groundwater discharge by means of natural radium isotopes. Hydrochemical techniques, including majority elements characterization and stable isotopes (¹⁸O, ²H and ³H) determination, allowed classifying hydrochemical facies and establishing a renewal pattern for water within the system. Geophysics was useful in determining the aquifer geometry, the features of the basement and the petrophysical characteristics of the geological formations. Preliminary results show an important tectonic complexity and the possibilities for groundwater uses in the area of study.  相似文献   

Natural background levels and threshold values of monitored parameters in the Cambrian-Vendian groundwater body,Estonia     

Andres Marandi  Enn Karro 《Environmental Geology》2008,54(6):1217-1225

The Cambrian-Vendian groundwater body plays an important role in drinking water supply of capital Tallinn and other settlements in northern Estonia. Water quality in this deep-seated confined groundwater body is influenced by the intrusion of present-day seawater and pumping-induced upward migration of deeper saline groundwater. The aim of this study is to evaluate the threshold values applying the methodology worked out within the EU 6th FP project “Background criteria for the identification of groundwater thresholds (BRIDGE)” and to compare the results with the values proposed by local authorities. A database containing 250 monitoring points was completed and used for the calculation of natural background levels (as the 90 and 97.7 percentile) in groundwater. The calculation of threshold values is based on natural background levels and reference values. In case of Cambrian-Vendian groundwater body the receptor is drinking water, thus limit values set by Estonian drinking water standard were used as reference values. The threshold values proposed by local authorities are more or less the same as calculated by BRIDGE methodology. Exceptionally different values are derived in case of chloride and ammonium.  相似文献   

Detection of free vertical convection and double-diffusion in groundwater monitoring wells with geophysical borehole measurements     

Susann Berthold  Frank Börner 《Environmental Geology》2008,54(7):1547-1566

Two algorithms for in-situ detection and identification of vertical free convective and double-diffusive flows in groundwater monitoring wells or boreholes are proposed. With one algorithm the causes (driving forces) and with the other one the effects (convection or double-diffusion) of vertical transport processes can be detected based on geophysical borehole measurements in the water column. Five density-driven flow processes are identified: thermal, solutal, and thermosolutal convection leading to an equalization, as well as saltfingers and diffusive layering leading to an intensification of a vertical density gradient. The occurrence of density-driven transport processes could be proven in many groundwater monitoring wells and boreholes; especially shallow sections of boreholes or groundwater monitoring wells are affected dramatically by such vertical flows. Deep sections are also impaired as the critical threshold for the onset of a density-driven flow is considerably low. In monitoring wells or boreholes, several sections with different types of density-driven vertical flows may exist at the same time. Results from experimental investigations in a medium-scale testing facility with high aspect ratio (height/radius = 19) and from numerical modeling of a water column agree well with paramters of in-situ detected convection cells.  相似文献   

Soil erosion susceptibility assessment and validation using a geostatistical multivariate approach: a test in Southern Sicily   总被引：2，自引：0，他引：2  

Christian Conoscenti  Cipriano Di Maggio  Edoardo Rotigliano 《Natural Hazards》2008,46(3):287-305

A certain number of studies have been carried out in recent years that aim at developing and applying a model capable of assessing water erosion of soil. Some of these have tried to quantitatively evaluate the volumes of soil loss, while others have focused their efforts on the recognition of the areas most prone to water erosion processes. This article presents the results of a research whose objective was that of evaluating water erosion susceptibility in a Sicilian watershed: the Naro river basin. A geomorphological study was carried out to recognize the water erosion landforms and define a set of parameters expressing both the intensity of hydraulic forces and the resistance of rocks/soils. The landforms were mapped and classified according to the dominant process in landsurfaces affected by diffuse or linear water erosion. A GIS layer was obtained by combining six determining factors (bedrock lithology, land use, soil texture, plan curvature, stream power index and slope-length factor) in unique conditions units. A geostatistical multivariate approach was applied by analysing the relationships between the spatial distributions of the erosion landforms and the unique condition units. Particularly, the density of eroded area for each combination of determining factors has been calculated: such function corresponds, in fact, to the conditional probability of erosion landforms to develop, under the same geoenvironmental conditions. In light of the obtained results, a general geomorphologic model for water erosion in the Naro river basin can be depicted: cultivated areas in clayey slopes, having fine-medium soil texture, are the most prone to be eroded; linear or diffuse water erosion processes dominate where the topography is favourable to a convergent or divergent runoff, respectively. For each of the two erosion process types, a susceptibility map was produced and submitted to a validation procedure based on a spatial random partition strategy. Both the success of the validation procedure of the susceptibility models and the geomorphological coherence of the relationships between factors and process that such models suggest, confirm the reliability of the method and the goodness of the predictions.  相似文献   

Reviews on books,internet and scientific media     

J. Matschullat  M. W. Pitts 《Environmental Geology》2008,54(4):891-892

  相似文献   

Environmental hydrogeology of the southern sector of the Samborombon Bay wetland,Argentina     

Eleonora Carol  Eduardo Kruse  Jorge Pousa 《Environmental Geology》2008,54(1):95-102

The Samborombon Bay wetland is located on the west margin of the Rio de la Plata estuary, in the Province of Buenos Aires, Argentina. This paper analyses the geological, geomorphologic, soil and vegetation characteristics of the southernmost sector of this wetland and their influence on surface water and groundwater. The study area presents three hydrologic units: coastal dunes, sand sheets and coastal plain. Coastal dunes and sand sheets are recharge zones of high permeability with well-drained, non-saline soils, and a few surface water flows. Changes in the water table are related to rainfall. Groundwater in coastal dunes is Ca–Mg–HCO₃ to Na–HCO₃, and of low salinity (590 mg/l). Groundwater in sand sheets is mainly Na–HCO₃ with a salinity of about 1,020 mg/l. The coastal plain exhibits medium to low permeability sediments, with submerged saline soils poorly drained. Groundwater is Na–Cl with a mean salinity of 16,502 mg/l. A surface hydrological network develops in the coastal plain. Surface water levels near the shoreline are affected by tidal fluctuations; far from the shoreline water accumulates because of poor drainage. Both sectors have Na–Cl water, but the former is more saline. Human intervention and sea level rise may affect the wetland severely.  相似文献   

Aspects of conservation in the excavation site of the Athribis temple in Egypt     

Hans Leisen  Esther von Plehwe-Leisen  Christina Verbeek  Christine Jürgens  Sabine Krause 《Environmental Geology》2008,56(3-4):689-697

  相似文献   

Interference of Multiple Strip Footings on Sand Using Small Scale Model Tests   总被引：2，自引：1，他引：1  

Jyant Kumar  Manas Kumar Bhoi 《Geotechnical and Geological Engineering》2008,26(4):469-477

By using small scale model tests, the interference effect on the vertical load-deformation behavior of a number of equally spaced strip footings, placed on the surface of dry sand, was investigated. At any stage, all the footings were assumed to (i) carry exactly equal magnitude of load, and (ii) settle to the same extent. No tilt of the footing was permitted. The effect of clear spacing (s) among footings on the results was explored. A new experimental setup was proposed in which only one footing needs to be employed rather than a number of footings. The bearing capacity increases continuously with decrease in spacing among the footings. The interference effect becomes further prominent with increase in soil friction angle. In contrast to an increase in the bearing capacity, with decrease in spacing of footings, an increase in the footing settlement associated with the ultimate state of shear failure was observed. The present experimental observations were similar to those predicted by the available theory, based on the method of characteristics. As compared to the theory, the present experimental data, however, indicates much greater effect of interference especially for larger spacing among footings.  相似文献