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131.
The Sergi Formation (Upper Jurassic) represents the main hydrocarbon reservoir of the Recôncavo Basin, Brazil. The basal vertical facies succession of the Sergi Formation comprises reservoirs formed by a complex fluvio–aeolian–lacustrine interaction. Facies architecture and detailed petrophysical analysis of these reservoirs have enhanced the understanding of heterogeneity at a variety of scales and has allowed the development of predictive models that describes the range of styles of mixed fluvial–aeolian reservoirs. At megascopic scale, the reservoirs are predominantly composed of sand bodies deposited by fluvial channel and aeolian facies associations. Regional flooding surfaces and sequence boundaries are their main flow barriers. The regional flooding surfaces are composed of fine-grained sediments deposited by lacustrine facies associations and the sequence boundaries act as flow barriers due to mechanically infiltrated clays. Based on its geometrical relations, reservoirs linked to fluvial–aeolian–lacustrine interaction formed two types of reservoirs at macroscopic scale: (i) with good lateral continuity of aeolian packages and relatively simple stratigraphic correlation and (ii) of highly compartmentalized aeolian packages with complex stratigraphic correlation and truncation by fluvial deposits. Mesoscopic heterogeneity reflects lithofacies, sedimentary structures, and lamina-scale variability within aeolian and fluvial facies associations.  相似文献   
132.
Authigenic carbonates from outcrops of the northern Apennines consist of small and irregular lenses and exhibit numerous features indicative of cold-seep settings. Detailed petrographic, mineralogical and geochemical studies from two Miocene deposits are presented. The first carbonate outcrop, named Fosso Riconi, is located in the foredeep basin of the Apenninic chain, whereas the second deposit represents a satellite basin called Sarsetta. The stable isotope data from specific carbonate minerals show a wide range of values well known from other palaeoseeps of the Apennine Mountains. The majority of seep carbonates are formed by low-Mg calcite and ankerite. Those minerals have δ13C values between ?7 and ?23‰ V-PDB, suggesting variable amounts of carbonate derived from oxidized methane, seawater (dissolved inorganic carbon) and sedimentary organic matter. Dolomite samples have the lowest δ13C values (?30.8 to ?39.0‰ V-PDB), indicating methane as the main carbon source. The findings suggest an evolutionary formation of the seeps and development of authigenic carbonates influenced by the activity of chemosynthetic organisms, of which large lucinid clams are preserved. Bioirrigation by the clams controlled the sediment–water exchange, and is here considered as an explanation for the anomalous Mg content of the calcite. We hypothesize that the seep carbonates were formed during periods of active methane-rich seepage, whereas during periods of slow seepage carbonate formation was reduced. Despite different geological settings, the two examined deposits of Sarsetta and Fosso Riconi show similar features, suggesting that a common pattern of fluid circulation played a major role in carbonate formation at both seep sites.  相似文献   
133.
The Italian catalogue contains many earthquakes of moderate to high epicentral intensity which are located in areas of low seismicity and near big cities. Some of them have been inserted in the catalogue after one historical record only. This study investigates many such events in the 1000–1690 time-window showing that a great number of them are fake. Starting by an operational definition of ‘fake quake’, this paper shows the procedures adopted, and the main results which contribute in a significant way to the reassessment of seismicity and seismic hazard.  相似文献   
134.
Using rigorous probabilistic techniques we define and compute the shadowing factor, the conditional mean slope and the conditional standard deviation of the slope for a random rough surface described as an isotropic Gaussian stochastic process with Gaussian autocorrelation function. We use these quantities in order to obtain the bidirectional reflectance distribution function for incoherent light scattering by rough surfaces. The calculated quantities depend on reduced, affine invariant parameters, such that changing roughness is equivalent to rescaling the slopes of incident and emergent direction. We discuss some possible applications of these scaling properties to remote sensing.  相似文献   
135.

Green manuring of legume crops can improve soil fertility and sustainability. To evaluate its agronomic and environmental effectiveness, gaseous losses of ammonia (NH3) in the surface layer need to be quantified by direct measurements in the field. However, the application of the eddy-covariance technique to atmospheric NH3 is challenging: its high reactivity, water solubility, and low background concentrations all hinder the response time of closed-path sensors for fast measurements of NH3 concentration. Ammonia emissions following green manuring were measured for 21 days using a flux system equipped with a fast-pulsed quantum-cascade tunable-infrared-laser spectrometer. The noisy cross-covariance function for this configuration indicates flux measurements are close to the limit of detection; the low signal-to-noise ratio further increases the uncertainties, introducing a mirroring effect on the fluxes, which results in the rapid alternation between emission and deposition, within the limit of detection (around 13 and 20 ng m?2 s?1, at the 95 and 99% confidence limits, respectively). An evaluation of the measurement errors is presented, focussing on three technical aspects of the eddy-covariance system: (1) time lag, (2) random error, and (3) limit of detection. The NH3 fluxes measured by the spectrometer are close to its limit of detection, with a random error of the same order as the flux.

  相似文献   
136.
Methane occurrences displaying signatures of a possible abiotic origin had previously been reported in the South‐West Carpathians (Romania). Such an accumulation, at Tisovi?a, was intercepted by a well drilled in an ophiolitic rocks massif, whereas in two other localities—situated tens of kilometres faraway—the concerned methane is released via thermal groundwater outflows that are apparently not associated with any ultramafic products. By using groundwater ionic compositions, corroborated with previously published isotopic (13C‐CH4, 2H‐CH4, 3He/4He) and molecular gas analyses, we assessed in more detail the conjectured abiotic provenance of methane, and quantitatively investigated the hypothesis of a progressive mixing between two, abiotic and thermogenic, methane end‐members. The corresponding geofluids behaviour was modelled by hypothesizing a “concealed” ophiolite serpentinization setting (largely similar to that at Tisovi?a), whose abiotic methane production was “diverted” towards remote discharges at ground surface, via a ~20‐km‐long flowpath supposedly generated by recently operating extensional tectonics.  相似文献   
137.
138.
Dimethylsulfoxide (DMSO) is an important degradation product of the climate-influencing gas dimethylsulfide (DMS). In the Ross Sea, Antarctica, dissolved DMSO (DMSOd) concentrations exhibited substantial seasonal and vertical variations. Surface water DMSOd concentrations in pre-bloom waters were very low (<1 nM) but increased rapidly up to 41 nM during the spring Phaeocystis antarctica bloom (late November). Increases in DMSOd concentrations lagged by several days increases in DMS concentrations. Although DMSOd concentrations reached relatively high levels during the spring bloom, concentrations were generally higher (36.3–60.6 nM) during summer (January), even though phytoplankton biomass and DMS concentrations had decreased by that time. During both seasons, DMSOd concentrations were substantially higher within the surface mixed layer than below it. DMSOd production from biological DMS consumption (BDMSC) was higher during late November (3.4–5.2 nM d?1) than during the summer (0.7–2.4 nM d?1); therefore, production via BDMSC alone could not explain the higher DMSOd concentrations encountered during the summer. Mixed layer-integrated DMSOd production from BDMSC was 2.5–13.7 times greater than production from dissolved DMS photolysis during the P. antarctica bloom, while photolysis contributed 1.3 times more DMSO than BDMSC before the bloom. The DMSO yield from BDMSC was consistently higher within the upper mixed layer than at depths below. Experimental incubations with water from the mixed layer showed that exposure to full spectrum sunlight for 72 h caused an increase in the DMSO yield whereas exposure to only photosynthetically active radiation did not. This suggests that ultraviolet radiation is a potential factor shifting the fate of biologically consumed DMS toward DMSO. In general, the highest DMSO yields from BDMSC were in samples with slow biological DMS turnover, whereas fast turnover favored sulfate rather than DMSO as a major end-product. This study provides the first detailed information about DMSOd distribution and production in the Ross Sea and points to DMSOd as an important biological and photochemical degradation product of DMS and a major reservoir of methylated sulfur in these polar surface waters.  相似文献   
139.
The Kokchetav complex in Kazakhstan contains garnet-bearing gneisses that formed by partial melting of metasedimentary rocks at ultrahigh-pressure (UHP) conditions. Partial melting and melt extraction from these rocks is documented by a decrease in K2O and an increase in FeO + MgO in the restites. The most characteristic trace element feature of the Kokchetav UHP restites is a strong depletion in light rare earth elements (LREE), Th and U. This is attributed to complete dissolution of monazite/allanite in the melt and variable degree of melt extraction. In contrast, Zr concentrations remain approximately constant in all gneisses. Using experimentally determined solubilities of LREE and Zr in high-pressure melts, these data constrain the temperature of melting to ~1,000 °C. Large ion lithophile elements (LILE) are only moderately depleted in the samples that have the lowest U, Th and LREE contents, indicating that phengite retains some LILE in the residue. Some restites display an increase in Nb/Ta with respect to the protolith. This further suggests the presence of phengite, which, in contrast to rutile, preferentially incorporates Nb over Ta. The trace element fractionation observed during UHP anatexis in the Kokchetav gneisses is significantly different from depletions reported in low-pressure restites, where generally no LREE and Th depletion occurs. Melting at UHP conditions resulted in an increase in the Sm/Nd ratio and a decoupling of the Sm–Nd and Lu–Hf systems in the restite. Further subduction of such restites and mixing with mantle rocks might thus lead to a distinct isotopic reservoir different from the bulk continental crust.  相似文献   
140.
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