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41.
We have been awarded NASA Key Project observing time on ISO, in order to establish the true frequency of far-infrared excesses in a volume-limited sample of main sequence and related stars, and address the relative success or failure of single stars in processes related to the forming of planetary systems. For a volume-limited subset of main sequence and related stars, PHT03 measurements at 3.6, 11.5, 20 and 60 micron will be obtained, using a 120 arsec aperture in all cases to eliminate possible companion confusion with differing apertures, to ascertain spectral energy distributions. For the M dwarfs, 100 micron observations will also be obtained. For some, brighter sources, more extensive wavelength coverage and improved spatial resolution will be attempted, using CAM and SWS. Spatially over-sampled PHOT observations will be made at 60 micron of the brightest and nearest Vega-like sources to measure the characteristic sizes of the emitting regions and obtain some information regarding their shapes and orientations. The goal is not a map, but scan profiles along 3 position angles which can be deconvolved to find the intrinsic size and shape of the half-maximum contour of the emitting region. Photometry of selected lines of sight through the zodiacal dust will also be carried out to look for outer solar system (Kuiper Belt) material. Observation at a range of wavelengths, ecliptic latitudes and at 2 epochs is designed to help untangle foreground Zodiacal from background Kuiper flux, not necessarily to look for individual macroscopic objects.  相似文献   
42.
We describe for the first time the generation and measurement of capillary waves in a water surface in a wind tunnel running with air at pressures of 15-1000 mbar. These experiments suggest a stronger dependence of wave generation on atmospheric density than the simple proportionality that might be expected from energy transfer arguments. Additionally, airflow over a nonaqueous fluid (kerosene) was found to produce waves of higher amplitude than for water under the same conditions. These preliminary results may indicate different efficiencies of wave generation on other planets, for which empirical terrestrial relations therefore do not apply, and thus may have a bearing on the lack of strong shoreline features on Mars and the possibility of specular glints from hydrocarbon lakes on Titan.  相似文献   
43.
Flow-through seagrass core microcosms were used to examine responses of species and processes to a logarithmic gradient of dosing with14C-labeled tributyltin-chloride (TBT-CI). Experiments involved delivery of TBT-CI to the water column of replicate cores of a treatment (n=16) once per week; one-half of the cores were sacrificed after 3 wk of dosing, the others were dosed for 6 wk. Initial water column concentrations for the three treatments averaged 0.205, 2.23, and 22.21 μg I?1, expressed as the TBT+ cation, but these concentrations dropped rapidly. Retained14C tracer, an estimate of total organotin species, was distributed to sediments, plants, and other biological tissues, all of whose tracer concentrations increased with time. Measures to indicate responses of both autotrophic and heterotrophic organisms were made; in general, treatment effects were demonstrable statistically only at the highest dose level. Accumulation of chlorophyll and biomass on glass slides was highest when suspended for the entire experiment in the water of the highest treatment; this unexpected result was perhaps an indirect effect related to reduced grazing activity in the microcosms. The highest dose of TBT-CI resulted in virtual population mortality of a few macrobenthic species and decreased loss of plant material in litter bags, both demonstrated within the first 3 wk of dosing. Reduced litter loss was coincident with mortality of an amphipod (Cymadusa compta) capable of shredding plant material, and a causal relation between the two effects is plausible. Thus, if concentrated to similar levels in aThalassia bed, TBT+ may have direct species-level effects and process-level effects, potentially causing ecosystem change via disruption of a species-process linkage influential in seagrass detrital food web dynamics.  相似文献   
44.
Equilibrium constants for copper(II)-carbonate and -bicarbonate species have been determined at 25°C from consideration of malachite, Cu2(OH)2CO3(s), solubility in UV-photo-oxidized perchlorate solutions of 0.72 m ionic strength. The ratios of total dissolved copper, T(Cu), to free copper(II) ion, [Cu 2+], in 30 malachite saturated experimental solutions of 1–10 × 10?3eq kg?1 H2O initial total alkalinity (TAi in the pH range 5.0–9.3 were fitted to a copper(II)-ion speciation model. The experimental data indicate the existence of CuCO3+, CuHCO3+ and Cu(OH)CO3? in addition to the hydrolys and Cu(OH)CO3? in addition to the hydrolysis products in the range of conditions defined by this study. The stoichiometric equilibrium constants, applicable to seawater at 0.72 m ionic strength, 25°C and 1 atm are
βCuCO3=[CuCO03][Cu2+][CO2?3]=(1.59±0.03)×106
βCuHCO3=[CuHCO+3][Cu2+][HCO?3]=(2.3±0.3)×102
1βCu(OH)CO3=[Cu(OH)CO?3H[Cu2+][CO2?3]=(7.6±0.3)×10?4
A speciation model employing the equilibrium constants determined in this study and copper(II) hydrolysis constants from previous work suggests that the inorganic speciation in seawater (pH = 8.2, TA = 2.3 meq kg ?1, 25°C) is dominated by the CuCO30 complex (82%) and that only 2.9% of the total inorganic copper exists as the free copper(II) ion. Hydrolysis products, CuOH+ and Cu(OH)20, account for 6.5% while CuHCO3+ and Cu(OH)CO3? species comprise 1.0 and 6.3% of the total inorganic copper, respectively.  相似文献   
45.
Laboratory investigations were conducted on the formation of NaF° ion-pairs at the ionic strength of seawater using specific ion electrodes. Sodium and fluoride ion electrodes produced results which are consistent with the ion-pairing model for these ionic interactions. The stoichiometric association constant for NaF°, K1NaF, was determined at 15, 25, and 35°C. It was assumed that K1NaF was a function of temperature, pressure, and ionic strength but not of solution composition. The value for K1NaF at 25°C and I = 0.7 m is 0.045 ± 0.006. K1NaF increased with decreasing temperature. This result was used to recompute values of K1MgF and K1CaF accounting for the presence of NaF° ion-pairs. The value for K1NaF indicates that 1.1% of the fluoride in seawater is ion-paired with sodium at 25°C and 35‰ salinity. This fraction increases to approximately 2% at the lower temperatures found in the deep ocean. The percentage of free fluoride in natural seawater was measured at 15, 25, and 35°C to verify the speciation calculated from equilibrium constants.  相似文献   
46.
The quantitative measurement of surface roughness of planetary surfaces at all scales provides insights into geological processes. A characterization of roughness variations at the scale of a few tens of meters is proposed that complements the analysis of local topographic data of the martian surface at kilometer scale, as achieved from the Mars Orbiter Laser Altimeter (MOLA) data, and at the subcentimeter scale using photometric properties derived from multi-angular observations. Relying on a Gabor filtering process, an algorithm developed in the context of image classification for the purpose of texture analysis has been adapted to handle data from the High Resolution Stereo Camera (HRSC). The derivation of roughness within a wavelength range of tens of meters, combined with analyses at even longer wavelengths, gives an original view of the martian surface. The potential of this approach is evaluated for different examples for which the geological processes are identified and the geological units are mapped and characterized in terms of roughness.  相似文献   
47.
The successful management of shark populations requires juvenile recruitment success. Thus, conservation initiatives now strive to include the protection of areas used by pre‐adult sharks in order to promote juvenile survivorship. Many shark species use inshore areas for early life stages; however, species often segregate within sites to reduce competition. Using a fisheries‐independent gillnet survey from the Northern Gulf of Mexico (2000–2010) we describe distribution patterns and preferred habitat features of the juveniles of six shark species. Our results suggest that multiple shark species concurrently use the area for early life stages and although they overlap, they exhibit distinct habitat preferences characterized by physical variables. Habitat suitability models suggest that temperature, depth, and salinity are the important factors driving juvenile shark occurrence. Within each site, across the sampled range of physical characteristics, blacktip shark (Carcharhinus limbatus) preferred higher temperature (>30 °C) and mid‐depth (~5.5 m); bonnethead shark (Sphyrna tiburo) preferred higher temperature (>30 °C) and mid‐salinity (30–35 PSU), finetooth shark (Carcharhinus isodon) preferred low salinity (<20 PSU) with mid‐depth (~4 m), scalloped hammerhead shark (Sphyrna lewini) preferred high temperature (>30 °C) and salinity (>35 PSU), Atlantic sharpnose shark (Rhizoprionodon terraenovae) preferred high temperature (>30 °C) and deep water (>6 m), and spinner shark (Carcharhinus brevipinna) preferred deep water (>8 m) and high temperature (>30 °C). The other investigated factors, including year, month, latitude, longitude, bottom type, inlet distance, coastline and human coast were not influential for any species. Combining habitat preferences with the sampled environmental characteristics, we predicted habitat suitability throughout the four sites for which physical characteristics were sampled. Habitat suitability surfaces highlight the differences in habitat use between and within sites. This work provides important insight into the habitat ecology of juvenile shark populations, which can be used to better manage these species and protect critical habitat.  相似文献   
48.
Elemental abundances for volatile siderophile and chalcophile elements for Mars inform us about processes of accretion and core formation. Such data are few for Martian meteorites, and are often lacking in the growing number of desert finds. In this study, we employed laser ablation inductively coupled plasma–mass spectrometry (LA‐ICP‐MS) to analyze polished slabs of 15 Martian meteorites for the abundances of about 70 elements. This technique has high sensitivity, excellent precision, and is generally accurate as determined by comparisons of elements for which literature abundances are known. However, in some meteorites, the analyzed surface is not representative of the bulk composition due to the over‐ or underrepresentation of a key host mineral, e.g., phosphate for rare earth elements (REE). For other meteorites, the range of variation in bulk rastered analyses of REE is within the range of variation reported among bulk REE analyses in the literature. An unexpected benefit has been the determination of the abundances of Ir and Os with a precision and accuracy comparable to the isotope dilution technique. Overall, the speed and small sample consumption afforded by this technique makes it an important tool widely applicable to small or rare meteorites for which a polished sample was prepared. The new volatile siderophile and chalcophile element abundances have been employed to determine Ge and Sb abundances, and revise Zn, As, and Bi abundances for the Martian mantle. The new estimates of Martian mantle composition support core formation at intermediate pressures (14 ± 3 GPa) in a magma ocean on Mars.  相似文献   
49.
A principal method for studying past hydroclimatic change is the reconstruction of paleo-lake levels. Here, we provide high-resolution lake-level records from New Long Pond and Rocky Pond in southeastern Massachusetts, which each contain evidence for multiple, sub-centennial-to-millennial scale low stands during the transition between the Late Pleistocene (15.0 ka) and Middle Holocene (ca 7.0 ka). Data from New Long Pond also demonstrate sedimentary evidence for a drop in water levels in the early to mid AD 20th century, when long-term trends in instrumental data show lower-than-average precipitation in the northeastern United States. Local data show the most precipitous declines in precipitation and groundwater levels are concurrent with the most severe drought in the AD 1960s, which occurred during a period of low sea-surface temperatures in the western North Atlantic. Ground penetrating radar and sediment core data indicate five intervals with numerous paleo-shoreline deposits between ca 15.0 and 7.0 ka, similar to the layer deposited in the AD 1960s. Many of the intervals of low lake levels coincide with proposed meltwater release events or abrupt climate oscillations in the circum North Atlantic. For example, we document at least three low stands during the Younger Dryas (12.9–11.6 ka) and in association with the “9.2” and “8.2” ka events. The combined evidence of (1) concurrent paleo-droughts in southeastern New England with documented North Atlantic abrupt cooling events and (2) recent drought with the modern association of low sea-surface temperatures indicates that freshening and cooling of the western North Atlantic is a viable mechanism for decreasing moisture within the region. Large-scale changes in seasonality and ice sheet extent also may have increased the susceptibility of the northeast to dry conditions triggered by changes in the North Atlantic.  相似文献   
50.
The basaltic Kaupulehu 1800–1801 lava flow of Hualalai Volcano, Hawaii contains abundant ultramafix xenoliths. Many of these xenoliths occur as bedded layers of semi-rounded nodules, each thinly coated with a veneer (typically 1 mm thick) of lava. The nodule beds are analogous to cobble deposits of fluvial sedimentary systems. Although several mechanisms have been proposed for the formation of the nodule beds, it was found that, at more than one locality, the nodule beds are overbank levee deposits. The geological occurrence of the nodules, certain diagnostic aspects of the flow morphology and consideration of the inferred emplacement process indicate that the Kaupulehu flow had an exceptionally low viscosity on eruption and that the flow of the lava stream was extremely rapid, with flow velocities of at least 10 m s-1 (more than 40 km h-1). This flow is the youngest on Hualalai Volcano and future eruptions of a similar type would pose considerable hazard to life as well as property.  相似文献   
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