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261.
Clumped isotope thermometry of carbonatites as an indicator of diagenetic alteration 总被引:2,自引:0,他引:2
We measure the clumped isotopic signature of carbonatites to assess the integrity of the clumped isotope paleothermometer over long timescales (107-109 years) and the susceptibility of the proxy to closed system re-equilibration of isotopes during burial diagenesis. We find pristine carbonatites that have primary oxygen isotope signatures, along with a Carrara marble standard, do not record clumped isotope signatures lighter than 0.31‰ suggesting atoms of carbon and oxygen freely exchange within the carbonate lattice at temperatures above 250-300 °C. There is no systematic trend in the clumped isotope signature of pristine carbonatites with age, although partial re-equilibration to lower temperatures can occur if a carbonatite has been exposed to burial temperatures for long periods of time. We conclude that the solid-state re-ordering of carbon and oxygen atoms is sufficiently slow to enable the use of clumped isotope paleothermometry on timescales of 108 years, but that diagenetic resetting can still occur, even without bulk recrystallization. In addition to the carbonatite data, an inorganic calibration of the clumped isotope paleothermometer for low temperature carbonates (7.5-77 °C) is presented and highlights the need for further inter-lab standardization. 相似文献
262.
Lars-Eric Heimbürger Daniel Cossa Christophe Migon Bernard Averty Josephine Ras 《Geochimica et cosmochimica acta》2010,74(19):5549-4052
Recent findings on the distribution of methylated mercury (MeHgT) in waters have highlighted the importance of organic carbon remineralization on the production of these compounds in the open ocean. Here, we present the first time-series (20 monthly samplings between July 2007 and May 2009) of high-resolution vertical profiles (10-12 depths in a 2350 m water column) of MeHgT distributions in an open ocean environment, the Ligurian Sea (North-western Mediterranean Sea). Concentrations varied within the sub-picomolar range (general mean: 0.30 ± 0.17 pmol L−1, n = 214) with the lowest values at the surface, increasing with depth up to the oxygen minimum zone, and decreasing slowly at greater depth. Concentrations in the surface waters never exceeded 0.15 pmol L−1, while the highest concentrations (up to 0.82 pmol L−1) were associated to the hypoxycline during the autumn bloom. A detailed vertical MeHgT profile reveals a “double-peak” pattern, coincidental with the two microbial layers described by Tanaka and Rassoulzadegan (2002), the so-called “microbial food web” in the euphotic zone (<100 m) and the “microbial loop” in the aphotic zone (>100 m). Temporal variations in the MeHgT abundance and distribution in the water column were linked to seasonality. The highest MeHgT concentrations were found in the oxygen minimum zone during the period of stratification, and coincide with the greatest abundance of nano- and picophytoplankton (cyanobacteria, nanoflagellates, etc.) in the euphotic layer. None of our deep MeHgT measurements (∼100 m above the sea bottom) revealed a significant sedimentary source of MeHgT. We explored the correlation between MeHgT concentrations and the apparent oxygen utilization, a proxy of organic matter remineralization, over the study period. Results of this study strengthen the hypothesis that net mercury methylation in the open ocean occurs in the water column, is linked to organic matter regeneration, and is promoted by the presence of small-sized nano- and picophytoplankton, that dominate under oligotrophic conditions. 相似文献
263.
Daniel Novik Warshawsky 《Geoforum》2010,41(5):763-775
While some non-profits have suffered under the political and economic pressures of neoliberal urban governance reform, others have emerged as important institutional players in local governance regimes. This article highlights how non-profits food banks in Chicago have commercialized in order to respond to increased demand, enhance their institutional independence from government, and reassert their local dominance in emergency food service delivery. From a food bank member agency perspective, the consolidation of food bank institutional power has produced new bureaucratic limitations, user fees, and increased competition. These shifts reveal the rise of metropolitan food banks as important players in neoliberal urban governance regimes, as they control the conceptualization of hunger, management of poverty, and organization of food distribution systems. 相似文献
264.
Élisa Morichon Thierry Allard Daniel Beaufort David Quirt 《Physics and Chemistry of Minerals》2010,37(3):145-152
Natural radiation-induced defects were identified in specimens of sudoite (Al–Mg di-trioctahedral chlorite) related to unconformity-type
uranium deposits at the base of the Athabasca Group (Saskatchewan, Canada), using electron paramagnetic resonance (EPR) spectroscopy
at X- and Q-band frequencies. X-band spectra indicate the presence of a main native defect, named the As-center, whose EPR signal is dominated by an axially distorted spectrum with apparent principal components as follows: g
// = 2,051 and g
⊥ = 2,005, and a secondary defect with apparent component g = 2,025. The study of oriented specimens shows that the main defect has its g
// component perpendicular to the (ab) plane of sudoite. The As-center corresponds to an electron hole located on oxygen atoms of the structure and is likely associated with Si, according
to the lack of hyperfine structure. The As-center in sudoite has EPR parameters similar to the A-center in kaolinite and dickite, and the Ai-center in illite. The saturation behavior of EPR spectra as a function of power demonstrates that native defects of sudoite
are different from those known in other clays, such as kaolinite, dickite or smectite, but are similar to those of illite.
The isochronal annealing data suggest that the main defect in sudoite is stable to more than 300°C. The corresponding defects
characterized in sudoite may have the potential for tracing past radionuclide migration around unconformity-type uranium deposits. 相似文献
265.
Volker Kahlenberg Daniela Girtler Erik Arroyabe Reinhard Kaindl Daniel M. Többens 《Mineralogy and Petrology》2010,100(1-2):1-9
Single crystals of devitrite (Na2Ca3Si6O16) were synthesized as pale-yellow transparent needle shaped crystals using a Na2MoO4-flux. Experiments aiming to prepare the K-equivalent of devitrite from the corresponding K2MoO4-flux were unsuccessful. The crystal structure of devitrite was determined from single-crystal X-ray diffraction data (Mo-Kα radiation, 2θmax.?=?25.34°, Rint?=?2.66%) and refined in space group P $ \bar{1} $ (no. 2) to R(|F|)?=?3.08% using 2,513 observed reflections with I?>?2σ(I). Unit-cell parameters are: a?=?7.2291(8), b?=?10.1728(12), c?=?10.6727(12) Å, α?=?95.669(9), β?=?109.792(10), γ?=?99.156(9)°, V?=?719.19(14) Å3, Z?=?2. The structure belongs to the group of multiple chain silicates consisting of dreier quadruple chains, i.e. the crystallochemical formula can be written as $ {\hbox{N}}{{\hbox{a}}_2}{\hbox{C}}{{\hbox{a}}_3}\left\{ {{\mathbf{uB}}{,4}_\infty^1} \right\}\left[ {^3{\hbox{S}}{{\hbox{i}}_6}} \right.\left. {{{\hbox{O}}_{16}}} \right\} $ . Linkage between the bands running along [100] is provided by double chains of edge sharing CaO6-octahedra as well as additional more irregularly coordinated Na- and Ca-cations located in the tunnel-like cavities of the mixed tetrahedral-octahedral framework. Structural investigations were completed by Raman and infrared spectroscopical studies. The allocation of the bands to certain vibrational species was aided by density functional theory (DFT) calculations. 相似文献
266.
Geochemical and mineralogical evidence for Sahara and Sahel dust additions to Quaternary soils on Lanzarote,eastern Canary Islands,Spain 总被引:1,自引:0,他引:1
Daniel R. Muhs James Budahn Gary Skipp Joseph M. Prospero DeAnna Patterson E. Arthur Bettis III 《地学学报》2010,22(6):399-410
Africa is the most important source of dust in the world today, and dust storms are frequent on the nearby Canary Islands. Previous workers have inferred that the Sahara is the most important source of dust to Canary Islands soils, with little contribution from the Sahel region. Soils overlying a late Quaternary basalt flow on Lanzarote, Canary Islands, contain, in addition to volcanic minerals, quartz and mica, exotic to the island’s bedrock. Kaolinite in the soils also likely has an exotic origin. Trace‐element geochemistry shows that the soils are derived from varying proportions of locally derived basalt and African dust. Major‐element geochemistry, clay mineralogy and interpretation of satellite imagery suggest that dust additions to the Canary Islands come not only from the Sahara Desert, but also from the Sahel region. 相似文献
267.
The southeast area of the Argentine Pampas is characterized by the presence of an unconfined aquifer in a wide plain. A methodology is proposed that deals with the aquifer vulnerability where the homogeneity of the hydrogeological variables used by traditional methods (in this case, DRASTIC-P) causes vulnerability maps to show more than 80% of the territory under the same class. This absence of discrimination renders vulnerability maps of little use to decision-makers. In addition, the proposed methodology avoids the traditional vague classification (high, low, and moderate vulnerability) which is highly dependent on subjectivity in its association of each class with hydrogeological considerations. That traditional vulnerability assessment methodology was adapted using a geographic information system to reclassify classes, based on the Natural Breaks (Jenks) method. The pixel-to-pixel comparison between the result obtained by the DRASTIC-P and the reclassified classes generates the so-called operational vulnerability index (OVI), which shows four classes, associating each with different hydrogeological requirements to make decisions. 相似文献
268.
269.
Medium- and Long-term Recovery of Estuarine and Coastal Ecosystems: Patterns,Rates and Restoration Effectiveness 总被引:1,自引:0,他引:1
Ángel Borja Daniel M. Dauer Michael Elliott Charles A. Simenstad 《Estuaries and Coasts》2010,33(6):1249-1260
Many estuarine and coastal marine ecosystems have increasingly experienced degradation caused by multiple stressors. Anthropogenic
pressures alter natural ecosystems and the ecosystems are not considered to have recovered unless secondary succession has
returned the ecosystem to the pre-existing condition or state. However, depending upon the scales of time, space and intensity
of anthropogenic disturbance, return along the historic trajectory of the ecosystem may: (1) follow natural restoration though
secondary succession; (2) be re-directed through ecological restoration, or (3) be unattainable. In order to address the gaps
in knowledge about restoration and recovery of estuarine and coastal ecosystems, this special feature includes the present
overview and other contributions to provide a synthesis of our knowledge about recovery patterns, rates and restoration effectiveness.
From the 51 examples collated in this contribution, we refine the recovery from the list of stressors into six recovery mechanisms:
(1) recovery from sediment modification, which includes all aspects of dredging and disposal; (2) recovery by complete removal
of stressors limiting natural ecosystem processes, which includes tidal marsh and inundation restoration; (3) recovery by
speed of organic degradation, which includes oil discharge, fish farm wastes, sewage disposal, and paper mill waste; (4) recovery
from persistent pollutants, which includes chemical discharges, such as TBT; (5) recovery from excessive biological removal,
related to fisheries and (6) recovery from hydrological and morphological modification. Drawing upon experience both from
these many examples and from an example of one comprehensive study, we show that although in some cases recovery can take
<5 years, especially for the short-lived and high-turnover biological components, full recovery of coastal marine and estuarine
ecosystems from over a century of degradation can take a minimum of 15–25 years for attainment of the original biotic composition
and diversity may lag far beyond that period. 相似文献
270.
Jörg Giese Diane Seward Finlay M. Stuart Eliane Wüthrich Edwin Gnos Daniel Kurz Urs Eggenberger Guido Schreurs 《Geostandards and Geoanalytical Research》2010,34(1):39-48
Apatite fission-track and (U-Th)/He analyses require the liberation of intact idiomorphic apatite grains from rock samples. While routinely being carried out by mechanical methods, electrodynamic disaggregation (ED) offers an alternative approach. The high-voltage discharges produced during the ED process create localised temperature peaks (10000 K) along a narrow plasma channel. In apatite, such high temperatures could potentially reduce the length of fission tracks, which start to anneal at temperatures > 60 °C, and could also enhance He diffusion, which becomes significant at 30–40 °C over geological time scales. A comparison of fission-track analyses and (U-Th)/He ages of apatites prepared both by mechanical (jaw crusher, disk mill) and ED processing provides a way of determining whether heating during the latter method has any significant effect. Apatites from three samples of different geological settings (an orthogneiss from Madagascar, the Fish Canyon Tuff, and a muscovite-gneiss from Greece) yielded statistically identical track length distributions compared to samples prepared mechanically. Additionally, (U-Th)/He ages of apatites from a leucogranite from Morocco prepared by both methods were indistinguishable. These first results indicated that during electrodynamic disaggregation apatite crystals were not heated enough to partially anneal the fission tracks or induce significant diffusive loss of He. 相似文献