Volatiles in amphiboles from xenoliths,Vulcan's Throne,Grand Canyon,Arizona, USA     

Dean W. Matson  David W. Muenow  Michael O. Garcia 《Geochimica et cosmochimica acta》1984,48(8):1629-1636

Analyses of major element and volatile components of amphiboles from Vulcan's Throne, a Recent volcano on the north rim of the Grand Canyon, Arizona, USA, have been performed by using the electron microprobe and high temperature mass spectrometry. The amphiboles occur as megacrysts, as oikocrysts in peridotite and pyroxenite xenoliths, in amphibole-rich selvages on lherzolite xenoliths, and as grains in hornblendite xenoliths. Total volatiles range from 1.27 to 1.75 wt.%. In all samples, H₂O is the principal volatile species. Lesser amounts of structurally bound fluorine, chlorine, and oxygen were also released. The amphiboles studied are hydroxyl-deficient. The O(3) site is probably partially occupied by O^2?, which was detected as O₂ during degassing of the amphibole. Ti shows a strong positive correlation with the amount of hydroxyl deficiency in the amphiboles except for one oxidized sample. Thus, Ti probably is significant in charge balancing the substitution of O^2? for OH^? and the substitution probably occurred during crystallization rather than by dehydrogenation. Small amounts of both oxidized and reduced carbon and sulfur-bearing volatile species (e.g., CO₂, CO, CH₄, SO₂, H₂S) were detected in all samples. The observation of reduced carbon species supports the hypothesis that the oxygen fugacity of at least portions of the upper mantle is probably less than the quartz-fayalite-magnetite buffer.  相似文献   

Counterurbanisation and the characteristics of persons migrating to West Cornwall   总被引：1，自引：0，他引：1  

K.G. Dean  D.P. Shaw  B.J.H. Brown  R.W. Perry  W.T. Thorneycroft 《Geoforum》1984,15(2):177-190

Studies at the macro-scale have indicated that many remote rural areas are for the first time in over a century experiencing population growth while metropolitan areas are losing population. In this paper theories of counterurbanisation directed towards explaining the redistribution of population at a national or regional scale are criticised and a more localised research framework is proposed. Such a framework is constructed for the examination of migration into West Cornwall. Results from a postal questionnaire survey of seven study areas in West Cornwall are used to illustrate differences between three population subgroups, namely, return migrants, non-return migrants and non-migrants. Clear differences emerge not only between the population subgroups but between the study areas as well. In conclusion, it is suggested that this middle-range approach should be adopted more widely in order to gain greater insight into the counterurbanisation process and to increase the prospect of relating macro-processes to local trends and human experience.  相似文献   

Accumulation of organic matter in Cretaceous oxygen-deficient depositional environments in the central Pacific Ocean     

Walter E. Dean  George E. Claypool  Jörn Thide 《Organic Geochemistry》1984,7(1):39-51

Complete records of organic-carbon-rich Cretaceous strata were continuouslycored on the flanks of the Mid-Pacific Mountains and southern Hess Rise in the central North Pacific Ocean during DSDP Leg 62. Organic-carbon-rich laminated silicified limestones were deposited in the western Mid-Pacific Mountains during the early Aptian, a time when that region was south of the equator and considerably shallower than at present. Organic-carbon-rich, laminated limestone on southern Hess Rise overlies volcanic basement and includes 136 m of stratigraphic section of late Albian to early Cenomanian age. This limestone unit was deposited rapidly as Hess Rise was passing under the equatorial high-productivity zone and was subsiding from shallow to intermediate depths. The association of volcanogenic components with organic-carbon-rich strata on Hess Rise in the Mid-Pacific Mountains is striking and suggests that there was a coincidence of mid-plate volcanic activity and the production and accumulation of organic matter at intermediate water depths in the tropical Pacific Ocean during the middle Cretaceous.Pyrolysis assays and analyses of extractable hydrocarbons indicate that the organic matter in the limestone on Hess Rise is composed mainly of lipid-rich kerogen derived from aquatic marine organisms and bacteria. Limestones from the Mid-Pacific Mountains generally contain low ratios of pyrolytic hydrocarbons to organic carbon and low hydrogen indices, suggesting that the organic matter may contain a significant proportion of land-derived material, possibly derived from numerous volcanic islands that must have existed before the area subsided. The organic carbon in all samples analyzed is isotopically light (δ¹³C ? 24 to ? 29 per mil) relative to most modern rine organic carbon, and the lightest carbon is also the most lipid-rich.There is a positive linear correlation between sulfur and organic carbon in samples from Hess Rise and from the Mid-Pacific Mountains. The slopes and intercepts of C-S regression lines however, are different for each site and all are different from regression lines for samples from modern anoxic marine sediments and from Black Sea cores.The organic-carbon-rich limestones on Hess Rise, the Mid-Pacific Mountains, and other plateaus and seamounts in the Pacific Ocean are not synchronous but do occur within the same general middle Cretaceous time period as organic-carbon-rich lithofacies elsewhere in the world ocean, particularly in the Atlantic Ocean. Strata of equivalent age in the deep basins of the Pacific Ocean are not rich in organic carbon, and were deposited in oxygenated environments. This observation, together with the evidence that the plateau sites were considerably shallower and closse to the equator during the middle Creataceous suggests that local tectonic and hydrographic conditions may have resulted in high surface-water productivity and the preservation of organic matter in an oxygen-deficient environment where an expanded mid-water oxygen minimum developed and impinged on elevated platforms and seamounts.  相似文献   

Use of large Acacia trees by the cavity dwelling Black-tailed Tree Rat in the Southern Kalahari     

J.A. Eccard  W.R.J. Dean  M.C. Wichmann  S.M. Huttunen  E. Eskelinen  K.A. Moloney  F. Jeltsch 《Journal of Arid Environments》2006,64(4):604-615

Recent extensive harvesting of large, often dead Acacia trees in arid savanna of southern Africa is cause for concern about the conservation status of the arid savanna and its animal community. We mapped vegetation and nests of the Black-tailed Tree Rat Thallomys nigricauda to assess the extent to which the rats depend on particular tree species and on the existence of dead, standing trees. The study was conducted in continuous Acacia woodland on the southern and eastern edge of the Kalahari, South Africa. Trees in which there were tree rat nests were compared with trees of similar size and vigour to identify the characteristics of nest sites. Spatial analysis of tree rat distribution was conducted using Ripley's-L function. We found that T. nigricauda was able to utilize all available tree species, as long as trees were large and old enough so that cavities were existing inside the stem. The spatial distribution of nest trees did not show clumping at the investigated scale, and we therefore reject the notion of the rats forming colonies when inhabiting continuous woodlands. The selection of a particular tree as a nest site was furthermore depending on the close proximity of the major food plant, Acacia mellifera. This may limit the choice of suitable nest sites, since A. mellifera was less likely to grow within a vegetation patch containing a large trees than in patches without large trees.  相似文献   

The necessity of fundamental emission in type III bursts     

Dean F. Smith  William D. Davis 《Solar physics》1975,41(2):439-447

Observations of some type III radio bursts in the hectometer and kilometer wave range are compared with theoretical predictions. It is shown that the burst emission must be near the plasma frequency in the region between 10 R _⊙ and 50 R _⊙ in order to be consistent with the observed steep rise in brightness temperature for these bursts. The results of Fainberg, Malitson et al., and Haddock and Alvarez are discussed and compared with the interpretation of emission near the plasma frequency.  相似文献   

Characterizing Spatial Databases via their Derivation: A Complement to Content Ontologies     

Denis J Dean 《Transactions in GIS》2007,11(3):399-412

Developing an ontology that succinctly describes the contents of a spatial database is a very difficult undertaking. Yet most current efforts to develop spatial ontologies remain focused on describing content. Ontologies describing other aspects of spatial databases may prove to be much easier to develop and nearly as useful as content ontologies, and yet these alternative ontologies have received little attention from the research community. This paper explores one such alternative, specifically, an ontology that describes how a spatial database may have been derived. Derivation ontologies are shown to be highly complementary to content ontologies, and in some cases can perform nearly identical tasks. It is also shown that derivation ontologies are much more straightforward to develop than are content ontologies. Finally, we present a genetic programming (GP)‐based approach to automatically developing derivation ontologies for existing databases. It is concluded that while derivation ontologies cannot replace content ontologies, they are a useful and practical complement that offer their own unique set of strengths to the problem of semantically characterizing spatial data.  相似文献   

Data Assimilation in Truncated Plurigaussian Models: Impact of the Truncation Map     

Dean S. Oliver  Yan Chen 《Mathematical Geosciences》2018,50(8):867-893

Assimilation of production data into reservoir models for which the distribution of porosity and permeability is largely controlled by facies has become increasingly common. When the locations of the facies bodies must be conditioned to observations, the truncated plurigaussian model has been often shown to be a useful method for modeling as it allows gaussian variables to be updated instead of facies types. Previous experience has also shown that ensemble Kalman filter-like methods are particularly effective for assimilation of data into truncated plurigaussian models. In this paper, some limitations are shown of the ensemble-based or gradient-based methods when applied to truncated plurigaussian models of a certain type that is likely to occur for modeling channel facies. It is also shown that it is possible to improve the data match and increase the ensemble spread by modifying the updating step using an approximate derivative of the truncation map.  相似文献   

Randomized maximum likelihood based posterior sampling     

Ba  Yuming  de Wiljes  Jana  Oliver  Dean S.  Reich  Sebastian 《Computational Geosciences》2022,26(1):217-239

Minimization of a stochastic cost function is commonly used for approximate sampling in high-dimensional Bayesian inverse problems with Gaussian prior distributions and multimodal posterior distributions. The density of the samples generated by minimization is not the desired target density, unless the observation operator is linear, but the distribution of samples is useful as a proposal density for importance sampling or for Markov chain Monte Carlo methods. In this paper, we focus on applications to sampling from multimodal posterior distributions in high dimensions. We first show that sampling from multimodal distributions is improved by computing all critical points instead of only minimizers of the objective function. For applications to high-dimensional geoscience inverse problems, we demonstrate an efficient approximate weighting that uses a low-rank Gauss-Newton approximation of the determinant of the Jacobian. The method is applied to two toy problems with known posterior distributions and a Darcy flow problem with multiple modes in the posterior.

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武汉地铁三号线土层盾构开挖引起的地表沉降研究   总被引：1，自引：1，他引：0       下载免费PDF全文

黄丁俊  张添锋  孙德安  唐雪峰 《水文地质工程地质》2015,42(1):79-86

为了研究红黏土的变形特性,使用常规固结仪和自制收缩仪,对压实桂林红黏土进行了无荷载条件下4次膨胀和收缩试验。结果表明:红黏土的胀缩变形过程是不可逆的;随着干湿循环次数增加,膨胀试验试样高度变化较小,收缩试验试样高度逐渐增大,膨胀变形和收缩变形均呈逐渐减小趋势;稳定后膨胀率和收缩率均逐渐减小,收缩系数不断减小,最终趋于一个较稳定数值;采用绝对膨胀率、绝对收缩率、相对膨胀率、相对收缩率等参数可以定量分析干湿循环作用下压实红黏土的胀缩变形程度及其变化规律。  相似文献   

Garnet-bearing Xenoliths from Salt Lake Crater, Oahu, Hawaii: High-Pressure Fractional Crystallization in the Oceanic Mantle     

Keshav  Shantanu; Sen  Gautam; Presnall  Dean C. 《Journal of Petrology》2007,48(9):1681-1724

The focus of this study is a suite of garnet-bearing mantlexenoliths from Oahu, Hawaii. Clinopyroxene, olivine, and garnetconstitute the bulk of the xenoliths, and orthopyroxene is presentin small amounts. Clinopyroxene has exsolved orthopyroxene,spinel, and garnet. Many xenoliths also contain spinel-coredgarnets. Olivine, clinopyroxene, and garnet are in major elementchemical equilibrium with each other; large, discrete orthopyroxenedoes not appear to be in major-element chemical equilibriumwith the other minerals. Multiple compositions of orthopyroxeneoccur in individual xenoliths. The new data do not support theexisting hypothesis that all the xenoliths formed at 1 6–22GPa, and that the spinel-cored garnets formed as a consequenceof almost isobaric subsolidus cooling of a spinel-bearing assemblage.The lack of olivine or pyroxenes in the spinel–garnetreaction zones and the embayed outline of spinel grains insidegarnet suggest that the spinel-cored garnets grew in the presenceof a melt. The origin of these xenoliths is interpreted on thebasis of liquidus phase relations in the tholeiitic and slightlysilica-poor portion of the CaO–MgO–Al₂O₃–SiO₂(CMAS) system at pressures from 30 to 50 GPa. The phase relationssuggest crystallization from slightly silica-poor melts (ortransitional basaltic melts) in the depth range 110–150km beneath Oahu. This depth estimate puts the formation of thesexenoliths in the asthenosphere. On the basis of this study itis proposed that the pyroxenite xenoliths are high-pressurecumulates related to polybaric magma fractionation in the asthenosphere,thus making Oahu the only locality among the oceanic regionswhere such deep magmatic fractional crystallization processeshave been recognized. KEY WORDS: xenolith; asthenosphere; basalt; CMAS; cumulate; oceanic lithosphere; experimental petrology; mantle; geothermobarometry; magma chamber  相似文献