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141.
The level of complexity, and the number of parameters, to include in a hydrological model is a relatively contentious issue in hydrological modelling. However, it can be argued that explicitly representing important run‐off generation processes can improve the practical value of a model's outputs. This paper explores the benefits of including a new function into an existing semi‐distributed hydrological model (the Pitman model) that is widely used in the sub‐Saharan Africa region. The new function was designed to represent saturation‐excess surface run‐off processes at subcatchment scales and was motivated by the evidence of dambo (low topography riparian areas) type features in many sub‐Saharan river basins. The results for uncertainty versions of the model, with and without the new function, were compared for 25 catchments, which were divided up into those where evidence of dambos exists and those where there is no such evidence. The results suggest that the new function certainly improves the model results for the catchments where dambos exist, but not in situations where saturation‐excess surface run‐off is not expected to occur. The overall conclusion is therefore that the addition of the new function is justified.  相似文献   
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143.
Lake Vättern represents a critical region geographically and dynamically in the deglaciation of the Fennoscandian Ice Sheet. The outlet glacier that occupied the basin and its behaviour during ice‐sheet retreat were key to the development and drainage of the Baltic Ice Lake, dammed just west of the basin, yet its geometry, extent, thickness, margin dynamics, timing and sensitivity to regional retreat forcing are rather poorly known. The submerged sediment archives of Lake Vättern represent a missing component of the regional Swedish deglaciation history. Newly collected geophysical data, including high‐resolution multibeam bathymetry of the lake floor and seismic reflection profiles of southern Lake Vättern, are used here together with a unique 74‐m sediment record recently acquired by drill coring, and with onshore LiDAR‐based geomorphological analysis, to investigate the deglacial environments and dynamics in the basin and its terrestrial environs. Five stratigraphical units comprise a thick subglacial package attributed to the last glacial period (and probably earlier), and an overlying >120‐m deglacial sequence. Three distinct retreat–re‐advance episodes occurred in southern Lake Vättern between the initial deglaciation and the Younger Dryas. In the most recent of these, ice overrode proglacial lake sediments and re‐advanced from north of Visingsö to the southern reaches of the lake, where ice up to 400 m thick encroached on land in a lobate fashion, moulding crag‐and‐tail lineations and depositing till above earlier glacifluvial sediments. This event precedes the Younger Dryas, which our data reveal was probably restricted to north‐central sectors of the basin. These dynamics, and their position within the regional retreat chronology, indicate a highly active ice margin during deglaciation, with retreat rates on average 175 m a?1. The pronounced topography of the Vättern basin and its deep proglacial‐dammed lake are likely to have encouraged the dynamic behaviour of this major Fennoscandian outlet glacier.  相似文献   
144.
To date, studies of the stability of subsurface ice in the McMurdo Dry Valleys of Antarctica have been mainly based on climate-based vapor diffusion models. In University Valley (1800 m), a small glacier is found at the base of the head of the valley, and adjacent to the glacier, a buried body of massive ice was uncovered beneath 20–40 cm of loose cryotic sediments and sandstone boulders. This study assesses the origin and stability of the buried body of massive ice by measuring the geochemistry and stable O–H isotope composition of the ice and applies a sublimation and molecular diffusion model that accounts for the observed trends. The results indicate that the buried massive ice body represents an extension of the adjacent glacier that was buried by a rock avalanche during a cold climate period. The contrasting δ18O profiles and regression slope values between the uppermost 6 cm of the buried massive ice (upward convex δ18O profile and SD-18O = 5.1) and that below it (progressive increase in δ18O and SD-18O = 6.4) suggest independent post-depositional processes affected the isotope composition of the ice. The upward convex δ18O profile in the uppermost 6 cm is consistent with the ice undergoing sublimation. Using a sublimation and molecular diffusion model, and assuming that diffusion occurred through solid ice, the sublimation rate needed to fit the measured δ18O profile is 0.2 ? 10? 3 mm yr? 1, a value that is more similar to net ice removal rates derived from 3He data from cobbles in Beacon Valley till (7.0 ? 10? 3 mm yr? 1) than sublimation rates computed based on current climate (0.1–0.2 mm yr?1). We suggest that the climate-based sublimation rates are offset due to potential ice recharge mechanisms or to missing parameters, particularly the nature and thermo-physical properties of the overlying sediments (i.e., temperature, humidity, pore structure and ice content, grain size).  相似文献   
145.
Iron solid-phase differentiation along a redox gradient in basaltic soils   总被引:1,自引:0,他引:1  
Iron compounds in soil are multifunctional, providing physical structure, ion sorption sites, catalytic reaction-centers, and a sink for respiratory electrons. Basaltic soils contain large quantities of iron that reside in different mineral and organic phases depending on their age and redox status. We investigated changes in soil iron concentration and its solid-phase speciation across a single-aged (400 ky) lava flow subjected to a gradient in precipitation (2200-4200 mm yr−1) and hence redox history. With increasing rainfall and decreasing Eh, total Fe decreased from about 25% to <1% of the soil mass. Quantitative speciation of soil solid-phase iron was constrained by combining 57Fe Mössbauer spectroscopy (MBS) at 295 and 4.2 K with powder X-ray diffraction, selective chemical extractions, and magnetic susceptibility measurements. This approach allowed us to partition iron into (1) nanoparticulate and microcrystalline FeIII-(oxy)hydroxides, (2) microcrystalline and bulk FeIII-oxides, (3) organic/silicate bound FeIII, and (4) ferrous iron. The FeIII-(oxy)hydroxide fraction dominated solid-phase Fe, exhibiting a crystallinity continuum based on magnetic ordering temperature. The continuum extended from well-ordered microcrystalline goethite through nanocrystalline FeIII-(oxy)hydroxides to a nano FeIII-(oxy)hydroxide phase of extremely low crystallinity. Magnetic susceptibility was correlated (R2 = 0.77) with FeIII-oxide concentration, consistent with a contribution of maghemite to the otherwise hematite dominated Fe-oxide fraction. The FeIII-(oxy)hydroxide fraction of total Fe decreased with increasing rainfall and was replaced by corresponding increase in the organic/silicate FeIII fraction. The crystallinity of the FeIII-(oxy)hydroxides also decreased with increasing rainfall and leaching, with the most disordered members of the crystallinity continuum, the nano FeIII-(oxy)hydroxides, gaining proportional abundance in the wetter sites. This finding runs counter to the conventional kinetic expectation of preferential removal of the most disordered minerals in a reductive dissolution-dominated environment. We suggest the persistence of highly disordered Fe phases reflects the dynamic redox conditions of these upland soils in which periods of anoxia are marked by high water-throughput and Fe2+(aq) removal, while periodic Fe oxidation events occur in the presence of high concentrations of organic matter. Our 57Fe Mössbauer study shows basalt-derived nano-scale FeIII phases are more disordered than current synthetic analogs and have nano-structural characteristics that are linked to their formation environment.  相似文献   
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147.
This paper contains the results of an extensive isotopic study of United States Geological Survey GSD‐1G and MPI‐DING reference glasses. Thirteen different laboratories were involved using high‐precision bulk (TIMS, MC‐ICP‐MS) and microanalytical (LA‐MC‐ICP‐MS, LA‐ICP‐MS) techniques. Detailed studies were performed to demonstrate the large‐scale and small‐scale homogeneity of the reference glasses. Together with previously published isotopic data from ten other laboratories, preliminary reference and information values as well as their uncertainties at the 95% confidence level were determined for H, O, Li, B, Si, Ca, Sr, Nd, Hf, Pb, Th and U isotopes using the recommendations of the International Association of Geoanalysts for certification of reference materials. Our results indicate that GSD‐1G and the MPI‐DING glasses are suitable reference materials for microanalytical and bulk analytical purposes.  相似文献   
148.
149.
Understanding vulnerability to the impacts of global environmental change and identifying adaptation measures to cope with these impacts require localized investigations that can help find actual and exact answers to the questions about who and what are vulnerable, to what are they vulnerable, how vulnerable are they, what are the causes of their vulnerability, and what responses can lessen their vulnerability. People living in forests are highly dependent on forest goods and services, and are vulnerable to forest changes both socially and economically. In the Congo basin, climate change effects on forest ecosystems are predicted to amplify the existing pressure on food security urging expansion of current agricultural lands at the expense of forest, biodiversity loss and socioeconomic stresses. The paper aimed at exploring vulnerability and adaptation needs to climate change of local communities in the humid forest zone of Cameroon. Field work was conducted in two forest communities in Lekié and in Yokadouma in the Center and Eastern Regions of Cameroon respectively. The assessment was done using a series of approaches including a preparatory phase, fieldwork proper, and validation of the results. Results show that: (a) the adverse effects of climate conditions to which these communities are exposed are already being felt and exerting considerable stress on most of their livelihoods resources; (b) drought, changing seasons, erratic rain patterns, heavy rainfall and strong winds are among the main climate-related disturbances perceived by populations in the project sites; (c) important social, ecological and economic processes over the past decades seemed to have shaped current vulnerability in the sites; (d) Some coping and adaptive strategies used so far are outdated; and specific adaptation needs are identified and suggestions for facilitating their long-term implementations provided.  相似文献   
150.
The predicted Draconid meteor shower outburst during October 2011 had been observed by a portion of the Croatian Meteor Network whose stations encountered clear weather. A total of 95 Draconid orbits have been calculated from 18 contributing stations, and in this paper we present results for 63 orbits obtained from the fully automatic observation and processing pipeline. Two methods of trajectory estimation were applied, showing better fit results using a linearly changing velocity model versus a constant velocity model. The estimated mean radiant position has been found to be at RA = 262.6°, Dec = +55.7°, with estimated geocentric velocity Vg = 20.7 km/s.  相似文献   
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