Trace element behaviour during anatexis in the presence of a fluid phase     

Denis M. Shaw 《Geochimica et cosmochimica acta》1978,42(6):933-943

If anatexis takes place in the presence of an immiscible volatile-rich fluid phase, the behaviour of a trace element depends not only on partition coefficients D^{i ?} between mineral i and silicate liquid, but also on coefficients D^{i f} between mineral i and fluid. The limited experimental data available, as well as theoretical arguments, suggest that for common minerals these coefficients differ, in some cases (REE) notably.Theory has been developed to permit calculation of concentration variations with the fraction F of rock melted, if D-values are known. In its present state this theory neglects the influence of T, P and composition variations in liquid and fluid on the D-values: if such variations can be expressed as functions of F, appropriate modifications can be made. The theory also neglects the effects of T and P on the solubility of fluid in liquid and the resulting modifications to phase petrology, by assuming simply that a given mass of rock melts in the presence of a mass proportion v of fluid. By choosing different values of v, from 0 (dry melting) to 100 (large fluid excess), the response of the trace element concentrations can be followed, beginning with concentration c_o in the unmelted rock. Such treatment is highly idealised, but serves to indicate some limits on what can occur.  相似文献   

Modelling stalagmite growth and δC as a function of drip interval and temperature     

Christian Mühlinghaus  Denis Scholz  Augusto Mangini 《Geochimica et cosmochimica acta》2007,71(11):2780-2790

Growth and stable isotope composition of stalagmites are affected by climate changes. To understand the underlying mechanisms, we developed a time dependent multi-box model that describes stalagmite growth and stable isotope fractionation of carbon under disequilibrium conditions. The model takes variations of the drip interval, temperature and the amount of mixing between the impinging drops and the solution on top of the stalagmite into account, which allows to quantify the influence of these parameters. To calculate the variations of δ¹³C, the multi-box model was calibrated by comparison with an existing growth model. The results show that drip interval, temperature and the mixing coefficient do have a significant influence on δ¹³C. However, considering the higher natural variability of the drip interval, this parameter might have the largest influence.  相似文献   

Influence of observed and RCM-simulated precipitation on the water discharge over the Sirba basin, Burkina Faso/Niger     

Christophe Messager  Hubert Gallée  Olivier Brasseur  Bernard Cappelaere  Christophe Peugeot  Luc Séguis  Michel Vauclin  Romain Ramel  Gilles Grasseau  Laurent Léger  Denis Girou 《Climate Dynamics》2006,27(2-3):199-214

The forcing of a hydrologic model (ABC) by both observed and simulated precipitation from a regional climate model (MAR) has been performed over the Sirba watershed (39,000 km²) located in the Sahelian region. Two aspects have been more specifically examined: the spatial and temporal representations of precipitation. The comparison between simulated and observed discharges—using observed rainfall datasets as forcing of the hydrologic model—has shown that the representation of daily precipitation (which is mainly convective in the Sahelian region) was not sufficiently accurate to correctly simulate the hydrologic response of the watershed. Since this response drives the soil water budget and consequently the amount of evaporation in forthcoming coupling experiments, it is thus necessary to develop more realistic infra-daily precipitation associated with convective events. A new temporal disaggregation scheme has been then developed. Considering observed as well as simulated precipitation fields, this method has significantly improved the simulated discharge at the catchment outlet. The major role played by the temporal component compared to spatial component of the precipitation has been then underlined. In addition, the present study shows the unsuitability of the simulated precipitation from the RCM to directly force a hydrologic model at infra daily timescale even if the cumulative amount and the main features of the precipitation seasonal cycle are well simulated.  相似文献   

Estimating the uncertainty of coral isochron U–Th ages     

Denis Scholz  Augusto Mangini   《Quaternary Geochronology》2006,1(4):279-288

Recently, alternative models to estimate the age of diagenetically altered fossil reef corals have been presented based on either redistribution of U or its immediate daughters ²³⁴Th and ²³⁰Th. Here, we present three methods to estimate the uncertainty of ages derived using an amended version of our coral isochron method [Scholz et al., 2004. U-series dating of diagenetically altered fossil reef corals. Earth and Planetary Science Letters 218, 163–178], which is based on addition/loss of U. The obtained uncertainties are substantially larger than those previously published and should, in general, be more reliable. The isochron method yields larger uncertainties than alternative models based on Th redistribution due to -recoil processes. However, comparison of model open-system ages based on such redistribution of U-series daughters for different sub-samples from an individual coral specimen shows that the smaller errors derived with these models cannot account for the observed variability. We recognise that none of the available models is applicable to all corals, probably reflecting different diagenetic processes even in different sub-samples from one coral specimen. To better understand the diagenetic processes and precisely constrain the uncertainties of the ages derived from diagenetically altered corals, the application of all available models is recommended.  相似文献   

Sensitivity of a regional climate model to the resolution of the lateral boundary conditions     

B. Denis  R. Laprise  D. Caya 《Climate Dynamics》2003,20(2-3):107-126

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Experimental study of bubble coalescence in rhyolitic and phonolitic melts     

Jessica F Larsen  Marie-Helene Denis 《Geochimica et cosmochimica acta》2004,68(2):333-344

We have experimentally studied the process of bubble coalescence in rhyolite and phonolite melts of natural composition. The experiments involved decompression of water-saturated melts equilibrated at pressures and temperatures from 100 to 150 MPa and 775 to 840 °C in vertically oriented, rapid-quench capable, cold seal pressure vessels. One type of experiments (rhyolite MCR-100, 120, 150 and phonolite LSP-120 series') approximates a “static” bubble coalescence case, where we held the decompressed samples for ∼5 seconds to 4320 minutes (3 days) before quenching. The second type (rhyolite LPC-100 series) replicates an “expanding” bubble coalescence environment, where we continually decompressed the experiments at a rate of 0.5 MPa/s, examining samples quenched at ending pressures between 10 and 80 MPa. Our “static” case (MCR-100, 120, and 150, and LSP-120) results show significant increases in the modal bubble sizes and in the sizes of the largest bubbles, corresponding to measurable broadening in the size distributions. Their bubble number densities (N_V) decrease as a function of hold time at their final pressures (P_F), and can be fit well by power law functions. Our “expanding” case experiments (LPC-100) show a significant drop in N_V during the duration of the experiments that can be fit by an exponential equation as N_V vs. either time or P_F. Average estimates of bulk coalescence rates indicate a ∼1 order of magnitude drop in N_V for “static” case rhyolites in a 2-3 day period, and ∼2 orders of magnitude for phonolites within a 3 day period. Despite a ∼2 order of magnitude difference in viscosity, coalescene in the phonolite is only slightly faster than the rhyolite. The “expanding” case experiments show a ∼1 order of magnitude drop in N_V over 180 seconds. Thus, N_V's decrease 4 orders of magnitude faster in expanding vs. static bubbly rhyolite melts. Our results imply that significant bubble coalescence can occur in rhyolite magmas at relatively fast (∼20 m/s) ascent rates in the conduit. Thus, bubble interconnectivity, leading to high permeability, is possible during ascent. Bubble coalescence may occur during second boiling in magma bodies that are stalled in the crust. The timescales over which this occurs is much faster than the estimated rise rates for bubbles to reach the top of the magma chamber.  相似文献   

Heterogeneous bubble nucleation on Fe-Ti oxide crystals in high-silica rhyolitic melts     

James E. Gardner  Marie-Hélène Denis 《Geochimica et cosmochimica acta》2004,68(17):3587-3597

The nucleation of H₂O bubbles in magmas has been proposed as a trigger for volcanic eruptions. To determine how bubbles nucleate heterogeneously in silicate melts, experiments were carried out in which high-silica rhyolitic melts were hydrated at 740-800°C and 50-175 MPa, decompressed by 20-70 MPa, and held at the lower pressures for ≥10 s before being quenched. The hydration conditions were subliquidus, and all samples contain blocky magnetite + needle-shaped hematite ± plagioclase. Magnetite is abundant at 800°C and high pressures, whereas hematite becomes more abundant at lower temperatures and pressures. Bubbles nucleated in a single event in all samples, with the number density (N_T) of bubbles varying between 2 × 10⁷ and 1 × 10⁹ cm⁻³. At low degrees of supersaturation, one to a few bubbles nucleate on faces of magnetite, but at medium to high degrees of supersaturation, multiple bubbles nucleate on single magnetite grains. On hematite, one to a few bubbles nucleated at the ends of the needle-shaped crystals at medium supersaturations, but formed along their entire lengths at high supersaturations. N_T increases as water diffusivity decreases, indicating that the number of bubbles nucleated is influenced by their growth, which depletes the melt with respect to H₂O and lowers supersaturation. If volcanic eruptions are triggered by bubble formation in magmas stored in shallow-level magma chambers, then the supersaturations needed for heterogeneous nucleation suggest that only small amounts of crystallization are needed, whereas homogeneous nucleation is unlikely to trigger eruptions.  相似文献   

Methods for computing internal flattening, with applications to the Earth's structure and geodynamics     

C. Denis  M. Amalvict  Y. Rogister  & S. Tomecka-Sucho&#; 《Geophysical Journal International》1998,132(3):603-642

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A Chemical Equilibrium Model for Natural Waters   总被引：7，自引：0，他引：7  

Frank J. Millero  Denis Pierrot 《Aquatic Geochemistry》1998,4(1):153-199

This paper reviews the present status of the Pitzer chemical equilibrium model, which can be used to characterize the one-atmosphere activity coefficients of ionic and non-ionic solutes in natural waters as a function of temperature and ionic strength. The model considers the ionic interactions of the major seasalt ions (H, Na, K, Mg, Ca, Sr, Cl, Br, OH, HCO₃, B(OH)₄, HSO₄, SO₄, CO₃, CO₂, B(OH)₃, H₂O) and is based on the 25 °C model of Weare and co-workers. The model has been extended by a number of workers so that reasonable estimates can be made of the activity coefficients of most of the major seasalt ions from 0 to 250 °C. Recently coefficients for a number of solutes that are needed to determine the dissociation constants of the acids from 0 to 50 °C (H₃CO₃, B(OH)₃, H₂O, HF, HSO ₄ ^- , H₃PO₄, H₂S, NH ₄ ⁺ etc.) have been added to the model. These results have been used to examine the carbonate system in natural waters and determine the activity of inorganic anions that can complex trace metals. The activity and osmotic coefficients determined from the model are shown to be in good agreement with measured values in seawater. This model can serve as the foundation for future expansions that can examine the activity coefficient and speciation of trace metals in natural waters. At present this is only possible from 0 to 50 °C over a limited range of ionic strengths (<1.0) due to the limited stability constants for the formation of the metal complexes. The future work needed to extend the Pitzer model to trace metals is discussed.  相似文献   

Trace and major element models of granitoid genesis in the Pampean Ranges,Argentina     

Carlos W. Rapela  Denis M. Shaw 《Geochimica et cosmochimica acta》1979,43(7):1117-1129

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