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121.
The water chemistry of a groundwater-fed sinkhole-pond near St. Louis, Missouri, and its associated climate during the last glaciation are reconstructed by comparison with autecological data of modern ostracodes from about 5,500 sites in Canada. A 4.8-m succession of fossiliferous sediment yielded ostracode assemblages that collectively are generally found today in ponds in North America including the species Cyclocypris ampla, C. laevis, Cypridopsis vidua, Candona crogmaniana, C. distincta, and C. ohioensis. Fossils of Picea needles and the ostracode Cyclocypris sharpei imply that best analog sites for the succession are in central to south-central Canada. The pond formed 23,300 ± 400 cal yr BP when a sinkhole became plugged by a clay bed about 1 m thick. By about 20,250 cal yr BP, the pond had desiccated and was buried by loess. The sediment accumulation rate was about 0.18 cm/yr, and each sample interval (6 cm) represents a time slice of 33 years. Data from this record provides the first fairly high resolution proxy record of the glacial paleoclimate of the mid-latitude of North America. The analog data indicate the water in the hydrologically-open spring-fed pond was less than 1 m deep. The paleoclimatic reconstructions imply gradually drier conditions and uniform, cool temperatures. The shallow water depth indicates that the temperature reconstruction is robust with mean annual temperatures (MATs) that ranged between 0.8 and 3.9°C, and mean July temperatures that ranged from 16.8 and 18.1°C. Other estimated climatic parameters include mean annual precipitation (MAP; 430 to 840 mm/yr), and moisture balance (P-E; –111 to 298 mm/yr). Compared to values measured today at St. Louis, the MAP was about 400 mm less, MAT about 10°C cooler, and P-E, about the same. These values are consistent with other published reconstructions based on modern analog analysis of fossil beetles and pollen, and paleothermometry based on amino acid racemization. The total dissolved solids (TDS) progressively increased from about 87 to 431 mg/L. Changes in TDS reflect either the balance between the relative inputs of karst groundwater and overland flow, or changes in the duration of water-rock interaction associated with the groundwater. The postulated long-term 900 ± 200 year cyclicity of growing-season moisture and temperature, attributed to El Niño-Southern Oscillation cycles, is not expressed in the reconstructed hydrologic or climatic data. This is attributed, in part, to the mediating effect on temperature by monothermic groundwater input to this flow-through system.  相似文献   
122.
Flash-flood events resulting from paroxystic meteorological events concentrated in time and space are insufficiently documented as they produce destructive effects. They are hardly measurable and present single features that are not transposable to another event. In the South of France, the flash flood of November 1999 gives a perfect illustration of these characteristics. The physical complexity of the process and consequently the volume and the variety of the data to take into account are incompatible with the real time constraint allocated to the forecasters confronted to the occurrence of such phenomena. So, we have to make choices to afford acceptable simplifications to the complete mechanical model. MARINE (‘Modélisation de l'Anticipation du Ruissellement et des Inondations pour des évéNements Extrêmes’) is the operational and robust tool we developed for flash-flood forecasting. This model complies with the criterions of real-time simulation. It is a physically based distributed model composed of two parts: first the flood runoff process simulation in the upstream part of the basin modelled from a rainfall–runoff approach, then the flood propagation in the main rivers described by the Saint-Venant equations. It integrates remote sensed data – Digital Elevation Model, land-use map, hydrographic network for the observations from satellites and the rainfall evolution from meteorological radar. The main goal of MARINE is to supply real time pertinent information to the forecasters. Results obtained on the Orbieu River (Aude, France) show that this model is able to supply pertinent flood hydrograph with a sufficient precision for the forecasting service to take the appropriate safety decisions. Furthermore, MARINE has already been tested in the French National Flood Forecasting Service of Haute-Garonne in real conditions. To cite this article: V. Estupina Borrell et al., C. R. Geoscience 337 (2005).  相似文献   
123.
The catastrophic floods recently occurring in Europe warn of the critical need forhydrologic data on floods over long-time scales. Palaeoflood techniques provideinformation on hydrologic variability and extreme floods over long-time intervals(100 to 10,000 yr) and may be used in combination with historical flood data (last1,000 yr) and the gauge record (last 30–50 yr). In this paper, advantages anduncertainties related to the reconstruction of palaeofloods in different geomorphologicalsettings and historical floods using different documentary sources are described.Systematic and non-systematic data can be combined in the flood frequency analysisusing different methods for the adjustment of distribution functions. Technical toolsintegrating multidisciplinary approaches (geologic, historical, hydraulic and statistical)on extreme flood risk assessment are discussed. A discussion on the potential theoreticalbases for solving the problem of dealing with non-systematic and non-stationary data ispresented. This methodology is being developed using new methodological approachesapplied to European countries as a part of a European Commission funded project (SPHERE).  相似文献   
124.
We have used room temperature and cryogenic 57Fe Mössbauer spectroscopy, powder X-ray diffraction (pXRD), mineral magnetometry, and transmission electron microscopy (TEM), to study the synthetic precipitation of hydrous ferric oxides (HFOs) prepared either in the absence (abiotic, a-HFO) or presence (biotic, b-HFO) of nonmetabolizing bacterial cells (Bacillus subtilis or Bacillus licheniformis, ∼108 cells/mL) and under otherwise identical chemical conditions, starting from Fe(II) (10−2, 10−3, or 10−4 mol/L) under open oxic conditions and at different pH (6-9). We have also performed the first Mössbauer spectroscopy measurements of bacterial cell wall (Bacillus subtilis) surface complexed Fe, where Fe(III) (10−3.5-10−4.5 mol/L) was added to a fixed concentration of cells (∼108 cells/mL) under open oxic conditions and at various pH (2.5-4.3). We find that non-metabolic bacterial cell wall surface complexation of Fe is not passive in that it affects Fe speciation in at least two ways: (1) it can reduce Fe(III) to sorbed-Fe2+ by a proposed steric and charge transfer effect and (2) it stabilizes Fe(II) as sorbed-Fe2+ against ambient oxidation. The cell wall sorption of Fe occurs in a manner that is not compatible with incorporation into the HFO structure (different coordination environment and stabilization of the ferrous state) and the cell wall-sorbed Fe is not chemically bonded to the HFO particle when they coexist (the sorbed Fe is not magnetically polarized by the HFO particle in its magnetically ordered state). This invalidates the concept that sorption is the first step in a heterogeneous nucleation of HFO onto bacterial cell walls. Both the a-HFOs and the b-HFOs are predominantly varieties of ferrihydrite (Fh), often containing admixtures of nanophase lepidocrocite (nLp), yet they show significant abiotic/biotic differences: Biotic Fh has less intraparticle (including surface region) atomic order (Mössbauer quadrupole splitting), smaller primary particle size (magnetometry blocking temperature), weaker Fe to particle bond strength (Mössbauer center shift), and no six-line Fh (6L-Fh) admixture (pXRD, magnetometry). Contrary to current belief, we find that 6L-Fh appears to be precipitated directly, under a-HFO conditions, from either Fe(II) or Fe(III), and depending on Fe concentration and pH, whereas the presence of bacteria disables all such 6L-Fh precipitation and produces two-line Fh (2L-Fh)-like biotic coprecipitates. Given the nature of the differences between a-HFO and b-HFO and their synthesis condition dependences, several biotic precipitation mechanisms (template effect, near-cell environment effect, catalyzed nucleation and/or growth effect, and substrate-based coprecipitation) are ruled out. The prevailing present view of a template or heterogeneous nucleation barrier reduction effect, in particular, is shown not to be the cause of the large observed biotic effects on the resulting HFOs. The only proposed mechanism (relevant to Fh) that is consistent with all our observations is coprecipitation with and possible surface poisoning by ancillary bacteriagenic compounds. That bacterial cell wall functional groups are redox active and the characteristics of biotic (i.e., natural) HFOs compared to those of abiotic (i.e., synthetic) HFOs have several possible biogeochemical implications regarding Fe cycling, in the photic zones of water columns in particular.  相似文献   
125.
The abundances of Ni and Co in the Earth’s mantle are depleted relative to chondrites due to terrestrial core formation. Recently, the observed mantle depletions of these elements have been explained by liquid metal-liquid silicate equilibrium during core formation in a high pressure, high temperature magma ocean on the early Earth. However, different magma ocean models, which would be expected to give consistent results, have proposed vastly different pressures (24 to 59 GPa), temperatures (2200 to >4000 K) and oxygen fugacities (−0.15 to −2.4 ΔIW) for the Earth’s magma ocean. In an attempt to resolve the contradictory results from different magma ocean models and determine the thermodynamic conditions appropriate for core formation in the Earth, experiments were conducted to better constrain the influences of temperature and C on the partitioning behaviors of Ni and Co. Results of experiments at 7 GPa with temperatures of 1923-2673 K show that the metal-silicate partition coefficients for both Ni and Co decrease with increasing temperature, with the effect being more significant for Ni. Little change in the partitioning behaviors of either Ni or Co with varying C-content of the metallic liquid was found. By combining the new temperature data with previous results from pressure and oxygen fugacity studies, we parameterized the partitioning behavior of Ni and Co and applied the parameterizations to core formation in a terrestrial magma ocean. Multiple combinations of pressure, temperature, and oxygen fugacity can explain the observed mantle depletions of Ni and Co, and all of the very different previously proposed magma ocean conditions are generally consistent with valid solutions. By using the FeO content of the Earth’s mantle as an additional constraint on the oxygen fugacity, magma ocean conditions of 30-60 GPa, > 2000 K, and −2.2 ΔIW are suggested. Similar systematic approaches and studies of other moderately siderophile elements could further constrain the magma ocean conditions on the early Earth.  相似文献   
126.
Modes of thickening of analogue weak lithospheres   总被引:4,自引:2,他引:4  
Several compressional contexts, such as those involving juvenile or thickened crust, are expected to be associated with rather hot lithospheres whose mechanical behaviour remains poorly documented. In this paper, we present a series of analogue models dedicated to compression of lithospheres characterized by a thin upper brittle crust overlying a weak ductile crust and a ductile sub-Moho mantle. The models show that (1) deformation is controlled by the ductile layers that undergo distributed thickening, (2) thrust systems are limited to the upper brittle crust, (3) thrusting induces burial and stacking of upper crust pop-downs. The overall deformation patterns can be basically interpreted in terms of pop-down thrusting of the brittle crust and pure-shear type ductile flow of crust and mantle. Moreover, the models show that the sinking of supracrustal units does not require inverse density profiles but can be simply driven by compression. Model deformation patterns are consistent with those shared by many ancient belts, including not only Archaean granite–greenstone belts, but also more generally Paleoproterozoic ones. They provide also insights on deformation modes that may characterize modern thickened and abnormally hot domains like High Plateaus.  相似文献   
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129.
A fully instrumented physical model was designed and built to reproduce development by surging and monitor its effects during surging and after development. The model simulates a horizontal layer in a confined aquifer with control of vertical overburden pressure. An automatic apparatus produced development by surging in successive phases up to 24 hours. Aquifer tests in steady-state conditions were performed between successive phases. The paper reports the main results of three experiments performed with Johnson screens 200 mm in diameter; they had slot sizes between the D54 and D70 of the aquifer soil. This soil was placed under controlled conditions, and initial homogeneity was obtained as confirmed by initial control tests. Pore pressures (and thus hydraulic heads) were continuously monitored during development phases and aquifer tests by 22 electronic piezometers at distances between 0 and 1 m from the screen. These piezometers measured water pressures every 0.1 s when required. Solid particles passing through the screen were recovered to study the solid yield and the gradation of particles. Positive and negative values of local gradients reached values up to 400 close to the screen at the beginning of development and decreased with time of development. These high values produced high seepage forces displacing particles in the aquifer. The well yield was increased by a factor of 6 after development. These model test results confirmed empirical criteria on entrance velocity, internal stability criteria, and field values of "sand" production by development. In addition, they enabled a quantification of skin effects to be considered in interpreting an aquifer test.  相似文献   
130.
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